Reductive Coupling Of Nitriles Research Articles

ChemInform Abstract: Cobalt‐Catalyzed Regioselective Synthesis of Pyrrolidinone Derivatives by Reductive Coupling of Nitriles and Acrylamides.

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

Cobalt-Catalyzed Regioselective Synthesis of Pyrrolidinone Derivatives by Reductive Coupling of Nitriles and Acrylamides

A convenient and highly regioselective method for the synthesis of 5-methylenepyrrolidinone derivatives from various nitriles and acrylamides via a cobalt-catalyzed reductive coupling reaction is described. A possible mechanism that involves the formation of a cobaltaazacyclopentene intermediate from nitrile and acrylamide, protonation, keto-amide cyclization, and dehydration is proposed.

Sm°/Cat. I2 and SmI2 induced reductive coupling of nitriles with azides

AbstractThe intermolecular reductive coupling of nitriles with azides induced by Sm°/Cat. I2 or SmI2 was studied. Aromatic and aliphatic amidines were prepared in moderate to good yields under neutral and mild conditions respectively.

Samarium Diiodide Induced Reductive Coupling of Nitriles with Azides

A series of amidine derivatives were synthesized via the intermolecular reductive coupling of nitriles with azides induced by samarium diiodide in good yields under mild and neutral conditions.

Low-Valent Titanium Induced Reductive Coupling of Nitriles with Nitro Compounds

The intermolecular and intramolecular reductive coupling of a cyano group with a nitro group induced by a low-valent titanium reagent prepared from TiCl4/Sm was studied. Amidines and 2-aminoquinolines derivatives are preparied in good yields under mild conditions respectively.

ChemInform Abstract: Ring Construction by Zirconium‐Promoted Reductive Coupling of Nitriles with Alkenes.

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

Redox reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2). The reductive coupling of nitriles with retention of a metal-metal-bonded dirhenium unit

Redox reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2). The reductive coupling of nitriles with retention of a metal-metal-bonded dirhenium unit

ChemInform Abstract: Reductive Coupling of Nitriles via Formal (2 + 2) Cycloadditions to the Titanium‐Carbon Double Bond.

AbstractElectron deficient or sterically hindered nitriles, e.g. (II), react with the titanacyclobutane (III) to give the 1:1 complexes (I) with slower transformation to the 2:1 complexes (IV).

ChemInform Abstract: Carbon‐Carbon Bond Formation in the Reductive Coupling of Nitriles at a Multiply Bonded Dirhenium Center.

AbstractThe triply bonded dirhenium(II) complexes (I) react with nitriles to give products in which a metal‐metal bond is retained.

Reductive coupling of nitriles via formal [2 + 2] cycloadditions to the titanium-carbon double bond

La reaction du pivalonitrile avec le (t-butyl-3 di-η 5 -cyclopentadienyl-1,1) titanacyclobutane conduit a l'amino-5 tetramethyl-2,2,6,6 heptene-4-one-3 en passant par un intermediaire azatitanacyclobutene puis diazatitanacyclohexadiene

Carbon-carbon bond formation in the reductive coupling of nitriles at a multiply bonded dirhenium center

Carbon-carbon bond formation in the reductive coupling of nitriles at a multiply bonded dirhenium center

Titanacycles derived from reductive coupling of nitriles, alkynes, acetaldehyde, and carbon dioxide with bis(pentamethylcyclopentadienyl)(ethylene)titanium(II)

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTitanacycles derived from reductive coupling of nitriles, alkynes, acetaldehyde, and carbon dioxide with bis(pentamethylcyclopentadienyl)(ethylene)titanium(II)Steven A. Cohen and John E. BercawCite this: Organometallics 1985, 4, 6, 1006–1014Publication Date (Print):June 1, 1985Publication History Published online1 May 2002Published inissue 1 June 1985https://doi.org/10.1021/om00125a008RIGHTS & PERMISSIONSArticle Views831Altmetric-Citations154LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (882 KB) Get e-AlertsSupporting Info (1)»Supporting Information Supporting Information Get e-Alerts