Resonant Destabilization Research Articles

Tidal triggering of seismic swarm associated with hydrothermal circulation at Blanco ridge transform fault zone, Northeast Pacific

Seismicity associated with hydrothermal systems (e.g., submarine volcanoes, mid-oceanic ridges, oceanic transform faults, etc.) share a complex relationship with the tidal forcing and induced fluid flow process under different tectonic settings. The hydrothermal circulation drives the deformation at the brittle-ductile transition zone within a permeable brittle crust. Although the tidal loading amplitudes are too small to generate a brittle deformation, the incremental pressure exerted by the tidal loading can modulate the flow of hydrothermal fluid circulation and trigger the critically stressed faults or fracture zones. We present a compelling case of tidal modulation in seismicity along the Blanco Ridge Transform Fault Zone (BRTFZ), in the northeast Pacific. The strong diurnal and fortnightly periodicity has been observed in the deeper seismic swarm (7–15 km), whereas the shallow seismic swarm (0–7 km) does not exhibit any such tidal periodicity. The dominance of diurnal and fortnightly periodicity in the deeper seismic swarm is explained by the high amplitude tidal cycles providing additional stress on the fluid circulation at the crust-mantle boundary. Moreover, our robust statistical correlation of seismicity with tidal stress and resonance destabilization model under rate-and-state friction formalism suggests that the fault segments are conditionally unstable and more sensitive to periodic tidal stress perturbation.

Neural network potential calculations for melamine adsorption onto Pt (111) compared with density functional theory

Abstract The investigation of Pt-adsorbed melamine is important in elucidating the effect of molecular decoration on the enhancement of catalytic performance for fuel cells, and is an interesting system in which covalent stabilization between the surface and the molecule competes with resonance destabilization by the coordination. The present work discusses whether graph neural network potentials can predict the adsorption structure with the competition. The most stable structure predicted by preferred potential was consistent with that by density functional theory but underestimated resonance destabilization.

Drought-induced seismicity modulation in the New Madrid Seismic Zone, central United States

The New Madrid Seismic Zone (NMSZ) in the central United States is a seismically active intraplate region composed of two fault segments: the Reelfoot and Cottonwood Grove fault segments. It has witnessed several major earthquakes, including a devastating 1811–1812 earthquake sequence of three ~M7 events. Nearly 200 years later, earthquakes still continue today in this complex seismic zone. This seismic zone is located in a domain with higher hydrological load than surrounding regions, which may play a crucial role in seismicity modulation. However, the hydrological unloading or loading-induced seismicity modulation and the underlying earthquake dynamics on this stable plate interior remain equivocal. Our study demonstrates that increased climate variability and drought-induced hydrological unloading can be potential drivers for the crustal stress change in the upper Mississippi embayment and seismicity modulation in the NMSZ. The seismicity rate associated with the Reelfoot fault segment shows ~60% increase during drought-induced prolonged drier periods, linked to La Niña cycles, than during the relatively wetter periods. However, such a feature is lacking for the seismicity associated with the Cottonwood Grove fault segment. We argue that the near-lithostatic pore pressure condition explicitly on the Reelfoot fault segment leads to an increase in the amplitude of the velocity perturbation, making this fault segment more susceptible to seismicity modulation on a multi-annual or annual time scale by the resonance destabilization process.

Gravity-induced seismicity modulation on planetary bodies and their natural satellites

Ground-based monitoring of seismicity and modulation by external forces in the field of planetary seismology remains equivocal due to the lack of natural observations. Constrained by the natural observations (including Earthquakes, Moonquakes, and Marsquakes) and theoretical models, we present the variation in gravitational acceleration “g” of different solar system objects, combined with external harmonic forcings that are responsible for seismicity modulation on the planetary bodies and their natural satellites. From the global diversity in seismicity modulation, it has been observed that the plate-boundary regions on the Earth exhibit both short and long-period seismicity modulation. In contrast, the stable plate interior regions appear to be more sensitive to long-period seismicity modulation, however, lacking in short-period modulation. The deep Moonquakes are susceptible for both the lunar tidal period (13.6 days and 27 days) and long-period pole wobble modulation (206 days), whereas shallow emergent type moonquakes show a seismic periodicity at the lunation period (29.5 days). Further, the seasonal variation with an annual seismicity burst and seismic periodicity at polar wobble periods for high-frequency Marsquakes captured by InSight lander indicate a natural origin. Whereas diurnal and semi-diurnal periodicity along with Phobos’ tidal period, indicate possible artifacts due to different detection probabilities and non-seismic noise in the Martian environment. We argue that, in the context of rate-state-dependent fault friction, the gravity-induced resonance destabilization model appears to be better agreement with the contrast and relative diversity in seismicity modulation linked to the Earth, Moon, and Mars.

Fault resonance process and its implications on seismicity modulation on the active fault system

Various periodic external loading processes (e.g., snow, hydrological and atmospheric, earth tide and surface reservoir load, etc.) affect tectonic deformation and sometimes modulate seismicity in diverse tectonic settings. Small stress variations induced by external loads may influence the fault dynamics and destabilize fault zones. In this article, we report five cases of earthquake occurrence in the plate boundary and plate interior regions where such a destabilization seems to be operating. We test the possibility of resonance amplification assuming rate-and-state friction and look for the model parameters that could justify resonance destabilization. We find that frictional resonance destabilization is possible in regions that are near the stability boundary (velocity neutral areas). The critical slip distance for the evolution of friction is similar to laboratory estimates. In some cases, effective normal stress lower than the lithostatic stress have to be assumed for the model to be consistent with the observations, implying high pore pressure. We propose that crustal faults of conditionally stable frictional domains with anomalous pore pressure are sensitive to periodic stress perturbations by the external loading process.

Global simulations of energetic electron excitation of beta-induced Alfvén eigenmodes

The energetic electron (EE) excitation of beta-induced Alfvén eigenmodes is investigated by using the newly developed global eigenvalue code MAS, which is based on a hybrid model that consists of Landau fluid bulk plasma and drift kinetic EE. Specifically, the bulk plasma kinetic effects such as finite Larmor radius, diamagnetic drifts and Landau dampings, and the EE adiabatic fluid response of convection and non-adiabatic kinetic response of precessional drift resonance are incorporated in the simulations. The global eigenmode equation is solved for e-BAE mode structure and linear dispersion relation in tokamak non-perturbatively. The radial width of e-BAE mode structure becomes narrower as the toroidal mode number increases, which can be explained by the change of Alfvén continuous spectra that interact with kinetic Alfvén waves for corresponding eigenmode formation. The e-BAE growth rate exhibits a non-monotonic variation with toroidal mode number for precessional drift resonance destabilization, while the e-BAE real frequency is close to the continuum accumulation point that almost remains the same. The parametric dependence of e-BAE stability on EE density and that on temperature are analyzed by MAS non-perturbative simulations, which shows that the EE density can affect e-BAE real frequency and thus changes the resonance condition, resulting in e-BAE stabilization in the strong EE drive regime. Further, the EE non-perturbative effect on the symmetry breaking of e-BAE mode structure is reported. The poloidal symmetry breaking characterized by the ‘boomerang’ shape two-dimensional (2D) structure can be greatly enhanced by increasing EE temperature, together with the large radial variation of the poloidal phase angle of dominant principal poloidal harmonic. The radial symmetry breaking of e-BAE mode structure arises when EE density/temperature drive is not symmetric with respect to corresponding rational surface, which can lead to a net volume-averaged value of e-BAE parallel wave number which drives plasma intrinsic rotation. These results are helpful in understanding the e-BAE dynamics observed in recent experiments.

Selective Conversion of Unactivated C-N Amide Bond to C-C bond via Steric and Electronic Resonance Destabilization.

The chemo- and site-selective reaction at the particular C-N amide bond among a sea of other amides is a significant and long-standing challenge. Although the use of twisted amides has been demonstrated for modifications of inert C-N amide bonds, none of these methods can selectively activate a particular amide bond for C-C bond formation in the presence of similar amides. Using density functional theory as a guide, we report the first site-selective C-C bond modification of a particular C-N amide bond in polyamides with a low twist angle by combining ground-state steric distortion with electronic activation.

Seismicity modulation by external stress perturbations in plate boundary vs. stable plate interior

Characterization of critically stressed seismogenic fault systems in diverse tectonic settings can be used to explore the stress/frictional condition of faults, along with its sensitivity for seismicity modulation by periodic stress perturbation. However, the process of seismicity modulation in response to external stress perturbation remains debated. In this paper, the characteristic difference in the seismicity modulation due to resonance destabilization phenomenon governed by rate-and-state friction is presented and validated with the globally reported cases of seismicity modulation in diverse tectonic settings. The relatively faster-moving plate boundary regions are equally susceptible for both shorter-period (e.g., semi-diurnal, diurnal, and other small tidal constituents) and long-period (e.g., semi-annual, annual, pole tide and pole wobble) seismicity modulation processes in response to stress perturbations from natural harmonic forcing, including tidal, semi-annual, annual, or multi-annual time scales. In contrast, slowly deforming stable plate interior regions and diffuse deformation zones appear to be more sensitive for long-period seismicity modulation of semi-annual, annual, or even multi-annual time scales but less sensitive for short-period seismicity modulation. This finding is also supported by the theoretical model predictions from the resonance destabilization process and worldwide documented natural observations of seismicity modulation in diverse types of tectonic settings.

Study of the Alfven eigenmodes stability in CFQS plasma using a Landau closure model

The aim of this study is to analyze the stability of the Alfven eigenmodes (AE) in the Chinese First Quasi-axisymmetric Stellarator (CFQS). The AE stability is calculated using the code FAR3d that solves the reduced MHD equations to describe the linear evolution of the poloidal flux and the toroidal component of the vorticity in a full 3D system, coupled with equations of density and parallel velocity moment for the energetic particles (EP) species including the effect of the helical couplings and acoustic modes. The Landau damping and resonant destabilization effects are added in the model by a given closure relation. The simulation results indicate the destabilization of n = 1 to 4 AEs by EP during the slowing down process, particularly n = 1 and n = 2 toroidal AEs (TAE), n = 3 elliptical AE (EAE) and n = 4 non circular AE (NAE). If the resonance is caused by EPs with an energy above 17 keV (weakly thermalized EP), n = 2 EAEs and n = 3 NAEs are unstable. On the other hand, EPs with an energy below 17 keV (late thermalization stage) lead to the destabilization of n = 3 and n = 4 TAEs. The simulations for an off-axis NBI injection indicate the further destabilization of n = 2 to 4 AEs although the growth rate of the n = 1 AEs slightly decreases, so no clear optimization trend with respect to the NBI deposition region is identified. In addition, n = 2, 4 helical AE (HAE) are unstable above an EP β threshold. Also, if the thermal β of the simulation increases (higher thermal plasma density) the AE stability of the plasma improves. The simulations including the effect of the finite Larmor radius and electron-ion Landau damping show the stabilization of the n = 1 to 4 EAE/NAEs as well as a decrease of the growth rate and frequency of the n = 1 to 4 BAE/TAEs.

Modeling of the ECCD injection effect on the Heliotron J and LHD plasma stability

The aim of the study is to analyze the stability of the energetic particle modes (EPM) and Alfven Eigenmodes (AE) in Helitron J and LHD plasma if the electron cyclotron current drive (ECCD) is applied. The analysis is performed using the code FAR3d that solves the reduced MHD equations describing the linear evolution of the poloidal flux and the toroidal component of the vorticity in a full 3D system, coupled with equations of density and parallel velocity moments for the energetic particle (EP) species, including the effect of the acoustic modes. The Landau damping and resonant destabilization effects are added via the closure relation. The simulation results show that the n = 1 EPM and n = 2 global AE (GAE) in Heliotron J plasma can be stabilized if the magnetic shear is enhanced at the plasma periphery by an increase (co-ECCD injection) or decrease (ctr-ECCD injection) of the rotational transform at the magnetic axis (). In the ctr-ECCD simulations, the EPM/AE growth rate decreases only below a given , similar to the ECCD intensity threshold observed in the experiments. In addition, ctr-ECCD simulations show an enhancement of the continuum damping. The simulations of the LHD discharges with ctr-ECCD injection indicate the stabilization of the n = 1 EPM, n = 2 toroidal AE (TAE) and n = 3 TAE, caused by an enhancement of the continuum damping in the inner plasma leading to a higher EP β threshold with respect to the co- and no-ECCD simulations.

Effect of the tangential NBI current drive on the stability of pressure and energetic particle driven MHD modes in LHD plasma

The aim of the present study is to analyze the stability of the pressure gradient driven modes (PM) and Alfvén eigenmodes (AE) in the large helical device (LHD) plasma if the rotational transform profile is modified by the current drive of the tangential neutral beam injectors (NBI). This study forms a basic search for optimized operation scenarios with reduced mode activity. The analysis is performed using the code FAR3d which solves the reduced MHD equations describing the linear evolution of the poloidal flux and the toroidal component of the vorticity in a full 3D system, coupled with equations for density and parallel velocity moments of the energetic particle (EP) species, including the effect of the acoustic modes. The Landau damping and resonant destabilization effects are added via the closure relation. On-axis and off-axis NBI current drive modifies the rotational transform which becomes strongly distorted as the intensity of the neutral beam current drive (NBCD) increases, leading to wider continuum gaps and modifying the magnetic shear. The simulations with on-axis NBI injection show that a counter (ctr-) NBCD in inward shifted and default configurations leads to a lower growth rate of the PM, although strong n = 1 and 2 AEs can be destabilized. For the outward shifted configurations, a co-NBCD improves the AEs stability but the PM are further destabilized if the co-NBCD intensity is 30 kA T−1. If the NBI injection is off-axis, the plasma stability is not significantly improved due to the further destabilization of the AE and energetic particle modes (EPM) in the middle and outer plasma region.

Study of Alfven eigenmodes stability in plasma with multiple NBI driven energetic particle species

The aim of this study is to analyze the destabilization of Alfven Eigenmodes (AEs) by multiple energetic particle (EP) species in DIII-D and LHD discharges. We use the reduced MHD equations to describe the linear evolution of the poloidal flux and the toroidal component of the vorticity in a full 3D system, coupled with equations of density and parallel velocity moments for the energetic particle species, including the effect of the acoustic modes, diamagnetic currents, and helical couplings. We add the Landau damping and resonant destabilization effects using a closure relation. The simulations with multiple neutral beam injector (NBI) lines show three different regimes: the nondamped regime where the multibeam AE growth rate is larger compared to the growth rate of the AEs destabilized by the individual NBI lines, the interaction regime where the multibeam AE growth rate is smaller than the single NBI AEs, and the damped regime where the AEs are suppressed. Operations in the damped regime require EP species with different density profile flatness or gradient locations. In addition, the AE growth rate in the interaction regime is further reduced if the combined NBI lines have similar beam temperatures and the β of the NBI line with a flatter EP density profile increases. Then, optimization trends are identified in DIII-D high poloidal β and LHD low density/magnetic field discharges with multiple NBI lines as well as the configuration requirements to operate in the damped and interaction regimes. DIII-D simulations show a decrease in the n = 2 to 6 AE growth rate and n = 1 AE are stabilized in the LHD case. The helical coupling effects in LHD simulations lead to a transition from the interaction to the damped regime of the n = 2, –8, 12 helical family.

Analysis of the MHD stability and energetic particles effects on EIC events in LHD plasma using a Landau-closure model

The aim of this study is to perform a theoretical analysis of the magnetohydrodynamic (MHD) stability and energetic particle effects on a LHD equilibria, calculated during a discharge where energetic-ion-driven resistive interchange mode (EIC) events were triggered. We use the reduced MHD equations to describe the linear evolution of the poloidal flux and the toroidal component of the vorticity in a full 3D system, coupled with equations of density and parallel velocity moments for the energetic particles species, including the effect of the acoustic modes, multiple energetic particles (EP) species, helical couplings and helically trapped EP. We add the Landau damping and resonant destabilization effects using a closure relation. The simulations suggest that the helically trapped EP driven by the perpendicular neutral beam injector (NBI) further destabilizes the 1/1 MHD-like mode located at the plasma periphery (r/a = 0.88). If the of the EP driven by the perpendicular NBI is larger than 0.0025 a 1/1 EIC with a frequency around 3 kHz is destabilized. If the effect of the passing EP driven by the tangential NBI is included on the model, any enhancement of the injection intensity of the tangential NBI below leads to a decrease of the instability growth rate. The simulations indicate that the perpendicular NBI EP is the main driver of the EIC events, as it was observed in the experiment. If the effect of the helical couplings are added in the model, an 11/13 EIC is destabilized with a frequency around 9 kHz, inward shifted (r/a = 0.81) compared to the 1/1 EIC. Thus, one possible explanation for the EIC frequency chirping down from 9 to 3 kHz is a transition between the 11/13 to the 1/1 EIC due to a weakening of the destabilizing effect of the high n modes, caused by a decrease of the EP drive due to a loss of helically trapped EP or a change in the EP distribution function after the EIC burst. The experimental data during the EIC bursting phase shows a complex mode structure and an inward shift of the instability, although no direct evidence of the proposed transition has been observed yet.

Resonance promoted ring-opening metathesis polymerization of twisted amides.

The living ring-opening metathesis polymerization (ROMP) of an unsaturated twisted amide using the third-generation Grubbs initiator is described. Unlike prior examples of ROMP monomers that rely on angular or steric strain for propagation, this system is driven by resonance destabilization of the amide that arises from geometric constraints of the bicyclic framework. Upon ring-opening, the amide can rotate and rehybridize to give a stabilized and planar conjugated system that promotes living propagation. The absence of other strain elements in the twisted amide is supported by the inability of a carbon analogue of the monomer to polymerize and computational studies that find resonance destabilization accounts for 11.3 kcal mol-1 of the overall 12.0 kcal mol-1 ring strain. The twisted amide polymerization is capable of preparing high molecular weight polymers rapidly at room temperature, and post-polymerization modification combined with 2D NMR spectroscopy confirms a regioirregular polymer microstructure.

Analysis of Alfven eigenmodes destabilization by energetic particles in TJ-II using a Landau-closure modelaaThis manuscript has been authored by UT-Battelle, LLC under Contract No. DE-AC05- 00OR22725 with the U.S. Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a non-exclusive, paid-up, irrevocable, world-wide license to

Alfvén Eigenmodes (AE) can be destabilized by energetic particles in neutral beam injection (NBI) heated plasmas through inverse Landau damping and couplings with gap modes in the shear Alfvén continua. We describe the linear evolution of the poloidal flux and the toroidal component of the vorticity in a full 3D system using the reduced MHD equations, density and parallel velocity moments for the energetic particles as well as the geodesic acoustic wave dynamics. A closure relation adds the Landau damping and resonant destabilization effects in the model. We apply the model to study the Alfvén modes stability in TJ-II, performing a parametric analysis in a range of realistic values of energetic particle β (), ratios of thermal/Alfvén velocities (), energetic particle density profiles and toroidal modes (n) including toroidal and helical couplings. The study predicts a large helical coupling between different toroidal modes and the destabilization of helical Alfvén eigenmodes (HAE) with frequencies similar to the AE activity measured in TJ-II, between 50–400 kHz. The analysis has also revealed the destabilization of GAE (global Alfvén eigenmodes), TAE (toroidal Alfvén eigenmodes) and EPM (energetic particle modes). For the modes considered here, optimized TJ-II operations require a profile in the range of to stabilize AEs in the inner and middle plasma. AEs in the plasma periphery cannot be fully stabilized, although for a configuration with , only AE are unstable with a growth rate 4 times smaller compared to the standard case and a frequency of 100 kHz. We reproduce the frequency sweeping evolution of the AE frequency observed in TJ-II as the profile is varied. The AE frequency sweeping is caused by consecutive changes of the instability dominant modes between different helical families.

Resonance Destabilization in N-Acylanilines (Anilides): Electronically-Activated Planar Amides of Relevance in N-C(O) Cross-Coupling.

Transition-metal-catalyzed activation of amide N-C(O) bonds proceeds via selective metal insertion into the carbon-nitrogen amide bond. Herein, we demonstrate that N-acylanilines (anilides), the first class of planar amides that have been shown to undergo selective amide N-C cross-coupling reactions, feature a significantly decreased barrier to rotation around the amide N-C(O) bond. Most significantly, we demonstrate that amide nN → π*C═O resonance in simple anilides can be varied by as much as 10 kcal/mol. The data have important implications for the design of N-C(O) amide cross-coupling reactions and control of the molecular conformation of anilides by resonance effects.

Analysis of Alfvén eigenmode destabilization by energetic particles in Large Helical Device using a Landau-closure modelaaThis manuscript has been authored by UT-Battelle, LLC under contract no. DE-AC05-00OR22725 with the U.S. Department of Energy. The United States Government and the publisher, by accepting the article for publication, acknowledge that the United States Government retains a non-exclusive, paid-up, irrevocable, world-wide license to

Energetic particle populations in nuclear fusion experiments can destabilize the Alfvén Eigenmodes through inverse Landau damping and couplings with gap modes in the shear Alfvén continua. We use the reduced MHD equations to describe the linear evolution of the poloidal flux and the toroidal component of the vorticity in a full 3D system, coupled with equations of density and parallel velocity moments for the energetic particles. We add the Landau damping and resonant destabilization effects using a closure relation. We apply the model to study the Alfvén mode stability in the inward-shifted configurations of the Large Helical Device (LHD), performing a parametric analysis of the energetic particle β () in a range of realistic values, the ratios of the energetic particle thermal/Alfvén velocities (), the magnetic Lundquist numbers (S) and the toroidal modes (n). The n = 1 and n = 2 TAEs are destabilized, although the n = 3 and n = 4 TAEs are weakly perturbed. The most unstable configurations are associated with the density gradients of energetic particles in the plasma core: the TAEs are destabilized, even for small energetic particle populations, if their thermal velocity is lower than 0.4 times the Alfvén velocity. The frequency range of MHD bursts measured in the LHD are 50–70 kHz for the n = 1 and 60–80 kHz for the n = 2 TAE, which is consistent with the model predictions.

Collisionless microtearing modes in hot tokamaks: Effect of trapped electrons

Collisionless microtearing modes have recently been found linearly unstable in sharp temperature gradient regions of large aspect ratio tokamaks. The magnetic drift resonance of passing electrons has been found to be sufficient to destabilise these modes above a threshold plasma β. A global gyrokinetic study, including both passing electrons as well as trapped electrons, shows that the non-adiabatic contribution of the trapped electrons provides a resonant destabilization, especially at large toroidal mode numbers, for a given aspect ratio. The global 2D mode structures show important changes to the destabilising electrostatic potential. The β threshold for the onset of the instability is found to be generally downshifted by the inclusion of trapped electrons. A scan in the aspect ratio of the tokamak configuration, from medium to large but finite values, clearly indicates a significant destabilizing contribution from trapped electrons at small aspect ratio, with a diminishing role at larger aspect ratios.

UVA I-protection effectiveness of bioactive compound and organic UV filters: an in vitro assessment

This research work aimed at determining the UVA effectiveness (UVA I/UV ratio), by diffuse transmittance analysis, of sunscreens developed with a bioactive substance, the rutin, associating or not with organic UVB-UVA filters incorporated at a phosphate-base O/W emulsion. Sunscreens provided conflicting and unpredictable results concerning the anti-UVA protection, specially, at the UVA I region. Possible interactions among the organic UV filters and the polyphenolic bioactive substance may have accounted with improvement or reduction of UV protection by a complex and not yet elucidated mechanism, probably regarding wavelength delocalization to superior or inferior values, by resonant molecule stabilization or destabilization.

Substituent Effect on N‐Benzylideneanilines by DFT Energy Partition

AbstractTo investigate the substituent effect on π‐electron delocalization of the N‐benzylideneaniline (NBA), the vertical resonance energies ΔEV(θ) of eleven substituted NBAs were separated into π and σ parts at the B3LYP/6‐311G(d) level of the Density Functional Theory (DFT). When substituted with an electron‐releasing group –OH, the calculated ΔEV(θ) of NBA was increased, indicative of more resonance destabilization than the mother molecule. However, when substituted with an electron‐withdrawing group –NO2, the calculated ΔEV(θ) values indicated less resonance destabilization. The most destabilizing effect was observed especially when the –OH group located at the ortho‐position of the aromatic ring in the fragment –NCH–Ar. For most of the substituted NBA molecules, it was the destabilized σ framework that determined the destabilizing feature of the vertical resonance energy, instead of the stabilized π system. When the –NO2 substituent at the para‐position of the aromatic ring of the –NCH–Ar group, the π system had the highest stabilizing effect while the ( framework exhibited the highest destabilizing effect. While the –NO2 substituent was at the para‐position of the left aromatic ring (Ar–), the NBA had the least vertical resonance energy value.