Reduction Process Research Articles

In-situ transmission electron microscopy (TEM) investigation of the reduction process in graphene oxide

In-situ transmission electron microscopy (TEM) investigation of the reduction process in graphene oxide

Analysis of pore formation and carburizing mechanism of magnetite reduction by CO

To investigate the porosity and expansion mechanism of CO-reduced magnetite, the reduced microstructures of magnetite under conventional heating and microwave heating were compared. The microstructure characteristics of magnetite with various reduction degrees were examined in a 60%CO-Ar reduction atmosphere, and the formation and evolution mechanism of the structure were analyzed in conjunction with the reduction effect. The results indicate that the reduction product of CO reduced magnetite possesses a porous structure. Nevertheless, when the gas diffusion is restricted, the reduction process is sluggish and the porous structure is not readily formed. Microwave heating enhances the gas-phase diffusion capacity, thermodynamic carburizing capacity, and solid-phase carbon-oxygen diffusion capacity, resulting in a higher oxygen loss rate than that of conventional heating. Under the experimental conditions, the lattice shrinkage during the Fe3O4 → Fe0.88O transformation and the rapid expansion of Fe0.88O → Fe0.94O are the causes of the crack. Microwaves facilitate the formation of pores and cracks in the product. This study offers a novel concept for the development of foam steel.

Extraction and Identification of Flavonoids from the Leaves of Pilocarpus microphyllus: Focus on Antioxidant Activity and Neuroprotective Profile

This work is based on research aiming to extract and identify flavonoids from jaborandi (Pilocarpus microphyllus) leaves and investigate their antioxidant and acute antinociceptive capacity. Characterization of the constituents of the ethyl acetate fraction (EtOAcF) obtained from the methanolic extract (ME) was performed by UV-Vis spectrophotometry, infrared spectroscopy, high-performance liquid chromatography (HPLC), mass spectrometry (MS), and cyclic voltammetry, demonstrating the possible majority component of this fraction, the flavone chrysin. Its solubility properties in HPLC are very close to those of the flavonol quercetin, revealing the characteristic presence of this group. An MS spectrum of the fraction revealed a major protonated molecule of m/z 254.9 [M+H]+. The EtOAcF fraction showed three oxidation processes at 0.32 V, 0.54 V, and 0.73 V vs. Ag/AgCl. Three reduction processes at the respective potentials: 0.60 V, −0.03 V, and -0.24 V vs. Ag/AgCl, indicating potential antioxidant activity. At DPPH and ABTS antioxidant radical capture assay, The IC50 obtained was 0.5 mg/mL and 0.81 mg/mL, respectively. In vivo test to determine the mechanical nociceptive threshold in the von Frey test, the dose of 100 mg/kg of the EtOAcF was able to cause inhibition of behavioral changes in neuropathy. The results obtained in this study demonstrate the biological potential of an EtOAcF derived from jaborandi leaves.

A Numerical Study of the Thermochemical and Aerodynamic States of H2‐intensive Direct Reduction Shaft Furnace

In the urgent pursuit of deep decarbonization, the steel industry has paid significant attention to the hydrogen‐intensive direct reduction process, where the H2‐to‐CO (volume) ratio of feed gas for the shaft furnace (SF) is increased compared to the current level. In this work, the reduction process of iron oxide pellets in the SF is investigated numerically to clarify how the in‐furnace thermochemical and aerodynamic states are affected by increasing hydrogen content, with the goal to provide guidelines for more efficient operations of the unit. Multiscale modeling is conducted to investigate the complicated gas–solid countercurrent reactive flows in the SF where the reduction behavior of an individual iron oxide pellet is described using a three‐interface unreacted shrinking core model. The results show that an increase in the hydrogen content leads to a lower temperature level and hence a deteriorated thermochemical state. It also induces a lower gas pressure drop over the in‐furnace packed bed.

Effect of trace oxygen on smelter off‐gas reduction desulphurization process over FeSx/γ‐Al2O3 catalysts

AbstractEffects of trace oxygen on iron sulphides‐supported catalysts (FeSx/γ‐Al2O3) were evaluated through smelter off‐gas reduction process for sulphur synthesis. Catalytic performance was evaluated under different oxygen content conditions. The properties of fresh and used catalysts were investigated by means of X‐ray diffraction (XRD), thermogravimetry‐differential thermal analysis (TG‐DTA), X‐ray photoelectron spectroscopy (XPS), and elemental analysis and relationships of active phases and activity were analyzed. The relationship between different active crystal crystals (FeSx, FeS2, Fe, FeO, γ‐Fe2O3) and SO2/O2 adsorption and conversion was investigated. The mechanism of oxygen influence on the FeSx/γ‐Al2O3 surface was given and the lifetime of the catalyst in the reaction atmosphere close to real smelter off‐gas after dust and oxygen removal steps containing trace oxygen (0.5 O2 v/v.%) was explored.

Methyl ester production process from palm fatty acid distillate using hydrodynamic cavitation reactors in series with solid acid catalyst.

This study aims to optimize the reduction of free fatty acids (FFAs) in palm fatty acid distillate (PFAD) using hydrodynamic cavitation reactors (HCRs) in series and a solid acid catalyst for biodiesel production. Hydrodynamic cavitation is used to accelerate the esterification of FFAs using a heterogeneous acid catalyst. There are three HCRs units, and each HCR composed of a 3D-printed rotor and stator, is separated by flanges and equipped with a basket for holding Amberlyst-15 catalyst. Through response surface methodology (RSM), the esterification process is optimized by adjusting its optimal parameters, namely, methanol (2-12 wt%), circulation time (30-170min), and rotor speed (1000-3000rpm). The optimal conditions for achieving a maximum methyl ester purity of 89.76 wt% in converting FFA in first-step esterified oil are 9 wt% methanol (molar ratio of methanol to oil of 4:1), 133min of circulation time, and 2000rpm of rotor speed. An 82.48 wt% biodiesel yield is achieved from the HCRs in series under the optimal conditions. Scanning electron microscope images reveal that after the esterification process, there are minor cracks and defects on the catalyst's resin surface, indicating the presence of residual reactants. Further examination of the catalyst after the esterification process, reveals an average absorption pore diameter of 341.41 Å and BET surface area of approximately 41.68 m2/g. Although there were slight physical changes in the catalyst, HCRs technology offers a viable FFA reduction process that could enhance biodiesel production efficiency. Moreover, the optimized conditions achieved in this study contribute to the advancement of biodiesel production processes and provide insights into the performance of the catalyst used.

Carbon dioxide capture in large-scale CCGT power plant from flue gases obtained from various fuel mixtures

In this study, the thermodynamic analysis of a combined cycle gas turbine integrated with post-combustion carbon capture and storage using the solvent method is performed. The syngas obtained from the gasification of sewage sludge is mixed with methane and nitrogen-rich natural gas fuels at different proportions, used in the gas turbine, and the properties of fuel and flue gases are analyzed. The flue gas obtained from the fuel mixture is passed through the post-combustion carbon capture and storage at various load conditions to assess the heat and electricity required for the carbon capture process. The solvent used for the carbon capture from flue gases enables CO2 capture with the high efficiency of 90%. With the calculated results, the load conditions of flue gas using fuel mixtures are identified, which reduces the heat and power demand of post-combustion carbon capture and storage and provides the possibility to achieve neutral emission. The impact of selected operating conditions of post-combustion carbon capture and storage on the CO2 emission reduction process and on the power plant performances is investigated. Considering the factors of electricity generation, energy efficiency, heat supply to the consumers, operating load of post-combustion carbon cap-ture and storage and CO2 emission, the 50% mixture of syngas with both fuels performs better. Also, the use of a mixture of 2-amino-2methyl-1-propanol and piperazine with reboiler duty 3.7 MJ/kgCO2 in post-combustion carbon capture and storage slightly enhanced the performance of the power plant compared to the use of monoethanolamine with reboiler duty 3.8 MJ/kgCO2.

Simplification of solvation shell with water clusters in the simulation of electrochemical nitrogen reduction reaction.

Electrochemical methods for nitrogen reduction have received extensive attention due to the mild reaction conditions. In order to gain an insight into the mechanism of the electrochemical nitrogen reduction process, theoretical simulations are necessary. However, current simulation studies contain many imprecise approximations that may hinder the real recognition of the reaction process. Although solvation methods have recently been developed to provide efficient descriptions, their further applications are hindered by controversy over modeling of solvents and the enormous computational effort required. In this work, we simplify the solvation conditions by using water clusters and compare them with an accurate water layer model. The results demonstrate that the simplified water clusters can effectively capture protons, simulate the surface electric environment, and enable the calculation of the activation energy of the reaction. This method offers an affordable approach for simulating the surface potentials and solvents and provides a new reference for the theoretical study of the electrochemical nitrogen reduction reaction.

Gold Nanoparticles: Multifunctional Properties, Synthesis, and Future Prospects

Gold nanoparticles (NPs) are among the most commonly employed metal NPs in biological applications, with distinctive physicochemical features. Their extraordinary optical properties, stemming from strong localized surface plasmon resonance (LSPR), contribute to the development of novel approaches in the areas of bioimaging, biosensing, and cancer research, especially for photothermal and photodynamic therapy. The ease of functionalization with various ligands provides a novel approach to the precise delivery of these molecules to targeted areas. Gold NPs’ ability to transfer heat and electricity positions them as valuable materials for advancing thermal management and electronic systems. Moreover, their inherent characteristics, such as inertness, give rise to the synthesis of novel antibacterial and antioxidant agents as they provide a biocompatible and low-toxicity approach. Chemical and physical synthesis methods are utilized to produce gold NPs. The pursuit of more ecologically sustainable and economically viable large-scale technologies, such as environmentally benign biological processes referred to as green/biological synthesis, has garnered increasing interest among global researchers. Green synthesis methods are more favorable than other synthesis techniques as they minimize the necessity for hazardous chemicals in the reduction process due to their simplicity, cost-effectiveness, energy efficiency, and biocompatibility. This article discusses the importance of gold NPs, their optical, conductivity, antibacterial, antioxidant, and anticancer properties, synthesis methods, contemporary uses, and biosafety, emphasizing the need to understand toxicology principles and green commercialization strategies.

Safety and reliability of ultrasound-assisted reduction in the conservative management of completely displaced paediatric distal radius fractures.

To assess the efficacy of ultrasound-assisted reduction in the conservative management of completely displaced pediatric distal radius fractures. The efficacy of ultrasound-assisted reduction versus conventional reduction was compared in a single-centre, retrospective, cross-sectional study involving 51 consecutive paediatric patients with completely displaced distal radius fractures, following manual reduction, from May 2021 to May 2023. The study group received ultrasound-assisted reduction (n = 24), while the control group underwent conventional blind manual reduction (n = 27). Comparative analysis included general clinical data, initial reduction success rates, frequency of exposure to radiation during reduction, post-reduction alignment rates, post-reduction angulation, re-displacement rates, conservative treatment failure rates, pain scores, and wrist joint scores at the last follow-up. All enrolled cases underwent manual reduction and conservative management. In the study group, all 24 patients underwent successful initial reduction procedures, with only one exposure to radiation during the entire process. Notably, no patient experienced re-displacement while in plaster, and the conservative treatment proved effective. The reduction and positioning rates were impressive, with success rates of 86.63 ± 3.65% in the coronal plane and 94.79 ± 3.06% in the sagittal plane. Furthermore, the post-reduction angulation was only 3.58 ± 0.65 degrees in the coronal plane and 8.70 ± 1.45 degrees in the sagittal plane. By contrast, within the control group comprising 27 patients, only 15 achieved successful initial reductions. Unfortunately, 12 patients required multiple exposure to radiation throughout the procedure. Furthermore, nine patients underwent re-displacement while in plaster and seven did not achieve successful conservative treatment. The alignment rates of the control group were similar to those of the study group (84.67 ± 4.35% in the coronal plane and 82.56 ± 5.45% in the sagittal plane). Similarly, the post-reduction angulation remained consistent, measuring 3.93 ± 0.87 degrees in the coronal plane and 12.03 ± 1.32 degrees in the sagittal plane. There were no statistically significant differences in pain scores during the process of fracture reduction and in wrist joint function scores at the final follow-up (P > 0.05). Ultrasound-assisted reduction in the conservative management of completely displaced paediatric distal radius fractures can enhance the initial reduction success rate, decrease the risk of subsequent redisplacement, minimize patient exposure to radiation, and yield favorable clinical outcomes. It is a safe and reliable approach.

Photochemistry dominates over photothermal effects in the laser-induced reduction of graphene oxide by visible light

Graphene oxide (GO) possesses specific properties that are revolutionizing materials science, with applications extending from flexible electronics to advanced nanotechnology. A key method for harnessing GO’s potential is its laser-induced reduction, yet the exact mechanisms — photothermal versus photochemical effects — remain unclear. Herein, we discover the dominant role of photochemical reactions in the laser reduction of GO under visible light, challenging the prevailing assumption that photothermal effects are dominant. Employing a combination of Raman thermometry, X-ray photoelectron and photoluminescence spectroscopies, and electrical atomic force microscopy, we quantify the temperature and map the reduction process across micro and nano scales. Our findings demonstrate that the photochemical cleavage of oxygen-containing groups below a reduction threshold temperature is a decisive factor in GO reduction, leading to distinct characteristics that cannot be replicated by heating alone. This work clarifies the fundamental mechanisms of GO transformation under visible laser irradiation, highlighting the dominant role of photochemical processes. Distinguishing these subtleties enables the development of laser-reduced GO platforms for graphene-based applications compatible with industrial scales. We illustrate this potential by encoding information on GO surfaces as optical storage, allowing us to write binary sequences in long-term memory encoding invisible even through an optical microscope.

Precise Synthesis of Single‐Atom Catalysts for Boosting Next‐Generation Advanced Oxidation and Reduction Processes in Sustainable Energy Applications

AbstractSingle‐atom catalysts (SACs) demonstrate high selectivity, maximal atom utilization, and unique active site configurations, establishing them as a rapidly expanding research field. Understanding the intrinsic relationship between structure and catalytic performance is crucial for the effective use of SACs in catalysis. However, providing a clear explanation of the coordination environment and intrinsic structural regulation of SACs remains a significant challenge for next‐generation renewable energy materials, especially in advanced oxidation and reduction processes critical for sustainable energy applications. This comprehensive review offers an in‐depth overview of the current progress and design of SACs, with a specific focus on precise synthesis, structural control, and the relationship between structure and performance. Furthermore, we elucidate the reaction mechanisms of various catalytic systems and the selective methods used to precisely synthesize and enhance catalytic reactions in the sustainable energy sector. Finally, this review explores the complex challenges in investigating and developing SACs and offers a perspective on solutions in advanced oxidation and reduction technologies for future research to overcome these challenges and achieve practical applications.

Cost benefit analysis of flood risk in the area of Thrace in Greece

Cost-benefit analysis can significantly aid the decision-making process for flood risk reduction and mitigation. Decision-makers can use it to weigh the expenses of various flood mitigation strategies against their possible upside in terms of lowering the risk of losses and damage. Decisions regarding how to allocate resources for flood risk management can be made more intelligently with the use of this information by policymakers and stakeholders. During severe rainfall or snowfall, these rivers are prone to flooding, which can harm structures such as homes, businesses, and infrastructure, have negative impacts to land uses and as a result they can cause high opportunity costs. Flooding in the Thrace region can have indirect and direct expenses, including property damage and lost commercial activity. These costs can include communication breakdowns and higher insurance rates. The predicted total economic losses from erosion for all of Greece are €356 million and €649 million for a 0.5- and 1-meter sea level increase, respectively.

Structural damage detection using a sensitivity-based model updating approach with autocorrelation function data

ABSTRACT This study presents a novel sensitivity equation for estimating structural parameters using autocorrelation function (ACF) data of dynamic responses. The proposed method reduces the need for extensive excitation frequencies, making structural parameter identification more practical and cost-effective, especially for large-scale structures. Furthermore, due to the quadratic relationship between ACF and the structural dynamic response, this approach exhibited greater sensitivity to damage than time-history-based methods. The method’s effectiveness was evaluated using simulated data from truss and offshore jacket platform models. Incomplete measurements were addressed by using partially measured structural characteristics without model reduction and data expansion processes. Measurement and modelling errors were simulated by adding uniformly distributed random error into the damaged structure data. The low values of the coefficient of variation indicated the method’s robustness against these errors. The accuracy of the method was confirmed through low root mean square error (RMSE) values and high variance accounted for (VAF) values.

Preparation of Vanadium (3.5+) Electrolyte by Hydrothermal Reduction Process Using Citric Acid for Vanadium Redox Flow Battery

In this study, vanadium (3.5+) electrolyte was prepared for vanadium redox flow batteries (VRFBs) through a reduction reaction using a batch-type hydrothermal reactor, differing from conventional production methods that utilize VOSO4 and V2O5. The starting material, V2O5, was mixed with various concentrations (0.8 M, 1.2 M, 1.6 M, 2.0 M) of citric acid (CA) as the reducing agent and stirred for 60 min at 90 °C using a hot plate to ensure complete dispersion in the solution. The resulting solution was subsequently subjected to a hydrothermal reduction reaction (HRR) furnace at 150 °C for 24 h to generate vanadium (3.5+). The mixed states of the produced vanadium (3+) and vanadium (4+) were confirmed using UV-vis spectroscopy. The electrochemical properties of the electrolyte were investigated through cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), revealing that the optimal concentration of the CA was 1.6 M. The current efficiency, energy efficiency, and voltage efficiency of the electrolyte produced via the HRR process was compared with that prepared using VOSO4 in charge and discharge experiments. The results demonstrate that the HRR process yields an enhanced electrolyte across all efficiency metrics produced through the given improved performance in all efficiencies. These findings indicate that the HRR process using citric acid can facilitate the straightforward preparation of vanadium (3.5+) electrolyte, making it suitable for large-scale production.

Unravelling the potential of low-valent tunable vanadium complexes in the nitrogen reduction reaction (NRR).

Density functional theory calculations have been carried out to investigate the potential of several hitherto unknown low-valent tripodal vanadium complexes towards conversion of dinitrogen to ammonia as a function of different equatorial (PiPr2 and SiPr) and bridgehead groups (B, C and Si). All the newly proposed vanadium complexes were probed towards understanding their efficiency in some of the key steps involved in the dinitrogen fixation process. They were found to be successful in preventing the release of hydrazine during the nitrogen reduction reaction. We have performed a comprehensive mechanistic study by considering all the possible pathways (distal, alternate and hybrid) to understand the efficiency of some of the proposed catalysts towards the dinitrogen reduction process. The exergonic reaction free energies obtained for some of the key steps and the presence of thermally surmountable barrier heights involved in the catalytic cycle indicate that these complexes may be considered as suitable platforms for the functionalization of dinitrogen.

A nonlinear manifold model order reduction approach for thermo‐mechanically coupled plasticity

AbstractThis study employs a nonlinear manifold mode order reduction (MOR) approach to address the high computational cost inherent in multi‐physical nonlinear models, which are discretized by the finite element method (FEM), with a particular focus on thermo‐mechanically coupled plasticity under finite strain conditions. Utilizing nodal snapshots obtained from a full‐order simulation, a projection matrix is constructed through singular value decomposition (SVD), facilitating the construction of a reduced system within a lower‐dimensional space. This reduction process entails the multiplication of the discretized residual vector and stiffness matrix by a linear projection matrix, complemented by the incorporation of a nonlinear projection component to ensure accurate reconstruction within the nonlinear part. Subsequently, a comprehensive three‐dimensional benchmark test is conducted to assess the accuracy and efficacy of the reduced‐order model.

Kinetic Analysis of Molten Oxide Reduction Using Bottom-Blown Hydrogen Injection

Hydrogen-based smelting reduction has received widespread attention as an important technology for realizing low-carbon development in hydrogen metallurgy. In this study, the thermodynamics of smelting reduction was firstly analyzed by using FactSage 8.1 thermodynamic software, on the basis of which smelting reduction experiments of iron oxides by using bottom-blown hydrogen were carried out. The experiments used oxidized pellets as experimental materials, and the effects of the reduction process were analyzed in terms of the reduction temperature, the reduction time, and the hydrogen flow rate. The experimental results show that under the experimental conditions of a temperature of 1550 °C and a hydrogen flow rate of 0.2 Nm3/h, the reduction rate of iron oxides in the process of reducing iron oxides by hydrogen is significantly faster in the first 10 min than after 10 min. The hydrogen utilization rate reached a maximum of 41.87%, then decreased continuously and finally maintained at about 20%. Using the method of model fitting, it was found that the hydrogen-based molten reduction conformed to the phase boundary reaction model (Gα=1−(1−α)1/2), the corresponding mechanism function is fα=2(1−α)1/2, where α stands for the reduction conversion, and the reaction rate constant k(T) is 2.37 × 10−4 s−1 under the experimental conditions.

Effect of Size Reduction Processes on Rice Flour Properties and the Quality of their Bakery Products

Currently, there is an incremental demand for ricebased products among health-conscious consumers in the dynamic food market. The method and the machinery used in the size reduction processes have a crucial impact on the physicochemical properties of rice flour, thereby affecting the quality and consistency of the final products. Consequently, certain starch modification techniques can be implemented to eliminate some baker-unfriendly properties associated with rice flour. This brief review is focusing on literature pertaining to different rice milling techniques, certain physicochemical and functional flour properties, a comparison of rice flour properties relevant to different rice milling techniques, the relationship between different rice flour properties and their effect on the quality of bakery products, and finally the improvement of flour properties by different starch modification techniques.

Electrochemical reduction and recovery of trace gold(I) from environmentally friendly thiosulfate leaching solutions using carbon electrodes

Efficient recovery of Au(S2O3)23− at low concentrations is a key challenge for the development of environmentally friendly, cyanide-free thiosulfate leaching methods in industry. In the study, carbon materials including activated carbon (AC), graphite, and graphene were used as electrodes for electrochemical reduction and recovery (electro reduction-recovery) of trace gold(I) from thiosulfate leaching solutions (Au(S2O3)23−). The results demonstrated that Au(S2O3)23− could be efficiently recovered in the form of Au0 with nearly 100 % recovery from both simulated and actual gold ore leaching solutions, significantly simplifying traditional recovery and reduction processes. Even in the presence of impurities such as cations and S2O32−, recovery remained high, around 90 %. Among the parameters studied, applied voltage was the most critical for optimizing recovery, as it enhanced ion migration and significantly improved gold reduction. The study investigated the relationship between the intrinsic properties of carbon materials and their electrochemical reduction and recovery capabilities. Rich porosity of carbon materials promoted interactions with Au(S2O3)23−, enhancing the electric double layer capacity, while π–π∗ satellite transitions played a dominant role in the charge transfer, thereby improving the reduction rate. This research offers new insights of the mechanisms behind the recovery of trace Au(S2O3)23− from thiosulfate leaching solutions through carbon electrodes.