Residual Soil Research Articles

Variability of Soil Aggregate Disintegration During Splash Erosion Under Different Circumstances

ABSTRACTThe duration of rainfall is a significant factor in the process of splash erosion. Nevertheless, there is a lack of comprehensive documentation regarding the extent and characteristic of soil aggregate disintegration resulting from raindrop impact during splash erosion. To examine the properties of the aggregate disintegration mechanism during various of splash erosion, three soil samples (S‐1, S‐2, and S‐3 labeled as the organic matter was 19.77, 31.70, and 26.83 g kg−1) were employed to simulated splash erosion under six durations of rainfall (5, 10, 15, 20, 30, and 40 min). Aggregates ranging in size from 1 to 5 mm were utilized in the preparation of test soils for different antecedent moisture contents (3%, 5%, 10%, and 15%). The result demonstrated that the slaking effect, as observed in the fast wetting of the Le Bissonnais method, is attributed to the sudden release of air entering the water, irrespective of the water immersion duration. Upon increasing moisture content, under fast wetting conditions, the mean weight diameter (MWD) values for S‐2 and S‐3 samples increased from 1.25 and 1.31 to 1.85 and 1.61, respectively. Subsequently, at a moisture content of 10%, the MWD decreased to 1.84 and 1.49 for S‐2 and S‐3 samples, respectively. In contrast, S‐1 sample exhibited an increasing trend from 0.34 to 0.93. The sensitivity of aggregates to disintegration from slaking (RSI) decreased by 0.58, 0.43, and 0.29, while mechanical impact (RMI) decreased by 0.23, 0.11, and 0.08 with increasing moisture content, respectively. The rate of splash erosion for the S‐1 sample exhibited an initial increase followed by a subsequent decrease as the duration of rainfall increased. The S‐1 sample, with the lowest organic matter content, exhibited the highest content of microaggregate content (< 0.25 mm) of splashed particles (referring to soil particles transported out of the splash area by raindrops), ranging from 31.62% to 65.57%. The content of macroaggregate (> 0.25 mm) in the residual soil (indicating soil particles that were left in the area affected by splashing) exhibited a gradual reduction as the duration of rainfall increased. As the soil reached saturation, the influence of physicochemical dispersion became more pronounced with the prolonged duration of rainfall. The forces of slaking and physicochemical dispersion predominantly disrupted > 1 mm aggregates, while the destruction of aggregates within the 0.25–1 mm range was insufficient. This study is valuable for understanding the splash erosion process and provides a scientific foundation for the improvement of soil erosion prediction models.

Persistence and Dissipation Kinetics of λ-Cyhalothrin in Okra Fruits and Soil

Understanding pesticide residue levels in food items and soil is crucial for ensuring food safety. In this context, a study on persistence and dissipation kinetics of λ-cyhalothrin residues in okra fruits and soil was conducted for two consecutive years. λ-cyhalothrin was applied in okra at the recommended dose (15 g a.i. ha-¹) and double dose (30 g a.i. ha-¹). Okra fruit and soil samples were collected at different intervals after second spray and the residues were estimated using GC-MS/MS. The initial residue level in okra fruits was higher at double dose and declined gradually falling below the limit of quantification (0.01 mg kg-¹) within 7 to 10 days of application. Dissipation followed first-order kinetics, with half-life of 2.17 to 2.43 days. In soil, the initial residues dropped below the limit of quantification within 3 to 5 days of application. Since the initial residue levels in both okra fruits and soil were below the corresponding EU–MRL (0.2 mg kg-1), λ-cyhalothrin can be safely used in okra cultivation.

Saga of Soggy Sauerkraut

The creation of undesirable (soggy) sauerkraut resulted in the loss of $1,000,000 worth of organic sauerkraut in 2022, which prompted a multistep investigation of the cause and potential solution. The cause of this condition has been previously reported as unique fermentation conditions and the lack of key trace nutrients essential for cabbage (Brassica oleracea var. capitata) cell wall integrity. Because the condition was limited to organic sauerkraut in 2022, this investigation initially focused on differences in fermentation conditions between organic and conventional sauerkraut. No differences in fermentation conditions accounted for the condition; therefore, attention was focused on analyzing the mineral content of cabbage grown for sauerkraut production that pinpointed a deficiency in critical micronutrients such as iron, copper, manganese, boron, and zinc. This deficiency was traced to the use of poultry manure that was contaminated with glyphosate residue from conventionally fed turkeys and chickens that consumed genetically engineered (GE) feed and used as the fertilizer for organic cabbage production. The presence of glyphosate, a potent mineral chelator and antibiotic, was identified as a significant factor that impairs the absorption and physiological function of essential minerals in the shikimate metabolic pathway whereby cell walls and lignin are produced, thus compromising the structural quality of the sauerkraut. After this discovery, the study progressed to evaluate various remediation strategies aimed at eliminating glyphosate from the soil and restoring nutrient uptake. Corn grain and silage were selected as the test crops for this phase. Among the tested remediation solutions were raw sauerkraut juice containing Lactobacillus plantarum, which is reported to degrade glyphosate in the rumen of dairy cows and two patented proprietary microbial mixtures, PB027 and PB027SK, that degrade glyphosate by all three of the known metabolic pathways. These treatments were specifically formulated to degrade residual glyphosate in the soil. The results showed that these interventions could reduce soil glyphosate levels by 80% to 90% within 6 to 7 months to significantly enhance both the yield and quality of corn grain and silage. The increase in corn grain yield from glyphosate degradation on the Shiocton silt loam soil was 907.89 kg·ha−1 (13.5 bushels/acre). The increase in yield on the irrigated Kidder sandy loam soil was quantified at 726.31 kg·ha−1 (10.8 bushels/acre) for corn grain and 6.62 t·ha−1 (2.68 t/acre) for silage, with an additional improvement in silage feed quality beneficial for milk production. The findings underscore the importance of addressing both micronutrient sufficiency and glyphosate residue in soil to ensure the optimal growth of cabbage and the quality of sauerkraut produced. By successfully identifying manure as a subtle source of nutrient immobilization and implementing effective soil remediation techniques, this research highlights a clear path forward for improving crop yield and quality to ultimately enhance the structural integrity and consumer acceptance of sauerkraut. This study has broader applications for the nutritional content and crop yields of many organic crops that use conventional poultry and animal manures that may contain glyphosate in desiccated plant tissues or GE feeding operations.

Bioremediation of soils contaminated with nicosulfuron by the bacterial complex ES58

Nicosulfuron residues in soil can be harmful to the environment. In this study, acid-producing Klebsiella oxytoca ES5 and Klebsiella grimontii ES8 were isolated to construct the ES58 bacterial complex. The culture medium was optimized using response surface methodology, nicosulfuron degradation by ES58 reached 97.21% in 96h. The optimal degradation conditions were: temperature: 25℃, pH 6, initial nicosulfuron concentration: 50mgL-1 and inoculum volume: 2%. The two individual strains and the bacterial complex were tested for the ability of nitrogen fixation, phosphorus solubilization, potassium decomposition and iron carrier production. The results revealed that both strains and the bacterial complex had the ability to promote the growth, with bacterial complex being more capable than the two individual bacterial strains. After 28 d of bioremediation of nicosulfuron-contaminated soil by ES58, degradation rate of nicosulfuron was 90.84% in the unsterilized soil. Furthermore, the remediation process restored the activities of catalase, invertase, dehydrogenase and urease in the soil. The ES5-specific gene budA and ES8-specific gene ldh were detected in the soil at the 28th day. ES58 exhibited different effects on the growth indexes of nicosulfuron-sensitive crops. The study provides a novel strategy for nicosulfuron degradation effective by constructing and utilizing bacterial complex.

Drainage estimation across mountainous regions from large-scale soil moisture observations

Drainage is a crucial soil hydrological process that governs the partitioning of rainfall into runoff, groundwater recharge, soil water storage and evapotranspiration. Despite its significance, the drainage process is poorly understood due to the difficulty in direct measurements and insufficient understanding of its underlying physical mechanisms. To address these challenges, we present an innovative, physically-based, data-driven approach, SM2D (Soil Moisture to Drainage), to estimate drainage. SM2D was applied and examined using soil moisture data from a large-scale observation network over mountainous areas during 2014–2020. The soil moisture threshold governing drainage initiation proves to be significantly lower than the commonly employed field capacity metric in hydrological models. This threshold is influenced by factors such as mean soil moisture, bulk density, residual soil moisture, soil organic carbon, and parameters n and α of soil retention curve. Notably, field capacity has minimal impact on this threshold. Additionally, our analysis reveals that the drainage process is more influenced by the Soil Water Storage Increment (SWSI) than by mean soil moisture (MSM) that has traditionally been recognized as a key factor in drainage control. In comparison to commonly used exponential equations and those in models such as the Soil & Water Assessment Tool (SWAT), SM2D demonstrates superior performance in estimating drainage. The exponential equation derived from the SWSI outperforms those derived from other soil moisture metrics, including the commonly utilized MSM, challenging prevailing norms in drainage equations. SM2D holds the potential to generate extensive drainage datasets from satellite or large-scale soil moisture observations, advancing large-scale hydrological studies.

Landscape and local factors drive pesticide distribution in perennial agroecosystems

Abstract Pesticides constitute a major threat to biodiversity, but our understanding of the complex interactions between local and landscape factors influencing their distribution in agroecosystems remains limited. We conducted a pioneering study where we screened spiders, rodents, plants and soils for multiple pesticide residues in perennial crops (orchards and vineyards) managed under organic (N = 8) and integrated pest management (N = 8) systems. We then quantified the proportional representation of major habitat types in surrounding landscapes. Additionally, we conducted interviews with farmers to gain precise insights into pesticide applications. We expected that landscape factors would be more important for mobile entities (i.e. spiders and rodents), while management type would be relatively more important for the sedentary entities (i.e. soils and plants). We detected various pesticides within studied crop types, including several forbidden in the European Union. We found that pesticide distribution in spiders was influenced by the proportion of semi‐natural habitats in the landscape, with pesticide concentration decreasing as the proportion of semi‐natural habitats increased. Additionally, we observed that the spectrum of pesticides in spiders increased with the dominance of web‐building spiders. In contrast, pesticide levels in rodents were not affected by either landscape composition or local management type. For plants, pesticide distribution was affected by the proportion of forests and shrublands and, to some extent, by local management practices. In the case of soil, pesticide distribution was primarily determined by local management. This study marks an effort in demonstrating that both local and landscape factors play crucial roles in shaping pesticide distribution within perennial crops. Importantly, the relative importance of these factors varied across the four matrices investigated. Synthesis and applications: To comprehend the factors that determine pesticide distribution in crops, it is crucial to monitor diverse ecosystem components rather than focusing on a few model species. This approach underscores the necessity for ecologically sensitive management at landscape scale. Such management should involve the preservation and enhancement of (semi)natural habitats around crops. These combined insights can form the foundation for conservation and management initiatives aimed at mitigating the impact of pesticides on biodiversity within crops.

Drivers of greenhouse gas emissions in agricultural soils: the effect of residue management and soil type

Developing successful mitigation strategies for greenhouse gases (GHGs) from crop residue returned to the soil can be difficult due to an incomplete understanding of factors controlling their magnitude and direction. Therefore, this study investigates the effects of varying levels of wheat residue (WR) and nutrient management on GHGs emissions (CO2, N2O, and CH4) across three soil types: Alfisol, Vertisol, and Inceptisol. A combination of laboratory-based measurements and a variety of data analysis techniques was used to assess the GHG responses under four levels of WR inputs (0, 5, 10, and 15 Mg/ha; WR0, WR5, WR10, and WR15) and three levels of nutrient (NP0: no nutrient, NP1: nutrients (N and P) were added to balance the residue C/nutrient stoichiometry of C/N/P= 100: 8.3: 2.0 to achieve 30% stabilization of added residue C input at 5 Mg/ha (R5), and NP2: 3 × NP1). The results of this study clearly showed that averaged across residue and nutrient input, Inceptisol showed negative N2O flux, suggesting consumption which was supported by its high legacy phosphorus (19.7 mg kg⁻1), elevated pH (8.49), and lower clay content (13%), which reduced microbial activity, as indicated by lower microbial biomass carbon (MBC) and alkaline phosphatase (Alk-P) levels. N2O emissions were more responsive to nutrient inputs, particularly in Vertisol under high WR (15 Mg/ha) input, while CH4 fluxes were significantly reduced under high residue inputs, especially in Vertisol and Inceptisol. Alfisol exhibited the highest total carbon mineralization and GWP, with cumulative GWP being 1.2 times higher than Vertisol and 1.4 times higher than Inceptisol across residue and nutrient input. The partial least square (PLS) regression revealed that anthropogenic factors significantly influenced CO2 and N2O fluxes more than CH4. The anthropogenic drivers contributed 62% and 44% of the variance explained for N2O and CH4 responses. Our study proves that different biogeochemical mechanisms operate simultaneously depending on the stoichiometry of residue C and nutrients influencing soil GHG responses. Our findings provide insight into the relative contribution of anthropogenic and natural drivers to agricultural GHG emissions, which are relevant for developing process-based models and addressing the broader challenge of climate change mitigation through crop residue management.

Quantifying Residual Soil Moisture through Empirical Orthogonal Functions Analysis to Support Legume-Based Cropping Systems

AbstractThis study investigates spatiotemporal variability of residual soil moisture during the OND (October-November-December) season in Ethiopia and its implications for crop productivity. Employing advanced statistical techniques, we analyze spatial and temporal distribution of soil moisture across Ethiopia from 1981 to 2020, focusing on selected crops including legumes: chickpea, field peas, common bean, soybean and alfalfa, to assess the potential of residual moisture to support post-rainy season cropping. Results indicate pronounced east-west moisture gradients, with eastern regions of Ethiopia exhibiting lower moisture levels (< 60 kg.m-2) compared to western regions (> 150 kg.m-2). The central highlands, which are pivotal for agricultural activities, demonstrate significant variability in moisture (standard deviations > 25 kg.m-2), with implications on agricultural sustainability. The northern and southeastern tips of the country are particularly vulnerable to prolonged drought, where climate change and frequent dry spells exacerbate moisture deficits, consequently impacting crop productivity. Despite these challenges, promising opportunities for future crop production emerge in the southeastern region, which is characterized by increasing moisture trend over time ($$\:\tau\:=0.59$$). Findings further indicate that residual moisture adequately meets and supports crop water requirements in the western, central, and southwestern Ethiopia. In these regions, residual moisture supports more than 90% of cropland water requirements of various crops during the initial and late-season growth stages, whereas water requirement coverage drops to less than 20% during the mid-season growth stage. Therefore, by utilizing residual soil moisture alongside supplemental irrigation, Ethiopian farmers can meet crop water needs for double cropping and enhance resilience to climate variability.

Residual Assessment of Emerging Pesticides in Aquatic Sinks of Lahore, Pakistan

In recent decades, the use of pesticides has become fundamental to agricultural growth. However, the persistent and toxic nature of pesticides has led to significant concerns regarding their ecological and human health consequences. Therefore, for a better understanding of pesticide contamination and its potential risks, here we assessed the levels of five emerging pesticides—acetochlor, imidacloprid, MCPA, atrazine, and allethrin—in soil samples from ponds used for irrigation and in drinking water samples from nearby areas in Lahore, Pakistan. Our findings revealed that 100% of the samples were contaminated, posing substantial ecological and human health risks. Based on the toxic units (TUsum), all the soil samples showed higher toxic pressure, exceeding acute and chronic toxicity thresholds for earthworms, while 100% of water samples posed chronic toxicity risks to crustaceans and 10% to algae. Pollution index (PI) analysis further classified 100% of the soil samples and 10% of the water samples as highly polluted. These findings show high-pesticide residues in both soil and water and highlight immediate risk assessment and mitigation measures to protect non-target organisms. This preliminary information can be used to adopt risk assessment monitoring programmes and help higher authorities in making policies and guidelines to mitigate the escalating risk for ecology and humans.

Study on the mechanical properties and microscopic evolution mechanisms of weathered granite soil

Studying the effects of weathering on the mechanical properties and microscopic evolution of weathered granite soil (WGS) is essential for connecting microstructure with macroscopic behavior. This study conducts systematic monotonic and cyclic triaxial tests, along with a series of microscopic tests on WGS samples, to explore the influence of weathering on WGS mechanical properties and the mechanism of granite weathering. Results indicate that both effective internal friction angle and effective cohesion decrease progressively with increased weathering. Completely weathered granite (CWG) exhibits greater dynamic strength compared to granite residual soil (GRS). Additionally, as weathering progresses, quartz fragments are lost, while feldspar and biotite weather to form secondary minerals such as kaolinite and illite, leading to an overall enrichment in aluminum and iron in the granite. Weathering causes structural deterioration of WGS. Finally, the mechanical parameters of WGS and their chemical weathering indices show a coefficient of determination ranging from 60 to 99%. This study helps elucidate the fundamental causes of performance changes in WGS, thereby optimizing engineering design and enhancing disaster prediction accuracy, while providing new research perspectives and experimental evidence for WGS.

Archaeometallurgical characterization of Greco-Roman copper-based and iron nails from Tel Abu Seify, North Sinai, Egypt

The current study focuses on the investigation of a collection of copper alloy and iron nails discovered amid numerous metal artifacts in the archaeological excavations of Tel Abu Seify, North Sinai, Egypt. This site, identified as a shipbuilding and repair facility, dates back to the Greco-Roman era (Circa 332BCE–A.D. 641). Different analytical methods were employed to ascertain the composition of the alloys, manufacturing techniques, and characteristics of the corrosion products in the nails. A range of techniques were utilized to achieve this goal, including optical and metallographic microscopy, X-ray radiography, portable X-ray fluorescence, SEM-EDS, micro-Raman spectroscopy, and X-ray diffraction. The results indicated that 19 of the examined nails were composed of copper alloy, except for two nails made of iron. The analysis revealed that the tin bronze nails were predominantly composed of copper, with a minor presence of tin (4.3 wt%), lead (4.7 wt%), and traces of iron and arsenic. Additionally, the iron nails were made of low-carbon iron alloys. Microscopic examination indicated that the nails were manufactured via cold hammering. The patina observed on the copper nails encompassed cuprite, atacamite, clinoatacamite, antlerite, and cerussite, often interspersed with the soil residues. The rust surfaces of the iron nails comprised hematite, magnetite, goethite, akaganeite, and lepidocrocite. The iron nails and some copper nails exhibited partial or total mineralization, whereas most copper nails remained in good condition, generally retaining their metallic cores.

Antibiotics and Pesticides Enhancing the Transfer of Resistomes among Soil-Bayberry-Fruit Fly Food Chain in the Orchard Ecosystem.

While substantial amounts of antibiotics and pesticides are applied to maintain orchard yields, their influence on the dissemination and risk of antibiotic resisitome in the orchard food chain remains poorly understood. In this study, we characterized the bacterial and fungal communities and differentiated both antibiotic resistance genes (ARGs) and virulence factor genes (VFGs) in the soil, Chinese bayberry (matured and fallen), and fruit fly gut, collected from five geographic locations. Our results showed that fruit fly guts and soils exhibit a higher abundance of ARGs and VFGs compared with bayberry fruits. We identified 112 shared ARGs and 75 shared VFGs, with aminoglycoside and adherence factor genes being among the most abundant. The co-occurrence network revealed some shared microbes, such as Bacillus and Candida, as potential hosts of ARGs, highlighting the vector risks for both above- and below-ground parts of the orchard food chain. Notably, the elevated levels of antibiotics and pesticide residues in orchard soils increase ARGs, mobile genetic elements (MGEs), and VFGs in the soil-bayberry-fruit fly food chain. Our study highlighted that agricultural management, including the overuse of antibiotics and pesticides, could be the key factor in accumulating resistomes in the orchard food chain.

Preparation Method and Benefit Analysis for Unburned Brick Using Construction Solid Waste from Residue Soil

Highly efficient resource utilization of construction solid waste has significant environmental and socioeconomic benefits. In this study, a fabrication method and process optimization of unburned brick from construction residue soil were investigated based on experiments. The effects of cementing the material content, the raw material treatment process, the brick moisture content, and the molding method on the compressive strength of unburned brick were studied and discussed. The experimental results show that 5–20% of ordinary cement can produce a strength grade of 5 MPa–20 MPa for unburned brick, and the utilization rate of the residue soil is greater than 80%. In the case of well-dispersed residual particles, complete drying and rolling are not necessary, and soil particle size within 5 mm is beneficial for obtaining proper sand grading and low mud content, which will improve the strength of unburned brick. The pressure for the press forming of unburned brick should be 10 MPa, and the optimal moisture content of the residue-soil mixture is about 13%. The proposed residue-soil unburned brick has remarkable environmental and economic benefits with low carbon emissions, low cost, and high profit. The methods proposed and optimized in this study can provide important technical support for realizing the large-scale production of residue-soil unburned brick.

Physical Vulnerability and Landslide Risk Assessment in Tegucigalpa City, Honduras

Quantitative disaster risk studies for slow-moving rotational and translational landslides in small regions (e.g., cities and watersheds) are very scarce. The limitations of risk modeling associated with these hazards include (i) the lack of data for physical modeling, (ii) methodological restrictions on estimating landslide intensity with statistical models and determining the temporal probability of landslides, and (iii) the absence of characterizations of the physical vulnerability of exposed assets. The present study combines and updates different methodologies to overcome these limitations for quantitative landslide disaster risk estimation, creating a novel methodological approach that was applied in a pilot study in Tegucigalpa city, Honduras. Tegucigalpa, the capital city of Honduras, has the highest number of recorded landslides in the country. In a previous study, landslides were found to be mainly concentrated in areas with colluvium and residual soils. As an input for the disaster risk assessment, this study generated landslide risk vulnerability functions based on empirical data. The application of the proposed methodology allowed us to estimate the average annual loss (AAL) caused by landslides in the study area—a key disaster risk metric that is lacking in other landslide disaster risk studies—enabling comparisons with disaster risk estimates associated with other hazards. In particular, the AAL value obtained for the study region was USD 7.26 million.

Understanding the interaction between soil ORP and enzyme activity: How does wetland type affect constructed wetland performance for the advanced treatment of swine wastewater?

Constructed wetlands (CWs) are widely used for the advanced treatment of swine wastewater. Wetland type is the most critical parameter for engineering applications; therefore, the performance of horizontal/vertical subsurface flow CWs (HSFCWs and VSFCWs) was explored over one year of operation. The effects of five antibiotics (40 μg/L each), copper (Cu, 1.0 mg/L), and their combination on CW performance and soil oxidation–reduction potential (ORP) and enzyme activity were investigated. The annual removal efficiencies of HSFCWs and VSFCWs for total organic carbon (TOC), nitrogen, and phosphorus were 72.03 %–84.49 % and 87.15 %–90.72 %, for antibiotics were 91.35 %–99.52 % and 87.33 %–99.57 %, and for Cu were 97.37 %–97.44 % and 95.52 %–96.85 %, respectively. The CWs removed antibiotics through substrate adsorption, plant absorption, and biodegradation. Total antibiotic residues in HSFCW and VSFCW soils ranged from 6.29 to 17.31 and 24.57 to 589.07 μg/kg, respectively, and enrofloxacin and roxithromycin posed medium and high risks in VSFCW non-rhizosphere soil. The amount of residual antibiotics in Phragmites australis parts was in the order of fibrous roots > rhizomes > aboveground. ORP and enzyme activities were greater in rhizosphere soil than in non-rhizosphere soil and greater in the VSFCWs than in the HSFCWs. CW performance and soil enzyme activities decreased under the stress of antibiotics and coexistence of antibiotics and Cu. These findings advance our knowledge of CW design, elucidate the unique advantages of CWs, and offer efficient operation strategies for swine wastewater advanced treatment, helping researchers recognize the adverse effects of antibiotics on CWs.

Bearing Behavior of Large-Diameter Monopile Foundations of Offshore Wind Turbines in Weathered Residual Soil Seabeds

The southeastern rock base sea area is the most abundant wind resource area, and it is also the mainstream construction site of offshore wind farms (OWFs) in China. The weathered residual soil is the main seabed component in the rock base area, which is the important bearing stratum of the offshore wind turbine foundation. Previous studies on the mechanical properties of seabed materials and bearing characteristics of the pile foundations in OWFs have mainly focused on the submarine soil-based seabed, resulting in a lack of direct reference for the construction of offshore wind power in the rocky seabed. Therefore, the mechanical properties of weathered residual soil and the bearing behaviors of monopile foundations are mainly investigated in this study. Firstly, dynamic triaxial tests are conducted on the weathered residual soil, and experiments analyze insight into the evolution law of the hysteresis curve, cumulative strain, and stiffness attenuation. Then, the horizontal loading behaviors of monopile foundations in residual soil are analyzed by numerical simulations; more critically, the service performances under wind and wave coupling loads are evaluated, which provide a direct theoretical basis for the construction and design of offshore wind turbine foundations in rock base seabeds.

Modeling the response of crop emergence to sowing depth and soil water deficit in direct-seeded rice

Abstract Background and aims Dry direct seeding of rice in the tropics often suffers from poor crop establishment owing to soil water deficit. A potential solution is sowing deeply to utilize residual soil moisture farther below the surface. We evaluated rice emergence under various sowing depths and soil moisture conditions and tested a model framework of it as a simultaneous function of sowing depth and soil moisture. Methods We combined data from three field experiments and one growth chamber experiment to collect emergence data for four rice cultivars (Dontokoi, Dular, Rc222 and Rc420). We independently parameterized the relationships between emergence and sowing depth or soil water tension using logistic functions. We expressed the final emergence as the product of the two functions. Results Emergence responses to sowing depth and soil moisture fitted the cultivar-specific logistic functions well. For Dular, a cultivar that tolerates deep sowing, emergence was greatest when sown at 4 to 5 cm below the surface under soil water deficit, versus 1 to 2 cm under wet conditions, and our combined model successfully reproduced this result. Conclusion Our emergence model framework supports adjustment of sowing depth to account for available soil water, making the model a powerful new tool for drought adaptation in direct-seeded rice.

Soil Water Characteristics Curves (SWCC) of Residual Soils Stabilized using Emerging and Novel Bioinspired Technique

The development of unsaturated soil mechanics stemmed from the inadequacies of classical soil mechanics in addressing the partial pore spaces found in real-world soil systems. However, assessing soil parameters under partial saturation is resource-intensive. To streamline this, the Soil-Water Characteristic Curve (SWCC) theory was introduced. Widely applied across geotechnical engineering, water resources, and agriculture, SWCC predicts parameters of unsaturated soil systems. In geotechnical engineering, SWCC is vital for designing systems near the Earth's surface, like slopes, clay liners and foundations. Furthermore, most of conventional soil improvement techniques pose a lot of environmental concerns. thus, emergence of green construction materials widely known as bio mediated and bioinspired soil improvement techniques like Enzymatic induced calcite precipitation (EICP). EICP, an emerging eco-friendly as it employs use of simply chemical compound that reduces carbon footprints, bioinspired technique as it mimics natural forming process, was applied to stabilize tropical soil for SWCC determination. SWCC parameters were derived by subjecting EICP-treated soils at varying concentration of cementation solutions (0 – 1.00 M) using pressure plate method. Results revealed that saturated water content θs, retention water content θr, and air entry value Ψa increased with higher cementation solution concentration. The values of θs, θr, and Ψa improved from of 0.663, 0.23405, and 3.4832 at 0 concentration of cementation solution to 0.701, 0.22864, and 7.7086, respectively upon treatment with 1.00 M cementation solution. Finally, it has been demonstrated EICP is capable of improving the SWCC parameters of residual soil, thus the EICP technique can be exploited in stabilization of residual for construction of compacted clay liner.

Physical–Chemical and Thermal Properties of Clays from Porto Santo Island, Portugal

The use of clays for thermal treatments and cosmetic purposes continues to be a worldwide practice, whether through the preservation of native cultural traditions, pharmaceutical formulations or integrative health and well-being practices. Special clays, such as bentonites, are very common for healing applications due to their high cation exchange capacity (CEC), high specific surface area (SSA) and alkaline pH values and, therefore, are used in multiple therapeutic and dermocosmetic treatments. Numerous bentonitic deposits occur on Porto Santo Island with different chemical weathering degrees. This research evaluates which residual soils have the most suitable characteristics for pelotherapy. The texture of residual soils varies from silt loam to loamy sand and SSA between 39 and 90 m2/g. The pH is alkaline (8.7 to 9.6), electrical conductivity ranges from 242 to 972 µS/cm, and CEC from 50.4 to 86.8 µS/cm. The residual soils have a siliciclastic composition (41.36 to 54.02% SiO2), between 12.52 and 17.65% Al2O3 and between 52 and 82% smectite content, which are montmorillonite and nontronite. Specific heat capacity (0.5–0.9 J/g°C) and cooling kinetics (14.5–19 min) show that one residual soil has the potential to be suitable for pelotherapy according to the literature. Moreover, the residual soils have As, Cd, Co, Cr, Hg, Mn, Ni, Pb, Sb and V concentrations higher than the limits of guidelines for cosmetics and pharmaceutical products.

Excitation energy transfer based naphthalimide-boron-dipyrromethene dyads as two-photon fluorescent probes for palladium(0) detection and live cell imaging

Increasing industrial demand has accelerated the consumption and contamination of palladium (Pd) worldwide. The implementation of fluorescent probes, especially with two-photon excitation, holds great promise for Pd detection in environmental and biological analysis. In this work, two naphthalimide (NPI)-boron-dipyrromethene (BDP) dyads (named NBH and NBN) were developed as two-photon fluorescent probes for Pd(0) detection based on an excitation energy transfer (EET) strategy, employing NPI as the energy donor and BDP as the acceptor. Spectroscopic studies revealed that both probes exhibited a fast response to Pd(0) in a pronounced fluorescence "ON-OFF" manner. The Pd-catalyzed Tsuji-Trost reaction activated an intramolecular photoinduced electron transfer (PET) process between the aniline and BDP moieties, resulting in the fluorescence quenching of the BDP fluorophore. The reaction-based probes exhibited excellent sensitivity and selectivity for Pd(0) species with a detection limit as low as 2.4 nM. These probes were successfully applied to the determination of Pd residues in drug, soil, and water samples. A simple smartphone-based platform was also constructed to determine Pd(0) via an RGB reader. With negligible cytotoxicity, confocal imaging study validated their feasibility of monitoring Pd(0) in living cells through multiple excitation channels.