In the industrialization of high-efficiency (BiSb)2Te3-based bulk thermoelectric materials, the cost-effectiveness, and rapid fabrication methods are of considerable interest; herein, mass production of nearly 2 Kg/min of desired Bi0.5Sb1.5Te3 powders with greater powder uniformity was successfully manufactured using water atomization than that of any other routes. In particular, the solidification of thermoelectric metal powders using different water source temperatures has not yet been studied. Hence, for the first time, we have reported the influence of the solidification rate on the microstructural and thermoelectric performances of cold and hot water-assisted p-type Bi0.5Sb1.5Te3 alloys using the water atomization method. The rapid solidification using low temperature (278 K) cold water assisted- Bi0.5Sb1.5Te3 atomized powders produces smaller particle sizes with a greater degree of lattice defects decreasing the lattice thermal conductivity (κL) significantly compared to the hot water source (359 K). Thus, a notable decrement in the lattice thermal conductivity (κL) of 0.47 W/m.K. and the corresponding total thermal conductivity (κ) at 0.93 W/m.K. at 400 K was obtained for the cold water-Bi0.5Sb1.5Te3 owing to the fine distributions of grains and extensively larger fractions of twin boundary density in the misorientation angle from 80 to 92°. As a result, the cold water-Bi0.5Sb1.5Te3 shows a substantially maximum figure of merit, ZTmax. of 1.37 at 400 K compared to hot water-Bi0.5Sb1.5Te3 (≈1.21). Hence, the cold water-assisted atomization approach would be beneficial for the large production of thermoelectric materials with improved thermoelectric performances, and it is very promising to be scalable in the commercialization of large-scale devices.
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