This study investigated the effect of grain boundary engineering (GBE) on the corrosion behavior and high-temperature mechanical properties of GH3535 alloy in 45LiCl-55KCl wt.% molten salt at 550°C. After corrosion for 300 h, a triple-layered product was formed on the solid solution specimen (Non-GBE), consisting of discontinuous NiCr2O4 outer-layer, Ni3Fe middle-layer, and NiCr2O4 inner-layer. For the GBE specimen, quite milder corrosion occurred on it that its surface still kept original polishing scratches. The real mass loss of the Non-GBE alloy (6.85 mg/cm2) is one order of magnitude higher than that of GBE (0.65 mg/cm2). The beneficial effect of GBE on improving alloy's corrosion resistance is owing to: surface carbide dissolution, discontinuous random high angle grain boundary and low dislocation density. High proportion of Σ3n grain boundaries and less carbide precipitation ensure stable high-temperature deformation performance of GBE sample in molten salt.
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