3D printing technology, as a rapid prototyping method, can accurately reconstruct the internal structural characteristics of samples, making it highly promising for rock engineering applications. However, current 3D printing materials used to reconstruct rocks suffer from low strength and high ductility, which is inconsistent with the high strength and brittleness of natural rocks. This paper explores the use of silane coupling agents KH550 (γ-aminopropyl triethoxysilane) and KH570 (γ-methacryloxypropyl trimethoxysilane) to modify nano SiO2 powder. Through sample preparation and uniaxial compression tests, the mechanical properties and failure characteristics of the modified nano SiO2 powder were analyzed. The results indicate that, using the preparation method with a mass ratio of E-44 epoxy resin, KH550 modified nano SiO2 powder, and 593 curing agent at 80:40:26, the samples achieved an uniaxial compressive strength of up to 30.55 MPa without enhanced brittle post-processing. The failure characteristics exhibited significant axial tensile damage. Additionally, combining CT scanning technology demonstrated that the structural and mechanical properties of the samples can be effectively reproduced. Therefore, the 3D printing materials discussed in this paper provide a viable reference for accurately reconstructing high-strength and high-brittleness rock masses.
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