Based on small-world network theory, we have developed a brain-inspired photonic reservoir computing (RC) network system utilizing quantum dot spin-vertical-cavity surface-emitting lasers (QD spin-VCSELs) and formulated a comprehensive theoretical model for it. This innovative network system comprises input layers, a reservoir network layer, and output layers. The reservoir network layer features four distinct reservoir modules that are asymmetrically coupled. Each module is represented by a QD spin-VCSEL, characterized by optical feedback and optical injection. Within these modules, four chaotic polarization components, emitted from both the ground and excited states of the QD Spin-VCSEL, form four distinct reservoirs through a process of asymmetric coupling. Moreover, these components, when emitted by the ground and excited states of a driving QD spin-VCSEL within a specific parameter space, act as targets for prediction. Delving further, we investigated the correlation between various system parameters, such as the sampling period, the interval between virtual nodes, the strengths of optical injection and feedback, frequency detuning, and the predictive accuracy of each module’s four photonic RCs concerning the four designated predictive targets. We also examined how these parameters influence the memory storage capabilities of the four photonics RCs within each module. Our findings indicate that when a module receives coupling injections from more than two other modules, and an RC within this module is also subject to coupling injections from over two other RCs, the system displays reduced predictive errors and enhanced memory storage capacities when the system parameters are fixed. Namely, the superior performance of the reservoir module in predictive accuracy and memory capacities follows from its complex interaction with multiple light injections and coupling injections, with its three various PCs benefiting from three, two, and one coupling injections respectively. Conversely, variations in optical injection and feedback strength, as well as frequency detuning, introduce only marginal fluctuations in the predictive errors across the four photonics RCs within each module and exert minimal impact on the memory storage capacity of individual photonics RCs within the modules. Our investigated results contribute to the development of photonic reservoir computing towards fast response biological neural networks.