In response to the phenomenon of automatic heat storage during the sintering process of iron ore, heat balance analysis concerning the main chemical reactions and physical heat carried by gas and solid materials was conducted. A unit heat storage model for the sintering process was established. Further, a mathematical model to solve the heat transfer characteristics between different sintering layer units was proposed and established based on temperature–time curves of the gas and solid phases. Using these models, the heat storage of each layer unit was calculated under the condition of uniform carbon allocation. Subsequently, the optimisation of carbon allocation at each layer unit for maximising the utilisation of heat storage was investigated. The heat required for sintering by the layer unit was taken as the constraint, and the maximum utilisation of heat stored in each layer unit was taken as the goal to optimise the carbon allocation in the height direction. The calculation results show that as the unit thickness is 100 mm and the total thickness of the layer is 600 mm, the heat transfer ratio of the upper unit to the lower unit is 34.22%, 30.29%, 14.74%, 9.49%, and 1.17%, respectively. The heat storage and available heat storage rate increase with the increase of layer height, with heat storage ranging from 0.69 × 104 to 5.14 × 104 KJ/t and heat storage rate ranging from 11.63% to 49.37%. After optimising carbon allocation, the unit achieved a maximum carbon reduction of 60.04%, resulting in an overall reduction in carbon allocation of 46.20%. This adjustment aligns more closely with the industrial processes.
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