Reduce NOx Emissions Research Articles

Pollutant emission during pyrolysis of waste wind turbine blades: Nitrogen-containing components and polycyclic aromatic hydrocarbons

Serious attention was lacked for various pollutants formed in both gas and tar phase during pyrolysis recycling of waste wind turbine blades (WWTB), especially for components of carcinogenic bisphenol A (BPA) and potentially toxic polycyclic aromatic hydrocarbons (PAHs) in tar. Pyrolysis temperature within 400–600 °C would significantly impact pollutant formations. Additionally, CO2 had a potential to mitigate pollutants emission as an economic alternative for N2. This article investigated the influence of these factors on nitrogenous and PAHs components during WWTB pyrolysis through fixed bed and thermogravimetric experiments. The results showed that NO2 was dominated in nitrogen containing pollutants and was related to the evolution of pyrrole nitrogen oxides. It was found 550 °C as a turning temperature, at which the polycondensation reaction appeared significantly. This resulted in a markedly increase for toxic N-PAHs in tar. At this temperature, CO2 could be used to mitigate nitrogen pollutants. 25% CO2 reduced NOX emission about 26% and selectively promoted NH3 releasing to over 4.3 times and depressed HCN generating to 0.6 times. Moreover, the primary depolymerization product of organic pact in WWTB was BPA. Increasing residence time, temperature and CO2 concentration were beneficial for converting hazardous BPA to high valued P-Isopropenylphenol (IPP). The value of IPP:BPA could increase to over 2 in this experiment. It was aimed to provide not only an evaluation for the yield and migration of pollutants, but also an cleaner recycling solution through graded pyrolysis WWTB to mitigate pollution and maximize the value of by-products.

Waste collection route optimisation for the second waste-to-energy plant in Budapest

The city of Budapest produces approximately 680–700 000 tonnes of municipal solid waste every year, of which <2/3 is being recycled or used for energetic purposes, the rest ends up in a landfill. To combat this environmental and logistical problem the installation of a second waste incineration plant has been proposed in the south of the city. The only cost associated with fuel consumption in the case of waste to energy powerplants (WtE plants) is the transport cost, as the city council provides economic support for waste disposal. Since the transportation has a huge influence on the cost of opertation, logistical optimisation of the transport routes promises a direct impact on cost savings. In this study the logistical optimisation of the Southern Budapest area was carried out using image processing and logic based algorithm programming. As a result the optimal transport of 230 000 tonnes of municipal solid waste (MSW) was solved resulting in a 4 835.2 km monthly travel distance reduction.This value can be translated to 7 823 €/month cost, 9 459.6 kg/month CO2 and 45.3 kg/month NOx emissions reduction in the urban areas.

Numerical Investigation of CO and NO Production From Premixed Hydrogen/Methane Fuel Blends

Abstract There is significant interest in utilizing hydrogen as an energy carrier in a net-zero carbon energy economy. A variety of fundamental and practical issues associated with premixed hydrogen/methane combustion must be addressed, particularly flame flashback, combustion instabilities, and NOx emissions. Significantly less attention has been given to CO emissions from hydrogen blending. However, recent H2 blending engine tests have clearly noted major reductions in CO emissions, reductions which substantially exceed what would be expected based upon C atom mass balances in the fuel. Moreover, NOx, CO, and combustor operability always tradeoff with each other, and so, for example, these CO reductions can also enable operational or design modifications to reduce NOx emissions and/or wider operability windows. This paper addresses H2 blending effects on CO emissions, addressing both the direct influences on CO emissions, as well as how it influences NOx–CO tradeoffs. The paper presents computations that differentiate between the kinetic and equilibrium effects of H2 blending, as well as how H2 blending can lead to reductions in both NOx and CO by moving the Pareto front downward. Finally, this work suggests that H2 blending, in addition to its CO2 reductions, can also increase plant operational flexibility and so provide additional value propositions to an evolving electricity market.

The Effect of Bioalcohol Additives on Biofuel Diesel Engines

This study experimentally investigated a water-cooled four-cylinder turbocharged diesel engine (DE) under different loads and fuel blend ratios. The integration of Computational Fluid Dynamics (CFD) simulations enables a deeper analysis of the combustion process. Through an in-depth analysis of the combustion process, the focus was placed on investigating the specific impacts of ethanol and n-butanol additives on diesel engine performance. Research shows that a fuel mixture consisting of 70% diesel, 10% biodiesel, and 20% ethanol reduced NOx emissions by 5.56% compared to pure diesel at 75% load. Furthermore, this study explores the combustion performance of diesel/biodiesel blended with butanol/ethanol. The findings indicate that n-butanol improves thermal efficiency, particularly at 100% load, with the D70B10E20 and D70B10BU20 blends demonstrating thermal efficiencies of 9.94%and 8.72% higher than that of diesel alone, respectively. All mixed fuels exhibited reduced hydrocarbon and CO emissions under different loads, with a notable reduction in hydrocarbon emissions of 34.4% to 46.1% at 75% load.

Experimental and numerical investigations on NH3/H2 fueled combustion in the combustor with block for improved micro power generation

To advance the application of zero-carbon fuels in micro-combustion, enhance energy conversion, and reduce NOx emissions in NH3/H2-fueled micro-power generators, a micro-combustor with an insertion block is proposed and tested under various chamber configurations and operational conditions. Experimental and numerical tests are conducted in micro-combustors with varied block settings, burner dimensions, NH3 blended ratios (mN), and fuel flow rates (Vf). The results indicate that mN significantly impacts the generation and consumption of H, O, and OH radicals, as well as NO, affecting flame regime and heat transfer. Specifically, adding 5∼15% NH3 improves the operating performance of the burner, with the highest mean temperature achieved in combustor #24C3-0.4 at mN=15%. Block insertion alters flame characteristics and enhances gas-wall heat transfer, the combustor with thinner blocks at higher mN and thicker blocks at lower mN contributes to better thermal performance. Furthermore, combustors with thinner blocks exhibit lower NO emissions. The working performance of the micro-thermophotovoltaic system can be enhanced by selecting the appropriate burner length with block thickness W=0.4 mm and position Lb=7 mm based on Vf. The maximum electrical power of 3.7 W is achieved with a burner length of 28 mm for the system using InGaAsSb cells at Vf=1200 mL/min.

Advancing urban mobility in developing countries: A mobile RSU approach for sustainable transportation

AbstractThe rapid and uncontrolled urbanization of cities in developing countries has engendered a plethora of urban mobility issues, including traffic congestion, accidents, and air pollution. To address these challenges, contemporary urban mobility trends are incorporating innovative technologies and sustainable governance practices. This article investigates how urban managers can leverage the opportunities presented by cost‐effective technologies and the management of urban data to enhance urban mobility in developing countries. Within this discourse, an RSU‐based approach is proposed that employs motorbike taxis for inter‐vehicular communication, given their status as the most widely used form of public transportation. This approach substantially diminishes investment costs and reinforces the sustainability of urban mobility. Through the implementation of this solution, a noteworthy reduction is anticipated in the emission of gases such as CO2, and NOx, known contributors to climate change and various respiratory diseases. To validate the efficacy of the proposed solution, four distinct scenarios are scrutinized in a case study centered on the city of Douala in Cameroon, utilizing tools such as OMNET++, SUMO, Veins, and INET. The proposed framework offers significant benefits in terms of environmental sustainability and operational efficiency. It enables a 10% reduction in CO2 emissions, a 15% reduction in NOx emissions, an 11% drop in fuel consumption, and a 15% reduction in waiting time in traffic jams. The envisaged solution aims to aid urban managers in their decision‐making processes, specifically in advancing sustainable urban mobility. Through the adoption of this approach, cities in developing countries can mitigate challenges associated with urban mobility and enhance the overall well‐being of their residents.

Energy, environmental, economic, and social assessment of photovoltaic potential on expressway slopes: A case in Fujian Province, China

Expressway slopes within the boundary of expressway construction land have the potential to be transformed from conventional land use to valuable utilization through the installation of photovoltaic (PV) systems. Considering the continuous increase in expressway mileage, the PV potential could be enormous; therefore, a method to quantify such potential is urgently needed. This study proposes a potential assessment method for expressway slope photovoltaics. First, the suitable locations of expressway slopes for installing PV systems are identified on the basis of publicly available digital maps, combined with the principles of PV site selection and geographic information systems. Then, the PVsyst model is used to simulate the power generation efficiency and power output of the PV systems and to evaluate their PV potential, contribution, and economic benefits. The implementation of the proposed method in Fujian Province, China, indicates that the installed capacity of PV systems could reach 16.3 GW, with an annual power output of 17,940 GWh, contributing to the peak shaving of power grids and regional energy supply. The reductions in CO2, SOx, and NOx emissions are 16.65 Mt, 8970 t, and 3947 t per year, respectively. Considering carbon trading, the payback period is shortened to 11.7 years, with the return on investment of 65.38 % and the net present value of 52.6 billion RMB over a 25-year operational period. Additionally, this project could create 19.88 % of jobs in the energy sector in Fujian Province, providing 27,861 jobs during the construction phase and 18,248 jobs during the operation and maintenance phase. Thus, this project is economically viable and generates positive energy, environmental, and social benefits, contributing to the promotion of local energy transition and sustainable development.

Health benefits of US light-duty vehicle electrification: Roles of fleet dynamics, clean electricity, and policy timing

We present a dynamic perspective to quantify the air quality-related health impacts of the electrification of light-duty vehicles in the United States between 2022 and 2050. Using a fleet turnover model and future electricity generation mix scenarios, we compare ambitious vehicle electrification to fleet renewal relying on newer internal combustion engine vehicles, without electric vehicles. The model includes vehicle-level pollutant emission factors and a reduced complexity air quality and valuation model and covers direct (tailpipe, brake wear, and tire wear) and indirect (production of electricity and liquid fuels) emissions of NOx, SO2, PM2.5, NH3, and VOCs, with a breakdown at the county level to identify geographical disparities in the distribution of health impacts. Short-term health benefits are mostly generated by reductions in NOx emissions from newer gasoline vehicles, while fleet electrification generates further benefits in the long term. The electricity mix plays a crucial role in the success of electrification policies. With continued grid decarbonization, electrification would reduce harmful air quality-related health impacts cumulatively by 84 to 188 billion USD over the study period, compared with fleet renewal without electric vehicles. In contrast, artificially freezing the 2022 grid would make electrification responsible for 32 to 71 billion USD additional health disbenefits compared with fleet renewal. Finally, we show that while fleet electrification achieves most of its benefits over fleet renewal in the long term, delaying the implementation of such policies would sacrifice meaningful cumulative benefits.

Investigating combustion efficiency and NOx emission reduction in fluidized bed ammonia-coal co-firing

Ammonia, a carbon-free fuel, can significantly reduce CO2 emissions when co-fired with coal in power plants. Fluidized bed combustion, known for its excellent gas-solid mixing and low NOx emissions, is a promising method for ammonia-coal co-firing. However, challenges remain in optimizing ammonia injection and controlling nitrogen oxide emissions. This study investigates these aspects using a lab-scale fluidized bed reactor with flexible ammonia injection points. Key variables, such as ammonia co-firing ratios, injection location, temperature, and outlet oxygen concentration, are examined. The results show that with ammonia injection ratios up to 70 %, NO and N2O emissions slightly increase, while ammonia escape is maintained below 5 ppm. Air staging effectively controls NOx emissions, and higher temperatures promote N2O decomposition, but increase NOx levels. Ammonia injection does not raise unburned carbon content. Rate of production and sensitivity analyses highlight the role of OH radicals in ammonia conversion and identify the critical reactions affecting NO generation. This study highlights the feasibility of fluidized bed ammonia-coal co-firing technology.

Numerical simulation of natural gas-ammonia combustion characteristics in a U-shaped radiant tube

NH3, recognized as a carbon-free fuel and a high-energy–density renewable hydrogen carrier, holds promise as a low-carbon alternative fuel. However, its direct combustion is often posed with challenges such as a limited ignition zone and high NOX emissions. To address this, the present paper proposes a strategy to blend more reactive hydrogen-containing fuels with ammonia to enhance combustion stability and concurrently reduce NOX emissions. This study developed numerical models for natural gas-ammonia combustion within a U-shaped radiant tube. The dynamic characteristics of combustion flame flow fields inside the radiation tube were investigated across various mixing ratios, analyzing the effects of nitrogen-containing fuel temperature on NOX generation and elucidating NOX generation patterns under different mixing ratios. The findings indicated that a 30 % NH3 blending ratio in the radiation tube yielded uniform wall temperature distribution along its length, minimal circumferential temperature variation, and an outlet NOX emission of only 20.3 ppm. Furthermore, Pearson correlation coefficient calculations revealed strong correlations between NH3 concentration (0.97), URT temperature (0.88), and NOX generation rate (0.88) within the U-type radiation tube combustion flame and NOX emission content.

A novel approach of in-cylinder NOx control by inner selective non-catalytic reduction effect for high-pressure direct-injection ammonia engine

As an efficient hydrogen carrier and carbon-free fuel, ammonia shows great promise in realizing zero-carbon propulsions. However, challenges such as poor ignition stability, low combustion efficiency, and fuel-NOx emissions are yet to overcome. In this paper, the high-pressure direct-injection ammonia/diesel dual-fuel combustion mode (HPDF) with post injection strategy is proposed as a solution. The study reveals that HPDF combustion mode enables in-cylinder reduction of NOx, which is attributed to the selective non-catalytic reduction (SNCR) reaction. The results uncover that NH2, NH, and N radicals have a significant reducing effect on NO and NO2, while N2O serves as an important byproduct of the reduction reactions. Subsequently, the generated N2O can be further reduced to N2 through the involvement of O, H, and OH radicals. Building upon these findings, an innovative ammonia post injection method for reducing NOx emissions is explored. The post injection strategy effectively reduces the NOx emissions with only a minor decrease in indicated thermal efficiency, but an over-delayed post injection could also cause significant increase in N2O and unburned NH3 emissions. A post injection proportion of 20%-30% with appropriate post injection timing is found to achieve desired emission reduction. Overall, the HPDF combustion mode is a promising solution for ammonia engine, due to the high thermal efficiency and low nitrogen oxide emissions, as well as the ability to further reduce the NOx emissions through ammonia post injection strategy.

Experimental Studies on Utilization of Biogas with Biodiesel/Diesel Blends in a CI Engine

The present study covers the utilization of a gaseous alternative fuel, raw biogas, in a diesel engine. Biogas alone cannot run a diesel engine, because gaseous fuel cannot burn by compression. It can be supplied to the CI engines in dual fuel mode by using an air-biogas mixer device. In this work, it is aimed to investigate the performance and emission characteristics of a biogas-biodiesel/diesel dual fuel mode diesel engine by employing a venturi gas mixer device for providing a homogeneous mixture. The performance and emission characteristics of the engine operated by dual-fuel mode were experimentally investigated, and compared to diesel. The results indicated that biogas inducted at a flow rate of 1L/min was found to have better performance and lower emission, than that of the other flow rates. On the other hand, dual-fuel mode with a biogas flow rate of BD10 BG@1L/min showed an average reduction in BTE of 9.94% and an average increment of 8.82% in BSFC as compared to diesel. Whereas an increment in CO and HC by 5.18% and 3.01% respectively and an average reduction in NOx emissions by 14.91% as compared to diesel. Keywords: Alternative Fuel, Biogas, Biodiesel, Diesel Engine, Dual-fuel, Venturi Gas Mixer

Numerical simulation of co-firing LRC and ammonia in Pangkalan Susu 3 & 4 coal-fired steam power plant (CFSPP) capacity 210 megawatts

The effort to reduce CO2 and NOx emissions plays a crucial role in mitigating climate change, improving air quality, complying with environmental regulations, and promoting clean technology innovation. Ammonia, as an emission-free fuel, shows significant potential as a co-firing agent with Coal in coal-fired steam power plants (CFSPP). Previous studies have demonstrated promising results in emission reduction through ammonia co-firing. This research presents a numerical analysis based on Computational Fluid Dynamics (CFD) to investigate the co-firing of ammonia with low-calorific Coal (LRC) in the CFSPP Pangkalan Susu Units 3 and 4, with a capacity of 210 MW. The study employs fluid flow modelling and chemical reaction analysis using the Discrete Phase Model (DPM) to provide accurate predictions of temperature distribution and pollutant concentrations in pulverized coal boilers. Cofiring simulations were conducted with ammonia additions of 5 % and 15 % on a calorific basis. Injection experiments from each burner (A-D) were performed to identify the optimal injection location. The simulation results indicate changes in combustion characteristics, particularly in temperature distribution. The main finding reveals a temperature decrease when ammonia is added as a co-firing material, attributed to the higher H2O content, which leads to increased moisture losses. In terms of efficiency, co-firing showed a decline compared to the baseline combustion of 100 % LRC coal due to the more significant moisture losses. The highest reduction in CO2 emissions was observed when 15 % ammonia was injected from burner B in case #6, with a mass fraction value of 0.171 at the boiler outlet. Similarly, the most significant reduction in NOx emissions occurred with a 15 % ammonia co-firing from burner B, yielding a mass fraction value of 8.81E-04 at the boiler outlet. This co-firing technology is expected to enhance decarbonization efforts and optimize the use of renewable energy in the future.

Experimental multiple parameters optimization of the injection strategies for a turbocharged direct injection hydrogen engine to achieve highly efficient and clean performance

Improving the brake thermal efficiency (BTE) and reducing NOx emissions are two main goals for hydrogen-powered internal combustion engines to achieve efficient and clean performance. This paper focuses on the multiple parameters optimization of injection and ignition both experimentally and numerically based on a 2.0L turbocharged direct injection hydrogen engine. Firstly, the effects of single and split injection on engine performance, in-cylinder mixing and combustion characteristics are investigated. Secondly, the single-factor effect of split injection parameters and spark timing on engine performance are obtained with different engine speeds. Significant interaction effects are detected between these factors. Thus, a multi-parameter optimization is conducted based on the response surface methodology method to analyze the co-relationship of factors (split injection control parameters and ignition) on responses (BTE, NOx emissions, and knock intensity) at high-load. Finally, a maximum BTE of 43.03% and a reduction in NOx emissions by 71.19% are achieved with the help of model prediction at 2500 rpm and a load of 1.40MPa. Further optimization of other engine speeds is conducted, and the boundary of high-efficiency region (BTE>40%) covers over 50% of the load map after optimization. These results can provide valuable support for the performance improvement of efficiency and clean hydrogen engines.

Multiphase Reactions of Hydrocarbons Into an Air Quality Model With CAMx‐UNIPAR: Impacts of Humidity and NOx on Secondary Organic Aerosol Formation in the Southern USA

AbstractSecondary organic aerosol (SOA) mass in the Southern USA during winter‐spring 2022 was simulated by integrating Comprehensive Air quality Model with extensions (CAMx) with the UNIfied Partitioning‐Aerosol phase Reaction (UNIPAR) model, which predicts SOA formation via multiphase reactions of hydrocarbons. UNIPAR streamlines multiphase partitioning of oxygenated products and their heterogeneous reactions by using explicitly predicted products originating from 10 aromatics, 3 biogenics, and linear/branched alkanes (C9‐C24). UNIPAR simulations were compared with those using Secondary Organic Aerosol Partitioning (SOAP) model, which uses simple surrogate products for each precursor. Both UNIPAR and SOAP showed similar tendencies in SOA mass but slightly underpredicted against observations at given five ground sites. However, SOA compositions and their sensitivity to environmental variables (sunlight, humidity, NOx, and SO2) were different between two models. In CAMx‐UNIPAR, SOA originated predominantly from alkanes, terpenes, and isoprene, and was influenced by humidity, showing high SOA concentrations with wet‐inorganic salts, which accelerated aqueous reactions of reactive organic products. NO2 was positively correlated with biogenic SOA because elevated levels of nitrate radicals and hygroscopic nitrate aerosol effectively oxidized biogenic hydrocarbons at night and promoted SOA growth via organic heterogeneous chemistry, respectively. Anthropogenic SOA, which formed mainly via daytime oxidation with OH radicals, was weakly and negatively correlated with NO2 in cities. In CAMx‐UNIPAR, the sensitivity of SOA to aerosol acidity (neutral vs. acidic aerosol at cation/anion = 0.62) was dominated by isoprene SOA. The reduction of NOx emissions could effectively mitigate SOA burdens in the Southern USA where biogenic hydrocarbons are abundant.

Flow field and emission characterization of a novel enclosed jet-in-hot-coflow canonical burner

The jet-in-hot-coflow is a canonical combustion setup, which has been used in several studies to study Flameless/MILD combustion and auto-ignition of fuels. However, the NOx and CO emission measurements from these combustion setups were not possible due to the entrainment of laboratory air and a lack of a well-defined physical system limit. These limitations have been overcome by a new enclosed jet-in-hot-coflow setup. The combustor was operated by injecting a mixture of CH4-Air in the central jet, and the coflow comprised of hot products from CH4-Air combustion in burners upstream. The coflow composition was further controlled by adding diluents such as N2 and CO2. Measurements were done using stereoscopic particle image velocimetry, suction probe gas analysis, thermocouples, and chemiluminescence imaging. Increasing central jet velocity and equivalence ratio led to lower NOx and a reaction zone that enlarged and shifted downstream. The reduction in NOx emission was attributed to the returning mechanism. Adding CO2 and N2 as diluents in the coflow resulted in a longer combustion zone and reduced temperatures in the combustion chamber, leading to decreased NOx production and increased reburning. These experiments provide relevant flowfield and emissions data for modelers and help characterize combustion regimes such as Flameless/MILD.

Efficient and low-NOx combustion in a grate-fired boiler by feeding biomass non-uniformly along grate width: An integrated modeling study with experimental validation

The distribution of air flows and fuel feeds are two crucial operational parameters determining the high-efficiency combustion and low-nitrogen emissions in biomass-fired grate boilers. However, current optimizations primarily focus on air distribution, with limited attention given to fuel feeds optimization. In this study, a three-dimensional integrated model was developed in FLUENT platform for simulating a grate-fired boiler with four feed inlets, in which the DPM model was adopted to track particle information in detail, and the Ergun model was used to account for the flow resistance generated by the thick packed bed, implemented in the form of a UDF code. The reliability of the model was validated through comprehensive on-site experimental data. It was found that key parameters such as temperature and ignition front of char are non-uniformly distributed along the width of the four grates. Specifically, a significant lag in volatiles release and char oxidation occurs near the water-cooled wall on both sides. On this basis, the optimization strategies on improving efficient and low-NOx combustion were proposed by redistributing the biomass fuel from near the sidewalls to the middle sections, and the optimal non-uniform feeding mode along the grate width was found. Results demonstrate that when the mass ratio of fuel between the middle and side grates is 0.30 to 0.20, yielding a maximum overall char burnout ratio of 84.74%. Additionally, the concentration of NO decreases from 163.2 mg/m3 of uniform feeding mode to 149.4 mg/m3 (at 11% O2). These predictions will provide reliable theoretical guidance for enhancing boiler efficiency and reducing NOx emissions in grate-fired boilers.

Nitrogen migration and gasification characteristics of pulverized coal using the novel gasification-combustion technology

This study proposes a feasible gasification-combustion technology for coal-fired boilers operating at low loads for the purpose of providing strong support for stable output of the power grid system that accommodates more renewable energy power. In this technology, a multi-nozzle impinging entrained-flow gasifier is used for the first time to preheat pulverized coal (PC), and the gasified fuel enters a down-fired combustor (DFC) for complete combustion with air-staged method. A 75 kW novel self-sustained gasification-combustion test rig was constructed. The stability and feasibility of the test rig were verified, and the gasification characteristics and nitrogen migration mechanism of PC under loads of 45 kW, 55 kW, 65 kW and 75 kW were investigated. The results demonstrated that the gasifier could continuously and steadily provide high-temperature gasified gas-char mixture to the combustor. The gas-char mixture, consisting of coal gas which was rich in high-concentration flammable gases (CO, H2, and CH4) and char with enlarged specific surface area, was easy to ignite, which could enhance the flame stability of boilers operating at low loads. Additionally, more than 61.6 % of coal-N was released in the gasifier. The liberated coal-N primarily transformed to N2 and NH3 instead of NOx, while the amount of NH3 produced was influenced by the gasification temperature. The gasified gas-char mixture entering the combustor achieved stable combustion with uniform temperature distribution. Before the injection of tertiary air, the released char-N and the NH3 in coal gas transformed primarily to N2, and there was no production of NO due to the strong reducing environment. The lowest NOx emission was 122.31 mg/Nm3 (@6% O2) at 65 kW, and the combustion efficiencies under all loads exceeded 99.62%, indicating that the gasification-combustion technology could enable efficient combustion and reduce NOx emission. Hopefully, the proposed technology could provide an innovative solution for the stable combustion of PC boilers at low loads and provide a feasible way to achieve clean combustion.

Ground ozone rise during the 2022 shanghai lockdown caused by the unfavorable emission reduction ratio of nitrogen oxides and volatile organic compounds

Ground-level ozone (O3) pollution has shifted from a scientific issue to a key focus of governmental action in China. In recent years, the concentration of NO2 in Shanghai has shown a decreasing trend of 3.7% annually, but ozone concentrations have exhibited significant interannual variability, particularly with a noticeable increase in 2022. This study focuses on investigating the mechanisms behind the increase in ozone concentration during the COVID-19 pandemic control period in 2022 in Shanghai, utilizing a combination of ground observation data, observation-based models, and chemical transport models for analysis. The results indicate that during the lockdown period, the mean values of daily maximum 8-h average O3 concentrations (MDA8 O3) in Shanghai increased by 17 μg/m³, with emission-related factors contributing 65.3%, primarily due to a blanket reduction in VOCs and NOx emissions during the lockdown, with a reduction ratio close to 1:1. However, this reduction ratio and intensity are not sufficiently reasonable to alleviate ozone pollution. Meanwhile, adverse meteorological conditions further exacerbated this effect, contributing 34.7%, with temperature rise having the greatest impact. Results from the chemical transport model show that with the total reduction in NOx and VOCs emissions unchanged, the greater the reduction in VOC emissions and the better the reduction effect on ozone pollution, reducing MDA8 O3 by approximately 10 μg/m³, especially for the control of reactive compounds such as alkenes, aromatics, and OVOCs. However, if the reduction ratio of NOx is greater than that of VOCs, ozone concentrations may not decrease but instead increase. This indicates that ozone concentration is influenced not only by the intensity of emissions reduction but also by the ratio of emissions reduction between NOx and VOCs. Our study emphasizes the critical role of carefully designed strategies, focusing on controlling the ratio of VOCs to NOx and increasing the intensity of VOCs reduction, to effectively alleviate ozone pollution in urban areas.

Towards cleaner energy: An innovative model to minimize NOx emissions in chemical looping and CO2 capture technologies

The urgent global challenges of climate change and environmental issues have catalyzed the development of CO2-capture-ready technologies incorporating fluidization, such as fluidized bed (FB) and circulating fluidized bed (CFB) combustion under oxy-fuel conditions, chemical looping combustion (CLC), chemical looping with oxygen uncoupling (CLOU), in-situ gasification chemical looping combustion (iG-CLC), and calcium (or carbonate) looping (CaL) systems. While these technologies have the potential to reduce CO2 emissions significantly, the persistent presence of nitrogen oxides (NOx = NO + NO2) as pollutants remains a critical environmental concern.This paper introduces a comprehensive fuzzy logic-based model for predicting NOx emissions (FuzzyNOx model) from solid fuel combustion in fluidized beds of chemical looping systems. This innovative model takes into account a wide range of operating parameters, including fuel type, fuel particle size, fuel moisture content, air/fuel ratio, and temperature. It also explores advanced coal and biomass combustion modes, including air-firing, oxyfuel, iG-CLC, and CLOU. Furthermore, it delves into the intricacies of two distinct facilities: the 5 kWth dual-fluidized bed Chemical-Looping-Combustion of Solid-Fuels (DFB-CLC-SF) facility at Czestochowa University of Technology, Poland, and the calcium looping dual-fluidized bed (CaL DFB) facility at Niigata University, Japan.Bituminous coal, semi-anthracite, and wood chips are utilized as fuels. Moreover, three various oxygen carriers (OCs) for chemical looping combustion were employed, namely ilmenite, copper oxide (60 % wt.) supported by carbonate waste from ore flotation, and copper oxide (60 % wt.) supported by ilmenite (20 % wt.) and fly ash. Bituminous coal, semi-anthracite, and wood chips are utilized as fuels.The developed knowledge-based fuzzyNOx model allows the optimization of operating parameters to reduce NOx emissions from CO2 capture technologies.