Holocene Mud Research Articles

Identification of the Storegga event offshore Shetland

The Shetland Islands (UK) are a seminal location for investigating palaeo-tsunami deposits. Onshore evidence suggests three tsunami have occurred during the Holocene: the Storegga tsunami ca. 8150 cal yr BP, the Garth tsunami ca. 5500 cal yr BP and the Dury Voe tsunami ca. 1500 cal yr BP. However, little research has been published on the impact of tsunami on the subtidal shelf where a large amount of North Sea hydrocarbon infrastructure is located. Here, we test the hypothesis that Holocene tsunami impacted shelf sediments, using radiocarbon dating and sedimentological characterization of cores recovered from the Fetlar Basin, offshore east Shetland. The cores contain distinct sand and shell lenses within a Holocene mud sequence, indicating a sudden change in hydrodynamic conditions. Radiocarbon dates bracketing the sand lenses overlap with the published dates for the Storegga event. Dates within the deposit are older (>9 cal. yr BP) which is consistent with reworking and redeposition of earlier sediments. Particle size analysis, ITRAX and MSCL data evidence increases in mean grain size, a reduction in sorting capacity, increased shell concentrations and peaks in associated elements (log(Ca/Fe), log(Ca/Ti) and Sr). These attributes indicate transport of allochthonous material from the inner shelf, and are typical of tsunami backwash-generated submarine debris flows. No evidence was found within the cores for any later Holocene tsunami, which may be due to either bioturbation, active currents, or lack of an initial deposit. The disturbance of sediments, and generation of a submarine debris flow within the Fetlar Basin by the Storegga event highlights the need to assess the potential impact of any future tsunami on planned and existing infrastructure at seabed. Erosion and deposition of allochthonous older marine sediment by the Storegga event also has consequence for interpretation of the coeval 8.2 ka cold event in marine sedimentary records in the tsunami affected region.

Late Quaternary marine transgressions off the Shandong Peninsula inferred from paleosalinity indicators: Implications for Holocene mud wedge formation

Mud depocenters play an important role in the sediment source–sink system of marginal seas; however, the factors controlling the formation of mud deposits are not well understood. This study focused on Core LHSD-1, which is located on the southern margin of the Shandong Peninsula mud wedge in the northwestern part of the South Yellow Sea. Elemental ratios, such as the C/S ratio (the mass ratio of total organic carbon and total sulfur) and Sr/Ba ratio, were used to track the changes in paleosalinity during the late Quaternary and to investigate the mechanisms that influenced the formation of the mud wedge off the Shandong Peninsula. Our results indicate that Core LHSD-1 likely recorded two transgression events, corresponding to MIS3 and MIS1. Following sea-level rise after the Last Glacial Maximum (LGM), transgressive deposition began in the study area at approximately 11.5 kyr BP. During the early Holocene, fluctuating water salinity was recorded by Sr/Ba ratios, which became stable at approximately 6.8 kyr BP when the sea level reached its highstand. At the same time, the modern current system was established, and a significant amount of terrestrial material, such as refractory organic carbon and iron, has been transported to the study area by enhanced coastal currents, which was documented by elevated C/S ratios (C/S > 2.8) in mud sediments. Our findings indicate that marine transgressions controlled the initial development of the mud depocenter and that the establishment of the modern ocean current system promoted the rapid deposition of mud sediments, which corresponded to the growth of global mud depocenters.

Glacial-interglacial sedimentation control on gas seepage exemplified by Vestnesa Ridge off NW Svalbard margin

Vestnesa Ridge is built-up of thick contourites mainly deposited during the last ∼5 million years. Methane leaks from deep gas reservoirs creating pockmarks on its crest, and which have been the focus of numerous studies. Sedimentation patterns in relation to the pronounced changes in oceanography and climate of the last glacial-interglacial cycles and its possible impact of seepage of gas have rarely been studied. Here, we present a detailed history of contourite development covering the last ∼130,000 years with most details for the last 60,000 years. The study is based on 43 marine sediment cores and 1,430 km of shallow seismic lines covering the ridge including methane seep sites, with the purpose of reconstructing changes in depositional patterns in relation to paleoceanographical changes on glacial, interglacial, and millennial time scale in relation to activity of seepage of gas. The results show that thick Holocene deposits occurred below ∼1,250 m water depth in the western part of the ridge. Both in pockmarks at western and eastern Vestnesa Ridge, seepage decreased at ∼10–9 ka in the early Holocene. The fine Holocene mud likely reduced seepage to a slow diffusion of gas and microbial oxidation probably prevented escape from the seafloor. Results also showed that seepage of gas was highly variable during the glacial, and low to moderate during the cold Heinrich stadial H1 (19–15 ka) and Younger Dryas stadial (13–12 ka). Seepage reached a maximum during the deglaciation in the Bølling and Allerød interstadials 15–13 ka and early Holocene 12–10 ka. The deglaciation was a period of rapid climatic, oceanographic, and environmental changes. Seepage of gas varied closely with these events indicating that slower tectonic/isostatic movements probably played a minor role in these millennial scale rapid fluctuations in gas emission.

"NOVOSIBIRSK" MUD VOLCANO AND EVIDENCE OF ITS ACTIVATIONS (LAKE BAIKAL)

An integrated study of mud volcanoes in the World Ocean is important for making assessment of potential geological-ecological disasters caused by rapid large-volume gas discharge into the water column and mud volcano eruptions at the bottom. The study of mud-volcanic activity in the past and determination of its periodicity are pioneering for the Baikal. The mud volcanoes and other hydrate-bearing structures are largely concentrated in the Middle Baikal basin along the tectonic faults. The most representative example of these phenomena is the "Gydratny" fault, four of six structures along which are mud volcanoes. An integrated geological-geophysical study (seismoacoustic and hydroacoustic sounding and geological sampling) of the "Novosibirsk" mud volcano, the largest and well-pronounced feature of the lake bottom relief, confirmed its structural identity with classical submarine mud volcanoes. The "Novosibirsk" mud volcano possesses all major elements of other single hydrate-bearing mud volcanoes of the lake which include volcanic cone in the bottom relief, vertical acoustically not transparent feeding channel, mud-volcanic breccia, gas saturation, and gas hydrates. This makes it one of the reference hydrate-bearing mud volcanic-type structures of Lake Baikal.The analysis of the bottom hydroacoustic profiling yielded evidence of the Late Pleistocene mud-volcanic eruptions shaped as two layers-flows at sub-bottom depths of 15 and 26 m (30 and 50 kyr ago, respectively). The presence of mud-volcanic breccia beneath the thin Holocene diatomic silt deposits testifies to the Holocene mud volcano activation due to the warm fluid rising from the depths to the volcano roots along the active segment of the tectonic fault in accordance with the model of the "Baikal-type" mud volcanism. Using the "Novosibirsk" mud volcano and the "Gydratny" fault as an example, it can be shown that the past tectonic activity of the Baikal basin may be determined based on the knowledge of the structure and evolution of the mud volcanoes of the lake.

Mechanism and genesis of Sanmen Bay as a sink of Holocene Yangtze River sediment, Zhejiang Province, China

Introduction: The Holocene mud deposits that extend from the Yangtze River mouth to the Taiwan Strait along the Zhejiang–Fujian coast, East China Sea (ECS), have attracted considerable research attention. However, there is a lack of consensus regarding the redistribution flux of Yangtze River sediment after it enters the sea. There are many bays along the Zhejiang and Fujian coasts, but their role in the source–sink process of Yangtze River sediment is not well-documented owing to limited data.Methods: In this study, data from shallow seismic profiles, core samples, and surface sediment samples were analysed to assess the role of Sanmen Bay, the second largest bay in Zhejiang Province, in the source–sink process of Yangtze River sediments.Results: The results showed that Sanmen Bay is an important sink for Yangtze River sediments. The characteristics of the clay minerals indicate that the fine-grained sediments in Sanmen Bay are mainly derived from Yangtze River sediments. The thickness of Holocene deposits in Sanmen Bay ranges from 8.2 to 32.0 m, with an average of 23.4 m and a total sediment volume of 5.06 × 104 Mt, accounting for 1% of Yangtze River sediment in this time period. The Bayesian age-depth model based on borehole accelerator mass spectrometry (AMS) 14C dating shows that a high sedimentation rate occurred in the early and late Holocene but decreased significantly in the mid-Holocene, which is similar to that of the inner shelf of the East China Sea (ECS).Conclusion: The variation in the Holocene sedimentation rate in Sanmen Bay is related to the southward transport process and mechanism of Yangtze River sediments. The results of this study provide a basis for understanding the source–sink process of sediment in large rivers.

Dissolved fluxes of nutrients and carbon at the sediment-water interface in the Adriatic Sea: review of early data and methods from the Italian National Research Council (CNR)

We report the measurement of the Fluxes of Dissolved Compounds at the Sediment-Water Interface (DFSWIs), obtained by analyzing data collected in the Italian Exclusive Economic Zone (EEZ) of the Northern and Central Adriatic Sea from 1982. We also describe the methods, honed by Italy’s Consiglio Nazionale delle Ricerche (CNR), employed to measure and calculate DFSWIs, including benthic chambers and landers, sediment-water interface micro-profiling, on-board incubation, and pore water modeling. Data analysis demonstrated that in situ measurements are the most reliable approaches, but that on-board collected data also supply interesting results. The DFSWI data allowed to divide the Adriatic seafloor into areas with similar DFSWI types and intensities and to define the role of sediments as sources or sinks of chemicals such as nutrients, Dissolved Inorganic Carbon (DIC), and metals. DFSWIs mainly depend on dissolved and solid river inputs, Marine Organic Matter (mOM) production, and sediment reworking. They show a seasonal temperature-related trend, which in summer induces increased chemical reaction kinetics and microbial activity. DFSWIs decline from the Po River mouths southward, along the Holocene mud wedge. North of the Po River Delta, the DFSWIs are weaker and confined to the areas in front of the major river mouths, due to poor Organic Matter (OM) inputs and strong reworking of bottom sediments. The area south of the Po Delta cusp is characterized by strong DFSWIs, due to the high deposition of solid inputs from the Po River, strong primary production, and protection from the Western Adriatic Current and Bora storms; in summer, higher temperatures, and calm hydrodynamic conditions generate near-bottom hypoxic to anoxic environments in this area. In Northern and Central Adriatic offshore areas, negative DIC and phosphate fluxes are due to poorly reactive OM reaching this area and to the mainly carbonate composition and oxic environment of local bottom sediments. DFSWI data analysis highlighted the important contribution of sediments to marine carbon and nutrient cycles. This is particularly important for carbon, which plays a major role in seawater acidification and global climate change. The study also provides average DFSWI data for each diagenetic area, which allow calculating the carbon and nutrient budgets in the Adriatic Sea.

Late Pleistocene to Holocene facies architecture and sedimentary evolution of the Zhejiang coast, East China Sea

The Holocene mud wedge that extends from the Yangtze River mouth to the Taiwan Strait along the Zhejiang–Fujian coast, East China Sea, has attracted considerable research attention; however, the pre-Holocene sedimentary evolution of the same area has been less well documented owing to limited data. We conducted an integrated analysis of 7000 km of high-resolution shallow seismic profiles and two ∼60–80-m-long borehole cores from the Zhejiang coast of eastern China to improve our understanding of the formation of the mud wedge in the context of the post-Late Pleistocene sedimentary evolution of the coastal area. Five major seismic units (numbered SU 1 to SU 5 in descending order) and various subunits that have formed since Marine Oxygen Isotope Stage (MIS) 5 were identified in the study area. SU 5 is recognizable only in the southeastern part of the study area and is interpreted to comprise subtidal to inner-shelf deposits (SU 5b) that were formed during MIS 5 and littoral to tidal-flat deposits (SU 5a) that were formed during the overall sea-level fall of MIS 4 and early MIS 3 (∼60–40 ka). These two subunits are divided by an intervening erosional surface that was likely generated by subaerial exposure of the study area during the sea-level lowstand of MIS 4. During the period from late MIS 3 to MIS 2, the study area was gradually exposed subaerially owing to further sea-level fall, with numerous small rivers incising the underlying strata to form a subaerial unconformity surface (T4). During the early postglacial transgression between ∼15.0 and ∼ 14.0 ka, the study area was progressively flooded, and the river channels were transformed into small estuaries (tidal rivers) that then coalesced into a large-scale, wave-dominated estuary during sea-level rise from ∼14.0 to ∼10.0 ka. The sandy fluvial and/or tidal-river deposits above T4 constitute SU 4. The wave-dominated estuary included a central estuarine bay on the landward side and an estuary-mouth complex on the seaward side, corresponding to fine-grained (muddy) deposits (SU 3a) and coarse-grained (sandy) deposits (SU 3b), respectively. The estuarine deposition concluded with the formation of a transgressive ravinement surface by erosional shoreface retreat during the rising sea level in the early MIS 1 from ∼13.5 ka in the southeasternmost part of the study area to ∼10.0 ka in the area closer to the shore. During the following transgressive phase, the study area was under coastal to shelf sedimentary environments during deposition of SU 2a. Tidal sand ridges (SU 2b) in the eastern part of the study area were formed at ∼11.5 ka and have been active since then. The maximum flooding surface was formed at ∼7.6 ka, and a mud wedge (SU 1) in the study area (except in the eastern part) has been developing since that time and is interpreted to have resulted from the deposition of sediments derived predominantly from the Yangtze River under the modern current system established since the maximum flooding in the Middle Holocene. The study provides new insights into the paleoenvironmental and paleogeographic evolution and facies architecture of the Zhejiang coast since MIS 5, which were controlled by preexisting geomorphological conditions and changes in sea level, hydrodynamics, and sediment supply.

Alluvial plain morphostratigraphy affected by recent mud and debris flows: a study in the Jacareí River basin (southern coast of Brazil)

Sedimentary records are important to understand the evolution of river systems. Morphostratigraphic studies associate sedimentary records with landforms. Mud and debris flows, common in the Serra do Mar mountain range, have a marked impact on the morphostratigraphy of adjacent alluvial plains. The objective of this study was to analyze morphostratigraphic units in an alluvial plain affected by recent mud and debris flows. The study area was the Jacareí River alluvial plain (coast of Paraná State, Brazil) which was hit by extreme gravitational events in March 2011. Geospatial and field survey data were analyzed in a GIS environment to produce a morphostratigraphic map. Units were identified in three contexts: formed earlier than 2011, formed by the 2011 mud and debris flows, and formed after 2011. The deposits instantly formed in 2011 present rocks and pebbles (debris flows) and massive sandy facies (mud flows), with a thickness of between 0.5 and 1 meter. They are easily identified due to abrupt changes in particle size, color, presence of roots, and quantity of organic matter. The results shed light on the evolutionary processes at work in the Jacareí River coastal plain landscape, withthe 2011 event representing a phase of the sedimentary cycle of alluvial plains along the Serra do Mar mountain range.

Microfossil evidence for a possible maar crater and tuff ring beneath Rangitoto Volcano, Auckland, New Zealand

ABSTRACT Distinctive low diversity foraminiferal and ostracod faunas in Holocene mud from a stratigraphic drillhole through Rangitoto Volcano (∼600 years old) indicate a highly sheltered, shallow-marine environment existed near the middle of the exposed entrance to Waitemata Harbour, Auckland, for at least 7000 years prior to Rangitoto’s eruption. Modern Analogue Technique estimates for these faunas indicate they accumulated at low tidal to shallow subtidal depths (0–11 m). The most similar analogue faunas lived subtidally in the extreme shelter inside the breached Onepoto maar lagoon, Auckland. Therefore, we infer the possible existence of a pre-7500 year-old maar crater and surrounding tuff ring buried beneath Rangitoto Volcano. This Holocene mud occurs in the drillhole 24–10 m lower than where the microfaunas indicate it accumulated. It is inferred to have slid into the adjacent harbour channel, along with 7 m of basaltic tuff and a piece of lava flow, near the start of the second phase of Rangitoto’s eruption.

Holocene water levels of Silver Lake, Montana, and the hydroclimate history of the Inland Northwest

AbstractThe wettest portion of the interior of western North America centers on the mountainous region spanning western Montana, Idaho, British Columbia, and Alberta. Inland ranges there capture the remnants of Pacific storms. Steep east–west hydroclimate gradients make the region sensitive to changes in inland-penetrating moisture that may have varied greatly during the Holocene. To investigate potential hydroclimate change, we produced a 7600-yr lake-level reconstruction from Silver Lake, located on the Montana–Idaho border. Ground-penetrating radar profiles and a transect of four shallow-water sediment cores that were dated using radiocarbon dating and tephrachronology revealed substantial changes in moisture through time. An organic-rich mud unit indicating wet and similar to modern conditions prior to 7000 cal yr BP is overlain by an erosional surface signifying drier than modern conditions from 7000–2800 cal yr BP. A subsequent time-transgressive increase in water levels from 2800–2300 cal yr BP is indicated by a layer of late Holocene muds, and is consistent with glacier expansion and increases in the abundance of mesic tree taxa in the region. Millennial-scale trends were likely driven by variations in orbital-scale forcing during the Holocene, but the regional outcomes probably depended upon factors such as the strength of the Aleutian Low, Pacific sea-surface temperature variability, and the frequency of atmospheric rivers over western North America.

Textures, provenances, and transport patterns of sediment on the inner shelf of the East China Sea

Although many studies have been carried out on the mud wedge in the inner shelf of the East China Sea (ECS), the sediment sources and seismic textures of the mud wedge are still unclear and remain controversial. Therefore, this study utilizes grain size and clay mineral analyses of surficial sediment samples and high-resolution sub-bottom seismic profile interpretation to identify the provenance and texture of these mud wedge sediments. The results show that sediment sources on the inner shelf of the East China Sea are mixed by the Yangtze River, small mountainous rivers along the Zhejiang-Fujian, and western Taiwan coasts. The sediments derived from the Ou and Min rivers are mainly concentrated in the shallowest shelf area within a water depth of 20 m which is located north of the Min River Estuary. Their contribution to the estuaries and coastal areas reflects the different sediment transport patterns of the two small mountainous rivers. The thickness of the Holocene mud wedge between Hangzhou Bay and Taizhou Bay is greater than 20 m at a water depth of approximately 10 m. The cause of this phenomenon is possibly related to the presence of the Zhoushan Islands, which are distributed along the Zhejiang coast and appear to effectively trap sediments from the Yangtze River, facilitating sediment accumulation. The findings of this study will help improve our understanding of the sediment transport and deposition mechanism of deposition on the inner shelf of the East China Sea.

Early diagenesis of sulfur in Bornholm Basin sediments: The role of upward diffusion of isotopically “heavy” sulfide

Sediment-hosted marine sulfur cycling has played a significant role in regulating Earth’s surface chemistry over our planet’s history. Microbially-mediated reactions involving sulfur are often accompanied by sulfur isotope fractionation that, in turn, is captured by sulfate and sulfide minerals, providing the opportunity to track changes in the microbial utilization of sulfur and thus the marine sulfur cycle. Studying sulfur diagenesis within the Bornholm Basin, Baltic Sea, we explore the interplay between carbon, sulfur and iron, focusing on the fate of sulfur and the dynamics of the sulfur and oxygen isotopic response as a function of the varying thickness of the organic carbon-rich Holocene Mud Layer (HML) across the basin. Using a one-dimensional reaction-transport model, porewater sulfate and sulfide profiles were used to calculate net sulfate reduction rates (SRR) and net sulfide production rates, respectively. These calculations suggest a positive relationship between the thickness of the HML and net rates of sulfate reduction and sulfide production. Given that ascending sulfide is enriched in 34S relative to that produced in-situ, a heightened sulfide flux promotes spatially variable precipitation of 34S-enriched pyrite (δ34S ≈ −10‰) close to the sediment–water interface. Modeling results indicate that this isotopically “heavy” sulfide is formed as a consequence of mixing between ascending sulfide (up to +6.3‰) and that produced in-situ (ca. −40‰). Further, we show that the sulfur and oxygen isotopic composition of porewater sulfate is controlled by the net SRR: when the net SRR is high (i.e., in sulfide-replete settings) the downcore increase in δ18OSO4 is dampened relative to increase in δ34SSO4, whereas when net SRR is low (i.e., in iron-rich parts of the basin) downcore δ18OSO4 values increase while δ34SSO4 values remain invariant. We conclude that sedimentation rates and open system diffusion strongly influence the distribution of sulfur species and their sulfur isotopic composition, as well as the oxygen isotopic composition of sulfate, through the interaction between iron, sulfur and methane. This work highlights the importance of considering diffusion to better understand open system diagenesis and the δ34S signatures of sulfate and sulfide in both modern settings and ancient rocks.

The uppermost Pleistocene–Holocene mud drape across the Marmara Sea: Quantification of detrital supply from southern Marmara rivers

The Marmara Sea (area 11,350 km2; volume 3378 km3; central basins >1100 m deep) straddles the North Anatolian Transform Fault separating the Eurasian and Aegean-Anatolian tectonic plates. Along with the shallow straits of Dardanelles and Bosphorus (depths ~63 m and ~40 m, respectively), the Marmara Sea forms the only marine connection between the Black Sea and the eastern Mediterranean. During Pleistocene glacial stages, the modern straits were subaerial valleys and the modern Marmara basin was occupied by the landlocked Propontis Lake. Previous researchers attributed major portions of a widely distributed uppermost Pleistocene–Holocene mud blanket (locally >10–25 m thick; volume 43–47 km3) to transport of suspended load through one or both of the straits, as either the Aegean Sea (at ~13.8 cal ka) or the Neoeuxine Lake (today's Black Sea, at ~11.1 cal ka) began to spill into the Marmara basin. To test these suggestions, the thicknesses and volume of the mud blanket were determined from >5000 line-km of airgun, sparker and boomer profiles and > 100 cores, and compared with the contemporary supply from local rivers to decide, by difference, if the straits might have had a significant role. Volume calculations for the detrital supply from rivers rely on (1) decades of daily water- and sediment-discharge data from gauging stations, acquired before 20th century dam construction and, independently, (2) the BQART model which uses a variety of hydrological, geomorphic, geological and climate data. These calculations demonstrate that >85–90% of the detritus in the offshore mud blanket was supplied by steep rivers (Kocasu River and its tributaries) and mountainous streams draining the highlands of the southern Marmara region. Geochemistry of the <38 μm fraction supports this source. Any input through the Dardanelles has been sporadic and limited to perhaps ~5 Gt of suspended load (equivalent to ~5.2 km3 of porous mud when deposited) because of changing directions and rates of flow since the Last Glacial Maximum. Resedimentation through mass wasting and transgressive shoreface erosion appear to be minor compared with river supply. The isolated nature of the Marmara basin and its supply from mostly a single watershed afford an opportunity to verify the reliability of this type of hindcast analysis, based upon sediment-discharge data and catchment models – analysis which cannot be completed with a comparable level of certainty along open marine coastlines elsewhere.

Observation of Diffusive Methane Emission from Holocene Mud Deposits on the Continental Shelf Offshore Southeastern Korea

Chun, J.-H.; Kim, Y.; Choi, J.-Y.; Kim, Y.J.; Lee, H.-J., and Kim, Y.H., 2020. Observation of diffusive methane emission from Holocene mud deposits on the continental shelf offshore southeastern Korea. In: Jung, H.-S.; Lee, S.; Ryu, J.-H., and Cui, T. (eds.), Advances in Geospatial Research of Coastal Environments. Journal of Coastal Research, Special Issue No. 102, pp. 127-136. Coconut Creek (Florida), ISSN 0749-0208.This study investigated gas-charged sediments found in Holocene mud deposits on the inner continental shelf offshore southeastern Korea. Headspace gases obtained from seven piston cores of Holocene mud deposits were analyzed using gas chromotography, and methane dissolved in the water column were analyzed using in situ methane sensors and gas chromotography. The methane concentration data from both sediments and water columns provide the evidences of diffusive methane emission from the inner continental shelf. The methane concentration of headspace gases ranged from 22.2 to 123.9 mM below the upper front of acoustic blanking zone (ABZ). The maximum anomaly of dissolved methane in the water column was 38.3 nM at a site 5 over rough seafloor in the ABZ, which is surrounded by water masses of relatively lower methane concentration. Dissolved methane concentrations were significantly lower (< 10 nM) in the upper water column (< 20 m water depth). Concentrations of dissolved methane within the whole water column in the gas-free zone (GFZ) were < 5 nM. These results imply that diffusive methane emission occurred from a rough seafloor with erosional features on the inner continental shelf at water depth of about 54 m; this diffusive methane emission was not related to high methane concentrations in piston core sediments of the shallow upper front of the ABZ.

Rapid Shifts in Chemical and Isotopic Compositions of Sediment Pore Waters in the Amami Sankaku Basin in Response to Initial Arc Rifting in the Mid‐Oligocene

AbstractPore waters were recovered from the sediment cores drilled in the back‐arc Amami Sankaku Basin (ASB) during the International Ocean Discovery Program Expedition 351. The sediment sequence is composed of the recent mud and ooze from late Oligocene/early Miocene accumulated at 7 m/Ma and rapid deposition of thick volcaniclastic sequence at 50 m/Ma. Such variations are reflected in the evolutions of chemical and isotopic compositions of pore waters. Cl and Ca concentrations in pore waters increased rapidly with depth and became enriched in the deep portion. Before arc rifting, extremely high deposition rates of volcaniclastic gravity‐flow sediments from the nearby Kyushu‐Palau arc into the ASB resulted in strong alteration, removing Mg and Si from pore waters. Mg concentrations were initially almost zero but abruptly shifted to substantial increases after ~29.5 Ma, indicating extended rifting of the active volcanic axis from the ASB. The δ18O and δD values of pore waters also evolved from more depleted and wide range to more positive and narrow range as a response to reduced alteration and increasing influence of seawater. Concentrations of Si and Mn in pore waters rapidly increased since ~29.5 Ma but suddenly declined at ~17.5 Ma due to the cessation of input of volcaniclastic materials. Covariations of Ca and Mg in pore waters are very similar to those in the back‐arc West Philippine Basin but significantly different from those in the Izu‐Bonin fore‐arc basin. Variations in chemical and isotopic compositions of pore waters can assist the reconstruction of tectonic activities.

Shallow gas in the Holocene mud wedge along the inner East China Sea shelf

Abstract High-resolution seismic surveys were carried out in the inner shelf of the East China Sea to investigate the distribution of shallow gas in Holocene sediments. Shallow gas is distributed extensively in the Holocene strata of the shelf which is dominated by the Yangtze River. Organic-rich, fine-grain sediments deposited throughout the Holocene are essential for gas generation and accumulation. The thickness of the Holocene sediment is the main controlling factor determining the distribution of shallow gas. Gas seepages were found mostly at a water depth up to 20 m, where sediment erosion mainly occurs. Coincidence between shallow gas seepage and high methane concentration in the water column suggests that gas emission from these sediments is a potentially significant source of greenhouse gas. The interaction between shallow gas migration and coastal erosion would therefore potentially lead to increased greenhouse gas emission and accelerated sediment erosion. Such results can be applied to other costal locations around the world.

Microbial methane production and oxidation in the Holocene mud beneath the Kanto Plain of central Japan

Microbial methane production and oxidation in the Holocene mud beneath the Kanto Plain of central Japan

Seismic morphology and infilling architecture of incised valleys in the northwest South Yellow Sea since the last glaciation

Based on the interpretation of ∼3000 km of high-resolution seismic profiles, the small local rivers that form the channel network of the northwestern South Yellow Sea are identified for the first time. Incised-valley systems orientated NW–SE and NE–SW were detected outside Dingziwan Bay and Rushan Bay, respectively. Analysis of the sedimentation and fill sequences of these valleys revealed six main types of fill architecture: horizontal or near-horizontal, lateral, undulate-wavy, concave, divergent, and chaotic. Stratigraphic sequence relationships and AMS 14C and OSL dating of two cores (QDZ03 and QDZ01) suggest that these incised valleys were formed during the period from late Marine Isotope Stage 3 (MIS 3) to MIS 1, between 30 and 11 ka BP. The incised-channel fill begins with fluvial sediments and shows a transition to estuarine sediments that are truncated by a transgressive ravinement. There is little evidence of lag deposits at the base of the fill and no evidence of capping by Holocene mud deposits. The incised-valley model presented in this paper differs from current classical sequence stratigraphic models and contributes to our understanding of incised valleys.

Kinetics of organic carbon mineralization and methane formation in marine sediments (Aarhus Bay, Denmark)

Abstract Sediments were sampled at nine stations on a transect across a 7–10 m thick Holocene mud layer in Aarhus Bay, Denmark, to investigate the linkages between CH4 dynamics and the rate and depth distribution of organic matter degradation. High-resolution sulfate reduction rates determined by tracer experiments (35S-SRR) decreased by several orders of magnitude down through the mud layer. The rates showed a power law dependency on sediment age: SRR (nmol cm−3 d−1) = 106.18 × Age−2.17. The rate data were used to independently quantify enhanced SO42− transport by bioirrigation. Field data (SO42–, TCO2, T13CO2, NH4+ and CH4 concentrations) could be simulated with a reaction-transport model using the derived bioirrigation rates and assuming that the power law was continuous into the methanogenic sediments below the sulfate-methane transition zone (SMTZ). The model predicted an increase in anaerobic organic carbon mineralization rates across the transect from 2410 to 3540 nmol C cm−2 d−1 caused by an increase in the sediment accumulation rate. Although methanogenesis accounted for only ∼1% of carbon mineralization, a large relative increase in methanogenesis along the transect led to a considerable shallowing of the SMTZ from 428 to 257 cm. Methane gas bubbles appeared once a threshold in the sedimentation accumulation rate was surpassed. The 35S-measured SRR data indicated active sulfate reduction throughout the SO42− zone whereas quasi-linear SO42− gradients over the same zone indicated insignificant sulfate reduction. This apparent inconsistency, observed at all stations, was reconciled by considering the transport of SO42− into the sediment by bioirrigation, which accounted for 94 ± 2% of the total SO42− flux across the sediment-water interface. The SRR determined from the quasi-linear SO42− gradients were two orders of magnitude lower than measured rates. We conclude that models solely based on SO42− concentration gradients will not capture high SRRs at the top of the sulfate reduction zone if they do not properly account for (i) SO42− influx by bioirrigation, and/or (ii) the continuity of organic matter reactivity with sediment depth or age.

OSL chronology of the Huksan Mud Belt, south-eastern Yellow Sea, and its paleoenvironmental implications

The Huksan Mud Belt (HMB) is located in the south-eastern Yellow Sea. The radiocarbon (14C) and optically stimulated luminescence (OSL) age datings of the pre-Holocene HMB sediments were compared precisely. OSL dates for the uppermost HMB sediments showed the recent and short-term chronological development of the HMB. OSL and 14C ages of the Holocene sediment (HMB cores 101–103) were relatively consistent. By contrast, the OSL ages of the pre-Holocene sediment unit were considerably older than the 14C ages (by approximately 30%), where the OSL ages corresponded broadly to marine isotope stages (MIS) 5 and 4 (from about 125 ka to > 50 ka). An overall comparison of 14C and OSL dates suggests that the age of the Holocene mud unit is well constrained by 14C dating. However, 14C ages older than 40 ka may be unreliable. The surficial sedimentation rate and depositional ages for a 6.5-m-thick sequence of the uppermost unit (12HMB cores) were determined. Twenty OSL samples gave an age of approximately 8.5 ka. Most of the OSL ages for each site were in stratigraphic order. The surficial sediment ages for the 12 HMB cores were 2.6 ka for P-08, 7.7 ka for P-10, 7.3 ka for P-11, and 0.05 ka for P-14. The approximate surficial sediment ages of the uppermost unit of the HMB-101, -102, and −103 cores were 6.7 ka, 6.8 ka, and 1.1 ka, respectively. The spatiotemporal differences in deposition and erosion of the HMB Holocene muds, supposedly driven by changes in large, strong tidal forces and marine water depth, and an increase in ocean current velocity, could account for the various surficial deposition ages in the area.