Magnetic Recyclability Research Articles

Exploring the formation of S-scheme heterojunctions in CuFe2O4/Bi2MoO6 porous cubes for photocatalytic removal of tetracycline

Exploring highly active and noble metal-free photocatalysts for the efficient photocatalytic degradation of antibiotics is of great significance. The CuFe2O4 nanostructured cube is synthesized by using a self-sacrificial template strategy, and two-dimensional Bi2MoO6 nanosheets are grown on the surface of CuFe2O4 through a solvothermal method to construct CuFe2O4/Bi2MoO6 S-scheme heterostructure. The CuFe2O4/Bi2MoO6 composite material exhibits eminent photocatalytic activity for the degradation of TC under simulated sunlight, with the optimal ratio CFO/BMO-2 achieving a degradation rate of 98.54 % within 30 min (initial concentration of TC: 50 mg L−1). In addition, CFO/BMO-2 also has excellent magnetic recyclability and cycling ability. Rice cultivation tests demonstrate that the biotoxicity of TC is effectively removed. Density functional theory calculations and in-situ irradiated X-ray spectroscopy deeply reveal the mechanisms of charge separation and transfer of S-scheme heterojunctions in CuFe2O4/Bi2MoO6. The construction of S-scheme heterojunctions promotes the separation of photo-induced charge carriers and improves photocatalytic degradation performance by retaining holes and electrons with strong redox ability. The work provides a practicable method for constructing efficient spinel photocatalysts to drive wastewater treatment reactions, and the constructed magnetically recyclable photocatalysts have certain practical application potential.

Photo-modified and photo-degradable starch/Fe3O4/TiO2 nanocomposite: exploring the feasibility of reducing workforce by magnetic recycling.

Plastics are known for their durability and long decomposition time in the environment, which make plastic recycling an effective approach to mitigate plastic waste risks. However, the global plastic recycling rate is less than 10% mainly due to the labor-intensive and time-consuming nature of the manual recycling process, which poses high health risks and costs. Therefore, the development of a fast, effective, and operational process in current recycling plants is crucial to address the environmental concerns associated with plastics. In the current study, the feasibility of starch/Fe3O4/TiO2 bio-nanocomposite (SFT) as photo-modifiable and photo-degradable was investigated to reduce the workforce in recycling packaging material. The SFT was modified by different UV-C exposure times, which significantly altered its functional properties. The UV-C exposure increased the hydrophobicity of the SFT films and led to a homogenous distribution of Fe3O4/TiO2 nanoparticles (FT). It also increased tensile strength (TS) and decreased elongation at break (EB) of the films. It seems that producing shorter polymer chains, creating new linkages among the polymeric chains, and the homogenous distribution of FT in the matrix of biopolymer by UV-C are the main reasons for these changes. Moreover, the photo-degradation of SFT specimens increased significantly with longer UV-C exposure times. The utilization of magnetic properties in bio-based nanocomposites holds promising potential for streamlining labor-intensive processes in waste recycling plants. However, the inappropriate visual properties of SFT remain a significant obstacle that requires further attention to enable its commercial viability.

An efficient, green, and magnetic recycling wastewater treatment technique enabled by ZnO/NiFe2O4/BiOBr 3D nanofibers photo-fenton process

A novel magnetic recycling ZnO/NiFe2O4/BiOBr 3D nanofibers photo-Fenton system was successfully prepared by parallel electrospinning combining with solvothermal method. ZnO/NiFe2O4 composite nanofibers was prepared via parallel electrospinning, then ZnO/NiFe2O4/BiOBr 3D nanofibers was obtained by solvothermal growth of BiOBr on electrospun ZnO/NiFe2O4 composite nanofibers. The composition, morphologies, structures and photocatalytic properties of ZnO/NiFe2O4/BiOBr 3D nanofibers were systematically tested and analyzed, and some meaningful results were obtained. The prepared ZnO/NiFe2O4/BiOBr 3D nanofibers, combined with H2O2, form a photo-Fenton system that exhibits excellent photocatalytic performance. When 0.05 mL of H2O2 is added to the photo-Fenton system, the degradation rate of organic dye Rhodamine B (RhB) reaches 99.61 % under light exposure for 10 min. Capture experiments and Electron Spin Resonance (ESR) measurements have confirmed that holes (h+) and hydroxyl radicals (·OH) are the primary active species that play a dominant role in the photocatalytic degradation of Rhodamine B (RhB). Furthermore, the ZnO/NiFe2O4/BiOBr 3D nanofibers have demonstrated exceptional photocatalytic degradation efficiency towards RhB, maintaining a degradation rate of over 95 % even after undergoing three recycling experiments. Significantly, this photo-Fenton system also has good magnetic properties, which can be separated from the treatment system under the applied magnetic field, avoiding secondary pollution of the treatment system, improving reuse rate and saving costs. This study provides valuable insights for the purposeful utilization of the photocatalytic materils.

Antisolvent crystallization of rare earth sulfate hydrates: Thermodynamics, kinetics and impact of iron

The thermodynamics and kinetics of ethanol antisolvent crystallization of rare earths from sulfate solutions has been explored, with a view towards separating the rare earths as part of a NdFeB magnet recycling process. The solubility of single and binary metal (Nd, Pr, Fe) phases in aqueous ethanol solutions has been determined. The impact of Fe and Pr on the crystallization of Nd is evaluated, the oxidation kinetics of Fe(II) to Fe(III) quantified, and the influence of Fe oxidation state on the thermodynamics and kinetics of crystallization investigated. Oxidation to Fe(III) is slow, with a half life of approx. 600 h. For pure Nd, the solubility of the obtained, stable sulphate octahydrate decreases exponentially with increased molar organic:aqueous (O/A) ratio, and is well described by the OLI model until O/A=0.2. Pr crystallizes as an isostructural octahydrate with similar solubility. Fe(II) precipitates as a mixed solid phase, with a solubility approximately 40 times higher than the rare earths at O/A=0.2. Fe(III) solutions exhibit liquid–liquid phase separation without precipitation at all evaluated concentrations. Nd and Pr coprecipitate together in proportion to their relative concentrations, with Pr precipitating at concentrations well below its pure component solubility. Fe(II) does not precipitate with Nd at O/A≤0.2 even at high concentration, with significant precipitation as separate particles at higher O/A for all concentrations. The crystallization kinetics and the morphology of the Nd phase is affected by the Fe oxidation state. The work highlights the potential of antisolvent crystallization for selective and efficient separation of REE from Fe.

Mapping complexity: Analyzing rare earth production life cycle inventories with network analysis

Understanding the significance of process clusters in life cycle inventory networks is crucial for optimizing supply chains, especially for critical elements like rare earth elements (REEs) production. This study employs network analysis (NA) to examine life cycle networks using facility-level energy/material data, extracting information from LCA networks. Based on Chinese facility reports, the investigation evaluates the environmental footprint of various rare earth production pathways, vital to the clean energy sector. It also considers rare earth permanent magnet manufacturing and magnet recycling. Using network metrics, including indegree/outdegree strength, closeness centrality, and betweenness centrality, the study assesses the resilience and sustainability of REEs production networks. Results highlight vulnerable nodes like "Neodymium Oxide" and "Nd Metal," aiding in identifying environmentally impactful materials and energy flows to develop more sustainable processes for meeting growing demand while enhancing environmental performance.

Phosphotungstic Acid-Supported Hercynite: A Magnetic Nanocomposite Catalyst for the Selective Esterification of Chloroacetic Acid.

This study presents the synthesis and characterization of a novel phosphotungstic acid-functionalized hercynite@SiO2 magnetic core-shell through a three-step procedure. The characterization involved various analyses including Fourier-transform infrared spectroscopy, P-XRD, TGA-DSC, EDAX, inductively coupled plasma optical emission spectroscopy, elemental mapping, scanning electron microscopy, transmission electron microscopy, and value stream mapping. The catalytic performance of the hercynite@SiO2-PTA nanomagnetic composite was examined in the esterification of chloroacetic acid. Results indicate that the developed procedure enables the production of chloroacetic acid esters using a wide range of primary, secondary, and tertiary aliphatic and aromatic alcohols with good to excellent yields and high selectivity. The significance of this work lies in its straightforward synthesis method, minimal time requirement, reduced utilization of hazardous chemicals, and cost-effectiveness. Additionally, the catalyst exhibited magnetic recyclability for up to five cycles with negligible loss in activity. Notably, the synthesized catalyst demonstrated nontoxicity and environmental friendliness.

Efficient Capture and Release of the Rare-Earth Element Neodymium in Aqueous Solution by Recyclable Covalent Organic Frameworks.

Rare-earth elements (REEs) are present in a broad range of critical materials. The development of solid adsorbents for REE capture could enable the cost-effective recycling of REE-containing magnets and electronics. In this context, covalent organic frameworks (COFs) are promising candidates for REE adsorption due to their exceptionally high surface area. Despite having attractive physical properties, COFs are heavily underutilized for REE capture applications due to their limited lifecycle in aqueous acidic environments, as well as synthetic challenges associated with the incorporation of ligands suitable for REE capture. Here, we show how the Ugi multicomponent reaction can be leveraged to postsynthetically modify imine-based COFs for the introduction of a diglycolic acid (DGA) moiety, an efficient scaffold for REE capture. The adsorption capacity of the DGA-functionalized COF was found to be more than 40 times higher than that of the pristine imine COF precursor and more than four times higher than that of the next-best reported DGA-functionalized solid support. This rationally designed COF has appealing characteristics of high adsorption capacity, fast and efficient capture and release of the REE ions, and reliable recyclability, making it one of the most promising adsorbents for solid-liquid REE ion extractions reported to date.

N-Alkylation of Amines Utilizing Magnetic Nano Chitosan Functionalized with EDTA/Co(II)

This research work has explored the application of a magnetic catalyst composed of coreshell nanoparticles [Fe3O4@SiO2@CS@EDTA/Co(II)], known as NCM@EDTA/Co(II), in the conversion of various alcohols containing electron-donating or electron-withdrawing groups into their respective secondary or primary amine derivatives. The investigation has focused on optimizing reaction conditions by considering factors, such as the inclusion of a base, duration of reaction time, reaction temperature, catalyst quantity, and choice of transition metal, in order to determine the optimal parameters. The most favorable outcomes have been achieved by using 0.2 mmol of catalyst per 1 mmol of substrate under reflux conditions for a duration ranging from 3 to 24 hours. The reaction has demonstrated high efficiency, with the catalyst's easy separation via an external magnetic field, stability, and recyclability, highlighting its potential applications in chemistry and industrial environments.

On the pre-treatment for recycling spent NdFeB permanent magnets: from disassembling, characterisation to de-coating

An evaluation of neodymium‑iron‑boron permanent magnets (NdFeB PMs) from different end-of-life products, as a secondary resource of rare-earth elements (REEs), is presented. De-coating of PM was investigate as pre-treatment to facilitate efficient direct magnet recycling. Thus, critical aspects from disassembling to the de-coating of the magnets were addressed. A challenge for the de-coating process is that the magnets have different sizes, weights, and their coating compositions are not known beforehand. It was shown that ammonia-based solutions was thermodynamically suitable to dissolve nickel and zinc coatings selectively, while keeping the bulk magnet stable. Nevertheless, the dissolution of Zn was much faster than the Ni one, and more efficient.

Vacuum processing temperature effect on highly coercive recycled NdFeB permanent magnets with Pr-based alloy addition

This study presents a modified method for recycling NdFeB scrap magnets, producing up to 100 kg of recycled sintered NdFeB magnets per batch. By adding a Pr-based alloy to N40H-grade NdFeB scrap and optimizing vacuum sintering and heat treatment conditions, we enhanced the magnetic properties and corrosion resistance of the recycled magnets. Various analyses, including BH Tracer measurements, FE-EPMA, accelerated corrosion tests, and C/N/O content analysis, evaluated differences in magnetic properties, microstructure, corrosion resistance, and impurity content. Optimal recycling involved vacuum sintering at 1085 °C, followed by heat treatments at 900 °C and 470 °C. Recycled magnets with PrCoGa alloy showed superior properties, such as an intrinsic coercivity (iHc) of 1414 kA/m, remanence (Br) of 1.290 T, and a maximum magnetic energy product ((BH)max) of 315.4 kJ/m, meeting N40H standards. Accelerated corrosion tests also indicated enhanced corrosion resistance in recycled magnets with Pr90Co8Ga2 alloy. This research offers a commercially viable approach for NdFeB magnet and rare earth element recycling.

Hydrogen-assisted recycling of Nd-Fe-B magnets from the end-of-life audio products

The transition towards green and sustainable technologies has significantly increased the demand for a subset of raw materials known as critical elements. Rare earth elements with their main use in Neodymium-Iron-Boron magnets (NdFeB) play a key role in clean energy technologies including electric vehicles and wind turbine generators. They are also a key component in electronic devices including mobile phones, hard disk drives, and loudspeakers. Here, we build on previous knowledge of the recycling of NdFeB magnets from hard disk drives, using a hydrogen process called HPMS (Hydrogen Processing of Magnet Scrap). This study investigates a new scrap stream from loudspeakers, specifically from vehicles and flat-screen TVs. The extracted magnets from loudspeakers typically had grades of N30/N33 with relatively low coercivity values. The interactions of the extracted magnets with hydrogen were monitored by gravimetric and thermal analyses. The thermodynamics and kinetics of the hydrogenation reaction appear to differ significantly based on their chemical composition, chemical homogeneity, coating state, and surface condition of the magnets. Overall, the HPMS process was demonstrated to successfully produce demagnetised hydrogen decrepitated powder at room temperature under 2 bar of hydrogen, in a commercially viable timeframe (approx. 4 h). Zinc was found to be the dominant coating material which peeled away during the HPMS process. The zinc content of the NdFeB alloy powder could be reduced after the hydrogen decrepitation by sieving. The remaining level of zinc had no noticeable impact on the magnetic properties of the recycled magnets. The particle size of the recycled alloy powder could be reduced to below 7 µm by ball milling and knife milling but with an increase in the oxygen level, limiting its sintering ability. Sintered magnet from the recycled alloy powder demonstrated similar magnetic properties (Br: 1.06 T, HcJ: 1240 kA/m, and (BH)max: 220 kJ/m3) after blending with 5 wt% of NdH3, making vehicles and flat-screen TV speakers ideal sources for a recycled magnet.

Preparation of Magnetically Recyclable MIL‐101‐immobilized Frustrated Lewis Pairs for the Reduction of Aldehydes and Ketones

Frustrated Lewis pairs (FLPs), composed of spatially hindered Lewis acids and bases, are promising catalysts for the catalytic hydrogenation of unsaturated organic substrates, but the lack of reusability limits their development. The functionalization of solid materials with molecular FLP is a promising method for preparing heterogeneous FLP catalysts. In this work, a magnetically recyclable FLP catalyst was successfully prepared for the reductive carbonyl compounds to the corresponding alcohols. FLP of 2‐Ph2PPhCHO/B(C6F5)3 was grafted into NH2‐MIL‐101@Fe3O4 composite material through an aldehyde‐amine condensation reaction. The as‐prepared FLP‐NH‐MIL‐101@Fe3O4 exhibited remarkable catalytic activity for aldehyde/ketone carbonyl compounds. In addition, FLP‐NH‐MIL‐101@Fe3O4 displays outstanding magnetic recyclability and can be reused 8 times without loss of activity.

Processability and Separability of Commercial Anti-Corrosion Coatings Produced by In Situ Hydrogen-Processing of Magnetic Scrap (HPMS) Recycling of NdFeB.

The recycling of NdFeB magnets is necessary to ensure a reliable and ethical supply of rare earth elements as critical raw materials. This has been recognized internationally, prompting the implementation of large-scale legislative measured aimed at its resolution; for example, an ambitious recycling quote has been established in the Critical Raw Materials Act Successful recycling in sufficient quantities is challenged by product designs that do not allow the extraction and recycling of these high-performance permanent magnets without excessive effort and cost. This is particularly true for smaller motors using NdFeB magnets. Therefore, methods of recycling such arrangements with little or no dismantling are being researched. They are tested for the hydrogen-processing of magnetic scrap (HPMS) method, a short-loop mechanical recycling process. As contamination of the recycled material with residues of anti-corrosion coatings, adhesives, etc., may lead to downcycling, the separability of such residues from bulk magnets and magnet powder is explored. It is found that the hydrogen permeability, expansion volume, and the chosen coating affect the viable preparation and separation methods as recyclability-relevant design features.

Silica Confinement for Stable and Magnetic Co−Cu Alloy Nanoparticles in Nitrogen‐Doped Carbon for Enhanced Hydrogen Evolution

AbstractAmmonia borane (AB) with 19.6 wt % H2 content is widely considered a safe and efficient medium for H2 storage and release. Co‐based nanocatalysts present strong contenders for replacing precious metal‐based catalysts in AB hydrolysis due to their high activity and cost‐effectiveness. However, precisely adjusting the active centers and surface properties of Co‐based nanomaterials to enhance their activity, as well as suppressing the migration and loss of metal atoms to improve their stability, presents many challenges. In this study, mesoporous‐silica‐confined bimetallic Co−Cu nanoparticles embedded in nitrogen‐doped carbon (CoxCu1−x@NC@mSiO2) were synthesized using a facile mSiO2‐confined thermal pyrolysis strategy. The obtained product, an optimized Co0.8Cu0.2@NC@mSiO2 catalyst, exhibits enhanced performance with a turnover frequency of 240.9 molH2 ⋅ molmetal ⋅ min−1 for AB hydrolysis at 298 K, surpassing most noble‐metal‐free catalysts. Moreover, Co0.8Cu0.2@NC@mSiO2 demonstrates magnetic recyclability and extraordinary stability, with a negligible decline of only 0.8 % over 30 cycles of use. This enhanced performance was attributed to the synergistic effect between Co and Cu, as well as silica confinement. This work proposes a promising method for constructing noble‐metal‐free catalysts for AB hydrolysis.

Silica Confinement for Stable and Magnetic Co-Cu Alloy Nanoparticles in Nitrogen-Doped Carbon for Enhanced Hydrogen Evolution.

Ammonia borane (AB) with 19.6 wt % H2 content is widely considered a safe and efficient medium for H2 storage and release. Co-based nanocatalysts present strong contenders for replacing precious metal-based catalysts in AB hydrolysis due to their high activity and cost-effectiveness. However, precisely adjusting the active centers and surface properties of Co-based nanomaterials to enhance their activity, as well as suppressing the migration and loss of metal atoms to improve their stability, presents many challenges. In this study, mesoporous-silica-confined bimetallic Co-Cu nanoparticles embedded in nitrogen-doped carbon (CoxCu1-x@NC@mSiO2) were synthesized using a facile mSiO2-confined thermal pyrolysis strategy. The obtained product, an optimized Co0.8Cu0.2@NC@mSiO2 catalyst, exhibits enhanced performance with a turnover frequency of 240.9 molH2 ⋅ molmetal ⋅ min-1 for AB hydrolysis at 298 K, surpassing most noble-metal-free catalysts. Moreover, Co0.8Cu0.2@NC@mSiO2 demonstrates magnetic recyclability and extraordinary stability, with a negligible decline of only 0.8 % over 30 cycles of use. This enhanced performance was attributed to the synergistic effect between Co and Cu, as well as silica confinement. This work proposes a promising method for constructing noble-metal-free catalysts for AB hydrolysis.

Ex-ante LCA of magnet recycling: Progressing towards sustainable industrial-scale technology

To alleviate the pressure on the rare earth supply chain, new technologies are under development for recovering, recycling and remanufacturing NdFeB magnets. In this study, the anticipated environmental performance of large-scale recycling is investigated and compared to the production of primary magnets. To do so, this ex-ante life cycle assessment combines input from measurements of pilot processes, expert technology forecasts, thermodynamic modeling, and equipment data from manufacturers. We examined the effect of four technology developments: process changes, size scaling, internal recycling, and optimization.The results show that at pilot scale, recovered NdFeB powders have lower impacts than primary powders for almost all impact categories. This demonstrates that the recovery of NdFeB alloys is environmentally beneficial. Magnets from anticipated large-scale recycling have over 80% lower impacts than primary magnets in most of the impact categories analyzed. All four investigated types of technology development contributed to this improved performance. The final configuration was validated by comparison with an industrial reference and theoretical optimum configuration. Four magnet manufacturing routes (sintering, extrusion, metal injection molding, bonding) have distinct environmental profiles, but all can progress to similarly low levels of impact. The choice among routes should be primarily based on the functional requirements.

Preparation of Magnetic Nano-Catalyst Containing Schiff Base Unit and Its Application in the Chemical Fixation of CO2 into Cyclic Carbonates

The development of a catalyst for the conversion of CO2 and epoxides to the corresponding cyclic carbonates is still a very attractive topic. Magnetic nano-catalysts are widely used in various organic reactions due to their magnetic separation and recycling properties. Here, a magnetic nano-catalyst containing a Schiff base unit was designed, synthesized and used as a heterogeneous catalyst to catalyze CO2 and epoxides to form cyclic carbonates without solvents and co-catalysts. The catalyst was characterized using Fourier transform infrared (FTIR), X-ray diffraction (XRD), thermogravimetric (TG), VSM, SEM, TEM and BET. The results show that the magnetic nano-catalyst containing the Schiff base unit has a high activity in the solvent-free cycloaddition reaction of CO2 with epoxide under mild conditions, and is easily separated from the reaction mixture driven by external magnetic force. The recovered catalyst maintains a high performance after five cycles.

Synthesis of magnetic NiFe2O4/rGO heterostructure as potential photocatalyst for a breakdown of malachite green (MG) dye under the visible source of light

The development of reactive radical generators, visible-light active photocatalysts with predictable stability, and efficient activity toward the breakdown of organic pollutant continue to be the primary goals of research in the area of photocatalytic environmental restoration. The present concern to on the development of an efficient heterostructure with a band gap operated on a visible region. The rGO incorporation into spinel material also decreases the agglomeration and provides a large surface area. The efficacy of NiFe2O4 (NF) nanoparticles, which are supported by rGO, as a photocatalyst for the breakdown of malachite green (MG) dye. The incorporation of rGO into NFO was investigated with the band gap property of the fabricated material using Tauc's plot profile. The NF/rGO nanocomposite underwent a reduction in magnetic properties determined through Vibrating Sample Magnetometer (VSM) analysis. However, the coercivity of the nanocomposite experienced a significant increase. When subjected to visible light, the degradation rate of malachite green (MG) dyes with NF/rGO was comparatively faster (93.84 %) than that of NF (64.33 %) and rGO (79.41 %). The cyclic photocatalytic degradation process exhibited notable reusability and stability of the magnetic recycling nanocomposite. The photocatalytic results revealed that the developed nanocomposite acts as a potential photocatalyst and it can also be employed in different applications.

Exploring mass and economic potentials of rare earth elements recycling from electric vehicles at end-of-life

AbstractRare earth elements (REEs) are fundamental for various modern technologies and industrial applications. One significant application of REEs is in the production of neodymium-iron-boron (NdFeB) magnets, which are key components in electric vehicles (EVs), wind turbines, and electronic devices. These applications play a crucial role in driving the ecological and digital transition, highlighting the significance of REEs as strategic materials. With the dominance of very few countries in the REEs global supply and the rising of EVs demand, several concerns regarding resource availability, supply chain security, and price volatility have heightened the importance of efficient NdFeB magnet recycling, especially in Europe. This study assessed the elemental recycling potential of REEs from EV components through collaboration with authorized treatment facilities and metal recyclers in Italy. The study focused on three representative electric vehicles: a compact car, a van, and a hybrid vehicle. NdFeB magnets were found in various components, including the electric drive motor, air conditioning system, electric power steering, alternator, and electric gear box. The content of NdFeB magnets and REEs inside these components has been determined and economic feasibility of their recycling has been estimated by considering the intrinsic value of the raw materials contained. Despite being preliminary results, the economic value of REEs and Cu recoverable attested a promising potential for recycling, while the direct dismantling of magnets from the engine proves economically unviable for the studied components. Therefore, the study emphasizes the need for the development of specific recycling processes such as demagnetization and mechanical processing of the motors. The study also analysed the dismantling times of the target components from the vehicle and their relative economic impact on the potential for recovery.

Wood-converted porous carbon decorated with MIL-101(Fe) derivatives for promoting photo-Fenton degradation of ciprofloxacin.

In response to the escalating concerns over antibiotics in aquatic environments, the photo-Fenton reaction has been spotlighted as a promising approach to address this issue. Herein, a novel heterogeneous photo-Fenton catalyst (Fe3O4/WPC) with magnetic recyclability was synthesized through a facile two-step process that included in situ growth and subsequent carbonization treatment. This catalyst was utilized to expedite the photocatalytic decomposition of ciprofloxacin (CIP) assisted by H2O2. Characterization results indicated the successful anchoring of MIL-101(Fe)-derived spindle-like Fe3O4 particles in the multi-channeled wood-converted porous carbon (WPC) scaffold. The as-synthesized hybrid photocatalysts, boasting a substantial specific surface area of 414.90 m2·g-1 and an excellent photocurrent density of 0.79 μA·cm-2, demonstrated superior photo-Fenton activity, accomplishing approximately 100% degradation of CIP within 120 min of ultraviolet-light exposure. This can be attributed to the existence of a heterojunction between Fe3O4 and WPC substrate that promotes the migration and enhances the efficient separation of photogenerated electron-hole pairs. Meanwhile, the Fe(III)/Fe(II) redox circulation and mesoporous wood carbon in the catalyst synergistically enhance the utilization of H2O and accelerate the formation of •OH radicals, leading to heightened degradation efficiency of CIP. Experiments utilizing chemical trapping techniques have demonstrated that •OH radicals are instrumental in the CIP degradation process. Furthermore, the study on reusability indicated that the efficiency in removing CIP remained at 89.5% even through five successive cycles, indicating the structural stability and excellent recyclability of Fe3O4/WPC. This research presented a novel pathway for designing magnetically reusable MOFs/wood-derived composites as photo-Fenton catalysts for actual wastewater treatment.