Residual Resistivity Research Articles

Quantum oscillation study of the large magnetoresistance in Mo substituted WTe2 single crystals

The list of interesting electrical properties exhibited by transition metal dichalcogenides has grown with the discovery of extremely large magnetoresistance (MR) and type-II Weyl semimetal behavior in WTe2 and MoTe2. The extremely large MR in WTe2 is still not adequately understood. Here, we systematically study the effect of Mo substitution on the quantum oscillations in the MR in WTe2. The MR decreases with Mo substitution, however, the carrier concentrations extracted from the quantum oscillations show that the charge compensation improves. We believe that earlier interpretations based on the two-band theory, which attribute the decrease in MR to charge imbalance, could be incorrect due to overparametrization. We attribute the decrease in MR in the presence of charge compensation to a fall in transport mobility, which is evident from the residual resistivity ratio data. The quantum scattering time and the effective masses do not change within experimental errors upon substitution. Published by the American Physical Society 2024

What do we learn from impurities and disorder in high-Tc cuprates?

A series of experimental studies established that the differing morphologies of the phase diagrams versus hole doping nh of the various cuprate families are mostly controlled by defects and disorder. In the minimally disordered cuprate Yttrium Baryum Copper Oxide (YBCO) we introduced controlled detfects that allowed us to probe the metallic and superconducting states. We demonstrate that the extent of the spin glass phase and the superconducting dome can be controlled by the concentration of spinless (Zn, Li) impurities substituted on the planar Cu sites. NMR frequency shift measurements establish that these defects induce, in their vicinity, a cloud with a Kondo-like paramagnetic behavior. Its “Kondo” temperature and spatial extent differ markedly between the pseudogap and strange metal regimes. We have performed transport measurements on single crystals with a controlled content of in-plane vacancies introduced by electron irradiation. At high T, the inelastic scattering of the carriers has been found independent of disorder and completely governed by the excitations of the correlated electronic state. The low T upturns in the resistivity associated with single-site Kondo-like scattering are qualitatively in agreement with local magnetism induced by spinless impurities. The apparent metal insulator crossover is only detected for a very large defect content, and part of the large resistivity upturn remains connected with Kondo-like paramagnetism. In the superconducting state, the defect-induced reduction of Tc scales linearly with the increase in residual resistivity induced by disorder. High-field magnetoresistance experiments permit us to determine the paraconductivity due to superconducting fluctuations. The latter vanishes beyond a temperature T’c and a field H’c that both decrease with increasing in-plane defect content. In the pseudogap regime, the weaker decrease of T’c with respect to that of Tc reveals a large loss of superconducting phase coherence in the presence of disorder. In light of our experimental results, we initiate a discussion of its interplay with pair breaking. Our data also permit us to confirm that the differing phase diagrams are due to competing orders or disorders that are family-specific. In the ideal phase diagram of a disorder-free cuprate, 2D superconductivity should persist at low doping. This ensemble of experimental results provides serious challenges for the theoretical understanding of superconductivity in these correlated electron systems.

Large magnetoresistance and de Haas–van Alphen oscillations in NbNiTe5 originated from nontrivial band topology

Quasi-one-dimensional topological materials have emerged as a captivating area of research due to their interesting electronic properties and potential applications. NbNiTe5 is one such quasi-1D material. In this work, we report the synthesis, structural characterization, and comprehensive investigation of the electrical transport and magnetic properties of NbNiTe5. NbNiTe5 crystallizes in the orthorhombic crystal system with the Cmcm space group. Experimental studies have uncovered metallic nature with a remarkably high residual resistivity ratio of 103, along with intriguing spin–orbit interaction-driven nonsaturating magnetotransport properties at low temperatures. A meticulous analysis incorporating magnetoconductivity measurements unveils signatures of weak anti-localization analyzed by using the Hikami–Larkin–Nagaoka formula. Furthermore, the de Haas–van Alphen oscillations demonstrate the high mobility of charge carriers with a significantly low effective mass at five frequencies: Fα=84.82 T, Fβ=131.21 T, Fγ=242.36 T, Fδ=31.93 T, and Fδ′=162.33 T. In light of these collective findings, NbNiTe5 can be defined as a quasi-1D topological semimetal.

Controllable suppression of the unconventional superconductivity in bulk and thin-film Sr2RuO4 via high-energy electron irradiation

In bulk Sr2RuO4, the strong sensitivity of the superconducting transition temperature Tc to nonmagnetic impurities provides robust evidence for a superconducting order parameter that changes sign around the Fermi surface. In superconducting epitaxial thin-film Sr2RuO4, the relationship between Tc and the residual resistivity ρ0, which in bulk samples is taken to be a proxy for the low-temperature elastic scattering rate, is far less clear. Using high-energy electron irradiation to controllably introduce point disorder into bulk single-crystal and thin-film Sr2RuO4, we show that Tc is suppressed in both systems at nearly identical rates. This suggests that part of ρ0 in films comes from defects that do not contribute to superconducting pairbreaking and establishes a quantitative link between the superconductivity of bulk and thin-film samples. Published by the American Physical Society 2024

The Growth of V5S8 Single Crystals by Chemical Vapour Transport

Single crystals of the d-electron antiferromagnetic metal V5S8 can be prepared by chemical vapour transport with gaseous iodine as a transport agent. We present the outcomes of an endeavour to synthesise high-purity single crystals of V5S8 with reduced crystalline disorder, important to the formation of novel quantum orders. We report results on the residual resistivity ratio of the single crystals as growth parameters are varied including growth temperature, temperature gradient and pre-growth processing of the initial apparatus and reagents. We demonstrate that single crystals of at least a few mm in size can be successfully grown at relatively low temperatures in the range 550–600 °C. The optimisation of this method may imply a better crystallographic organisation, reducing sulphur vacancies and increasing vanadium positional order. The resulting longer electron mean free paths may enhance the probability of finding exotic quantum states of matter at low temperatures. The results presented here may also be of relevance to the development of vanadium sulphide-based energy storage and spintronic devices.

Fabrication of the Cu/AgCuTi/Nb composite for superconducting radio-frequency material under extreme service conditions based on electroplating additive manufacturing

The primary objective of this study is the development of Cu/Nb composite materials for Superconducting Radio-Frequency (SRF) applications under extreme service conditions characterized by a strong RF electromagnetic field, extremely low temperatures, and relatively low heat loss. A novel integrated manufacturing approach is proposed, which combines cold-sprayed AgCuTi alloy as an intermediate coating on the Nb surface and an electroplated Cu layer with a subsequent heat treatment brazing effect. This strategy aims to address the significant challenge of non-intermelting Cu and Nb while also considering effective lateral heat transfer. Mechanical property tests showed that the bond strength of Nb/AgCuTi/Cu composites exceeded 150 MPa. Low-temperature thermal transport tests indicate that the Residual Resistance Ratio (RRR) of the Cu layer surpasses 150, with a thermal conductivity at 4.2 K exceeding 1600 W/(m·K). Moreover, both the composite interface and mechanical properties of the specimens remain stable even after undergoing cyclic cold shock experiments. These findings suggest that the Nb/AgCuTi/Cu composite material developed in this study meets the technical requirements for long-term stable and high-performance operation in high-current and high-power superconducting accelerators.

Evolution of structure, magnetism, and electronic/thermal-transports of Ti(Cr)-substituted Fe2CrV all-d-metal Heusler ferromagnets

All-d-metal full-Heusler alloys possess superior mechanical properties and high spin polarization, which would play an important role in spintronic applications. Despite this, their electrical and thermal transport properties have not been comprehensively investigated till now. In this work, we present an analysis on the evolution of structural, magnetic and transport properties of Cr- and Ti-substituted Fe2CrV all-d-metal Heusler alloys by combining theoretical calculations and experiments. Both series of alloys crystallize in Hg2CuTi-type structure. With increasing Ti doping, the calculated total magnetic moments of Fe50Cr25V25-xTix decrease linearly. The experimental saturation magnetization is highly consistent with theoretical calculations and Slater-Pauling rule when x < 4, indicating the highly ordered atomic occupation. The magnetization and Curie temperature can be significantly tuned by altering spin polarizations and exchange interactions. The introduction of the foreign atom, Ti, results in a linear increase in residual resistivity, while electron-phonon scattering keeps relatively constant. The maximum values for electrical and thermal transport properties are observed in the stoichiometric Fe2CrV composition.

Synthesis of α-Bi/SrTiO3 heterostructure through the Eu-induced reduction of Bi2O2Se/SrTiO3

Thin Bi films, especially noncentrosymmetric α-phase Bi films (α-Bi), have attracted considerable attention in recent years due to their intriguing physical properties such as ferroelectricity, nonlinear optical response, and coherent spin transport. However, the current experimental preparation of α-Bi films still presents substantial challenges, resulting in only isolated α-Bi islands being achieved. In this study, α-Bi/SrTiO3 (α-Bi/STO) was synthesized from a Bi2O2Se/STO (BOS/STO) heterostructure by depositing a Eu layer and reducing a BOS film. The so-formed α-Bi/STO interface features metallic conductivity with electron mobility of 7.7 × 104 cm2/V s and ultralow resistivity of 1 nΩ cm at 2 K, as well as high residual resistance ratios R300 K/R2 K up to 2353. Furthermore, we observed a complex weak antilocalization–weak localization–weak antilocalization crossover with increasing magnetic field at temperatures below 10 K. Our work presents the synthesis of α-Bi films, which could potentially serve as a valuable platform for experimental validation of diverse theoretical predictions associated with α-Bi heterostructures. Furthermore, this special synthesis method provides valuable insights into the preparation of other metastable films.

Microcalorimeter Absorber Optimization for ATHENA and LEM

High quantum efficiency (QE) X-ray absorbers are needed for future X-ray astrophysics telescopes. The Advanced Telescope for High ENergy Astrophysics (ATHENA) mission requirements for the X-ray Integral Field Unit (X-IFU) instrument dictate, at their most stringent, that the absorber achieve vertical QE > 90.6% at 7 keV and low total heat capacity, 0.731 pJ/K. The absorber we have designed is 313 µm square composed of 1.05 μm Au and 5.51 μm electroplated Bi films (Barret et al. in Exp Astron 55:373–426, 2023). Overhanging the TES, the absorber is mechanically supported by 6 small legs whose 5 μm diameter is tuned to the target thermal conductance for the device. Further requirements for the absorber for X-IFU include a > 40% reflectance at wavelengths from 1 to 20 μm to reduce shot noise from infrared radiation from higher temperature stages in the cryostat. We meet this requirement by capping our absorbers with an evaporated Ti/Au thin film. Additionally, narrow gaps between absorbers are required for high fill fraction, as well as low levels of fine particulate remaining on the substrate and zero shorts between absorbers that may cause thermal crosstalk. The Light Element Mapper (LEM) is an X-ray probe concept optimized to explore the soft X-ray emission from 0.2 to 2.0 keV. These pixels for LEM require high residual resistance ratio (RRR) thin 0.5 µm Au absorbers to thermalize uniformly and narrow < 2 μm gaps between pixels for high areal fill fraction. This paper reports upon technology developments required to successfully yield arrays of pixels for both mission concepts and presents first testing results of devices with these new absorber recipes.

Improving electrical transport properties of LaxCa0.89-xSr0.11MnO3 films via optimized La content

Optimized LaxCa0.89-xSr0.11MnO3 (x = 0.65, 0.68, 0.71 and 0.74) films were fabricated using spin-coating method. According to double exchange (DE) mechanism and Jahn-Teller effect, the enhancement of peak temperature coefficient of resistivity (TCR) was attributed to low residual resistivity and weak various electron scatterings, including electron–electron, electron–phonon and electron-magnon. Also, peak TCR temperature is not only influenced mainly by the DE mechanism, but also by the Mott transition. Moreover, optimized sintering improved film crystallinity, increasing peak TCR value. The resulting La0.71Ca0.18Sr0.11MnO3 film displayed a peak TCR of 10.74 %/K at 294.11 K. Appropriate chemical composition and sintering promoted the enhancement of electrical transport properties.

Flux creep and flux pinning behavior in Cu-doped FeSe0.4Te0.6 single crystals

This paper presents the preparation and comparative study of the superconducting properties and magnetic flux dynamics of FeSe and Fe1-xCuxTe0.6Se0.4 (x = 0, 0.005, 0.01, 0.015) single crystals, with the aim of investigating the origin of the second peak in FeTe0.6Se0.4. The Cu element significantly suppresses the superconducting transition temperature (Tc) of Fe1-xCuxTe0.6Se0.4 from 14.5 K at x = 0 to 9.23 K at x = 0.015, which is close to the 9 K of FeSe, while also suppressing the second peak effect. Additionally, the critical current density anisotropy (γ) is reduced. Dynamic relaxation rates (Q) indicate a crossover from rapid single-vortex pinning near the second peak to collective pinning, linking fast and slow magnetic flux relaxation with the second peak effect. By comparing the pinning properties of FeSe and Fe1-xCuxTe0.6Se0.4 (x = 0, 0.005, 0.01, 0.015), it is found that the second peak effect is closely related to the transition from δl - pinning to δTc - pinning in Fe1-xCuxSe0.4Te0.6 (x = 0, 0.005, 0.01, 0.015). While surface pinning centers dominate in FeSe, the pinning in Fe1-xCuxSe0.4Te0.6 (x = 0, 0.005, 0.01, 0.015) originates from the interaction between the core and normal centers. Furthermore, the electronic transport properties of the FeSe and Fe1-xCuxSe0.4Te0.6 (x = 0, 0.005, 0.01, 0.015) series are also studied. Te substitution suppresses the nematic transition in FeSe, while Cu substitution suppresses the superconducting transition in Fe1-xCuxSe0.4Te0.6 (x = 0, 0.005, 0.01, 0.015) and reduces the residual resistivity. Additionally, the upper critical field is reduced from 150 T in FeSe0.4Te0.6 to 41 T in Fe0.085Cu0.015Se0.4Te0.6, but still higher than the 12.5 T observed in FeSe.

Insensitivity of Tc to the residual resistivity in high-Tc cuprates and the tale of two domes

One of the few undisputed facts about hole-doped high-Tc cuprates is that their superconducting gap Δ has d-wave symmetry. According to ‘dirty’ d-wave BCS theory, even structural (non-magnetic) disorder can suppress Δ, the transition temperature Tc and the superfluid density ρs. The degree to which the latter is affected by disorder depends on the nature of the scattering. By contrast, Tc is only sensitive to the total elastic scattering rate (as estimated from the residual resistivity ρ0) and should follow the Abrikosov-Gor’kov pair-breaking formula. Here, we report a remarkable robustness of Tc in a set of Bi2201 single crystals to large variations in ρ0. We also survey an extended body of data, both recent and historical, on the LSCO family which challenge key predictions from dirty d-wave theory. We discuss the possible causes of these discrepancies, and argue that either we do not understand the nature of disorder in cuprates, or that the dirty d-wave scenario is not an appropriate framework. Finally, we present an alternative (non-BCS) scenario that may account for the fact that the superconducting dome in Tl2201 extends beyond that seen in Bi2201 and LSCO and suggest ways to test the validity of such a scenario.

Tailoring-compensated ferrimagnetic state and anomalous Hall effect in quaternary Mn–Ru–V–Ga Heusler compounds

Abstract Cubic Mn2Ru x Ga Heusler compound is a typical example of compensated ferrimagnet with attractive potential for high-density, ultrafast, and low-power spintronic applications. In the form of epitaxial thin films, Mn2Ru x Ga was shown to exhibit high spin polarization and high tunability of compensation temperature by freely varying the Ru content x over a broad range (0.3 &lt; x &lt; 1.0). Here, we systematically studied Mn-Ru-Ga-based polycrystalline bulk buttons prepared by arc melting and found that, in equilibrium bulk form, the cubic structure is unstable when x &lt; 0.75. To overcome this limitation, we alloyed Mn-Ru-Ga with a fourth element V. By adjusting the content of V in the Mn2Ru0.75V y Ga and Mn2.25-y Ru0.75V y Ga quaternary systems, the magnetic compensation temperature was regulated. Compensation was achieved near 300 K which was confirmed by both the magnetic and anomalous Hall effect measurements. Analyses of the anomalous Hall effect scaling in quaternary Mn-Ru-V-Ga alloys revealed the dominant role of skew scattering, notably that contributed by the thermally excited phonons, in contrast to many other 3d ferromagnets and Heusler compounds. We further showed that the Ga antisites and V content can simultaneously control the residual resistivity ratio (RRR) as well as the relative phonon and defect contribution to the anomalous Hall effect a’’/a’ in Mn-Ru-V-Ga, leading to a scaling relation a’’/a’ ∝ RRR1.8.

First-principles residual resistivity using a locally self-consistent multiple scattering method

First-principles residual resistivity using a locally self-consistent multiple scattering method

Synthesis of thin film infinite-layer nickelates by atomic hydrogen reduction: Clarifying the role of the capping layer

We present an integrated procedure for the synthesis of infinite-layer nickelates using molecular-beam epitaxy with gas-phase reduction by atomic hydrogen. We first discuss challenges in the growth and characterization of perovskite NdNiO3/SrTiO3, arising from post growth crack formation in stoichiometric films. We then detail a procedure for fully reducing NdNiO3 films to the infinite-layer phase, NdNiO2, using atomic hydrogen; the resulting films display excellent structural quality, smooth surfaces, and lower residual resistivities than films reduced by other methods. We utilize the in situ nature of this technique to investigate the role that SrTiO3 capping layers play in the reduction process, illustrating their importance in preventing the formation of secondary phases at the exposed nickelate surface. A comparative bulk- and surface-sensitive study indicates that the formation of a polycrystalline crust on the film surface serves to limit the reduction process.

Impact of local plastic deformation on thermo-magnetic instability of high-J c Nb3Sn strand

The future fusion reactor devices built by Institute of Plasma Physics, Chinese Academy of Science will be a compact burning plasma facility to fill the gap between ITER and the China Fusion Engineering Test Reactor, with the mission of studying the deuterium–tritium plasma in steady-state operation. The winding-package (WP) of its toroidal field coil is graded into high-field WP and low-field WP, and the high critical current density (J c) Nb3Sn strand will be applied to the high-field WP based on the current design. The thermo-magnetic instability is the main issue in the application of high-J c Nb3Sn strand, which may induce premature quenching in the low field regions. This issue can be improved by reducing the effective filament diameter (d eff) to suppress flux jumps and increasing the residual resistivity ratio (RRR) to enhance the release of heat generated by flux jumps. However, in the conductor manufacturing process, local plastic deformations (indentation) of strands can impact the sub-element layout and degrade the RRR of the strand, which would increase again the risk on instability. In this study, magnetization measurements and V–I tests were performed on samples with different indentation depths. The hysteresis loss and d eff of the indented sample was obtained from the test results. The impact of local plastic deformation on the thermo-magnetic instability of two types of Nb3Sn strand was confirmed by cross-sectional metallographic observation and quantitative microstructure analysis. It was shown that flux jumps were suppressed at indentation depths below 0.3 mm. Further indentation increase leads to severe flux jumps.

Crystal-chemical origins of the ultrahigh conductivity of metallic delafossites

Despite their highly anisotropic complex-oxidic nature, certain delafossite compounds (e.g., PdCoO2, PtCoO2) are the most conductive oxides known, for reasons that remain poorly understood. Their room-temperature conductivity can exceed that of Au, while their low-temperature electronic mean-free-paths reach an astonishing 20 μm. It is widely accepted that these materials must be ultrapure to achieve this, although the methods for their growth (which produce only small crystals) are not typically capable of such. Here, we report a different approach to PdCoO2 crystal growth, using chemical vapor transport methods to achieve order-of-magnitude gains in size, the highest structural qualities yet reported, and record residual resistivity ratios ( > 440). Nevertheless, detailed mass spectrometry measurements on these materials reveal that they are not ultrapure in a general sense, typically harboring 100s-of-parts-per-million impurity levels. Through quantitative crystal-chemical analyses, we resolve this apparent dichotomy, showing that the vast majority of impurities are forced to reside in the Co-O octahedral layers, leaving the conductive Pd sheets highly pure (∼1 ppm impurity concentrations). These purities are shown to be in quantitative agreement with measured residual resistivities. We thus conclude that a sublattice purification mechanism is essential to the ultrahigh low-temperature conductivity and mean-free-path of metallic delafossites.

Pressure-induced Lifshitz transition in the type-II Weyl semimetal WP2

We report evidences of a pressure-induced Lifshitz transition in the type-II Weyl semimetal WP2 via resistance, synchrotron X-ray diffraction, and Raman scattering measurements with the aid of density functional theory calculations up to 50 GPa. The resistance at 2 K and 300 K and residual resistance ratio rise precipitously at ca. 20 GPa. The pristine orthorhombic structure is robust against pressures up to 50 GPa. There occurs a discontinuity in the unit cell volume, lattice parameter, lattice parameter ratio and axial compressibility at ～20 GPa. Two Raman-active modes soften abruptly accompanied with appearance of a new Raman-active mode at ～15 GPa. Density functional theory calculations identify drastic changes in the Fermi surface topology at～30 GPa. Our findings stimulate further pursuit of pressure-induced superconductivity via a Lifshitz transition in WP2.

Anomalous Nernst effect and thermal conductivity in Co3Sn2S2 polycrystals

A polycrystalline sample of Co3Sn2S2 shandite was synthesized using spark plasma sintering for its densification. The unit cell parameters, a = 5.3688(1) Å and c = 13.1797(1) Å, refined from room temperature X-ray diffraction data, confirm the R-3m shandite structure. The frustrated nature of the Co magnetic network is invoked to explain the low effective paramagnetic moment of Co, μeff = 1.04μB/Co, whereas the ferromagnetic Curie temperature, TC = 175K, determined from T-dependent magnetic susceptibility corresponds to the metal to metal transition at that temperature. Interestingly, the residual resistivity ratio and resistivity values indicate that the electronic transport is driven by the in-plane contribution. This behaviour close to that of ab-plane transport of Co3Sn2S2 crystal fits well with the measurement of an anomalous Nernst effect (ANE). The latter reaches at T = 100K a maximum value Sxy = +1.5 μV K−1, i.e. a reduction by a factor of ≈2 as compared to crystal, explained by the reduction for the magnetization, M, of the former. This is also demonstrated by the H-dependent Sxy and M loops that match very well. Similarly, a hysteresis is found for the thermal conductivity demonstrating the existence of an anomalous thermal Hall effect of about 5 % of the total thermal conductivity. This study shows that ANE can be also measured in ceramics of Weyl ferromagnets.

Support of polaronic states and charge carrier concentrations of YBa2Cu3O7 -y ceramics by oxygen and Mn2O3 impurity.

The influence of oxygen and Mn2O3 impurity addition intervals 0.01 ≤ x ≤ 0.30 on the basic electrical conductivity, stabilization, crystallinity quality, grain boundary couplings, structural, orbital hybridization mechanisms, and superconducting properties of YBa2Cu3O7-yMnx ceramics has extensively been analyzed by electrical resistivity, X-ray diffraction investigations, and related theoretical results. It has been found that there is a strong link between the production conditions and fundamental characteristic features. All the results deduced have enabled us to discuss the variation of electron-electron and electron-phonon interactions, order parameter for super-electrons and cooper-pairs, organization of Cu-O coordination, homogeneities of oxidation states, microscopic structural problems, electronic density states, and grain boundary couplings between the adjacent layers in the YBa2Cu3O7-y ceramics. Similarly, we have discussed the change in the formation of pairing mechanisms and bipolarons in the polarizable lattices in the microdomain clusters. The results have shown that both the presence of oxygen and optimum manganese impurity of x = 0.07 led to the enhancement in the fundamental characteristic features related to the basic physical, quantum mechanical, and thermodynamics features. Thus, the material produced at the most ideal conditions has exhibited the best orthorhombic crystal structure with the distortion degree of 6.419 × 10-3, paring mechanism, and crystallinity quality due to the development of orthorhombicity and oxygen ordering degree. Namely, the addition of optimum manganese impurity has organized the Cu-O coordination and stabilized the crystal structure as much as possible. Numerically, the sample prepared with x = 0.07 Mn ions has displayed the largest crystallite size, c-axis length, residual resistivity ratio, onset, and offset critical temperatures of 10.977, 11.723 Å, 73 nm, 98.320 K, and 100.504 K, respectively. Conversely, the same material has demonstrated the smallest oxygen ordering degree of 6.714, strain of 44.015 × 10-3, and a- and b-axis lengths of 3.792 and 3.841 Å. On the other hand, the oxygen-free annealing condition and excess manganese impurity have completely damaged the whole mechanism because of the phase transition from orthorhombic to tetragonal (structural O-T transition) crystal structure. To sum up, the oxygen and optimum manganese impurity have encouraged the YBa2Cu3O7-y superconductors to use in much more application fields. RESEARCH HIGHLIGHTS: The presence of oxygen and an optimal level of Mn2O3 impurity in YBa2Cu3O7-y superconductors improved superconducting properties. The optimal level of Mn2O3 impurity promotes standard metallic characteristics. Ideal process conditions lead to the formation of super-electrons and cooper-pairs, expanding the superconducting energy gap. Optimal conditions lead to the expansion of orthorhombic distortion symmetry and average crystallite size. The excess manganese impurity results in a metal-to-insulator transition.