Relative Transport Efficiency Research Articles

Evaluation of the Efficiency of Maritime Transport Using a Network Slacks-Based Measure (SBM) Approach: A Case Study on the Korean Coastal Ferry Market

Safety is a key performance indicator for the sustainable management of a coastal ferry service business. An efficiency strategy that balances safety and transport performance should be considered. The purpose of this study is to evaluate the relative transport efficiency of coastal ferry operators through undesirable safety-related output. Coastal ferry operators create added value through logistics activities such as cargo and passenger transport. Accordingly, this study designed a three-stage network-slacks-based measure (SBM) model that delineated production through ferry transport services such as service generation, service execution, and transport value creation. Detention records and marine accidents caused by human errors or technical faults were considered undesirable safety-related outputs. Moreover, the relative transport efficiency of 23 Korean firms that have continuously managed a coastal ferry transport business from 2015 to 2018 was analyzed. The results showed that the differentiation of transport efficiency of firms improved when applying the three-stage network SBM model compared to applying the SBM model that did not consider the internal production stage. This fact suggests that it is more desirable to apply the three-stage network SBM model proposed in this study when a more stringent comparison of transport performance is needed in terms of service quality.

New Anionophores and Insights into Ion-Transport-Induced Cancer Cell Death

In this issue of Chem, Pellois, Gabbai, and colleagues introduce pnictogenium cations as useful transmembrane anion transporters, and Gale, Sessler, Injae, and co-workers provide insights into the cellular mechanism elicited by some of these compounds, leading to the induction of apoptosis in cancer cells.

On the variability of the Priestley‐Taylor coefficient over water bodies

AbstractDeviations in the Priestley‐Taylor (PT) coefficient αPT from its accepted 1.26 value are analyzed over large lakes, reservoirs, and wetlands where stomatal or soil controls are minimal or absent. The data sets feature wide variations in water body sizes and climatic conditions. Neither surface temperature nor sensible heat flux variations alone, which proved successful in characterizing αPT variations over some crops, explain measured deviations in αPT over water. It is shown that the relative transport efficiency of turbulent heat and water vapor is key to explaining variations in αPT over water surfaces, thereby offering a new perspective over the concept of minimal advection or entrainment introduced by PT. Methods that allow the determination of αPT based on low‐frequency sampling (i.e., 0.1 Hz) are then developed and tested, which are usable with standard meteorological sensors that filter some but not all turbulent fluctuations. Using approximations to the Gram determinant inequality, the relative transport efficiency is derived as a function of the correlation coefficient between temperature and water vapor concentration fluctuations (RTq). The proposed approach reasonably explains the measured deviations from the conventional αPT = 1.26 value even when RTq is determined from air temperature and water vapor concentration time series that are Gaussian‐filtered and subsampled to a cutoff frequency of 0.1 Hz. Because over water bodies, RTq deviations from unity are often associated with advection and/or entrainment, linkages between αPT and RTq offer both a diagnostic approach to assess their significance and a prognostic approach to correct the 1.26 value when using routine meteorological measurements of temperature and humidity.

Quantifying the Influence of Random Errors in Turbulence Measurements on Scalar Similarity in the Atmospheric Surface Layer

The influence of random errors in turbulence measurements on scalar similarity for temperature, water vapour, \(\hbox {CO}_{2}\), and \(\hbox {NH}_{3}\) is investigated using two eddy-covariance datasets collected over a lake and a cattle feedlot. Three measures of scalar similarity, namely, the similarity constant in the flux–variance relationship, the correlation coefficient between two scalars and the relative transport efficiency, are examined. The uncertainty in the similarity constant \(C_{s}\) in the flux–variance relationship resulting from random errors in turbulence measurements is quantified based on error propagation analyses and a Monte-Carlo sampling method, which yields a distribution instead of a single value for \(C_{s}\). For different scalars, the distributions of \(C_{s}\) are found to significantly overlap, implying that scalars are transported similarly under strongly unstable conditions. The random errors in the correlation coefficients between scalars and the relative transport efficiencies are also quantified through error propagation analyses, and they increase as the atmosphere departs from neutral conditions. Furthermore, the correlation coefficients between three scalars (water vapour, \(\hbox {CO}_{2}\), and \(\hbox {NH}_{3}\)) are statistically different from unity while the relative transport efficiencies are not, which highlights the difference between these two measures of scalar similarity. The results suggest that uncertainties in these measures of scalar similarity need to be quantified when using them to diagnose the existence of dissimilarity among different scalars.

On the Temperature and Humidity Dissimilarity in the Marine Surface Layer

The dissimilarity of temperature and humidity transfer in the marine surface layer (MSL) is investigated through the relative transport efficiency and correlation coefficient of these two scalars. We examine their variability and relationship with mean values, as well as spectral characteristics. It is shown that the dissimilarity between these two scalars in the MSL is a function of stability, the boundary-layer depth, and flow steadiness. In general the temperature and humidity are less correlated in shallow marine boundary layers compared to deep marine boundary layers, due to the stronger impact of the boundary-layer scale in breaking the “same source, same sink” assumption for scalar similarity. This is supported by the combination of our spectral analysis of scalar fluxes and corresponding measured and modelled boundary-layer depth. This assumption is also broken in near-neutral conditions, when there is an efficient latent heat transfer but negligible sensible heat transfer. Our data suggest that parametrization of humidity fluxes via similarity theory could still be reliable when the correlation coefficient \(>\)0.5, and in near-neutral conditions the humidity flux can be estimated without use of the sensible heat flux.

Estimation of turbulent fluxes using the flux-variance method over an alpine meadow surface in the eastern Tibetan Plateau

The flux-variance similarity relation and the vertical transfer of scalars exhibit dissimilarity over different types of surfaces, resulting in different parameterization approaches of relative transport efficiency among scalars to estimate turbulent fluxes using the flux-variance method. We investigated these issues using eddycovariance measurements over an open, homogeneous and flat grassland in the eastern Tibetan Plateau in summer under intermediate hydrological conditions during rainy season. In unstable conditions, the temperature, water vapor, and CO2 followed the flux-variance similarity relation, but did not show in precisely the same way due to different roles (active or passive) of these scalars. Similarity constants of temperature, water vapor and CO2 were found to be 1.12, 1.19 and 1.17, respectively. Heat transportation was more efficient than water vapor and CO2. Based on the estimated sensible heat flux, five parameterization methods of relative transport efficiency of heat to water vapor and CO2 were examined to estimate latent heat and CO2 fluxes. The strategy of local determination of flux-variance similarity relation is recommended for the estimation of latent heat and CO2 fluxes. This approach is better for representing the averaged relative transport efficiency, and technically easier to apply, compared to other more complex ones.

Flux-Variance Method for Latent Heat and Carbon Dioxide Fluxes in Unstable Conditions

Applied previously to momentum and heat fluxes, the present study extends the flux-variance method to latent heat and CO2 fluxes in unstable conditions. Scalar similarity is also examined among temperature (θ), water vapour (q), and CO2 (c). Temperature is adopted as the reference scalar, leading to two feasible strategies to estimate latent heat and CO2 fluxes: the first one relies on flux-variance similarity relations for scalars, while the second is based on the parameterization of relative transport efficiency in terms of scalar correlation coefficient and a non-dimensional quantity. The relationship between the θ-to-q transport efficiency (λ θ q ) and θ-q correlation coefficient (R θ q ) is used to describe the intermediate hydrological conditions. We also parameterize the θ-to-c transport efficiency (λ θ c ) as a function of the θ-c correlation coefficient (R θ c ) by introducing a new non-dimensional ratio (α). The flux-variance method is a viable technique for flux gap-filling, when turbulence measurements of wind velocity are not available. It is worth noting that the extended method is not exempt from a correction for density effects when used for estimating water or carbon exchange.

The Effect of Surface Heterogeneity on the Temperature–Humidity Correlation and the Relative Transport Efficiency

We derive a conceptual model of the flow over heterogeneous terrain consisting of patches with contrasting Bowen ratios. Upward moving eddies are assumed to carry heterogeneous properties, whereas downward moving eddies carry homogeneous properties. This results in a decorrelation of temperature and humidity as the contrast between the patches increases. We show that this model is able to reproduce the relationship developed by Lamaud and Irvine (Boundary-Layer Meteorol. 120:87–109, 2006). Some details differ from their expression but are in accordance with data obtained over African savannah. We extend the conceptual model to a combination of any scalars, not necessarily linked through the surface energy balance (as is the case for temperature and humidity). To this end we introduce a new parameter that describes the surface heterogeneity in surface fluxes. The results of the current model can be used to predict the discrepancy between similarity relationships for different scalars over heterogeneous terrain.

On the Anomalous Behaviour of Scalar Flux–Variance Similarity Functions Within the Canopy Sub-layer of a Dense Alpine Forest

Within the canopy sub-layer (CSL), variability in scalar sources and sinks are known to affect flux–variance (FV) similarity relationships for water vapour (q) and carbon dioxide (C) concentrations, yet large-scale processes may continue to play a significant role. High frequency time series data for temperature (T), q and C, collected within the CSL of an uneven-aged mixed coniferous forest in Lavarone, Italy, are used to investigate these processes within the context of FV similarity. This dataset suggests that MOST scaling describes the FV similarity function of T even though the observations are collected in the CSL, consistent with other studies. However, the measured FV similarity functions for q and C appear to have higher values than their temperature counterpart. Two hypotheses are proposed to explain the measured anomalous behaviour in the FV similarity functions for q and C when referenced to T. Respired CO2 from the forest floor leads to large positive excursions in the C time series at the canopy top thereby contributing significantly to both C variance increase and C vertical flux decrease—both leading to an anomalous increase in the FV similarity function. For q, transport of dry air from the outer-layer significantly increases both the variance and the water vapour flux. However, the expected flux increase is much smaller than the variance increase so that the net effect remains an increase in the measured FV similarity function for water vapour above its T counterpart. The hypothesis here is that identifying these events in the temporal and/or in the frequency domain and filtering them from the C and q time series partially recovers a scalar flow field that appears to follow FV similarity theory scaling. Methods for identifying both types of events in the time and frequency domains and their subsequent effects on the FV similarity functions and corollary flow variables, such as the relative transport efficiencies, are also explored.

Evaporation from three water bodies of different sizes and climates: Measurements and scaling analysis

Evaporation from small reservoirs, wetlands, and lakes continues to be a theoretical and practical problem in surface hydrology and micrometeorology because atmospheric flows above such systems can rarely be approximated as stationary and planar-homogeneous with no mean subsidence (hereafter referred to as idealized flow state). Here, the turbulence statistics of temperature ( T) and water vapor ( q) most pertinent to lake evaporation measurements over three water bodies differing in climate, thermal inertia and degree of advective conditions are explored. The three systems included Lac Léman in Switzerland (high thermal inertia, near homogeneous conditions with no appreciable advection due to long upwind fetch), Eshkol reservoir in Israel (intermediate thermal inertia, frequent strong advective conditions) and Tilopozo wetland in Chile (low thermal inertia, frequent but moderate advection). The data analysis focused on how similarity constants for the flux-variance approach, C T / C q , and relative transport efficiencies R wT / R wq , are perturbed from unity with increased advection or the active role of temperature. When advection is small and thermal inertia is large, C T / C q < 1 (or R wT / R wq > 1) primarily due to the active role of temperature, which is consistent with a large number of studies conducted over bare soil and vegetated surfaces. However, when advection is significantly large, then C T / C q > 1 (or R wT / R wq < 1). When advection is moderate and thermal inertia is low, then C T / C q ∼ 1. This latter equality, while consistent with Monin–Obukhov similarity theory (MOST), is due to the fact that advection tends to increase C T / C q above unity while the active role of temperature tends to decrease C T / C q below unity. A simplified scaling analysis derived from the scalar variance budget equation, explained qualitatively how advection could perturb MOST scaling (assumed to represent the idealized flow state).

Silacrown ionophores

A study is reported on the metal ion transport efficiency of various silacrown ether ionophores and their ethyleneoxy glycol hydrolysis products. The silacrowns are modified crown ethers in which an ethylene bridge has been replaced by a difunctional silyl group, e.g. dimethylsilyl. We have studied the relative transport efficiencies of the silacrowns with 4, 5, 6 and 7 oxygen atoms in the macrocycle for the alkali metals ions Li +, Na +, K +, Rb +, and Cs +. We have also performed experiments which illustrate that the silacrowns behave as short-term ion transporters. They will slowly hydrolyse in hydrophobic environments in contact with water to yield ethyleneoxy glycols which partition out of the hydrophobic phase into the hydrophilic phase, This terminates significant transport since the glycols are relatively inefficient ionophores. The potential of such shortterm ionophores is discussed.

Yield of deep spallation products of medium to heavy mass targets bombarded with 480 MeV protons

Absolute cross sections for short-lived alpha emitting, very neutron deficient nucleides resulting from the interaction of 480 MeV protons with several medium mass targets (Ho, Tm, Re, Ta, Au) have been measured at the TRIUMF facility (Vancouver, Canada). Activities were transported using a gas jet system and relative transport efficiencies for products of various Z were measured. Calculations for the production of such deep spallation products were performed using the empirical Silberberg–Tsao method and the more fundamental, intranuclear cascade – evaporation model, and compared against the observed values.