The in situ characterization of materials is a crucial challenge in room acoustics, as laboratories measurement cannot always be applied in consultancy practices. In particular, there is a lack of method to characterize in situ systems with perforated facings, which are commonly encountered systems in room acoustics. In this paper, the in situ characterization of a rigidly-backed porous material behind a rigid perforated facing by means of pressure–velocity measurements is presented. The method includes an inverse impedance model fitting based on measurement in a limited frequency range. The applicability of this method was studied by measuring a variety of perforated facings, whether in front of an air cavity or backed by a porous layer, and comparing the obtained impedance model parameters to reference values. Good agreement was observed between the retrieved parameters and the references, with the errors in all retrieved parameters moving mass, facing thickness, cavity depth, porous layer thickness and porous layer flow resistivity not exceeding 15%.