Fluid Residence Time Research Articles

Microbial growth within porous gravity currents

The effect of microbial activity on buoyancy-driven flow within a porous layer is analysed. The input fluid provides an energy source for the growth of biofilms on the porous rock. At each location within the porous layer, the porosity and permeability begin to decrease once the input fluid has invaded. This leads to an evolving rock heterogeneity that depends on the passing time of the input fluid. Hence, the evolution of the flow is partly controlled by its own history. We present an axisymmetric gravity current model, accounting for this effect. In general, a reduction in permeability leads to the flow having a lesser extent in the radial direction and greater thickness (extent in the cross-flow direction), whilst a reduction in porosity has negligible effect on the thickness but leads to a much greater radial extent. The flow is fastest near the free surface where the permeability is greatest. In the case where the porosity and permeability reduce as power-law functions of fluid residence time, the evolution of the flow and the rock properties are self-similar. Consumption of the input fluid by the microbes is also incorporated in the model and it generally leads to flows with lesser radial extent but little change in the thickness. The three impacts of microbial growth (volume loss owing to consumption and the reduction in permeability and porosity) each influence the flow in substantially different ways and the interplay is analysed. A motivation of the study, the underground storage of hydrogen, is briefly discussed.

Optimization of Turbulent Flow Heat Transfer in a 3D Cubic Shell Heat Exchanger using Non-Mixture Multiphase Nanofluids

The present work investigates the turbulent flow heat transfer in a three-dimensional cubic shell and tube heat exchanger employing non-mixture multiphase nanofluid, specifically SiO₂-H₂O. Computational Fluid Dynamics (CFD) simulations were carried out to study the variation of both shell and tube inlet velocities and optimize the thermal performance of the exchanger. The Reynolds-averaged Navier-Stokes (RANS) solver and the k-epsilon turbulent model were employed, and the results were validated against experimental data and numerical results from the available literature. Key results showed that reducing the tube’s Reynolds number to 75% of the shell’s inlet velocity yields the highest total heat transfer rate of 26,692 Watt, marking an impressive 54% improvement over the baseline conditions. Lowering the tube inlet velocity improved the fluid residence time leading to enhanced heat absorption and higher performance. However, reductions in either fluid Reynolds number below 75% led to diminished heat transfer rates, attributed to reduced turbulent kinetic energy and less effective thermal mixing. These findings provide valuable insights into the role of nanofluids in boosting heat transfer efficiency, offering practical implications for industries seeking to enhance energy conservation and optimize thermal systems such as air conditioning and heating systems, thermal power plants, automotive and aerospace industries, as well as solar thermal power plants.

CFD simulation of liquid-liquid extraction mechanism and enhancement schemes in microchannels based on three mass transfer models

Microreactors are highly efficient devices with a large specific surface area to improve the mass transfer efficiency. In this paper, a comprehensive three-dimensional CFD model was constructed based on three mass transfer theories to simulate the liquid-liquid two-phase flow and mass transfer process in a microchannel reactor, and two enhancement schemes were proposed. The multiphase flow and mass transfer characteristics were investigated by visualization and extraction experiments. The results indicated that the extraction efficiencies (E) and overall mass transfer coefficients (KLa) calculated by the penetration model and surface renewal model were within ±15 % errors compared to the experimental values. Moreover, E primarily increases with the increase of fluid residence time, while KLa increases with increasing flow rate. As the flow rate increases from 0.3 ml/min to 1.5 ml/min, E decreases by 15 %, and KLa rises from 0.78 s⁻¹ to 2.65 s⁻¹. Whereas the channel width decreases from 0.8 mm to 0.3 mm, E decreases by 3 %, and KLa rises from 0.44 s⁻¹ to 2.77 s⁻¹. Finally, microchannel with necked structure and baffles in mixing zone both improve the mass transfer efficient to some extent.

Antecedent Hydrologic Conditions Reflected in Stream Lithium Isotope Ratios During Storms

AbstractAntecedent hydrological conditions are recorded through the evolution of dissolved lithium isotope signatures (Li) by juxtaposing two storm events in an upland watershed subject to a Mediterranean climate. Discharge and Li are negatively correlated in both events, but mean Li ratios and associated ranges of variation are distinct between them. We apply a previously developed reactive transport model (RTM) for the site to these event‐scale flow perturbations, but observed shifts in stream Li are not reproduced. To reconcile the stability of the subsurface solute weathering profile with our observations of dynamic stream Li signatures, we couple the RTM to a distribution of fluid transit times that evolve based on storm hydrographs. The approach guides appropriate flux‐weighting of fluid from the RTM over a range of flow path lengths, or equivalently fluid residence times. This flux‐weighted RTM approach accurately reproduces dynamic storm Li‐discharge patterns distinguished by the antecedent conditions of the watershed.

The rheological behavior of aqueous magnetic fluids over a wide range of shear rates

Abstract A rheological measurement system was constructed to investigate the rheological behavior of magnetic fluids under a wide range of shear rates, and its feasibility was verified. The system is capable of measuring a shear rate range spanning five orders of magnitude, with a maximum shear rate of 106 s−1. It was utilized to study the time required for aqueous magnetic fluids in a magnetic field to reach a steady state, taking into account the coupling effect of the flow field and magnetic field. Additionally, the time needed for the magnetic fluids to return to their initial state after demagnetization was also measured. Based on these measurements, the rheological behavior of magnetic fluids with varying concentrations and magnetic field directions was studied. Results indicate that the residence time of the magnetic fluids in the magnetic field and the de-magnetization time have almost no effect on their viscosity. When the magnetic field direction is perpendicular to the flow direction, regardless of concentration, aqueous magnetic fluids exhibit shear thinning behavior; when it is parallel to the flow direction, high-concentration aqueous magnetic fluids show shear thickening, while low-concentration ones behave as Newtonian fluids. In this study’s shear rate range, no Newtonian regions were found in either high- or low-shear rate regions.

Vegetation patterns associated with nutrient availability and supply in high-elevation tropical Andean ecosystems

Abstract. Plants absorb nutrients and water through their roots and modulate soil biogeochemical cycles. The mechanisms of water and nutrient uptake by plants depend on climatic and edaphic conditions, as well as the plant root system. Soil solution is the medium in which abiotic and biotic processes exchange nutrients, and nutrient concentrations vary with the abundance of reactive minerals and fluid residence times. High-altitude ecosystems of the tropical Andes are interesting for the study of the association between vegetation, soil hydrology, and mineral nutrient availability at the landscape scale for different reasons. First of all, because of low rock-derived nutrient stocks in intensely weathered volcanic soils, biocycling of essential nutrients by plants is expected to be important for plant nutrient acquisition. Second, the ecosystem is characterized by strong spatial patterns in vegetation type and density at the landscape scale and hence is optimal to study soil-water–vegetation interactions. Third, the area is characterized by high carbon stocks but low rates of organic decomposition that might vary with soil hydrology, soil development, and geochemistry, all interconnected with vegetation. The páramo landscape forms a vegetation mosaic of bunch grasses, cushion-forming plants, and forests. In the nutrient-depleted nonallophanic Andosols, the plant rooting depth varies with drainage and soil moisture conditions. Rooting depths were shallower in seasonally waterlogged soils under cushion plants and deeper in well-drained soils under forest and tussock grasses (>100 cm). Vegetation composition is a relevant indicator of rock-derived nutrient availability in soil solutions. The soil solute chemistry revealed patterns in plant-available nutrients that were not mimicking the distribution of total rock-derived nutrients nor the exchangeable nutrient pool but clearly resulted from strong biocycling of cations and removal of nutrients from the soil by plant uptake or deep leaching. Soils under cushion plants showed solute concentrations of Ca, Mg, and Na of about 3 times higher than forest and tussock grasses. Differences were even stronger for dissolved Si with solute concentrations that were 16 times higher than forest and 6 times higher than tussock grasses. Amongst the macronutrients derived from lithogenic sources, P was a limiting nutrient with very low solute concentrations (<1 µM) for all three vegetation types. In contrast K showed greater solute concentrations under forest soils with values that were 2 to 3 times higher than under cushion-forming plants or tussock grasses. Our findings have important implications for future management of Andean páramo ecosystems where vegetation type distributions are dynamically changing as a result of warming temperatures and land use change. Such alterations may lead not only to changes in soil hydrology and solute geochemistry but also to complex changes in weathering rates and solute export downstream with effects on nutrient concentrations in Andean rivers and high-mountain lakes.

Study of Hydrodynamics and Residence Time Distribution in a Trickle Bed Reactor

This study focuses on investigating the hydrodynamics using computational fluid dynamics (CFD) simulation and residence time distribution (RTD) within a trickle bed reactor (TBR). CFD simulation was performed on a packed column filled with structured packing of glass beads, while the experiments for RTD studies were conducted in a TBR filled with random packing of Raschig rings. The geometry of TBR and size of packing during CFD simulation was kept close to that of the experimental setup. CFD simulation results were obtained which predicted the flow of fluid through the TBR at different vertical planes along the column. The fluctuations of liquid velocity at various positions inside the reactor were predicted by the CFD model. RTD studies were performed for both pulse input and step input using a non-reactive tracer such as sodium hydroxide. The flowrate of water was varied from 0.6 LPH to 6 LPH for pulse input, while for step input the ratio of water to tracer flowrates was kept at 1:1, 1:2 and 2:1. This study allows us to understand how hydrodynamics and residence time distribution may have an effect on the performance of TBR.

Isotopic and kinetic constraints on methane origins in Icelandic hydrothermal fluids

The origin of methane in hydrothermal fluids has long been a subject of debate – whether it is abiotic or biotic. In this study, we aim to unravel and quantify the sources of CH4 in active hydrothermal systems by adopting a holistic approach analyzing well characterized high-temperature hydrothermal fluids (∼230–310 °C) in Iceland. We employ a broad variety of geochemical and isotope indicators, encompassing chemical and isotope compositions of the targeted fluids. These signatures are then compared with results from chemical and isotope kinetic models and data from sedimentary-hosted hydrothermal systems. Carbon species in these fluids include CO2 (2.60–184 mmol/kg), CH4 (2.39·10−4–0.325 mmol/kg), dissolved organic carbon (4.78·10−3–0.112 mmol/kg), and CO (1.89·10−6–4.16·10−4 mmol/kg). Carbon and helium isotopes suggest a relatively uniform mantle-derived source of CO2 (δ13C-CO2: −4.80 to −1.50 ‰, CO2/3He: 1.49·109–4.14·1010 14C-CO2: 0.11–2.42 pMC). Methane, in contrast, has multiple sources. Overall, chemical equilibria among carbon species (CO2, CH4, CO) is not attained, suggesting kinetic controls. Tritium content (<0.8–1.42 TU) and hydrologic constraints indicate relatively short hydrothermal fluid residence times (∼5–200 years), with occasional inputs from older water components. Within this short timeframe, CH4 concentrations vary from lower, to significantly higher than those calculated using CO2 reduction kinetics. The isotope composition (δD-CH4: −172 to −138 ‰, δ13C-CH4: −32.0 to −24.6 ‰; 14C-CH4: 0.36–11.54 pMC) and geochemical and isotope modeling suggest that the majority (>80–90 %) of CH4 originates from a radiocarbon inactive source, i.e. mantle CH4, reduction of mantle CO2 and/or old organic matter, with relatively small contributions from both marine (<20 %) and terrestrial (<10 %) dissolved organic carbon. Measured isotopic compositions of CH4 do not match those expected for mantle-derived CH4 as well as values generated from reduction of mantle-derived CO2. Instead, differences in δD-CH4 and δ13C-CH4 values exist between systems fed by meteoric water and those fed by seawater, challenging the assumption of a uniform CO2 source and invariable reaction mechanisms. Differences between systems are best explained by variable extent of thermal decomposition and primary variations in the isotope composition of marine and terrestrial organic matter. Also, δD-CH4 and δ13C-CH4 values in meteoric water-fed systems closely resemble those in the Öxarfjördur sedimentary-hosted systems. In summary, our data supports a predominant thermogenic origin of CH4 in both seawater and terrestrial hydrothermal fluids in Iceland. The source of organic matter appears to be a combination of modern dissolved organic carbon and older sedimentary deposits. In addition, some of the hydrothermal systems studied (Krafla, Reykjanes, Theistareykir) which are characterized by low CH4 concentrations, may contain a significant portion of CH4 that may originate from CO2 reduction.

Fast electrokinetic mixing in microflows with different electrical conductivities

This work provides a novel three-dimensional numerical analysis of electrokinetic mixing in microflows with different electrical conductivities. Our study examines ferrofluid and water co-flow mixing quantitatively, which has been overlooked in previous micromixers based on electrokinetic instabilities. This has become possible by considering the actual diffusivity of ferrofluid. The findings reveal that thinner channels exhibit stronger suppression of instability due to the pronounced effect of walls on the flow, emphasizing the importance of 3D simulation for shallow channels. Additionally, increasing the electric field intensity was found to have dual opposing effects on instabilities and electrolyte mixing. It enhances the body force and instabilities, improving mixing, but also accelerates flow velocity, reducing fluid residence time and leading to weaker mixing of the flows. A notable observation was a decrease in the mixing index with the augmentation of electric field intensity; for a channel with H = 200 µm, the mixing index reduced by approximately 13% when the electric field strength was increased from 179 to 210 V/cm.

A paradigm shift for biocatalytic microreactors: Decoupling application from reactor design

Microreactors have been successfully applied to execute a broad range of biotransformations in flow. However, microreactors have typically been designed with a specific biotransformation or a specific biocatalyst immobilization method in mind, constraining their wider applicability. Furthermore, their design is typically either applicable for whole-cell or for enzyme biocatalysis, but not for both. We present a novel microreactor design which offers cartridge-like insertion of both immobilised enzymes and cells. A T-shaped lid opens and closes the reaction chamber (whilst leaving the rest of the microreactor unchanged), enables the easy insertion of immobilised biocatalysts, and thus allows the user to configure different reactor types. We demonstrated this novel concept showing three different reactor types: a hydrogel microreactor containing entrapped E. coli cells overexpressing transketolase (volumetric productivity of 2.23 ± 0.83 mmoll-ERY Lvoid1 min1), a packed-bed microreactor containing commercial beads with immobilised Candida antarctica lipase B (volumetric productivity of 317.69 ± 96.74 mmolBB Lvoid1 min1), and a micropillar microreactor containing surface-immobilised ω-transaminase (volumetric productivity of 0.08 ± 0.02 mmolACP Lvoid1 min1). The proposed design showed consistency and robustness for 10 consecutive T-shaped lid ‘open and close’ cycles and withstood the pressure of at least 4 bar. Design analysis further included Computational Fluid Dynamics models and Residence Time Distribution measurements. The presented design offers a standardised approach for multiple applications, underpinning process development and paving the way for off-the-shelf microreactor technology for biocatalysis.

New horizons on advanced nanoscale materials for Cultural Heritage conservation.

Nanomaterials have permeated numerous scientific and technological fields, and have gained growing importance over the past decades also in the preservation of Cultural Heritage. After a critical overview of the main nanomaterials adopted in art preservation, we provide new insights into some highly relevant gels, which constitute valuable tools to selectively remove dirt or other unwanted layers from the surface of works of art. In particular, the recent "twin-chain" gels, obtained by phase separation of two different PVAs and freeze-thawing, were considered as the most performing gel systems for the cleaning of Cultural Heritage. Three factors are crucial in determining the final gel properties, i.e., pore size, pore connectivity, and surface roughness, which belong to the micro/nanodomain. The pore size is affected by the molecular weight of the phase-separating PVA polymer, while pore connectivity and tortuosity likely depend on interconnections formed during gelation. Tortuosity greatly impacts on cleaning capability, as the removal of matter at the gel-target interface increases with the uploaded fluid's residence time at the interface (higher tortuosity produces longer residence). The gels' surface roughness, adaptability and stickiness can also be controlled by modulating the porogen amount or adding different polymers to PVA. Finally, PVA can be partially replaced with different biopolymers yielding gels with enhanced sustainability and effective cleaning capability, where the selection of the biopolymer affects the gel porosity and effectiveness. These results shed new light on the effect of micro/nanoscale features on the cleaning performances of "twin-chain" and composite gels, opening new horizons for advanced and "green"/sustainable gel materials that can impact on fields even beyond art preservation, like drug-delivery, detergency, food industry, cosmetics and tissue engineering.

Achieving high flame stability with low NO And Zero N2O and NH3 emissions during liquid ammonia spray combustion with gas turbine combustors

Liquid ammonia spray direct injection is more desirable than gaseous ammonia injection in large scale gas turbine combustors because it enables a larger volumetric energy density and allows a reduction in cost and size of the fuel supply system. However, previous studies have shown that the large evaporative cooling effects of liquid ammonia droplets vaporization impair flame stabilization, and inhibit efficient control of emissions such as NO, N2O and unburned fuels. This article reports the development and testing of a novel two-stage gas turbine combustor for pure liquid ammonia spray, which achieves approximately zero N2O and unburned fuel emissions with NO emissions as low as 282 ppmv (@16% O2) in a 50 kW micro gas turbine combustor test rig. The combustor design focused on optimization of the secondary injection holes to prevent the dilution of the primary zone (PZ) by air injected into the secondary zone; improving mixture formation using a multi-nozzle twin-fluid atomizer; and elongation of the combustor length to allow sufficient fluid residence time for N2O reduction as well as droplets vaporization and combustion. It was found that the mitigation of PZ dilution resulted in a significant increase in the combustion temperature thereby encouraging efficient combustion of the liquid droplets. On the other hand, the multi-nozzle twin fluid atomizer resulted in a more uniform combustor wall temperature, a more efficient combustion and lower NOx emissions than a single-nozzle pressure swirl atomizer. It is considered that the multi-nozzle injector allowed for an improved droplets dispersion, which is necessary to mitigate large local heat extraction from the flame. These features of the combustor enabled a substantial improvement in liquid ammonia spray flame stability and a better simultaneous control of NO, N2O and unburned fuel emissions never reported before.

Emergence of Unstable Focused Flow Induced by Variable‐Density Flows in Vertical Fractures

AbstractFluids with different densities often coexist in subsurface fractures and lead to variable‐density flows that control subsurface processes such as seawater intrusion, contaminant transport, and geologic carbon sequestration. In nature, fractures have dip angles relative to gravity, and density effects are maximized in vertical fractures. However, most studies on flow and transport through fractures are often limited to horizontal fractures. Here, we study the mixing and transport of variable‐density fluids in vertical fractures by combining three‐dimensional (3D) pore‐scale numerical simulations and visual laboratory experiments. Two miscible fluids with different densities are injected through two inlets at the bottom of a fracture and exit from an outlet at the top of the fracture. Laboratory experiments show the emergence of an unstable focused flow path, which we term a “runlet.” We successfully reproduce the unstable runlet using 3D numerical simulations and elucidate the underlying mechanisms triggering the runlet. Dimensionless number analysis shows that the runlet instability arises due to the Rayleigh‐Taylor instability (RTI), and flow topology analysis is applied to identify 3D vortices that are caused by the RTI. Even under laminar flow regimes, fluid inertia is shown to control the runlet instability by affecting the size and movement of vortices. Finally, we confirm the emergence of a runlet in rough‐walled fractures. Since a runlet dramatically affects fluid distribution, residence time, and mixing, the findings in this study have direct implications for the management of groundwater resources and subsurface applications.

Experimental investigations on heat transfer enhancement in a double pipe heat exchanger using hybrid nanofluids

Abstract Heat exchanger (HE) is an instrument that facilitates the operation of HE between two fluids that are at various temperatures. Double-pipe HEs are used in many organizations because of their low installation, design, maintenance costs, flexibility, and their suitability for high pressure applications. Heat transfer (HT) augmentation techniques (passive, active or compound techniques) are used in heat exchangers to reduce the HT surface area, to increase HT capacity and to reduce pumping power. Passive augmentation techniques are much cheaper and do not involve any external power input. They aim to improve the effective surface area, the residence time of the HT fluid and its thermal conductivity by the usage of nanofluids. Nanofluids are used for cooling applications in organizations, transportation, nuclear reactors, electrical and electronic devices and for biomedical applications. Hybrid nanofluids have higher thermal conductivity, low PD and frictional losses and pumping power as compared to the mono nanofluids. In this present work, experiments are conducted in a double pipe HE using TiO2, and SiC-water nanofluids by varying the volume concentration and cold fluid mass flow rate ranging from 17.5 to 34.5 lpm by making constant hot fluid mass flow rate. Further, experiments are conducted using TiO2–SiC/water hybrid nanofluids. Influence of nano and hybrid nanofluids on the overall HTC and friction factor are experimentally investigated. From the experiments, TiO2–SiC/water hybrid nanofluid with nanoparticle ratio TiO2:SiC = 1:2 is found to be optimum as the heat transfer enhancement is more with less improvement in friction factor. The overall heat transfer, and friction factor enhancement is 22.92 %, and 11.20 % higher respectively when compared with base fluid for TiO2:SiC = 1:2.

The low permeability of the Earth’s Precambrian crust

The large volume of deep groundwater in the Precambrian crust has only recently been understood to be relatively hydrogeologically isolated from the rest of the hydrologic cycle. The paucity of permeability measurements in Precambrian crust below 1.3 km is a barrier to modeling fluid flow and solute transport in these low porosity and permeability deep environments. Whether permeability-depth relationships derived from measurements shallower than 1.3 km can be extended to greater depths in unclear. Similarly, application of a widely-used permeability-depth relationship from prograde metamorphic and geothermal systems to deep Precambrian rocks may not be appropriate. Here, we constrain permeabilities for Precambrian crust to depths of 3.3 km based on fluid residence times estimated from noble gas analyses. Our analysis shows no statistically significant relationship between permeability and depth where only samples below 1 km are considered, challenging previous assumptions of exponential decay. Additionally, we show that estimated permeabilities at depths >1 km are at least an order of magnitude lower than some previous estimates and possibly much lower. As a consequence, water and solute fluxes at these depths will be extremely limited, imposing important controls on elemental cycling, distribution of subsurface microbial life and connections with the near-surface water cycle.

Investigation of residence time and fluid volume in spiral concentrators

The iron ore industry is flowing in northern Quebec with spirals as the leading concentrator equipment for which the understanding still needs to be improved. In general, the feed slurry throughput is thought to influence the spiral performance, although experimental evidence of that assumption is still lacking. A possible explanation for the difficulty of making an obvious assessment of the effect of the spiral feed rate may lie in a possible invariability of the residence time of the slurry in the spiral trough. The results of three tracer tests conducted on a WW6Plus Mineral Technologies spiral show that the fluid remains for approximately 7.5 s in the spiral trough and that this period is independent of the spiral feed rate. Direct measurements of the volume of liquid in the spiral trough confirmed the previous tracer results and showed that the volume of fluid retained in the spiral increases proportionally to the spiral volumetric feed rate. These tests point towards confirming the invariability of the fluid residence time in spirals.

Process intensification in the extraction of Mn from spent Li-ion battery simulated leachate via (G1/W+G2)/O microdispersion system with phase inversion

Recycling valuable metals from spent Li-ion batteries effectively alleviates the shortage of metal resources as well as avoids harm to human health and ecological environment. In this study, D2EHPA/TBP/sulfonated kerosene was selected as the extractant to conduct the process intensification in the reactive extraction of Mn. Five different methods with stepwise intensified mass transfer were designed to prepare liquid/liquid, gas/liquid/liquid and gas/liquid/gas/liquid systems, respectively. Effects of the dispersion method, fluid flow rates and residence time on the mass transfer performance were systematically investigated. The optimal structure and its efficient operating interval for process intensification were recommended, in which the Murphree efficiency of Mn reached 95.3% at the outlet of the dispersion module and reached 99.2% within a contacting volume of 2.12 mL, while was only 35–45% within 21.36 mL in the millimeter-dispersed emulsion system. The intensification fundamentals were discussed, via calculating the mass transfer coefficients and establishing corresponding mathematical models. This study provided simple and effective methods for process intensification of reactive extraction with viscous extractants in recycling valuable metals from spent Li-ion batteries.

Experimental performance evaluation of a solar parabolic dish collector using spiral flow path receiver

The solar receiver design plays a crucial role in the performance and efficiency of a parabolic dish solar collector. This experimental study examines a finned spiral flow path receiver in a 16 m2 parabolic dish collector to enhance heat transfer from the receiver surface to the heat transfer fluid. The solar receiver is evaluated outdoors at water flow rates of 0.04 kg/s, 0.05 kg/s, 0.06 kg/s, and 0.12 kg/s. At water flow rates of 0.04 kg/s, 0.05 kg/s, and 0.06 kg/s, the receiver's average energy efficiency was 31.27 %, 44.34 %, and 50.69 %, respectively. At water flow rates of 0.12 kg/s, the peak energy and exergy efficiency are around 65.81 % and 6.85 %, respectively. The proposed solar receiver shows an increased heat transfer coefficient from the receiver surface to the fluid with more fluid residence time due to the spiral flow path and fins. The economic evaluation demonstrates that the solar receiver with a flow rate of 0.12 kg/s produces the most significant economic outcomes compared to other selected water flow rates. The proposed solar receiver's estimated levelized cost of energy, net present value, benefit-to-cost ratio, and payback period values are 0.18 ($/kWh), 925.61 $, 8.40 and 1.62 years. Thus, the finned spiral flow path receiver with a flow rate of 0.12 kg/s produces optimal performance among the selected water flow rates. The significant results benefit the solar community in designing an effective finned solar receiver for concentrated solar collectors.

Numerical Evaluation of Novel Curved Rib Turbulators for Thermal Performance Improvement in Circular Geometries

Internal heating/cooling using roughness elements such as ribs are a promising passive heat-transfer enhancement technique for many thermal applications. The curved ribs are roughness elements that boost the fluid residence time and enhance the thermal-hydraulic performance of the system. In the present study, curved ribs of different cross-sections were fitted at the inner wall of the circular tube to intensify convection heat transfer to the fluid flowing through it. Novel curved ribs of inline configurations of different shapes and geometrical parameters were numerically studied for convection heat transfer using a three-dimensional computational model. The finite volume method discretizes the tube fluid flow domain’s mass, momentum, and energy equations. The local heat transfer enhancement over the tube surface is 2.75 times the smooth tube flow, with Reynolds numbers ranging from 10,000 to 50,000. The cost-effectiveness of this heat transfer enhancement method was quantified using a thermohydraulic performance evaluation factor. This factor accounts for the increased heat transfer at the same pumping power and the same available surface area for heat dissipation. The average heat transfer enhancement at the same Reynolds number and pumping power was found to be 120% to 450% and 98% to 260% of the smooth tube flow.

Hydrogeochronology: Resetting the timestamp for subsurface groundwaters

Waters recharging the subsurface contain a variety of naturally occurring geochemical components, the concentrations of which are principally a function of the atmosphere and surface environment. Over time, water-rock interactions and radiogenic processes in the subsurface control a complex geochemical evolution, impacting the initial surface-related signatures associated with recharged groundwaters. The rates of these geochemical changes are considerable in many important geologic settings, requiring characterisation and quantification of the dominant subsurface processes and evolving fluid characteristics. Constraining this is critically important for the discipline of fluid ‘age’ dating - hydrogeochronology. Age dating, or quantification of fluid residence times is typically evaluated through two categories of tracers; those that are incorporated at the point of recharge and decrease over time through radioactive decay (e.g. 3H, 14C, 81Kr) and those that increase over time (e.g. radiogenic noble gases) due to subsurface production and accumulation in fluids. As these fluids, elements, and tracers have different provenance, the calculated ‘age’ of any fluid represents the average, or mean residence time, of all components. Likewise, additional mechanisms of subsurface tracer production or loss can have significant bearing on any element-specific calculated residence times. The inevitable temporal discrepancies between tracers can be generated or accentuated in the subsurface which can prove difficult to reconcile in hydrogeochronologic modelling approaches.By incorporating geochemical data into existing neutron flux-based models, this study evaluates specifically how subsurface production of ‘diminishing’ tracers in the fluid phase, via neutron capture of parent elements, can produce complexity in the dating of host fluids. The in situ rates and production routes of 3H, 14C, 36Cl 39Ar, and 81Kr in different subsurface fluids are modelled for a variety of host rock lithologies to evaluate the effect such baseline crustal production in different geochemical settings may have on calculated residence times within naturally occurring systems. In particular this model provides a quantitative evaluation for how site-specific subsurface radiogeochemistry may result in enhanced baselines of 36Cl, 39Ar, (and potentially 14C) relative to canonical assumptions, and substantially impact residence time estimates calculated from these tracers for a range of subsurface environments. Additionally, we evaluate the role geologic environments can have on low levels of baseline production and calculated residence times for 3H and 81Kr. This study quantitatively evaluates the dependence of geologic environments on these subsurface processes and the impacts this may have on hydrogeochronologic studies. The ability to quantify production of tracers in the subsurface and recalibrate associated residence times in a wide range of geologic settings is of direct relevance to areas such as groundwater resource management, Carbon Capture and Storage, hydrogen storage and nuclear waste management strategies, the hydrocarbon and energy industry, and investigations of the timing and evolution of subsurface microbial life.