River Taw Research Articles

Impacts of reduced synthetic fertiliser use under current and future climates: Exploration using integrated agroecosystem modelling in the upper River Taw observatory, UK

The intensification of farming and increased nitrogen fertiliser use, to satisfy the growing population demand, contributed to the extant climate change crisis. Use of synthetic fertilisers in agriculture is a significant source of anthropogenic Greenhouse Gas (GHG) emissions, especially potent nitrous oxide (N2O). To achieve the ambitious policy target for net zero by 2050 in the UK, it is crucial to understand the impacts of potential reductions in fertiliser use on multiple ecosystem services, including crop production, GHG emissions and soil organic carbon (SOC) storge. A novel integrated modelling approach using three established agroecosystem models (SPACSYS, CSM and RothC) was implemented to evaluate the associated impacts of fertiliser reduction (10%, 30% and 50%) under current and projected climate scenarios (RCP2.6, RCP4.5 and RCP8.5) in a study catchment in Southwest England. 48 unique combinations of soil types, climate conditions and fertiliser inputs were evaluated for five major arable crops plus improved grassland. With a 30% reduction in fertiliser inputs, the estimated yield loss under current climate ranged between 11% and 30% for arable crops compared with a 20–24% and 6–22% reduction in N2O and methane emissions, respectively. Biomass was reduced by 10–25% aboveground and by <12% for the root system. Relative to the baseline scenario, soil type dependent reductions in SOC sequestration rates are predicted under future climate with reductions in fertiliser inputs. Losses in SOC were more than doubled under the RCP4.5 scenario. The emissions from energy use, including embedded emissions from fertiliser manufacture, was a significant source (14–48%) for all arable crops and the associated GWP20.

Bioenergy crop production and carbon sequestration potential under changing climate and land use: A case study in the upper River Taw catchment in southwest England

Reductions in CO2 emissions are essential to support the UK in achieving its net zero policy objective by around mid-century. Both changing climate and land use change (LUC) offer an opportunity to deploy suitable bioenergy crops strategically to enhance energy production and C sequestration to help deliver net zero through capturing atmospheric CO2. Against this background, we applied process-based models to evaluate the extent of net primary productivity (NPP) losses/gains associated with perennial bioenergy crops and to assess their C sequestration potential under changing climate in the upper River Taw observatory catchment in southwest England. In so doing, we also determined whether LUC from permanent grassland to perennial bioenergy crops, considered in this study, can increase the production and C sequestration potential in the study area. The results show that a warming climate positively impacts the production of all crops considered (permanent grassland, Miscanthus and two cultivars of short rotation coppice (SRC) willow). Overall, Miscanthus provides higher aboveground biomass for energy compared to willow and grassland whereas the broadleaf willow cultivar ‘Endurance’ is best suited, among all crops considered, for C sequestration in this environment, and more so in the changing climate. In warmer lowlands, LUC from permanent grassland to Miscanthus and in cooler uplands from permanent grassland to ‘Endurance’, enhances NPP. Colder areas are predicted to benefit more from changing climate in terms of above and belowground biomass for both Miscanthus and willow. The study shows that the above LUC can help augment non-fossil energy production and increase C sequestration potential if C losses from land conversion do not exceed the benefits from LUC. In the wake of a changing climate, aboveground biomass for bioenergy and belowground biomass to enhance carbon sequestration can be managed by the careful selection of bioenergy crops and targeted deployment within certain climatic zones.

Exploring the effects of land management change on productivity, carbon and nutrient balance: Application of an Ensemble Modelling Approach to the upper River Taw observatory, UK

Agriculture is challenged to produce healthy food and to contribute to cleaner energy whilst mitigating climate change and protecting ecosystems. To achieve this, policy-driven scenarios need to be evaluated with available data and models to explore trade-offs with robust accounting for the uncertainty in predictions. We developed a novel model ensemble using four complementary state-of-the-art agroecosystems models to explore the impacts of land management change. The ensemble was used to simulate key agricultural and environmental outputs under various scenarios for the upper River Taw observatory, UK. Scenarios assumed (i) reducing livestock production whilst simultaneously increasing the area of arable where it is feasible to cultivate (PG2A), (ii) reducing livestock production whilst simultaneously increasing bioenergy production in areas of the catchment that are amenable to growing bioenergy crops (PG2BE) and (iii) increasing both arable and bioenergy production (PG2A + BE). Our ensemble approach combined model uncertainty using the tower property of expectation and the law of total variance. Results show considerable uncertainty for predicted nutrient losses with different models partitioning the uncertainty into different pathways. Bioenergy crops were predicted to produce greatest yields from Miscanthus in lowland and from SRC-willow (cv. Endurance) in uplands. Each choice of management is associated with trade-offs; e.g. PG2A results in a significant increase of edible calories (6736 Mcal ha−1) but reduced soil C (−4.32 t C ha−1). Model ensembles in the agroecosystem context are difficult to implement due to challenges of model availability and input and output alignment. Despite these challenges, we show that ensemble modelling is a powerful approach for applications such as ours, offering benefits such as capturing structural as well as data uncertainty and allowing greater combinations of variables to be explored. Furthermore, the ensemble provides a robust means for combining uncertainty at different scales and enables us to identify weaknesses in system understanding.

Deposition and erosion behaviour of cohesive sediments in the upper River Taw observatory, southwest UK: Implications for management and modelling

Fine sediment is a key driver of water quality degradation in rivers globally and improved knowledge of its source and transport is required to assess the efficacy of sediment control options and pollution abatement strategies. Here the transport characteristics (deposition, erosion and flocculation) of fine sediment were studied experimentally in an annular flume to provide parameters necessary to model fine sediment transport in the upper River Taw in southwest England. Deposition experiments were carried out using a sediment–water mixture in the flume and in-situ size distributions of sediment flocs were measured to assess flocculation and settling behavior of sediment. The influence of bed shear stress and bed consolidation were investigated in a series of erosion experiments. These data were used to calibrate and test a mathematical model of fine sediment transport in annular flumes (FLUME model) and the measured and modelled data were in good agreement. Transport parameters for cohesive sediments, such as the critical shear stresses for deposition and erosion as well as the particle density, porosity and settling velocity as a function of floc size were established. The density and settling velocity of the cohesive sediments were sensitive to the biological activity within the floc structure. Data from the flume experiments are necessary as input parameters to models such as RIVFLOC or SHETRAN that simulate fine sediment transport in the River Taw at the catchment scale and assess the efficacy of sediment control options and catchment management scenarios

Dynamics of fluvial hydro-sedimentological, nutrient, particulate organic matter and effective particle size responses during the U.K. extreme wet winter of 2019–2020

The floc size distribution of suspended sediment is a critical driver for in-channel sedimentation and sediment-associated contaminant and nutrient transfer and fate in river catchments. Real-time, in situ, floc size characterisation is possible using available technology but, to date, limited high resolution floc data have been published for fluvial systems draining upland extensive grassland catchments. To that end, suspended sediment floc size distribution and turbidity were characterised at 15-minute intervals using Laser In-Situ Scattering and Transmissometry (LISST) diffraction and a YSI turbidity sonde for six storm events in the upper River Taw (15 km2) catchment in SW England. Maximum event discharges (Q) ranged between 4.3 and 20.0 m3 s−1, with clockwise hysteretic responses (HI = 0.18–0.48) of total suspended solid concentrations (TSS) and Q. The sediment flushing index was highest in the early autumn (0.93) and storm event TSS fluxes varied from 0.04 to 2.9 t km−2. This suggests a change in sources or composition of sediment during higher Q and highly variable patterns of sediment flux from event-to-event. The proportion of particulate organic matter (POM) to TSS was highly variable (5–89%) and did not increase with Q, indicating POM source limitation. The fine-grained tail (D10 and D16) of the floc size distributions decreased during hydrograph rising limbs, with the finest floc sizes associated with the highest TN and TP concentrations at peak Q. The results suggest that dynamic interactions between wet ground and extreme rainfall events can flush significant amounts of sediment from the relatively undisturbed extensive grassland upland catchment. We strongly encourage a sensors-based approach to reveal the spatio-temporal complexity of floc size and associated pollutant export during high Q generated by extreme rainfall since this can help to elucidate processes and mechanisms and generate high-resolution data for water quality modelling without significant user intervention.

Exploring the Effects of Land Management Change on Productivity, Carbon and Nutrient Balance: Application of a Hierarchical Modelling Approach to the Upper River Taw Observatory, UK

Exploring the Effects of Land Management Change on Productivity, Carbon and Nutrient Balance: Application of a Hierarchical Modelling Approach to the Upper River Taw Observatory, UK

Experimental Investigation of Erosion Characteristics of Fine-Grained Cohesive Sediments

In this short communication, the erosion process of the fine, cohesive sediment collected from the upper River Taw in South West England was studied in a rotating annular flume located in the National Water Research Institute in Burlington, Ontario, Canada. This study is part of a research project that is underway to model the transport of fine sediment and the associated nutrients in that river system. The erosion experimental data show that the critical shear stress for erosion of the upper River Taw sediment is about 0.09 Pa and it did not depend on the age of sediment deposit. The eroded sediment was transported in a flocculated form and the agent of flocculation for the upper River Taw sediment may be due to the presence of fibrils from microorganisms and organic material in the system. The experimental data were analysed using a curve fitting approach of Krone and a mathematical model of cohesive sediment transport in rotating circular flumes developed by Krishnappan. The modelled and measured data were in good agreement. An evaluation of the physical significance of Krone’s fitting coefficients is presented. Variability of the fitting coefficients as a function of bed shear stress and age of sediment deposit indicate the key role these two factors play in the erosion process of fluvial cohesive sediment.

Extending the geographic reach of the water hyacinth plant in removal of heavy metals from a temperate Northern Hemisphere river

Water hyacinth (Eichhornia crassipes) has been used for environmentally sustainable phytoremediation of water, though its use has been geographically restricted. For the first time we extend its geographical reach by investigating its potential for clean-up of water from a highly polluted British river (Nant-Y-Fendrod, a tributary of the River Tawe). Investigations using the plant were conducted at three levels: a bench-scale study using polluted river water and synthetic solutions; an in-situ trial using water hyacinth within the Nant-Y-Fendrod; and a bankside trial to pump and treat river water. The removal of the largest number of heavy metals (21) from water in a single study using ICP-MS is reported, including Sb, for the first time. Results are promising, with bench-scale tests demonstrating up to 63% removal of Al, 62% Zn, 47% Cd, 22% Mn and 23% As, during just seven hours exposure to the plant. When extended to three weeks exposure, removal is evident in the order Al > Cd > Zn > Mn > Ni > As > V. Furthermore, in-situ mean removal of 6%, 11% and 15% of Mn, Zn and Cd respectively is demonstrated. As the world learns to adapt to climate change, studies of the type reported here are needed to exploit the remarkable phytoremediation potential of water hyacinth.

The invasive alien plant, Impatiens glandulifera (Himalayan Balsam), and increased soil erosion: causation or association? Case studies from a river system in Switzerland and the UK

A monitoring investigation undertaken along the River Ibach, northwest Switzerland over the winter 2012/2013, found that riparian areas recently supporting the invasive plant Himalayan Balsam (HB) recorded significantly higher erosion rates than nearby uninvaded areas. This communication sythesises the latest findings about the influence of HB on sedimentation processes, again, from the Ibach, but also from a second river system in southwest UK. Erosion pins, a micro-profile bridge and a digital caliper were used to measure changes in soil surface profile (SSP) at selected riparian areas supporting HB plants along both rivers. Values were statistically compared against equivalent data recorded from nearby reference areas supporting mixed perennial vegetation. A comparison of source and sediment geochemistry was also undertaken on soil from HB-invaded and uninvaded floodplain areas along the Ibach, to assess the potential for identifying the extent to which either group acts as a sediment source. Erosion pin data indicate that soil loss from HB-colonised areas was significantly greater than soil loss from reference areas in two out of the four periods at the River Ibach site, and in two out of three measurement periods at the River Taw site. Colonisation of new HB sites may initially occur by hydrochorous processes, but HB plants may increase colonisation potential by trapping additional fine sediment and organic matter, including viable HB seeds. Geochemical results from the Ibach suggest that high inputs of suspended sediment originate from sources close to the river channel, but HB-invaded floodplain sources have geochemical properties that are most similar to suspended river sediment. The findings from both rivers led us to rethink our original hypothesis; that HB promotes soil erosion, to an amended hypothesis in which HB may be associated with areas where high erosion is sometimes recorded. Whilst initial colonisation may be due to hydrochorous processes, as HB becomes increasingly established, the displacement of perennial vegetation increases the risk of erosion during the winter period when live HB plants are absent. Preliminary geochemical findings of floodplain soils supporting different vegetation types along the Ibach tentatively suggest that at least some material originating from HB sites may enter the watercourse.

The oxygen isotopic composition of phosphate in river water and its potential sources in the Upper River Taw catchment, UK

The need to reduce both point and diffuse phosphorus pollution to aquatic ecosystems is widely recognised and in order to achieve this, identification of the different pollutant sources is essential. Recently, a stable isotope approach using oxygen isotopes within phosphate (δ18OPO4) has been used in phosphorus source tracing studies. This approach was applied in a one-off survey in September 2013 to the River Taw catchment in south-west England where elevated levels of phosphate have been reported. River water δ18OPO4 along the main channel varied little, ranging from +17.1 to +18.8‰. This was no >0.3‰ different to that of the isotopic equilibrium with water (Eδ18OPO4). The δ18OPO4 in the tributaries was more variable (+17.1 to +18.8‰), but only deviated from Eδ18OPO4 by between 0.4 and 0.9‰. Several potential phosphate sources within the catchment were sampled and most had a narrow range of δ18OPO4 values similar to that of river Eδ18OPO4. Discharge from two waste water treatment plants had different and distinct δ18OPO4 from one another ranging between +16.4 and +19.6‰ and similar values to that of a dairy factory final effluent (+16.5 to +17.8‰), mains tap water (+17.8 to +18.4‰), and that of the phosphate extracted from river channel bed sediment (+16.7 to +17.6‰). Inorganic fertilizers had a wide range of values (+13.3 to +25.9‰) while stored animal wastes were consistently lower (+12.0 to +15.0‰) than most other sources and Eδ18OPO4. The distinct signals from the waste water treatment plants were lost within the river over a short distance suggesting that rapid microbial cycling of phosphate was occurring, because microbial cycling shifts the isotopic signal towards Eδ18OPO4. This study has added to the global inventory of phosphate source δ18OPO4 values, but also demonstrated the limitations of this approach to identifying phosphate sources, especially at times when microbial cycling is high.

Orthophosphate-P in the nutrient impacted River Taw and its catchment (SW England) between 1990 and 2013.

Excess dissolved phosphorus (as orthophosphate-P) contributes to reduced river water quality within Europe and elsewhere. This study reports results from analysis of a 23 year (1990-2013) water quality dataset for orthophosphate-P in the rural Taw catchment (SW England). Orthophosphate-P and river flow relationships and temporal variations in orthophosphate-P concentrations indicate the significant contribution of sewage (across the catchment) and industrial effluent (upper R. Taw) to orthophosphate-P concentrations (up to 96%), particularly during the low flow summer months when maximum algal growth occurs. In contrast, concentrations of orthophosphate-P from diffuse sources within the catchment were more important (>80%) at highest river flows. The results from a 3 end-member mixing model incorporating effluent, groundwater and diffuse orthophosphate-P source terms suggested that sewage and/or industrial effluent contributes ≥50% of the orthophosphate-P load for 27-48% of the time across the catchment. The Water Framework Directive (WFD) Phase 2 standards for reactive phosphorus, introduced in 2015, showed the R. Taw to be generally classified as Poor to Moderate Ecological Status, with a Good Status occurring more frequently in the tributary rivers. Failure to achieve Good Ecological Status occurred even though, since the early-2000s, riverine orthophosphate-P concentrations have decreased (although the mechanism(s) responsible for this could not be identified). For the first time it has been demonstrated that sewage and industrial effluent sources of alkalinity to the river can give erroneous boundary concentrations of orthophosphate-P for WFD Ecological Status classification, the extent of which is dependent on the proportion of effluent alkalinity present. This is likely to be a European - wide issue which should be examined in more detail.

Determining riverine sediment storage mechanisms of biologically reactive phosphorus in situ using DGT.

Phosphorus (P) is the main reason many surficial water bodies in the UK are currently failing to meet the chemical standards set by the Water Framework Directive (WFD). This work focuses on the role of sediments in the upper reaches of the River Taw in the South West of the UK. Point and diffuse sources of P have been identified as well as a number of mitigation measures applied or planned to address the issues. However, it is unknown what effect these sources have had on the river's sediments and how they will react to diminishing inputs of P into the water column in the future. The diffusive gradient in thin-films (DGT) method is utilised in situ to quantify and identify labile, potentially bioavailable P fluxes and potential storage mechanisms at sites of known diffuse and point P inputs. In the vicinity of a heavily contaminated point source, data present here shows that sediments are still acting as a sink. The proposed mechanism for this is the formation of a 'calcium cap' which provides a geochemical barrier between the sediment and overlying water to prevent loss of labile P. The strong correlation between calcium and total P under most circumstances supports this hypothesis. This conclusion provides some confidence that even though P concentrations in some sediments are significantly elevated, mobility between the sediment and overlying water is restricted. In the context of routine monitoring against WFD targets, the molybdenum blue method generally employed to determine soluble reactive phosphorus was shown to not be equivalent to the DGT labile P pool, especially at pristine or moderately point/diffuse influenced sites. This is likely due to desorption of weakly bound P from colloids, which is unavailable to DGT devices. These results have the potential to be scaled up to the full catchment or other catchments which exhibit similar physical and chemical sediment composition and provide a stronger foundation for management and target setting than current monitoring approaches.

Using caesium‐134 and cobalt‐60 as tracers to assess the remobilization of recently‐deposited overbank‐derived sediment on river floodplains during subsequent inundation events

ABSTRACTRiver floodplains act as sinks for fine‐sediment and sediment‐associated contaminants. Increasing recognition of their environmental importance has necessitated a need for an improved understanding of the fate and residence times of overbank sediment deposits over a broad range of timescales. Most existing investigations have focused on medium‐term accretion rates, which represents net deposition from multiple flood events over several decades. In contrast, the fate of recently‐deposited sediment during subsequent overbank events has received only limited attention. This paper presents a novel tracing‐technique for documenting the remobilization of recent overbank sediment on river floodplains during subsequent inundation events, using the artificial radionuclides, caesium‐134 (134Cs) and cobalt‐60 (60Co). The investigation was conducted within floodplains of the Rivers Taw and Culm in Devon, UK. Small quantities of fine‐sediment (&lt; 63 µm dia.), pre‐labelled with known activities of either 134Cs or 60Co, were deposited at 15 locations across each floodplain. Surface inventories, measured before and after three consecutive flood events, were used to estimate sediment loss (in g m–2). Significant reductions provided evidence of the remobilization of the labelled sediment by inundating floodwaters. Spatial variations in remobilization were related to localized topography. Sediment remobilized during the first two events for the River Taw floodplain were equivalent to 63 · 8% and 11 · 9%, respectively, of the original mass. Equivalent values for the River Culm floodplain were 49 · 6% and 12 · 5%, respectively, of the original mass. Sediment loss during the third event proved too small to be attributed to remobilization by overbank floodwaters. After the third event, a mean of 22 · 5% and 35 · 2% of the original mass remained on the Taw and Culm floodplains, respectively. These results provide evidence of the storage of the remaining sediment. The findings highlight the importance of remobilization of recently‐deposited sediment on river floodplains during subsequent overbank events and demonstrate the potential of the tracing‐technique. Copyright © 2013 John Wiley &amp; Sons, Ltd.

Discolored Foraminifera Around St. Kitts, Eastern Caribbean Sea, and Their Environmental Significance

Discolored (chemically discolored) foraminiferal tests have long been known to occur in shallow-water, silici-carbonate sediments of the Caribbean, but their distributions and environmental significance have been little studied. To address this, nineteen sediment samples were collected from the shoreline around St. Kitts (<1 m), eleven from nearby coral reefs (6 – 27 m below sea level) and one from a shipwreck, the River Taw. Three species and one species-group were examined in detail: Amphistegina gibbosa, Archaias angulatus, Asterigerina carinata and Peneroplis spp. (= P. carinatus P. proteus). Discolored specimens were either gray or brown. The percentage of this group of species discolored per sample was calculated, as was the percentage of each species discolored per sample. The percentage of discolored miliolids was consistently greater than that of rotaliids. The mean percentage of discolored specimens along the shoreline exceeded that on the reefs, suggesting that discolored specimens have potential as a proxy for palaeodepth. It was, however, greatest around the River Taw. High percentages mark areas with either low rates of sediment reworking or high levels of iron and manganese associated with the chemical alteration of tests. Observations on the River Taw show that discolored foraminifera may be used to assess the impact of artificial reefs on marine ecosystems.

Export of dissolved organic carbon and nitrate from grassland in winter using high temporal resolution, in situ UV sensing

Co-deployment of two reagentless UV sensors for high temporal resolution (15min) real time determination of wintertime DOC and nitrate-N export from a grassland lysimeter plot (North Wyke, Devon, UK) is reported. They showed rapid, transient but high impact perturbations of DOC (5.3–23mg CL−1) and nitrate–N export after storm/snow melt which discontinuous sampling would not have observed. During a winter freeze/thaw cycle, DOC export (1.25kg Cha−1d−1) was significantly higher than typical UK catchment values (maximum 0.25kg Chad−1) and historical North Wyke data (0.7kg Cha−1d−1). DOC concentrations were inversely correlated with the key DOC physico-chemical drivers of pH (January r=−0.65), and conductivity (January r=−0.64). Nitrate–N export (0.8–1.5mgNL−1) was strongly correlated with DOC export (r≥0.8). The DOC:NO3–N molar ratios showed that soil microbial N assimilation was not C limited and therefore high N accrual was not promoted in the River Taw, which is classified as a nitrate vulnerable zone (NVZ). The sensor was shown to be an effective sentinel device for identifying critical periods when rapid ecosystem N accumulation could be triggered by a shift in resource stoichiometry. It is therefore a useful tool to help evaluate land management strategies and impacts from climate change and intensive agriculture.

The use of monitoring data for identifying factors influencing phytoplankton bloom dynamics in the eutrophic Taw Estuary, SW England

Using the Taw Estuary as an example, data routinely collected by the Environment Agency for England and Wales over the period 1990–2004 were interrogated to identify the drivers of excessive algal growth. The estuary was highly productive with chlorophyll concentrations regularly exceeding 100 μg L −1, mostly during periods of low freshwater input from the River Taw when estuarine water residence times were longest. However, algal growth in mid estuary was often inhibited by ammonia inputs from the adjacent sewage treatment works. The reported approach demonstrates the value of applying conventional statistical analyses in a structured way to existing monitoring data and is recommended as a useful tool for the rapid assessment of eutrophication. However, future estuarine monitoring should include the collection of dissolved organic nutrient data and targeted high temporal resolution data because the drivers of eutrophication are complex and often very specific to a particular estuary.

Nitrogen Cycling in Natural Waters using In Situ, Reagentless UV Spectrophotometry with Simultaneous Determination of Nitrate and Nitrite

Reliable, high temporal, and spatial resolution data is essential for enhancing our understanding of aquatic nitrogen biogeochemical cycling. This paper describes a novel UV spectrophotometric sensor (ProPS, TriOS GmbH, Oldenburg, Germany) for the real time, in situ, high resolution simultaneous mapping of nitrate/nitrite (linearity 0.01 - 6 mg N L(-1), RSD's NO3-N 4-10%, NO2-N 7-14%) in fresh and estuarine waters. Good agreement (t test at p = 0.05) was found with MOOS-1 certified reference material and with reference segmented flow analysis data. River Taw deployments identified a diurnal cycle for NO3-N (0.22-0.63 mg L(-1), RSD 3.9%) and for NO2-N (0.01-0.28 mg L(-1), RSD 12.4%) with the photo-oxidation of dissolved organic nitrogen a source of diurnal nitrate/nitrite, and a large cyclical amplitude (30-62% of mean nitrate/nitrite). In situ Tamar Estuary nitrate/nitrite concentrations, mapped through the salinity gradient, were strongly correlated with suspended particulate material and inversely correlated with dissolved oxygen and pH, indicating midestuarine, bacterially mediated nitrification/denitrification, with the raised estuarine nitrite also significantly correlated with particulate organic nitrogen. Such previously unquantified inputs have important implications for N loadings calculated from coarse scale sampling and laboratory analysis, pollution assessment, and our understanding of the biological rhythms of aquatic organisms.

Stream water chemistry and quality along an upland–lowland rural land-use continuum, south west England

Summary This study examined stream water quality across a range of catchments which are representative of the key environments and land uses of rural south-west England. These catchments included: (a) an acidic upland headwater catchment, rising on the moorlands of Dartmoor, with low-intensity sheep rearing; (b) a headwater catchment rising on the weathered granite lower slopes of Dartmoor, with cattle farming; (c) a lowland headwater clay catchment with sub-surface drainage and high intensity livestock farming, fodder crop cultivation, and hard-standing/slurry storage; and (d) the main River Taw, a lowland river system receiving drainage from a range of tributaries, exemplified by the above catchment types. Variations in water chemistry and quality were observed along an upland–lowland transition, from headwater streams to the main river channel. Within the livestock-dominated headwater streams, total phosphorus (TP) was dominated by particulate phosphorus (PP). These PP concentrations appeared to be mainly linked to two sets of processes: (1) in-stream sediment precipitation with sorption/co-precipitation of phosphate and/or localised in-channel mobilisation of sediment (by cattle or channel-clearing operations) under low flow conditions, and (2) sediment erosion and transportation associated with near-surface runoff during storm events. Under baseflow conditions, in-stream and/or riparian processes played a significant role in controlling general nutrient chemistry, particularly in the headwater streams which were heavily impacted by livestock.

Mathematical development and verification of a non-orthogonal finite volume model for groundwater flow applications

The mathematical development of a two-dimensional finite volume model for groundwater flow is described. Based on the hydraulic equations for saturated flow, the model deploys an improved least squares gradient reconstruction technique to evaluate the gradient at the control volume face, derived from the application of the finite volume formulation and using a cell-centred structured quadrilateral grid. The model has been compared to a finite difference model with orthogonal grids. The effects of grid non-orthogonality and skewness are investigated. The model was verified by comparison with analytical solutions and the results for a finite difference model. The finite volume model was then applied successfully to an aquifer discharging in a section of the River Tawe, UK, and the results were compared with results from MODFLOW and observed hydraulic heads. Results of the numerical model tests and field exercise showed that the use of finite volume method provides modellers with a consistent substitute for the finite difference methods with the same ease of use and an improved flexibility and accuracy in simulating irregular boundary geometries.

Design and construction of the Sail Bridge, Swansea, UK

This paper describes the design and construction of the Sail Bridge over the River Tawe at Swansea, South Wales. This pedestrian bridge represented a key element in the regeneration of the disused docks area, unlocking the potential for the new Port Tawe Innovation Village under development by the Welsh Development Agency. The development of the design and construction from planning stage through to completion of construction is discussed. This includes the selection of the bridge form along with the use of computer modelling techniques to develop the complex geometry, fabrication and bridge erection issues, aerodynamic investigations and the design of tuned mass dampers to control potential pedestrian-induced vibrations.