Rapid Build-up Research Articles

JADES: Balmer decrement measurements at redshifts 4 < z < 7

We present Balmer decrement, Hα/Hβ, measurements for a sample of 51 galaxies at redshifts z = 4 − 7 observed with the JWST/NIRSpec micro-shutter assembly (MSA), as part of the JWST Advanced Deep Extragalactic Survey (JADES). Leveraging 28-hour long exposures and the efficiency of the prism/clear configuration (but also using information from the medium-resolution gratings), we were able to directly probe the low-mass end of the galaxy population, reaching stellar masses, M⋆, as low as 107 M⊙. We find that the correlation between the Balmer decrement and M⋆ is already established at these high redshifts, indicating a rapid buildup of dust in moderately massive galaxies at such early epochs. The lowest-mass galaxies in our sample (M⋆ = 1 − 3 × 107 M⊙) display a remarkably low Balmer decrement of 2.88 ± 0.08, consistent with Case B, suggesting very little dust content. However, we warn that such a low observed Balmer decrement may also partly be a consequence of an intrinsically lower Hα/Hβ resulting from the extreme conditions of the ionised gas in these primeval and unevolved systems. We further compare the Balmer decrement to continuum-derived star formation rates (SFRs), finding tentative evidence of a correlation, which likely traces the underlying connection between the SFR and the mass of cold gas. However, we note that larger samples are required to distinguish between direct and primary correlations from indirect and secondary dependences at such high redshifts.

Dispersion of anhydrous ammonia inside a confined space onboard a hypothetical ammonia-powered vessel

Abstract In order to ensure the responsible use of anhydrous ammonia as clean marine fuel, safety aspects in respect of its post-release consequence cannot be understated. This contribution is aimed to address the gaps of understanding associated to events of ammonia loss of containment (LoC) in enclosed spaces onboard ammonia-fuelled vessels. A forced ventilated fuel preparation room (FPR) onboard a container vessel is chosen as a study case with minor and major release scenarios, which is based on the orifice size. The dispersion analysis was performed using three-dimensional computational fluid dynamics. The analysis revealed that toxicity associated to the rapid and persistent ammonia vapor cloud buildup is by far the most significant hazard in the space. In the major release scenario, gradual evaporation of rainout pool increases the vapor cloud persistence even far beyond the leak isolation time. The results and finding above underlines the importance of concerted effort in mitigating not only the ammonia vapor cloud, but also the accumulated ammonia liquid pool.

A first look at spatially resolved star formation at 4.8 <z< 6.5 with JWST FRESCO NIRCam slitless spectroscopy

We present the first results on the spatial distribution of star formation in 454 star-forming galaxies just after the epoch of reionisation (4.8 < z < 6.5) using Hαemission-line maps and F444W imaging that traces the stellar continuum from the JWST FRESCO NIRCam Slitless Spectroscopy Survey. The Hαequivalent width profiles of star-forming galaxies across the main sequence atz ∼ 5.3 with stellar masses 6.8≤ log(M*/M⊙) < 11.1 increase with radius, which provides direct evidence for the inside-out growth of star-forming galaxies just after the epoch of reionisation.GALFITwas used to calculate half-light radii,Reff, and central surface densities within 1 kiloparsec, Σ1kpcof Hαand the continuum. At a fixed stellar mass of Log(M*/M⊙) = 9.5, Σ1kpc, Hαis 1.04 ± 0.05 times higher than Σ1kpc, C,Reff, Hαis 1.18 ± 0.03 times larger thanReff, Cand bothReffmeasurements are smaller than 1 kiloparsec. These measurements suggest the rapid build-up of compact bulges via star formation just after the epoch of reionisation. By comparison to analogous work done at lower redshifts withHubbleSpace Telescope WFC3 slitless spectroscopy as part of the 3D-HST (z ∼ 1) and CLEAR (z ∼ 0.5) surveys, we find thatReff(z) evolves at the same pace for Hαand the continuum, but Σ1kpc(z) evolves faster for Hαthan the stellar continuum. As a function of the Hubble parameter,Reff, Hα/Reff,C = 1.1h(z) and Σ1 kpc, Hα/Σ1 kpc,C = h(z)1.3. These parametrisations suggest that the inside-out growth of the disk starts to dominate the inside-out growth of the bulge towards lower redshifts. This is supported by the redshift evolution in the EW(Hα) profiles from FRESCO, 3D-HST, and CLEAR at fixed stellar mass and when star-forming progenitors are traced, in which in EW(Hα) rapidly increases with radius within the half-light radius atz ∼ 5.3, but EW(Hα) increases only significantly with radius in the outer disk atz ∼ 0.5.

Characterizing the Average Interstellar Medium Conditions of Galaxies at z ∼ 5.6–9 with Ultraviolet and Optical Nebular Lines

Ultraviolet (UV; rest-frame ∼1200–2000 Å) spectra provide a wealth of diagnostics to characterize fundamental galaxy properties, such as their chemical enrichment, the nature of their stellar populations, and their amount of Lyman-continuum (LyC) radiation. In this work, we leverage publicly released JWST data to construct the rest-frame UV-to-optical composite spectrum of a sample of 63 galaxies at 5.6 < z < 9, spanning a wavelength range from 1500 to 5200 Å. Based on the composite spectrum, we derive an average dust attenuation E(B−V)gas=0.10−0.11+0.10 from Hβ/Hγ, an electron density ne=570−290+510 cm−3 from the [O ii] doublet ratio, an electron temperature Te=16700−1500+1500 K from the [O iii] λ4363/[O iii] λ5007 ratio, and an ionization parameter log(U)=−2.15−0.03+0.03 from the [O iii]/[O ii] ratio. Using a direct T e method, we calculate an oxygen abundance 12+log(O/H)=7.67±0.08 and a carbon-to-oxygen (C/O) abundance ratio log(C/O)=−0.86−0.10+0.13 . This C/O ratio is smaller than compared to z = 0 and z = 2–4 star-forming galaxies, albeit with moderate significance. This indicates the reionization-era galaxies might be undergoing a rapid buildup of stellar mass with high specific star formation rates. A UV diagnostic based on the ratios of C iii] λ λ1907, 1909/He ii λ1640 versus O iii] λ1666/He ii λ1640 suggests that the star formation is the dominant source of ionization, similar to the local extreme dwarf galaxies and z ∼ 2–4 He ii–detected galaxies. The [O iii]/[O ii] and C iv/C iii] ratios of the composite spectrum are marginally larger than the criteria used to select galaxies as LyC leakers, suggesting that some of the galaxies in our sample are strong contributors to the reionizing radiation.

Environmental Effects on the Stellar Mass Function in a z ∼ 3.3 Overdensity of Galaxies in the COSMOS Field* *Some of the data presented herein were obtained at Keck Observatory, which is a private 501(c)3 nonprofit organization operated as a scientific partnership among the California Institute of Technology, the University of California, and the National Aeronautics and Space Administration. The

We present an analysis of the number density of galaxies as a function of stellar mass (i.e., the stellar mass function (SMF)) in the COSMOS field at z ∼ 3.3, making a comparison between the SMF in overdense environments and the SMF in the coeval field. In particular, this region contains the Elentári proto-supercluster, a system of six extended overdensities spanning ∼70 cMpc on a side. A clear difference is seen in the high-mass slope of these SMFs, with overdense regions showing an increase in the ratio of high-mass galaxies to low-mass galaxies relative to the field, indicating a more rapid buildup of stellar mass in overdense environments. This result qualitatively agrees with analyses of clusters at z ∼ 1, though the differences between protocluster and field SMFs at z ∼ 3.3 are smaller. While this is consistent with overdensities enhancing the evolution of their member galaxies, potentially through increased merger rates, whether this enhancement begins in protocluster environments or even earlier in group environments is still unclear. Though the measured fractions of quiescent galaxies between the field and overdense environments do not vary significantly, implying that this stellar mass enhancement is ongoing and any starbursts triggered by merger activity have not yet quenched, we note that spectroscopic observations are biased toward star-forming populations, particularly for low-mass galaxies. If mergers are indeed responsible, high-resolution imaging of Elentári and similar structures at these early epochs should then reveal increased merger rates relative to the field. Larger samples of well-characterized overdensities are necessary to draw broader conclusions in these areas.

New insights into the glacial and relative sea-level history of the western Fraser Lowland based on sediment cores from geotechnical drilling for the Evergreen Tunnel, British Columbia, Canada

Abstract Geotechnical drilling for a tunnel between Port Moody and Burnaby, BC, Canada, uncovered a buried fjord. Its sedimentary fill has a thickness of at least 130 m and extends more than 37 m below present mean sea level. Recovered sediments record cyclical growth and decay of successive Cordilleran ice sheets. The oldest sediments comprise 58 m of almost stoneless silt conformably overlying ice-proximal sediments and till, which in turn overlie bedrock. These sediments may predate Marine Isotope Stage (MIS) 4. Glacial sediments assigned to MIS 4 overlie this basal succession and, in turn, are overlain by MIS 3 interstadial sediments and sediments from two MIS 2 glacial advances. Indicators of relative sea-level elevations that bracket glacial deposits of MIS 4 and 2 indicate the cyclic existence of moat-like isostatic depressions in the front of expanding ice sheets. Compared with present sea level, these depressions were at least 160 m during the onsets of MIS 4 and MIS 2. Assuming a maximum eustatic drawdown of 120 m during MIS 2, isostatic depression may have exceeded 200 m during retreat of glacial ice from the Evergreen tunnel area. This is consistent with region-specific low mantle viscosity and rapid Cordilleran Ice Sheet buildup and wasting.

A genome-wide CRISPR screen reveals that antagonism of glutamine metabolism sensitizes head and neck squamous cell carcinoma to ferroptotic cell death

Glutamine is a conditionally essential amino acid for the growth and survival of rapidly proliferating cancer cells. Many cancers are addicted to glutamine, and as a result, targeting glutamine metabolism has been explored clinically as a therapeutic approach. Glutamine-catalyzing enzymes are highly expressed in primary and metastatic head and neck squamous cell carcinoma (HNSCC). However, the nature of the glutamine-associated pathways in this aggressive cancer type has not been elucidated. Here, we explored the therapeutic potential of a broad glutamine antagonist, DRP-104 (sirpiglenastat), in HNSCC tumors and aimed at shedding light on glutamine-dependent pathways in this disease. We observed a potent antitumoral effect of sirpiglenastat in HPV- and HPV + HNSCC xenografts. We conducted a whole-genome CRISPR screen and metabolomics analyses to identify mechanisms of sensitivity and resistance to glutamine metabolism blockade. These approaches revealed that glutamine metabolism blockade results in the rapid buildup of polyunsaturated fatty acids (PUFAs) via autophagy nutrient-sensing pathways. Finally, our analysis demonstrated that GPX4 mediates the protection of HNSCC cells from accumulating toxic lipid peroxides; hence, glutamine blockade sensitizes HNSCC cells to ferroptosis cell death upon GPX4 inhibition. These findings demonstrate the therapeutic potential of sirpiglenastat in HNSCC and establish a novel link between glutamine metabolism and ferroptosis, which may be uniquely translated into targeted glutamine-ferroptosis combination therapies.

Synthesis of Primary Amines via Hydrogen Atom Transfer-Initiated Cyclization/Reduction Cascade of Unsaturated Nitriles.

We report a hydrogen atom transfer-initiated cyclization/reduction cascade for the synthesis of primary amines from δ,ε- and ε,ζ-unsaturated nitriles. The HAT transformation employs Mn(acac)3 as a catalyst and utilizes air as an oxidant along with NaBH4 as a dual-purpose reductant toward the olefin and subsequently C═N. Aromatic and aliphatic nitriles incorporating mono-, di-, and trisubstituted olefins are substrates for the reaction. Starting materials bearing malonates are transformed into the corresponding bicyclic lactams, enabling the rapid buildup of structural complexity.

Enhanced thermophilic high-solids anaerobic digestion of organic fraction of municipal solid waste with spatial separation from conductive materials in a single reactor volume

Despite benefits such as lower water and working volume requirements, thermophilic high solids anaerobic digestion (THSAD) often fails due to the rapid build-up of volatile fatty acids (VFAs) and the associated drop in pH. Use of conductive materials (CM) can promote THSAD through stimulation of direct interspecies electron transfer (DIET), while the need for their constant dosing due to poor separation from effluent impairs economic feasibility. This study used an approach of spatially separating magnetite and granular activated carbon (GAC) from the organic fraction of municipal solid waste (OFMSW) in a single reactor for THSAD. GAC and magnetite addition could both mitigate the severe inhibition of methanogenesis after VFAs build-up to ∼28–30 g/L, while negligible methane production was observed in the control group. The highest methane yield (286 mL CH4/g volatile solids (VS)) was achieved in magnetite-added reactors, while the highest maximum CH4 production rates (26.38 mL CH4/g VS/d) and lowest lag-phase (2.83 days) were obtained in GAC-added reactors. The enrichment of GAC and magnetite biofilms with various syntrophic and potentially electroactive microbial groups (Ruminiclostridium 1, Clostridia MBA03, Defluviitoga, Lentimicrobiaceae) in different relative abundances indicates the existence of specific preferences of these groups for the nature of CM. According to predicted basic metabolic functions, CM can enhance cellular processes and signals, lipid transport and metabolism, and methane metabolism, resulting in improved methane production. Rearrangement of metabolic pathways, formation of pili-like structures, enrichment of biofilms with electroactive groups and a significant improvement in THSAD performance was attributed to the enhancement of the DIET pathway. Promising results obtained in this work due to the spatial separation of the bulk OFMSW and CM can be useful for modeling larger-scale THSAD systems with better recovery of CM and cost-effectiveness.

Deposit sintering in modern Kraft recovery boilers − The role of NaOH?

Modern Kraft recovery boilers have become larger compared to earlier designs and burn higher black liquor dry solids (DS), leading to a more intense burning process and, therefore, increased sodium hydroxide (NaOH) concentration in the upper furnace. Indications of rapid deposit build-up and plugging issues in these boilers, specifically downstream of the superheaters, have been observed at lower temperatures than typically expected, which could be a consequence of the increased NaOH. Thermodynamic calculations were performed to explore the formation of NaOH(g) in boilers with high carbonate content in the fly ash particles and the effect of the presence of NaOH on the melting properties of the deposits. The results indicated that at low temperatures (<400 °C), almost no NaOH(g) is expected to be present in the flue gases. However, we propose that rapid cooling of flue gases across superheaters kinetically freezes the carbonation of NaOH(g), resulting in higher NaOH(g) concentrations than predicted by equilibrium calculations alone. At low temperatures, the remaining NaOH(g) vapors condense on the fly ash and form a melt, potentially leading to the sintering of deposits and plugging issues. To confirm this theory, sintering tests were carried out at 300–350 °C by doping electrostatic precipitator (ESP) ash from a recovery boiler with NaOH powder. It was observed that the doped pellets sintered and were much harder than the reference ones across various experimental conditions. The single particle reactor (SPR) test results showed that the pellets started to sinter immediately upon heating up to 350 °C, suggesting that NaOH melt-induced sintering is a rapid mechanism. The findings of this study may also have implications for boilers with a high sodium (Na) content.

Fabrication of 3D Polycaprolactone Macrostructures by 3D Electrospinning.

Building 3D electrospun macrostructures and monitoring the biological activities inside them are challenging. In this study, 3D fibrous polycaprolactone (PCL) macrostructures were successfully fabricated using in-house 3D electrospinning. The main factors supporting the 3D self-assembled nanofiber fabrication are the H3PO4 additives, flow rate, and initial distance. The effects of solution concentration, solvent, H3PO4 concentration, flow rate, initial distance, voltage, and nozzle speed on the 3D macrostructures were examined. The optimal conditions of 4 mL/h flow rate, 4 cm initial nozzle-collector distance, 14 kV voltage, and 1 mm/s nozzle speed provided a rapid buildup of cylinder macrostructures with 6 cm of diameter, reaching a final height of 16.18 ± 2.58 mm and a wall thickness of 3.98 ± 1.01 mm on one perimeter with uniform diameter across different sections (1.40 ± 1.10 μm average). Oxygen plasma treatment with 30-50 W for 5 min significantly improved the hydrophilicity of the PCL macrostructures, proving a suitable scaffold for in vitro cell cultures. Additionally, 3D images obtained by synchrotron radiation X-ray tomographic microscopy (SRXTM) presented cell penetration and cell growth within the scaffolds. This breakthrough in 3D electrospinning surpasses current scaffold fabrication limitations, opening new possibilities in various fields.

The biological controls of soil carbon accumulation following wildfire and harvest in boreal forests: A review.

Boreal forests are frequently subjected to disturbances, including wildfire and clear-cutting. While these disturbances can cause soil carbon (C) losses, the long-term accumulation dynamics of soil C stocks during subsequent stand development is controlled by biological processes related to the balance of net primary production (NPP) and outputs via heterotrophic respiration and leaching, many of which remain poorly understood. We review the biological processes suggested to influence soil C accumulation in boreal forests. Our review indicates that median C accumulation rates following wildfire and clear-cutting are similar (0.15 and 0.20 Mg ha-1 year-1, respectively), however, variation between studies is extremely high. Further, while many individual studies show linear increases in soil C stocks through time after disturbance, there are indications that C stock recovery is fastest early to mid-succession (e.g. 15-80 years) and then slows as forests mature (e.g. >100 years). We indicate that the rapid build-up of soil C in younger stands appears not only driven by higher plant production, but also by a high rate of mycorrhizal hyphal production, and mycorrhizal suppression of saprotrophs. As stands mature, the balance between reductions in plant and mycorrhizal production, increasing plant litter recalcitrance, and ectomycorrhizal decomposers and saprotrophs have been highlighted as key controls on soil C accumulation rates. While some of these controls appear well understood (e.g. temporal patterns in NPP, changes in aboveground litter quality), many others remain research frontiers. Notably, very little data exists describing and comparing successional patterns of root production, mycorrhizal functional traits, mycorrhizal-saprotroph interactions, or C outputs via heterotrophic respiration and dissolved organic C following different disturbances. We argue that these less frequently described controls require attention, as they will be key not only for understanding ecosystem C balances, but also for representing these dynamics more accurately in soil organic C and Earth system models.

Multiscale modeling of gas-induced fracturing in anisotropic clayey rocks

In the context of repositories for nuclear waste, understanding the behavior of gas migration through clayey rocks with inherent anisotropy is crucial for assessing the safety of geological disposal facilities. The primary mechanism for gas breakthrough is the opening of micro-fractures due to high gas pressure. This occurs at gas pressures lower than the combined strength of the rock and its minimum principal stress under external loading conditions. To investigate the mechanism of microscale mode-I ruptures, it is essential to incorporate a multiscale approach that includes subcritical microcracks in the modeling framework. In this contribution, we derive the model from microstructures that contain periodically distributed microcracks within a porous material. The damage evolution law is coupled with the macroscopic poroelastic system by employing the asymptotic homogenization method and considering the inherent hydro-mechanical (HM) anisotropy at the microscale. The resulting permeability change induced by fracture opening is implicitly integrated into the gas flow equation. Verification examples are presented to validate the developed model step by step. An analysis of local macroscopic response is undertaken to underscore the influence of factors such as strain rate, initial damage, and applied stress, on the gas migration process. Numerical examples of direct tension tests are used to demonstrate the model's efficacy in describing localized failure characteristics. Finally, the simulation results for preferential gas flow reveal the robustness of the two-scale model in explicitly depicting gas-induced fracturing in anisotropic clayey rocks. The model successfully captures the common behaviors observed in laboratory experiments, such as a sudden drop in gas injection pressure, rapid build-up of downstream gas pressure, and steady-state gas flow following gas breakthrough.

Numerical study on the temperature dependence of soot formation in acetylene pyrolysis blended with methane, formaldehyde, methanol, and dimethyl ether

Abstract This paper addresses the combined effects of varying C/H and C/O ratios as well as of the molecular structure of the fuels selected on the normalized soot volume fraction f V. For the simulations, an already existing and validated reaction mechanism for the pyrolysis of C2H2 in argon, Aghsaee et al. (Combust. Flame 2014, 161, 2263–2269), was used in the current work. It was extended with PAH reactions from coronene (C24H12) up to ovalene (C32H14), whereas general principles for the rapid build-up of large PAHs were presented. Soot formation was modeled according to Appel et al. (Combust. Flame 2000, 121, 122–136) by applying the method of moments. A validation of the extended reaction model was carried out for shock-wave-induced O2/C2H2 mixtures from literature. In the following, the influence of blends of methane (CH4), formaldehyde (CH2O), methanol (CH3OH), and dimethyl ether (CH3)2O on soot formation during C2H2 pyrolysis diluted in Ar was studied. Special emphasis was laid on the inception chemistry of soot formation. The role of intermediates, such as the propargyl radical (C3H3), leading towards benzene and polyaromatic hydrocarbon (PAH) formation and their interplay with hydrogen molecules (H2) to H atoms (H) ratio was examined. All blends increased the ratio of the concentrations of H2 and H leading thus to reduced soot inception and soot formation. However, soot suppressing effects were overrun by supporting ones when the additives provided suitable molecular groups, such as methyl radicals (CH3), in sufficient high concentrations for early aromatic ring formation. Thus, a prominent synergistic effect on soot formation was found for the CH4/C2H2 mixture only. Besides, species able to mirror characteristics of the soot formation process, such as the peak value of the normalized soot volume fraction, are presented. The findings of this work indicate the synergistic effect of H2/H and C/O ratios as well as of methyl radicals on the PAHs’ production of appropriate size able to initiate soot inception process in an aliphatic fuel.

Forecasting the Problem of Excessive Oil Entrainment in a Desalter Using Spinning Drop Method.

Frequent desalter upsets in the refineries processing opportunity crude oils are often triggered by a rapid and uncontrollable buildup of the rag layer, a thick water-in-oil emulsion, at the oil-brine interface. This is caused by spontaneous emulsification of brine in oil. This study investigates a unique observation from a spinning drop (SD) tensiometer, revealing the low apparent interfacial tension and rigidity of SD caused by spontaneous emulsification. Fine droplets of brine generated through spontaneous emulsification decorate the SD surface and form a stable, low-energy bilayer. Simulated rag layers using the brines from upset incidences exhibit similar behavior, indicating that spontaneous emulsification is driven by chemical species in brine, which promote osmotic water transport. The rate of rag layer buildup correlates with the rate of spontaneous emulsification, with the temperature coefficient of interfacial tension reduction serving as a sensitive indicator. An imminent upset in the operation can be forecasted by measuring this temperature coefficient, enabling preventive measures.

Bacterial degradation of ctenophore Mnemiopsis leidyi organic matter.

Blooms of gelatinous zooplankton, an important source of protein-rich biomass in coastal waters, often collapse rapidly, releasing large amounts of labile detrital organic matter (OM) into the surrounding water. Although these blooms have the potential to cause major perturbations in the marine ecosystem, their effects on the microbial community and hence on the biogeochemical cycles have yet to be elucidated. We conducted microcosm experiments simulating the scenario experienced by coastal bacterial communities after the decay of a ctenophore (Mnemiopsis leidyi) bloom in the northern Adriatic Sea. Within 24 h, a rapid response of bacterial communities to the M. leidyi OM was observed, characterized by elevated bacterial biomass production and respiration rates. However, compared to our previous microcosm study of jellyfish (Aurelia aurita s.l.), M. leidyi OM degradation was characterized by significantly lower bacterial growth efficiency, meaning that the carbon stored in the OM was mostly respired. Combined metagenomic and metaproteomic analysis indicated that the degradation activity was mainly performed by Pseudoalteromonas, producing a large amount of proteolytic extracellular enzymes and exhibiting high metabolic activity. Interestingly, the reconstructed metagenome-assembled genome (MAG) of Pseudoalteromonas phenolica was almost identical (average nucleotide identity >99%) to the MAG previously reconstructed in our A. aurita microcosm study, despite the fundamental genetic and biochemical differences of the two gelatinous zooplankton species. Taken together, our data suggest that blooms of different gelatinous zooplankton are likely triggering a consistent response from natural bacterial communities, with specific bacterial lineages driving the remineralization of the gelatinous OM.IMPORTANCEJellyfish blooms are increasingly becoming a recurring seasonal event in marine ecosystems, characterized by a rapid build-up of gelatinous biomass that collapses rapidly. Although these blooms have the potential to cause major perturbations, their impact on marine microbial communities is largely unknown. We conducted an incubation experiment simulating a bloom of the ctenophore Mnemiopsis leidyi in the Northern Adriatic, where we investigated the bacterial response to the gelatinous biomass. We found that the bacterial communities actively degraded the gelatinous organic matter, and overall showed a striking similarity to the dynamics previously observed after a simulated bloom of the jellyfish Aurelia aurita s.l. In both cases, we found that a single bacterial species, Pseudoalteromonas phenolica, was responsible for most of the degradation activity. This suggests that blooms of different jellyfish are likely to trigger a consistent response from natural bacterial communities, with specific bacterial species driving the remineralization of gelatinous biomass.

Deciphering Lyman-α emission deep into the epoch of reionization

During the epoch of reionization, the first galaxies were enshrouded in pristine neutral gas, with one of the brightest emission lines in star-forming galaxies, Lyman α (Lyα), expected to remain undetected until the Universe became ionized. Providing an explanation for the surprising detection of Lyα in these early galaxies is a major challenge for extragalactic studies. Recent James Webb Space Telescope observations have reignited the debate about whether residence in an overdensity of galaxies is a sufficient and necessary condition for Lyα to escape. Here, we take unique advantage of both high-resolution and high-sensitivity images from the James Webb Space Telescope Near Infrared Camera to show that all galaxies in a sample of Lyα emitters with redshift >7 have close companions. We exploit on-the-fly radiative-transfer magnetohydrodynamical simulations with cosmic ray feedback to show that galaxies with frequent mergers have very bursty star formation histories that drives episodes of high intrinsic Lyα emission and facilitates the escape of Lyα photons along channels cleared of neutral gas. We conclude that the rapid buildup of stellar mass through mergers presents a compelling solution to the long-standing puzzle of the detection of Lyα emission deep in the epoch of reionization.

Discovery of Organic Optoelectronic Materials Powered by Oxidative Ar-H/Ar-H Coupling.

Efficient and streamlined synthetic methods that facilitate the rapid build-up of structurally diverse π-conjugated systems are of paramount importance in the quest for organic optoelectronic materials. Among these methods, transition-metal-catalyzed oxidative Ar-H/Ar-H coupling reactions between two (hetero)arenes have emerged as a concise and effective approach for generating a wide array of bi(hetero)aryl and fused heteroaryl structures. This innovative approach bypasses challenges associated with substrate pre-activation processes, thereby allowing for the creation of frameworks that were previously beyond reach using conventional Ar-X/Ar-M coupling reactions. These inherent advantages have ushered in new design patterns for organic optoelectronic molecules that deviate from traditional methods. This ground-breaking approach enables the transcendence of the limitations of repetitive material structures, ultimately leading to the discovery of novel high-performance materials. In this Perspective, we provide an overview of recent advances in the development of organic optoelectronic materials through the utilization of transition-metal-catalyzed oxidative Ar-H/Ar-H coupling reactions. We introduce several notable synthetic strategies in this domain, covering both directed and non-directed oxidative Ar-H/Ar-H coupling strategies, dual chelation-assisted strategy and directed ortho-C-H arylation/cyclization strategy. Additionally, we shed light on the role of oxidative Ar-H/Ar-H coupling reactions in the advancement of high-performance organic optoelectronic materials. Finally, we discuss the current limitations of existing protocols and offer insights into the future prospects for this field.

On the Response of Chondrites to Diurnal Temperature Change—Experimental Simulation of Asteroidal Surface Conditions

AbstractThermal fatigue is a process that degrades rocks and pebbles exposed to space by diurnal cycling. We simulate the diurnal temperature variation at 1 AU of 5 mm‐sized sample cubes using an evacuated cryostat, allowing conditions that are closer to those expected in space. Sample cubes of ordinary, CV, CM2, and C2 chondrites were investigated using scanning electron microscopy and microcomputed tomography scans. In contrast to previous work, the ordinary and CV chondrite samples did not show any cracking. The CM2 chondrites respond with the formation and extension of cracks. Pre‐existing cracks present in the C2 chondrite Tagish Lake closed in the course of cycling to different degrees, which has not been reported before in the context of thermal fatigue driven rock breakdown. Most changes in crack length occur in the initial ∼20 cycles indicating a rapid buildup of strain followed by a rapid release by the formation and extension of cracks when exposed to diurnal temperature variation. The overall cracking rate is comparable to that of previous work on CM2 chondrites and in 15%–20% of the observed cracking occasions they are associated with fine‐grained rims around chondrules implying that the comminution of CM‐like rocks and pebbles is controlled by the abundance of chondrules (and other coarse‐grained components) and their rims. We propose that thermal fatigue‐driven comminution of rocks and especially pebbles on asteroids under the here studied conditions is controlled by the abundance of hydrated minerals. This, in turn, can result in different abundances and natures of finer‐grained material on asteroid surfaces.

Tribocorrosion of TiC-based composites incorporating Ni and Co binders in saline solutions

Metallic binders impart necessary toughness to ceramic-metal composites, yet are vulnerable to corrosion and wear. Thus far, the tribocorrosion mechanism remains little understood, obstructing the design of durable composites for ocean drilling applications. Against this backdrop, we selected the TiC-based composites encompassing the Ni and Co binders having different standard electrode potentials as model systems, and studied their tribocorrosion behaviors with the aid of microscopic characterizations and first-principles calculations. Results showed that the TiC-Ni system maintained lower corrosion current densities at the pure corrosion condition, due to the reduced tendency of galvanic corrosion. Such system also realized lower coefficient of friction (COF) and wear losses at the pure wear condition, benefiting from the reduced adhesion at the sliding interfaces as well as the improved composite fracture toughness. Under corrosion-wear interactions, however, the TiC-Co system revealed alleviated material losses, as the rapid build-up of oxide tribolayers enhanced the surface hardness and facilitated the transfer layer formation. Thus, contrary to the intuition that corrosion-resistant binders should be beneficial to the tribocorrosion resistance, the current work highlighted the binder's ability to generate surface layers that helped to resist corrosion-accelerated wear, a point that needs to be emphasized in future development of robust composite materials.