In this paper, a model for effective thermal conductivity of high porosity open-cell metal foams is developed by assuming the foam morphology as 3D tetradecahedron structure. The effective thermal conductivity of metal foams is first studied using the numerical simulation method, which the geometrical model (the ratio of the edge length of node to the radius of ligament) is calibrated with the experimental data. The geometrical model is divided into four distinctive layers along the heat transfer direction. The effective thermal conductivity of four layers is then determined by fitting the numerical results. Consequently, the model for effective thermal conductivity of metal foams is proposed based on the Fourier law. Several other analytical models and the experimental data are used to verify the effectiveness of the present model. The results show that the present model can be satisfactorily accurate to calculate the effective thermal conductivity of metal foam by considering the ratio of the edge length of node to the radius of ligament as a second order polynomial function of the porosity. The effective thermal conductivity of each layer is related to the porosity of each layer and overall porosity of metal foam. Compared with the experimental data, the present model has high accuracy with relative RMS deviation of less than 10%. The finding of this study can help guide the thermal design of porous media.