Resolved Scanning Transmission X-ray Microscopy Research Articles

Strongly-Interacted NiSe2/NiFe2O4 Architectures Built Through Selective Atomic Migration as Catalysts for the Oxygen Evolution Reaction.

The interactions between the catalyst and support are widely used in many important catalytic reactions but the construction of strong interaction with definite microenvironments to understand the structure-activity relationship is still challenging. Here, strongly-interacted composites are prepared via selective exsolution of active NiSe2 from the host matrix of NiFe2O4 (S-NiSe2/NiFe2O4) taking advantage of the differences of migration energy, in which the NiSe2 possessed both high dispersion and small size. The characteristics of spatially resolved scanning transmission X-ray microscopy (STXM) coupled with analytical Mössbauer spectra for the surface and bulk electronic structures unveiled that this strongly interacted composite triggered more charge transfers from the NiSe2 to the host of NiFe2O4 while stabilizing the inherent atomic coordination of NiFe2O4. The obtained S-NiSe2/NiFe2O4 exhibits overpotentials of 290mV at 10mAcm-2 for oxygen evolution reaction (OER). This strategy is general and can be extended to other supported catalysts, providing a powerful tool for modulating the catalytic performance of strongly-interacted composites.

Single shot acquisition of spatially resolved spin wave dispersion relations using X-ray microscopy

For understanding magnonic materials the fundamental characterization of their frequency response is essential. However, determining full dispersion relations and real space wavelength measurements are challenging and time-consuming tasks. We present an approach for spin wave excitation by a modified Sinc pulse, which combines a cosine signal with a conventional Sinc function. The resulting adjustable frequency bands lead to a broadband spin wave excitation at uniform power levels. Subsequently, time resolved scanning transmission X-ray microscopy is used for direct imaging of all excited spin waves in real space. To demonstrate the capabilities of this approach, a modified Sinc excitation of an ultra-thin yttrium-iron-garnet film is shown that simultaneously reveals phase, amplitude, and k-space information from a single measurement. Consequently, this approach allows a fast and thorough access to the full dispersion relation including spatial maps of the individual spin wave modes, enabling complete characterization of magnonic materials down to the nanoscale in real and reciprocal space.

Non-standing spin-waves in confined micrometer-sized ferromagnetic structures under uniform excitation

A non-standing characteristic of directly imaged spin-waves in confined micrometer-sized ultrathin Permalloy (Ni80Fe20) structures is reported along with evidence of the possibility to alter the observed state by modifications to the sample geometry. Using micromagnetic simulations, the presence of the spin-wave modes excited in the Permalloy stripes along with the quasi-uniform modes was observed. The predicted spin-waves were imaged in direct space using time resolved scanning transmission x-ray microscopy, combined with a ferromagnetic resonance excitation scheme (STXM-FMR). STXM-FMR measurements revealed a non-standing characteristic of the spin-waves. Also, it was shown by micromagnetic simulations and confirmed using STXM-FMR results that the observed characteristic of the spin-waves can be influenced by the local magnetic fields in different sample geometries.

Demonstration of k-vector selective microscopy for nanoscale mapping of higher order spin wave modes.

As a potential route towards beyond CMOS computing magnonic waveguides show outstanding properties regarding fundamental wave physics and data transmission. Here, we use time resolved scanning transmission X-ray microscopy to directly observe spin waves in magnonic permalloy waveguides with nanoscale resolution. Additionally, we demonstrate an approach for k-vector selective imaging to deconvolute overlapping modes in real space measurements. Thereby, we observe efficient excitation of symmetric and antisymmetric modes. The profiles of higher order modes that arise from sub-micron confinement are precisely mapped out and compared to analytical models. Thus, we lay a basis for the design of multimode spin wave transmission systems and demonstrate a general technique for k-specific microscopy that can also be used beyond the field of magnonics.

Probing the Electronic Structure of BiVO4 Coated ZnO Nanodendrite Core- Shell Nanocomposite Using X-ray Spectroscopic and Spatially Resolved Scanning Transmission X-ray Microscopy Studies

Probing the Electronic Structure of BiVO4 Coated ZnO Nanodendrite Core- Shell Nanocomposite Using X-ray Spectroscopic and Spatially Resolved Scanning Transmission X-ray Microscopy Studies

Software defined photon counting system for time resolved x-ray experiments

The time structure of synchrotron radiation allows time resolved experiments with sub-100 ps temporal resolution using a pump-probe approach. However, the relaxation time of the samples may require a lower repetition rate of the pump pulse compared to the full repetition rate of the x-ray pulses from the synchrotron. The use of only the x-ray pulse immediately following the pump pulse is not efficient and often requires special operation modes where only a few buckets of the storage ring are filled. We designed a novel software defined photon counting system that allows to implement a variety of pump-probe schemes at the full repetition rate. The high number of photon counters allows to detect the response of the sample at multiple time delays simultaneously, thus improving the efficiency of the experiment. The system has been successfully applied to time resolved scanning transmission x-ray microscopy. However, this technique is applicable more generally.