Polycyclic Aromatic Hydrocarbons Ratios Research Articles

Polycyclic Aromatic Hydrocarbons Contamination and Quality of Locally Produced Crude Palm Oil in South-South Zone, Nigeria

Background: Oil palm, Elaeis guineensis Jacq is a perennial crop mainly cultivated for its vegetable oil. The fatty acid composition of crude palm oil (CPO) is mostly composed of palmitic, stearic oleic, and linoleic acids. Objectives: This study evaluated the quality of locally produced CPO from six states of South-South zone, Nigeria. Methods: The parameters of CPOs were characterized by specific gravity (SG), acid value (AV), percentage of free fatty acid (%FFA), and saponification value (SV) and peroxide value (PV). Polycyclic aromatic hydrocarbons (PAHs) in CPO were quantified using standard procedures, the related risk due to daily consumption of 25 g was characterized by lifetime cancer risk (LCR) and margin of exposure (MOE). Results: The study observed that the mean values of the parameters were 0.931 SG; 5.01 mgKOH g-1 AV; 2.28% FFA; 177.27 mgKOH g-1 SV and 29.65 meqO2 kg-1 PV. Apart from %FFA, the others did not meet the requirements recommended by the Codex Alimentarius Commission of the joint WHO/FAO. Diagnostic ratios of PAHs suggested a mixture of petrogenic and pyrogenic origins. The MOEs showed low health concern while 16PAH-LCR values which ranged from 2.48E-04 - 4.48E-04 were unacceptable. The screening value 0.003 was significantly (p> 0.05) lower than the computed total BaP equivalent (BaPeq) values indicating potential human health concerns. It is recommended that CPO processing and storage methods should be properly monitored to prevent quality reduction and contamination, which might have adverse effect on consumers.

Investigation of 200 anthropogenic activities in a representative alpine peatland in the Altay Mountains, northwestern China.

Peatlands records can be used to reconstruct and understand the history of environmental evolution, as well as a more accurate reflection of human activities. The black carbon (BC) and polycyclic aromatic hydrocarbons (PAHs) are ideal natural archives of anthropogenic activities. To identify the information of anthropogenic activities recorded by peatlands in the middle and high latitudes of the alpine mountains in the arid and semi-arid regions of China. this study analyzed the concentrations of BC, δ13C ratios of BC, PAHs, and molecular diagnostic ratios of PHAs (including Benzo(a) anthracene (BaA), Chrysene (Chr), fluoranthene (Flt), anthracene (Ant), phenanthrene (Phe), Benzo(a) pyrene (BaP), and pyrene (Pyr) in a 30-cm peat profile from the Altay Mountain, northwestern China. Our results revealed concentrations of BC from 11.71 to 67.5mg·g-1, and PAHs from 168.09 to 263.53ng·g-1. The δ13CBC value ranged from - 31.37 to - 26.27‰, with an average of - 29.54‰, indicating that the BC mainly comes from biomass combustion. The ratios of BaA/(BaA + Chr), Flt/(Flt + Pyr), and Ant/(Ant + Phe) exceeded 0.35, 0.5, and 0.1, respectively, revealing that the PAHs pollutants mainly originated from the combustion of biomass and fossil fuel burning. Furthermore, based on these findings and our knowledge of social development in Altay, industrial transport and tourism have influenced the emission, transport, and deposition of BC and PAH in peatlands in the Altay mountains since the 1980s. After 1980, pollutant concentrations decreased with the implementation of environmental policies. The results not only reveal the influence of anthropogenic activities on the sedimentary characteristics of peatlands in the Altay Mountains, but also provide an important theoretical basis for the conservation of fragile mountain peatlands.

Effect of changes in the fuel type of thermal power plants on the spatial distribution and levels of PAH pollution in the Vorkuta agglomeration beyond the Arctic Circle

The paper is a study of the composition of 15 polycyclic aromatic hydrocarbons (PAHs) in the snow cover of Vorkuta (Komi Republic) in the impact zone of the fuel and energy complex in 2017 and 2023. We have identified high aerotechnogenic pollution of the Vorkuta city and adjacent territories with PAHs during heating with fuel oil and coal, with a mean concentration of 301.6 ng/L (meltwater plus particles) and spatial distribution of 85.2 μg/m2. There is a significant decrease in PAH levels when the fuel for thermal power plants has been changed to natural gas, with a mean concentration of 26.1 ng/L (meltwater plus particulates) and spatial distribution of 4.9 μg/m2. The deposition areas of different PAH fractions are identified in the impact zones of Thermal Power Plants 1 and 2, the Central Boiler House and the urbanised areas of the Vorkuta agglomeration. 2-4-ring PAHs dominate in the emissions, accounting for 92–100 % of the sum of PAHs from coal/oil combustion and 66–93 % from natural gas combustion. The indicator ratios of PAHs in the snow cover of Vorkuta in both 2017 and 2023 indicate their predominantly pyrogenic genesis. The environmental risk coefficients of PAHs in the snow cover and their change from 2017 to 2023 are calculated. TEQ changed from 2.1 ng/L (mean) in the 2017 season to 1.7 ng/L (mean) in the 2023 season. The risk quotients have been reduced from moderate risk to low risk. Reconstruction of thermal power plants when replaced by more environmentally friendly fuel (natural gas) reduces the amount of atmospheric emissions of organic pollutants.

Disentangling the association of PAH molecules with star formation

Context. Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous complex molecules in the interstellar medium and are used as an indirect indicator of star formation. On the other hand, the ultraviolet (UV) emission from young massive stars directly traces the star formation activity in a galaxy. The James Webb Space Telescope (JWST), along with the UltraViolet Imaging Telescope (UVIT), opened up a new window of opportunity to better understand the properties of PAH molecules that are associated with star-forming regions. Aims. We investigate how the resolved scale properties of PAH molecules in nearby galaxies are affected by star formation. Methods. We analyzed the PAH features observed at 3.3, 7.7, and 11.3 μm using F335M, F770W, and F1130W images obtained from the JWST. These images helped us identify and quantify the PAH molecules. Additionally, we used UVIT images to assess the star formation associated with these PAH-emitting regions. Our study focused on three galaxies, namely NGC 628, NGC 1365, and NGC 7496, which were selected based on the availability of both JWST and UVIT images. Bright PAH emission regions were identified in the JWST images, and their corresponding UV emission was estimated using the UVIT images. We quantified the star formation properties of these PAH emitting regions using the UVIT images. Furthermore, we investigated the relation between the star formation surface density (ΣSFR) and the PAH ratios to better understand the impact of star formation on the properties of PAH molecules. Results. Based on the resolved scale study of the PAH-bright regions using JWST images, we found that the fraction of ionized PAH molecules is high in the star-forming regions with high ΣSFR. We observed that emission from smaller PAH molecules is higher in star-forming regions with higher ΣSFR. Conclusions. Our study suggests that the PAH molecules excited by the photons from star-forming regions with higher ΣSFR are dominantly smaller and ionized molecules. UV photons from the star-forming regions could be the reason for the higher fraction of the ionized PAHs. We suggest that the effect of the high temperature in the star-forming regions and the formation of smaller PAH molecules in the star-forming regions might also result in the higher emission in the F335MPAH band.

Polycyclic aromatic hydrocarbons (PAHs) evidence for frequent combustion events on land during the Permian–Triassic transition in Northwest China

The Siberian Traps large igneous province and intensive continental arc volcanism are regarded as the primary drivers of the severe environmental changes that triggered the end-Permian mass extinction. However, detailed correlations between volcanism and the collapse of terrestrial ecosystems remain ambiguous. This study used polycyclic aromatic hydrocarbons (PAHs) records and mercury spikes from the terrestrial Dalongkou section as refined proxies for volcanic combustion events. The mercury anomalies, PAH concentrations, and PAH ratios provide insight into the terrestrial ecosystem collapse during the Permian–Triassic (P–T) transition. Based on the multiple PAH ratios, the source and composition of PAHs exhibit obvious pyrolytic-derived origins during the late Permian. Combined with the biostratigraphic records and our PAH proxies in the Dalongkou section, terrestrial ecosystems experienced stepwise crisis and change owing to volcanic effects and frequent high-temperature combustion events during the P–T transition. During the main terrestrial P–T crisis interval, the increased PAH concentrations indicate that the combustion events were gradually enhanced under worse climatic conditions. Based on the PAH records, enhanced soil erosion accompanied by frequent wildfires was found to occur under extremely high-temperature climatic conditions caused by intensive volcanic activity during the P–T transition.

Spatial-temporal Distribution and Source Analysis of Polycyclic Aromatic Hydrocarbons in the Sediments of Poyang Lake

The concentrations, spatial-temporal distribution, and influencing factors of 16 polycyclic aromatic hydrocarbons (PAHs) in the sediments of Poyang Lake were studied, and a quantitative source analysis of PAHs in different areas of the lake was conducted. PAHs were widespread within the sediments. The concentrations of ∑16PAHs in the surface sediments of all sites ranged from 203 to 2 318 μg·kg-1. The concentrations of PAHs in the surface sediments of the lake body were higher than those in the surface sediments of the inlet rivers. The ratio of PAHs in Poyang Lake was 4 rings > 5 rings > 6 rings > 3 rings > 2 rings; the composition of 4-ring PAHs was dominant, and its content accounted for 86.11% of ∑16PAHs. The 2- and 3-ring and some 4-ring PAHs, including Flua and Pyr, were more susceptible to SOM, and the 4 through 6-ring PAHs were more susceptible to ORP and heavy metals and other environmental factors. Spatially, the higher concentration of ∑16PAHs occurred in the area of the lake adjacent to Duchang County and Poyang County, where the terrain was relatively closed, and the water exchange with the surrounding area was less than that in other sections, which was not conducive to the migration, transformation, and degradation of pollutants. In the temporal distribution, the changes in PAHs concentration level and the development of GDP in Jiangxi Province showed high consistency, and the influence of economic development and human activities might have been the main reason for the increasing PAHs concentration level. The main sources of PAHs in surface sediments of Poyang Lake included petroleum pollution and oil and coal and biomass combustion sources, and there were some spatial differences in PAHs sources in different regions. This study can provide a reference for PAHs pollution in surface sediments of Poyang Lake, which is important for the ecological environmental protection and management of Poyang Lake.

Characterization of persistent organic contaminants in the atmosphere of Gadani's ship breaking yards and its surrounding: Implications for sustainable ship recycling practices

Gadani is internationally renowned for its extensive ship-breaking operations, positioning it as one of the globe's primary ship-breaking hubs. A comprehensive study was conducted to evaluate the presence of organic contaminants in the air within Gadani, encompassing the areas surrounding ship-breaking facilities, proximate residential settlements, and adjacent roadways. Passive air samplers were employed to collect a total of 30 air samples. The analytical results unveiled a notably elevated concentration of specific organic compounds, with a pronounced prevalence of polycyclic aromatic hydrocarbons (PAHs), short-chain chlorinated paraffins (SCCPs), and polychlorinated biphenyls (PCBs) at the ship-breaking yard. Notably, dichlorodiphenyltrichloroethanes (DDTs) and DDE were detected at substantially lower levels. In particular, sites in close proximity to ship-breaking activities exhibited elevated concentrations of PCBs (Σ7PCB 0.065429 to 7.345714 ng/sample), PAHs (Σ8PAH 2.44 to 134.23 ng/sample), and SCCPs (0.18 to 25.6 ng/sample). Conversely, DDTs and DDE demonstrated higher concentrations near residential settlements. The evaluation of Molecular Diagnostic Ratios for PAHs revealed anthracene/anthracene + phenanthrene ratios of 0.88, 0.69, and 0.5 for ship-breaking areas, roadside locations, and community surroundings, respectively. Furthermore, the benz[a]anthracene/benz-[a]anthracene + chrysene molecular ratios were measured at 0.77 (ship-breaking sites), 0.82 (roadside), and 0.83 (community), respectively. The molecular ratio of fluoranthene/fluoranthene + pyrene at ship-breaking sites was 0.23, while roadside and community ratios were 0.36 and 0.89, respectively. These findings underscore the significant contribution of ship-recycling activities to the atmospheric release of SCCPs, PCBs, and PAHs, emphasizing the global imperative for responsible ship recycling practices.

History of organic pollution in montane lake Issyk-Kul, Kyrgyzstan, Central Asia, inferred from a sediment core

In arid regions, montane lakes are valuable water sources and play important ecological roles. However, recent human-induced inputs of organic pollutants are threatening lake ecology in such regions and becoming a matter of great concern. To investigate pollutant histories and sources, we measured polycyclic aromatic hydrocarbons (PAHs) and n-alkanes in a dated sediment core that spans the last ∼350 years, from montane Lake Issyk-Kul (Kyrgyzstan, Central Asia). Results showed that organic pollutants were delivered to Lake Issyk-Kul in four stages and that their concentrations increased from Stage I (∼1670–1800 CE) to Stage IV (∼2000–2010 CE). Furthermore, we tracked the sources of sedimented PAHs using their ratios combined with n-alkanes data. Ratios of PAHs Ant/(Ant + Phe), Flt/(Flt + Pyr) and Bap/BghiP indicated that inputs during Stage II (∼1800–1970 CE) and Stage III (∼1970–2000 CE) came mainly from high-temperature combustion of coal and vehicle emissions. PAHs in Stage I and Stage IV, however, were mainly derived from low-temperature combustion and petrogenic sources. Diagnostic PAH ratios, combined with the natural n-alkane ratio (NAR＜0) and unresolved complex mixtures (UCM), showed that the sources of PAHs in Stage I were mainly from erosion of bedrock and partly influenced by forest wildfires, different from the source during Stage IV, which was mainly from refined petroleum caused by accidental spills. Our assessment of the contamination history of the lake indicates that toxicity risk to the waterbody from sediment PAHs is low, but recent discharges arising from traffic deserve attention.

Radio Jet Feedback on the Inner Disk of Virgo Spiral Galaxy Messier 58

Spitzer spectral maps reveal a disk of highly luminous, warm (>150 K) H2 in the center of the massive spiral galaxy Messier 58, which hosts a radio-loud active galactic nucleus (AGN). The inner 2.6 kpc of the galaxy appears to be overrun by shocks from the radio jet cocoon. Gemini NIRI imaging of the H2 1–0 S(1) emission line, Atacama Large Millimeter/submillimeter Array CO 2–1, and Hubble Space Telescope multiband imagery indicate that much of the molecular gas is shocked in situ, corresponding to lanes of dusty molecular gas that spiral toward the galactic nucleus. The CO 2–1 and ionized gas kinematics are highly disturbed, with velocity dispersion up to 300 km s−1. Dissipation of the associated kinetic energy and turbulence, likely injected into the interstellar medium by radio-jet-driven outflows, may power the observed molecular and ionized gas emission from the inner disk. The polycyclic aromatic hydrocarbon (PAH) fraction and composition in the inner disk appear to be normal, in spite of the jet and AGN activity. The PAH ratios are consistent with excitation by the interstellar radiation field from old stars in the bulge, with no contribution from star formation. The phenomenon of jet-shocked H2 may substantially reduce star formation and help to regulate the stellar mass of the inner disk and supermassive black hole in this otherwise normal spiral galaxy. Similarly strong H2 emission is found at the centers of several nearby spiral and lenticular galaxies with massive bulges and radio-loud AGNs.

Characterization and health risk assessment of PM2.5-bound polycyclic aromatic hydrocarbons in Yangon and Mandalay of Myanmar

To better understand the potential adverse health effects of atmospheric fine particles in the Southeast Asian developing countries, PM2.5 samples were collected at two urban sites in Yangon and Mandalay, representing coastal and inland cities in Myanmar, in winter and summer during 2016 and 2017. The concentrations of 21 polycyclic aromatic hydrocarbons (PAHs) in PM2.5 were determined using a gas chromatography–mass spectrometry (GC–MS). The concentrations of PAHs in PM2.5 in Yangon and Mandalay ranged from 7.6 to 180 ng m−3, with an average of 72 ng m−3. The PAHs were significantly higher in winter than in summer, and significantly higher in Mandalay than in Yangon. The health risk analysis of PAHs, based on the toxic equivalent quantity (TEQ) calculation, and the incremental lifetime cancer risk (ILCR) assessment indicated that PM2.5 in Myanmar has significant health risks with higher health risks in Mandalay compared to Yangon. Diagnostic ratios of PAHs, correlation of PAHs with other species in PM2.5 and the positive matrix factorization (PMF) analysis showed that TEQ is strongly affected by biomass burning and vehicular emissions in Myanmar. Additionally, it was found that the aging degree of aerosols and air mass trajectories had great influences on the concentration and composition of PAHs in PM2.5 in Myanmar, thereby affecting the toxicity of PM2.5.

Anthropogenic emission controls organic aerosols at Gosan background site in the outflow from northeast Asia

Anthropogenic activities release substantial amounts of organic components into the atmosphere. In this study, eight groups of organic compounds such as polycyclic aromatic hydrocarbons (PAHs), hopanes, steranes, n-alkanes, fatty acids, fatty alcohols, phthalate esters, and lignin and resin acids were identified in the ambient aerosol samples collected from a regional background site in the Korean Climate Observatory at Gosan (KCOG), South Korea. The total identified organics were most abundant in winter (220 ± 60.3 ng m−3), followed by spring, autumn, and summer, with the predominance of n-fatty acids. All classes of aliphatic lipid components showed a significant positive correlation with fossil fuel-derived organic carbon (OC-FF) and biomass burning-derived organic carbon (OC-BB), indicating that they were abundantly emitted from anthropogenic sources such as fossil fuel combustion and biomass burning. The composition profiles and diagnostic ratios of PAHs indicate that they were largely derived from coal and/or biomass combustion in the continent. In contrast, hopanes are predominantly emitted from gasoline or diesel engines, particularly in the summer, from commercial ships. The high concentration of phthalates in the summer suggested that plastic emissions from the open ocean substantially contributed to the Gosan aerosols. The low ratios of unsaturated/saturated fatty acids indicate that Gosan organic aerosols were photochemically aged during atmospheric transport. The temporal and seasonal variations of organic species over KCOG provide crucial information on the emission strengths of different contributing sources in the East Asian outflow. Positive Matrix Factorization (PMF) results and 14C-based source apportionment studies demonstrated that anthropogenically derived organic aerosols largely contributed to the aerosol mass over KCOG. Thus, the East Asian continent might be the major source region for organic aerosols over the western North Pacific, except in the summer.

GOALS-JWST: Small Neutral Grains and Enhanced 3.3 μm PAH Emission in the Seyfert Galaxy NGC 7469

We present James Webb Space Telescope (JWST) Near Infrared Spectrograph (NIRSpec) integral field spectroscopy of the nearby luminous infrared galaxy NGC 7469. We take advantage of the high spatial/spectral resolution and wavelength coverage of JWST/NIRSpec to study the 3.3 μm neutral polycyclic aromatic hydrocarbon (PAH) grain emission on ∼200 pc scales. A clear change in the average grain properties between the star-forming ring and the central AGN is found. Regions in the vicinity of the AGN, with [Ne iii]/[Ne ii] > 0.25, tend to have larger grain sizes and lower aliphatic-to-aromatic (3.4/3.3) ratios, indicating that smaller grains are preferentially removed by photodestruction in the vicinity of the AGN. PAH emission at the nucleus is weak and shows a low 11.3/3.3 PAH ratio. We find an overall suppression of the total PAH emission relative to the ionized gas in the central 1 kpc region of the AGN in NGC 7469 compared to what has been observed with Spitzer on 3 kpc scales. However, the fractional 3.3 μm–to–total PAH power is enhanced in the starburst ring, possibly due to a variety of physical effects on subkiloparsec scales, including recurrent fluorescence of small grains or multiple photon absorption by large grains. Finally, the IFU data show that while the 3.3 μm PAH-derived star formation rate (SFR) in the ring is 27% higher than that inferred from the [Ne ii] and [Ne iii] emission lines, the integrated SFR derived from the 3.3 μm feature would be underestimated by a factor of 2 due to the deficit of PAHs around the AGN, as might occur if a composite system like NGC 7469 were to be observed at high redshift.

Occurrence, distribution and sources of petroleum contamination in reef-associated sediments of the Gulf of Mannar, India

The distribution of saturated hydrocarbons and polycyclic aromatic hydrocarbons (PAHs) was assessed in superficial sediment samples collected from Mandapam island groups, Gulf of Mannar, India. The hydrocarbon distribution pattern and the n-alkane indices (e.g., carbon preference index (CPI) and natural n-alkanes ratio (NAR)) were deployed to differentiate between the biogenic and anthropogenic sources. Petroleum pollution was indicated by the pristane/phytane ratio close to 1. Presence of a prominent unresolved complex mixture (UCM) as well as hopane concentrations further supported this assertion. The evaluation of petrogenic sources of contamination were also comprehended by various diagnostic ratios of PAHs. The sites associated with shipping activities, tourism, and located near the mainland and accessible portions of the islands exhibited high petroleum contamination. Correlation analysis underlines the significance of combining petroleum-specific marker compounds and diagnostic ratios to improve the assessment of human influence on marine ecosystems.

Profiles, exposure assessment and expanded screening of PAHs and their derivatives in one petroleum refinery facility of China

This study investigated environmental distribution and human exposure of polycyclic aromatic hydrocarbons (PAHs) and their derivatives in one Chinese petroleum refinery facility. It was found that, following with high concentrations of 16 EPA PAHs (∑Parent-PAHs) in smelting subarea of studied petroleum refinery facility, total derivatives of PAHs [named as XPAHs, including nitro PAHs (NPAHs), chlorinated PAHs (Cl-PAHs), and brominated PAHs (Br-PAHs)] in gas (mean= 1.57 × 104 ng/m3), total suspended particulate (TSP) (mean= 4.33 × 103 ng/m3) and soil (mean= 4.37 × 103 ng/g) in this subarea had 1.76–6.19 times higher levels than those from other subareas of this facility, surrounding residential areas and reference areas, indicating that petroleum refining processes would lead apparent derivation of PAHs. Especially, compared with those in residential and reference areas, gas samples in the petrochemical areas had higher ∑NPAH/∑PAHs (mean=2.18), but lower ∑Cl-PAH/∑PAHs (mean=1.43 × 10−1) and ∑Br-PAH/∑PAHs ratios (mean=7.49 × 10−2), indicating the richer nitrification of PAHs than chlorination during petrochemical process. The occupational exposure to PAHs and XPAHs in this petroleum refinery facility were 24–343 times higher than non-occupational exposure, and the ILCR (1.04 × 10−4) for petrochemical workers was considered to be potential high risk. Furthermore, one expanded high-resolution screening through GC Orbitrap/MS was performed for soils from petrochemical area, and another 35 PAHs were found, including alkyl-PAHs, phenyl-PAHs and other species, indicating that profiles and risks of PAHs analogs in petrochemical areas deserve further expanded investigation.

Sediment record of polycyclic aromatic compounds and black carbon over the last ~400 years in Sanjiaolongwan Maar Lake, northeast China

Fuel usage is an important catalyst for socio-economic development and human well-being. Human activities have resulted in significant increases in emissions from biomass burning (BB) and fossil fuel (FF) combustion which have significantly adversely affected human, ecosystem, and planetary health in this era of the Anthropocene. Sanjiaolongwan Maar Lake (SJLW), as a typical crater lake, uniquely receives atmospheric deposition from long-distance transport, and thus, its sediments reflect environmental change and human impacts on a broad scale. In this study, the concentrations and compositions of combustion products, including polycyclic aromatic compounds (PACs, i.e., polycyclic aromatic hydrocarbons (PAHs) and their oxygenated (OPAHs) and nitrogen heterocyclic derivatives (AZAs)) and black carbon (BC and its constituents char and soot), in SJLW over the past 400 years were investigated. The results showed that the PACs and soot concentrations and fluxes in SJLW have rapidly increased since 1950. The concentrations of the total PACs increased ~4 times after the 1950s. Such a fast increase is consistent with the rapid industrialization after the establishment of the People's Republic of China (PRC), which has further accelerated beginning with the implementation of the reform and opening up policy of the PRC in 1978. Moreover, the variations in the compositions of PACs, as well as the decrease in the char/soot ratio, demonstrate a transition in energy usage from BB to FF combustion. The decrease in the benzo[e]pyrene/benzo[a]pyrene ratio indicated an increase in local emissions (because of increasing industrialization in northeast China). The temporal profile of perylene concentrations, fluxes, and perylene/5-ring PAHs ratios strongly suggest that perylene mainly originated from non-pyrogenic sources. The records of PACs and BC in SJLW offer valuable perspectives on human impacts and provide important references for the start of the Anthropocene.

New insights on black carbon in pelagic Atlantic sediments

Black carbon (BC) is ubiquitous in pelagic sediments and presumed to have an older radiocarbon age due to long ocean residence times and pre-aging in terrestrial soils. Here, we analyzed sediments from five regions in the subtropical Atlantic Ocean to quantify the black carbon fraction of the total organic carbon pool. Black carbon, derived from the chemothermal oxidation method, comprised between 17 ± 6% of the sedimentary organic carbon in the Northwest Argentina Basin and 65 ± 18% in the Amazon Delta. Black carbon sediment accumulation rates were six times greater in the Sierra Leone Rise (8.4 ± 4.1 mg cm−2 kyr−1) compared to the remote Northwest Argentina Basin (1.3 ± 0.4 mg cm−2 kyr−1), possibly due to enhanced regional atmospheric deposition from annual African grassland fires. The radiocarbon age for BC from subtropical Atlantic sediments were more modern compared to the bulk total organic carbon, and BC source was apportioned as biomass burning byproducts from their stable carbon isotopic signatures and characteristic ratios of polycyclic aromatic hydrocarbons. This study demonstrated that subtropical Atlantic Ocean sediments serve as an important sink for young BC.

Lichens as bio-monitors of polycyclic aromatic hydrocarbons: Measuring the impact of features and traffic patterns

The role of road characteristics, including gradient and speed control devices, in influencing emission dynamics remains to be fully elucidated. Most studies have focused on fuel consumption as an indirect indicator of sector emissions instead of directly quantifying specific pollutants, like polycyclic aromatic hydrocarbons (PAHs). This research approach is often due to the complexities involved in capturing these pollutants and their subsequent analysis. Bio-monitors, such as lichens, offer an economically viable method. Their wide distribution across various habitats enables the comparison of PAH levels in diverse environments. Against this background, The present work analyses the ability of tropical lichens to indicate the effect that traffic patterns and geometric design features of roads (traffic activity, road gradient, traffic control devices, and vehicular speed) have on the emission of PAH concentration. Results showed that PAHs in lichens strongly correlated with the road gradient (Spearman correlation, p<0.005 with R=0.98). Each 1% increase in road gradient implies a rise of 24 ngPAH/gLichen in National Road. Additionally, a trend coherent of PAH concentration with the vehicle speed profile was observed on Panamericana Road. Speed control devices were associated with higher concentrations of PAHs due to acceleration and braking actions that increment fuel consumption. Finally, the results evidenced that lichens helped determine the source of aromatics and their carcinogenic potential using the diagnostic ratio of PAHs and the carcinogenic equivalence sum, respectively.

Multi-class organic pollutants in PM2.5 in mixed area of Shanghai: Levels, sources and health risk assessment

The occurrence of 25 multi-class pollutants comprising phthalate esters (PAEs), polycyclic aromatic hydrocarbons (PAHs), and synthetic musks (SMs) were studied in PM2.5 samples collected at an industrial/commercial/residential/traffic mixed area in Shanghai during four seasons. During the whole period, a slight exceedance of the PM2.5 annual limit was observed, with an average of 36.8 μg/m3, and PAEs were the most predominant, accounting for >70 % of the studied organic pollutants in PM2.5, followed by PAHs and SMs. Statistically significant differences were observed for the concentrations of PM2.5, PAEs, PAHs, and SMs in winter and summer. This seasonal variation could be derived from anthropogenic activities and atmospheric dynamics. Principal component analysis (PCA) and PAHs ratios suggested a mixed source mainly derived from vehicle emissions and industrial processes. Moreover, gaseous pollutants were also accounted for, indicating the emission of PAHs might accompany the NO2 emission process. Finally, inhalation of PM2.5-bound organic pollutants for carcinogenic and non-carcinogenic risks were estimated as average values for each season, showing outside the safe levels in autumn and winter in some cases, suggesting that new policies should be to developed to reduce their emissions and protect human health in this area.

Occurrence, Sources, and Health Risks of Polycyclic Aromatic Hydrocarbons in Road Environments from Harbin, a Megacity of China.

To obtain a comprehensive understanding about that occurrence, sources, and effects on human health of polycyclic aromatic hydrocarbons (PAHs) in road environmental samples from Harbin, concentrations of 32 PAHs in road dust, green belt soil, and parking lot dust samples were quantified. The total PAH concentrations ranged from 0.95 to 40.7 μg/g and 0.39 to 43.9 μg/g in road dust and green belt soil, respectively, and were dominated by high molecular weight PAHs (HMW-PAHs). Despite the content of PAHs in arterial roads being higher, the composition profile of PAHs was hardly influenced by road types. For parking lot dust, the range of total PAH concentrations was 0.81-190 μg/g, and three-ring to five-ring PAHs produced the maximum contribution. Compared with surface parking lots (mean: 6.12 μg/g), higher total PAH concentrations were detected in underground parking lots (mean: 33.1 μg/g). The diagnostic ratios of PAHs showed that petroleum, petroleum combustion, and biomass/coal combustion were major sources of PAHs in the samples. Furthermore, according to the Incremental Lifetime Cancer Risk model, the cancer risks of three kinds of samples for adults and children were above the threshold (10-6). Overall, this study demonstrated that PAHs in the road environment of Harbin have a certain health impact on local citizens.

Past fire dynamics inferred from polycyclic aromatic hydrocarbons and monosaccharide anhydrides in a stalagmite from the archaeological site of Mayapan, Mexico

Abstract. Speleothems (cave stalagmites) contain inorganic and organic substances that can be used to infer past changes in local and regional paleoenvironmental conditions. Specific biomarkers can be employed to elucidate the history of past fires, caused by interactions among climate, regional hydrology, vegetation, humans, and fire activity. We conducted a simple solid–liquid extraction on pulverised carbonate samples to prepare them for analysis of 16 polycyclic aromatic hydrocarbons (PAHs) and three monosaccharide anhydrides (MAs). The preparation method requires only small samples (0.5–1.0 g); PAHs and MAs were measured by GC–MS and LC–HILIC–MS, respectively. Detection limits range from 0.05–2.1 ng for PAHs and 0.01–0.1 ng for MAs. We applied the method to 10 samples from a ∼ 400-year-old stalagmite from Cenote Ch'en Mul, at Mayapan (Mexico), the largest Postclassic Maya capital of the Yucatán Peninsula. We found a strong correlation (r = 0.75, p &lt; 0.05) between the major MA (levoglucosan) and non-alkylated PAHs (Σ15). We investigated multiple diagnostic PAH and MA ratios and found that although not all were applicable as paleo-fire proxies, ratios that combine PAHs with MAs are promising tools for identifying different fire regimes and inferring the type of fuel burned. In the 1950s and 1960s, levoglucosan and Σ15 concentrations roughly doubled compared to other times in the last 400 years, suggesting greater fire activity at Mayapan during these two decades. The higher concentrations of fire markers may have been a consequence of land clearance at the site and exploration of the cave by Carnegie Institution archaeologists.