Refined, Bleached And Deodorized Palm Oil Research Articles

Adsorption of 3‐monochloropropane‐1,2‐diol ester and glycidyl ester from refined bleached deodorized palm oil using zeolite‐based adsorbents

AbstractPalm oil processing can result in different food products like cooking oil and margarine. Nevertheless, these food products might contain harmful contaminants, namely 3‐monochloropropane‐1,2‐diol ester (3‐MCPDE) and glycidyl ester (GE), which can negatively affect animal organs and potentially cause human cancer. Therefore, the objective of this study was to lower the concentration of 3‐MCPDE and GE in refined, bleached, and deodorized palm oil (RBDPO) using zeolite as an adsorbent. Adsorption experiments were conducted in a batch reactor, varying the percentage of adsorbents, temperature, type of zeolite, and the use of a mixture of zeolite and activated carbon (AC). The sample was analyzed before and after adsorption using gas chromatography–mass spectroscopy (GC–MS) to confirm the concentration alteration of 3‐MCPDE and GE. The study showed that the most effective temperature for adsorption was 35°C and used a zeolite percentage of 2%. Beta zeolites resulted in the highest removal of 3‐MCPDE (86%) among the evaluated zeolites attributed to their elevated pore volume, Si/Al ratio, and overall acidity strength. Through a synergistic combination of beta zeolite and AC, the removal percentage of 3‐MCPDE was enhanced to 94%, with a corresponding 75% reduction in GE. This study paves the way for addressing 3‐MCPDE and GE concerns in RBDPO by combining zeolite and AC.

Impact of low molecular weight acid and moisture on the thermal ageing properties of palm oil

<span>This study examines the effect of low molecular weight acid (LMA), moisture and oxygen on the thermal ageing characteristics of refined, bleached, and deodorised palm oil (RBDPO). The paper moisture was varied between 0.5% and 3.5%. The oil was initially subjected to 0.2 g of LMA and 20 mbar of oxygen pressure. The thermal ageing experiment was performed at 120 °C and 140 °C for 28 days. Several dielectric and physiochemical parameters were measured which included dielectric dissipation factor, relative permittivity, resistivity, moisture in oil, acidity, and thermogravimetric analysis (TGA). It is found that LMA and moisture in paper do not affect the <span>relative permittivity of RBDPO and mineral oil (MO). The dielectric dissipation factor of RBDPO and MO reveals slight increment trends within the ageing time. The decrements of resistivities occur after 7 days of ageing</span> <span>for both RBDPO and MO while only RBDPO shows decrement trend of moisture in oil. The ageing patterns of relative permittivities, dielectric dissipation factors and resistivities for RBDPO are similar to MO. The</span> <span>increment of acidity for RBDPO is more apparent that MO throughout the ageing time. All RBDPOs are more resistant to ageing than MO based on the TGA.</span></span>

Optimization of water washing for mitigation of 3-monochloropropane 1,2 diol ester in palm oil physical refining process

The presence of 3-monochloropropane-1,2 diol ester (3-MCPDE) and glycidyl ester (GE) in processed palm oils is of concern, as these oils are widely used for edible purposes. The mitigation method studied here optimizes the removal of chloride through water washing of crude palm oil (CPO), to limit the formation of 3-MCPDE. The contaminant removal obtained via washing CPO supports the quantitative findings. By utilizing 5% water in the washing step, water-soluble chlorides in CPO are removed by up to 76%, resulting in a 71% reduction of 3-MCPDE to within statutory limits. In this study, a linear correlation was developed between the chloride and the corresponding 3-MCPDE with a correlation coefficient (R 2) of 0.99. Using the correlations, 1.0 mg/kg of 3-MCPDE in refined, bleached and deodorized palm oil (RBDPO) will be obtained from CPO with 1.2 mg/kg chloride with 7% wash water usage. The study also showed minor GE reduction between 7 and 11% was attained after water washing.

Mitigation of 3-MCPDE and GE in palm oil in Indonesia

Among consumed-vegetable oils, RBDPO (refined, bleached and deodorized palm oil) is indicated containing higher level of 3-MCPDE and GE, which have been classified as potentially carcinogenic and/or genotoxic to human. Those contaminants in RBDPO are formed during deodorization process with high temperature and also correlate with chloride content and quality of CPO as raw material. The maximum limit for 3-MCPDE and GE content in vegetable oil has been set at 2500 and 1000 µg kg-1, and as low as 750 and 500 µg kg-1 when used for production of baby food and cereal-based foods for infants and young children. The mitigation of 3-MCPDE and GE in RBDPO is quite challenging for palm oil refineries in producing a good quality of palm oil in term of sensory, stability, safety, and nutritional value, especially in Indonesia. It has been proven that modification of conventional refining process can reduce the 3-MCPDE and GE content. They are including pre-treatment of CPO by water washing to reduce the chloride content, alkali neutralization to remove any acids present in the oil prior to deodorization, using neutral bleaching earth, adding antioxidants after bleaching to reduce free radical-mediated formation of 3-MCPDE and GE, lowering the deodorization temperature with a longer time, and even double bleaching and/or double deodorization of the palm oil. Post-refining treatment using specific adsorbents is also applied to remove the 3-MCPDE and GE. However, palm oil refineries have to apply combination of several mitigation strategies to adequately reduce the levels of 3-MCPDE and GE, including using good quality of CPO with low FFA, chloride, and oxidized components content.

Mitigation of 3-MCPDE and GE in palm oil in Indonesia

Among consumed-vegetable oils, RBDPO (refined, bleached and deodorized palm oil) is indicated containing higher level of 3-MCPDE and GE, which have been classified as potentially carcinogenic and/or genotoxic to human. Those contaminants in RBDPO are formed during deodorization process with high temperature and also correlate with chloride content and quality of CPO as raw material. The maximum limit for 3-MCPDE and GE content in vegetable oil has been set at 2500 and 1000 µg kg-1, and as low as 750 and 500 µg kg-1 when used for production of baby food and cereal-based foods for infants and young children. The mitigation of 3-MCPDE and GE in RBDPO is quite challenging for palm oil refineries in producing a good quality of palm oil in term of sensory, stability, safety, and nutritional value, especially in Indonesia. It has been proven that modification of conventional refining process can reduce the 3-MCPDE and GE content. They are including pre-treatment of CPO by water washing to reduce the chloride content, alkali neutralization to remove any acids present in the oil prior to deodorization, using neutral bleaching earth, adding antioxidants after bleaching to reduce free radical-mediated formation of 3-MCPDE and GE, lowering the deodorization temperature with a longer time, and even double bleaching and/or double deodorization of the palm oil. Post-refining treatment using specific adsorbents is also applied to remove the 3-MCPDE and GE. However, palm oil refineries have to apply combination of several mitigation strategies to adequately reduce the levels of 3-MCPDE and GE, including using good quality of CPO with low FFA, chloride, and oxidized components content.

Clean energy-based teaching industry development policy in the Pelalawan technopark area

The Teaching Industry (TI) is an institutionalized R&D and innovation activity with a collaborative business model involving local governments, universities, and industry. The development of a TI by ST2P at Technopark Pelalawan based on palm oil as commodities are important to accelerate the downstream of Palm oil product, considering the potential for Palm oil plantations in Pelalawan around 393,330 hectares. The purpose of developing this TI is to encourage local government policies in developing clean energy-based industries through the development of the CPO TI at Technopark Pelalawan. This study is a qualitative descriptive analysis method, which analyzes, describes, and summarizes various conditions, and situations from various data from interviews and field observations. The result is a CPO Teaching Industry, which produces RBDPO (Refined, Bleached, and Deodorized Palm Oil) palm oil which undergoes a refining process to remove free fatty acids and purification to remove color and odors. The challenges faced by the development of the Teaching Industry are then formulated. The recommendations for the development of the Teaching Industry at Techno Park Pelalawan include accelerating the formation of managers, preparing SOPs and blueprints, and implementing CPO refinery technology as an early stage of development.

Lightning Impulse Breakdown Voltage RBDPO with the Presence of Metallic Particles Under a Uniform Electric Field

The performance of liquid insulation in power transformer is vulnerable to particles, especially the metallic particles. This paper presents the experimental study on the effect of metallic particles on the palm oil (PO) as dielectric insulating fluid under lightning impulse breakdown voltage. The type of PO used in this study is refined, bleached and deodorized Palm Oil (RBDPO) Olein. Two different types of metallic particles (copper and iron) with different concentrations (clean, low, medium, and high) were studied. The lightning impulse test has been carried out according to IEC 60897 standard and under the influence of a uniform electric field. For the comparative purpose, similar test has been carried out with mineral oil (MO). The presence of metallic particles reduces the average lightning impulse breakdown voltage of MO and PO but shows less significant effect to MO. This is because the streamers in the PO propagate faster and further than in the MO at the same voltage level. Hence, causing the breakdown voltage of PO lower than MO. Under negative lightning impulse, the breakdown voltage of MO is slightly higher than RBDPO. From the study, the increment of the number of particle level contamination will reduce the lightning impulse breakdown voltages of the PO.

Investigation on the Dielectric Properties of Palm Oil with Silicon Carbide Doping for Transformer Application

The dielectric strength of insulating liquids of transformer acts an important parameter in the operation of transformer. Thus, great interest and many studies have been extensively done to improve the dielectric strength. One of study is the introduction of nanoparticle in the transformer oils. Study of the nanoparticles for the last few years had been found that, it can be dispersed in the transformers oils to be nanofluids and directly enhance the transformer performance. In this study, an investigation has been carried out to focus on the effect of silicon carbide (SiC) nanoparticle to AC (alternating current) breakdown voltage of the Refined, Bleached, and Deodorized Palm Oil (RBDPO). AC breakdown test have been conduct according to the standard of the IEC 60156. Besides that, a number of parameters will be evaluated such as dielectric dissipation factor (tan δ), relative permittivity (ε), and resistivity (ρ). Based on the results of the experiment, the electrode gap at 2.5 mm having the highest AC breakdown voltage compared to the other electrode gap which are 1.0 mm, 1.5 mm and 2.0 mm. Furthermore, doping with different concentrations of the silicon carbide (SiC) in Refined, Bleached, and Deodorized Palm Oil (RBDPO) found decreasing of AC breakdown voltage from 52.09 kV (without SiC) to 45.3 kV for 0.001 g/L, 43.2 kV for 0.003 g/L and 40.1 kV for 0.005 g/L respectively.

Novel Approach of Biodiesel Production Waste Utilization to Support Circular Economy in Biodiesel Industry

Current development of industry nowadays is more towards sustainability and greener production that minimize the production of waste, for example the production of biodiesel energy from Refined, Bleached, and Deodorized Palm Oil (RBDPO). However, biodiesel production is still could not eliminate the hazardous waste that is glycerin pitch. Glycerin pitch is a waste found in the glycerin purification unit which is a unit used to produce the high-grade glycerin, a side product of biodiesel production. Up until now, the existing glycerin pitch is still not well managed and remains as a hazardous waste. Glycerin pitch contains a sodium salt that can be recovered to produce biodiesel transesterification catalyst, sodium methoxide. Applying a concept of circular economy, a catalyst recovery building block is attached to integrated biodiesel process with glycerol purification. The process consists of three units, solid-liquid extraction to separate inorganic salt contains in the pitch, Chlor-Alkali process to convert inorganic sodium salt to sodium hydroxide, and catalyst making reactor to produce a sodium methoxide. Using a simulation process, the amount of catalyst recovered in the process is 43.78%.

Experimental Study on the Partial Discharge Characteristics of Palm Oil and Coconut Oil Based Al2O3 Nanofluids in the Presence of Sodium Dodecyl Sulfate.

This experimental study aims to examine the partial discharge (PD) properties of palm oil and coconut oil (CO) based aluminum oxide (Al2O3) nanofluids with and without surfactants. The type of surfactant used in this study was sodium dodecyl sulfate (SDS). The volume concentrations range of Al2O3 dispersed in oil samples was varied from 0.001% to 0.05%. The ratio of surfactants to nanoparticles was set to 1:2. In total, two different types of refined, bleached and deodorized palm oil (RBDPO) and one type of CO were measured for PD. Mineral oil (MO) was also examined for comparison purpose. PDIV measurements for all samples were carried out based on rising voltage method whereby a needle-sphere electrode configuration with a gap distance of 50 mm was chosen in this study. Al2O3 improves the PDIVs of RBDPO, CO and MO whereby the highest improvements of PDIVs are 34%, 39.3% and 27%. The PD amplitude and repetition rate of RBDPO improve by 38% and 81% while for CO, it can increase up to 65% and 80% respectively. The improvement of PD amplitude and repetition rate for MO are 18% and 95%, regardless with and without SDS. Without SDS, the presence of Al2O3 could cause 26%, 75% and 65% reductions of the average emission of light signals for RBDPOA, RBDPOB and CO with the improvement of PD characteristics but both events do not correlate at the same volume concentration of Al2O3. On the other hand, the average emission of light signal levels of the oils increases with the introduction of SDS. The emission of light signal in MO does not correlate with the PD characteristics improvement either with or without SDS.

An integrated simulation–optimisation approach for free fatty acid removal in palm oil deodorisation process

AbstractDeodorisation is the key process to produce high‐quality refined, bleached and deodorised palm oil (RBDPO) in a palm oil refinery. In this work, an integrated simulation–optimisation approach was adopted for the analysis of a deodorisation process in an operating palm oil refinery. The process includes a deodoriser unit that removes free fatty acids (FFA) from bleached palm oil (BPO), and a vacuum scrubber utilising palm fatty acid distillate (PFAD) to reduce the FFA content entering the vacuum system. Being a proprietary technology, deodoriser is not found in the standard models of commercial simulation software. Approximation was made in simulation, with results compared to plant data. Detailed analyses showed that the reduction of FFA content relies on deodorisation temperature and pressure, stripping steam flowrate, as well as the temperature and flowrate of PFAD entering the vacuum scrubber. An optimisation model was solved to maximise profit from the deodorisation. Results showed that the FFA content entering the vacuum system is reduced significantly by 49.7%, leading to higher recovery of FFA in PFAD and lower loss into the condenser section. Applying the optimum values to the refinery has resulted in FFA levels greater than 91.2% in PFAD and RBDPO yield improvement of 0.5%.

Statistical Analysis of AC Dielectric Strength for Palm Oil under the Influence of Moisture

This paper presents a statistical study on the AC Breakdown Voltage (BDV) of Refined, Bleached and Deodorized Palm Oil (RBDPO) olein under the influence of moisture. Different moisture contents of the RBPDPO were prepared by drying the RBDPO in the oven at different time intervals. The AC BDV test of RBDPO was performed whereby the distance between 2 electrodes was set to 1 mm. The statistical analyses of AC BDV data for RBDPO were carried out based on normal, lognormal and Weibull distributions. It was shown that as the moisture content increased, the AC BDV of RDBPO decreased exponentially. Statistical analyses revealed that the AC BDV data with different moisture contents had platykurtic distributions. Moisture could influence the skewness of the distribution whereby the tail shifted from right to left as the content increased. At different moisture contents of RBDPO, most of the AC BDV data of RBDPO could be represented by Weibull distribution.

Mitigation of 3-monochloropropane-1,2-diol esters and glycidyl esters in refined palm oil: A new and optimized approach

Refined, bleached and deodorized palm oil (RBDPO) is reported to contain high amount of 3-monochloropropane-1,2-diol esters (3-MCPDE) and glycidyl esters (GE) due to high-temperature deodorization step and rich in organochlorines. Therefore, a new palm oil refining process was developed to mitigate this problem. The conventional physical refining process was modified and optimized using response surface methodology with selected processing parameters (water and acid dosages, pre-treatment and deodorization temperatures and deodorization duration). Formation of esters in oil during refining was modelled, and a new refining approach which had been optimized and validated was developed. The new method achieved significant reduction in ester contents (78% reduction for 3-MCPDE, 53% reduction for GE; p < 0.05), with free fatty acid content and color maintained at < 1.0% and < 3.0 R. Similar mitigation effect was confirmed by testing the new refining approach with different grades of crude palm oil.

Effect of surfactants on the lightning breakdown voltage of palm oil and coconut oil based Al2O3 nanofluids

In this paper, the effect of different types of surfactants on the lightning breakdown voltages of palm oil (PO) and coconut oil (CO) based aluminium oxide (Al2O3) nanofluids is investigated. Three different types of surfactants were used in this study known as cationic (cetyl trimethyl ammonium bromide (CTAB)), anionic (sodium dodecyl sulfate (SDS)) and non-ionic (oleic acid (OA)). The volume percentage concentrations of Al2O3 dispersed into PO and CO were varied from 0.001% to 0.05%. The ratio of surfactant to the nanoparticles was set to 50% from the volume concentration of nanoparticles which equivalent to 1:2. In total, two types of refined, bleached and deodorized palm oil (RBDPO) and one type of CO were examined for lightning breakdown voltage. The test was carried out based on needle-sphere electrodes configuration with 25 mm gap distance. The presence of Al2O3 improves both positive and negative lightning breakdown voltages of RBDPO and CO. Under the positive and negative polarities, the CTAB does provide further improvements on the lightning breakdown voltages of RBDPOA (1st type of samples) and CO at most of the volume of concentration of Al2O3. SDS and OA could also further improve the lightning breakdown voltage of CO at certain volume concentration of Al2O3. On the other hand, the lightning breakdown voltage of RBDPOB based Al2O3 nanofluid (2nd type of samples) does not further improve with the introduction of surfactants. At most of the volume concentration of Al2O3, the introduction of CTAB further increases the times to breakdown and decrease the average streamer velocities of RBDPOA under both polarities. The same finding is observed for CO under positive polarity with CTAB and SDS as well as under negative polarity in the presence of all surfactants. The streamer velocities and times to breakdown patterns of RBDPOB based Al2O3 nanofluid are inconsistent in the presence of all surfactants. It is found that RBDPO and CO based Al2O3 nanofluids have second mode of streamer whereby the streamer velocities are from 1 km s−1 to 1.63 km s−1 regardless with or without surfactants.

Comparison of mass balance and oil quality in plant refinery I and IV

Refinery process is the process of refining crude palm oil (CPO) to remove Free Fatty Acid (FFA), odors, and reducing color, so that it meets the quality requirements. Fractionation is a process of separating triglycerides based on palm oil based on its melting point which aims to separate the solid fraction (stearin) and liquid fraction (olein). The fractionated oil comes from the refining process. The purpose of the mass balance comparison is to determine the quality and quantity of oil produced from the refinery and fractionation processes. The production capacity at the refinery plant I and IV were 1,700 and 1,800 respectively. The amount of refined bleached and deodorized palm oil (RBDPO) produced based on the mass balance calculation at plant I and IV were 73,597 and 77,377 kg/h respectively with criteria were free of impurities and FFA.

Moving Windows Prediction of Refined, Bleached and Deodorized Palm Oil Quality Using Multiple Least Squares and Partial Least Squares Regressions

With the goal of shaping a smart, economically-sustainable palm oil refining industry, this paper aims to improve the prediction modelling of Refined, Bleached and Deodorized Palm Oil (RBDPO) quality for early quality fault detection and remediation via the novel use of a moving windows form of prediction in addition to the conventional static window form. In this study, both Multiple Least Squares Regression (MLSR) and Partial Least Squares Regression (PLSR) model training techniques and prediction computations are carried out in the form of two moving data windows types, namely the expanding and rolling fixed-size data windows, together with the conventional static window form of prediction as control. Prediction improvement is observed consistently across both regression techniques when carried out in moving windows form, where both types of moving windows predictions, i.e. expanding and rolling windows, have fared significantly better than the static window form, with an average prediction error reduction of 20.6 % for Free Fatty Acid prediction, 55.9 % for Moisture Content prediction, 32.6 % for Iodine Value prediction and 34.2 % for Colour Value prediction in RBDPO. Among the moving windows themselves, the superiority of expanding windows over rolling windows and vice versa is insignificant. On the whole, this study paves the way for a revamped RBDPO quality prediction form which better reflects the dynamic, transient nature of the palm oil refining process, thus further consolidating its reliability for widespread practical use.

Biodiesel synthesis from refined bleached and deodorized palm oil (RBDPO) by transesterification using durian shell based carbon modified with KOH as heterogeneous catalyst

In this study, an attempt had been made to use durian shell as carbon source for catalyst support for transesterification reaction. In this research, refined bleached and deodorized palm oil (RBDPO) and methanol were used as feedstock. The aim of this work was to evaluate the capability of durian shell based carbon as heterogeneous catalysts in transesterification of RBDPO. Carbonization of durian shell was conducted at 600°C for 2 h. The carbon resulted was modified by impregnation with potassium hydroxide (KOH) followed by drying and calcination. The modified activated carbon was characterized by Scanning Electron Microscopy – Energy Dispersive X-Ray Spectroscopy (SEM-EDS). This heterogeneous catalyst was utilized in transesterification of RBDPO. Transesterification of RBDPO was performed at 60°C and 500 rpm. Effect of process variables such as the load of catalyst and reaction time was investigated. The highest yield of 97.29% biodiesel was obtained by using 12:1 molar ratio of methanol to RBDPO at a reaction time of 90 minutes in the presence of 3 w% catalysts. The resulted biodiesel was then characterized for its ester content, density, and viscosity. The biodiesel properties met the Indonesia standard (SNI). The results confirmed that activated carbon from durian shell modified with KOH is suitable as a heterogeneous catalyst in the synthesis of biodiesel.

Kinetic model for FAME production using inmobilized Lipase in a solvent- free system

A kinetic model was developed to describe FAME production from refined, bleached and deodorized palm oil (RBDPO) in a solvent-free system, using Thermomyces lanuginosus lipase, in free and immobilized form. The limitations of substrate mass transfer, enzymatic inhibition and discontinuous feeding of alcohol were considered. The kinetic model for the enzyme in free and immobilized form was validated experimentally, under the same process conditions (34°C, 0.145mg protein/g oil, 4.1:1 Methanol: Oil molar ratio). The kinetic model predicted a FAME content of 73.47 wt % at 9 hours, with a relative error of 0.140% using the enzyme in free form, while the FAME content predicted by the kinetic model was 47.04 wt % at 9 hours with a relative error of 0.026 using the enzyme in immobilized form. The decrease in the percentage of esters using the enzyme in immobilized form was attributed to limitations by external mass transfer.

Impact of Fe3O4, CuO and Al2O3 on the AC Breakdown Voltage of Palm Oil and Coconut Oil in the Presence of CTAB

This paper presents an experimental study on the AC breakdown voltages of Refined, Bleached and Deodorized Palm Oil (RBDPO) Olein and Coconut Oil (CO) in the presence of conductive (Iron (II,III) Oxide, Fe3O4), semi-conductive (Copper (II) Oxide, CuO) and insulative (Aluminium Oxide, Al2O3) nanoparticles without and with surfactant. The type of surfactant used in this study was Cetyl Trimethyl Ammonium Bromide (CTAB). The volume concentrations range of Fe3O4, CuO and Al2O3 was varied from 0.001% to 0.05%. Transmission Electron Microscope (TEM) was used to characterize the nanoparticles in RBDPO and CO. AC breakdown voltage tests were carried out for RBDPO and CO of which the AC breakdown voltage at 1% probability was determined based on Weibull distribution. It is found that only Al2O3 can improve the average AC breakdown voltage of RBDPO and CO. The AC breakdown voltages at 1% probability for RBDPO and CO can be improved through introduction of Fe3O4, CuO and Al2O3 at certain volume concentrations. Al2O3 provides the highest enhancement of AC breakdown voltages at 1% probability for RBDPO and CO with the highest percentage of improvement can be up to 52%. CTAB has no clear effect on the improvement of AC breakdown voltages of RBDPO and CO based Fe3O4, CuO and Al2O3 nanofluids.

Effects of Molecular Structure on the Physical, Chemical, and Electrical Properties of Ester‐Based Transformer Insulating Liquids

AbstractThis article presents the experimental studies carried out on the environmental friendly polyol ester insulating liquids to investigate the effect of molecular structure on the physical, chemical, and electrical properties. Six different polyol esters that can be produced from the transesterification of various methyl esters with neopentylglycol/trimethylolpropane alcohols were synthesized and compared with those of refined, bleached, and deodorized palm oil (RBDPO) and mineral transformer oil. The finding suggests that the physical properties like fire point, pour point, and viscosity are very much affected by the molecular weight and molecular composition of the polyol esters. The electrical properties are also highly influenced by the molecular structure‐related characteristics, such as the polarity, dipole polarization, carbon chain length, and degree of branching. The results confirm the findings of previous studies that the polyol esters and RBDPO have more polarity and dipole polarization compared to mineral oil. The experimental evidence showed that the newly synthesized insulating liquids have favorable thermal and electrical properties, thus suggesting that the insulating liquids have the potential to replace conventional insulating liquids to provide a more sustainable power system in the future.