Range Of Oxygen Concentrations Research Articles

Temperature evolution of laser-ignited micrometric iron particles: A comprehensive experimental data set and numerical assessment of laser heating impact

This study examines the effects of laser heating on the ignition and critical combustion characteristics, such as temperature and burn time, of individual iron particles. It provides time-dependent temperature profiles of laser-ignited particles across a broad spectrum of particle size distributions and oxygen concentrations obtained from experiments, which are a useful database for further development and validation of iron particle combustion models. The herein reported datasets significantly complement those existing in the literature. In the current study, the raw data are thoroughly re-evaluated using refined approaches. For the experimental canonical configuration of single iron particle combustion, an ignition system based on laser heating provides several advantages in overcoming temperature field uncertainties and facilitating controlled environments for optical diagnostics. Despite the inherent uncertainties in laser heating, associated with non-uniform intensity profiles and particle size variations, this study addresses the critical question of how these uncertainties affect in situ measurements of particle temperature and time to reach peak temperature. This study, conducted using a numerical model, reveals a dependence of the particle temperature after laser heating on particle size. However, this dependence does not significantly impact the key parameters of iron-particle combustion, such as the maximum temperature and burn time of the laser-ignited iron particle. The study also presents a comparison between the simulated particle temperature histories and those derived from two-color pyrometry measurements for a wide range of particle size distributions and oxygen concentrations. Notably, by implementing a laser-heating sub-model into an iron particle combustion model, assuming external-diffusion-limited oxidation only up to stoichiometric FeO, the temperature evolution up to the maximum temperature is reasonably captured for a wide range of particle sizes (20–53μm) and oxygen volumetric fractions (14–21vol% O2 mixed with N2). However, with increasing oxygen concentration, the external-diffusion limited model significantly overestimates the heating rate and subsequently the maximum particle temperature.

Quantifying oxygen diffusion during thermal degradation of combustible porous media

Oxygen diffusion controlled combustion occurs when local oxygen transport is slower than the chemistry, commonly found in porous combustible material or combustible material embedded within an inert porous medium. This mode of combustion, such as smouldering, can pose dangerous fire risks and also be harnessed in environmentally beneficial applications. However, the oxygen diffusion limitation is poorly understood in all contexts and persists as a key knowledge gap. Quantitative analysis of oxygen diffusion effects is therefore crucial for understanding the combustion behavior of combustible porous media and developing precise smouldering simulation models. In this paper, a reactive transport model incorporating both oxygen diffusion and chemical consumption was developed. Using coal as the model fuel, the impacts of key parameters on global mass loss during the one-dimensional diffusion combustion of coal samples were simulated and compared with TGA experiments conducted within a range of oxygen concentrations between 3–21%. Using this method, key kinetic and oxygen diffusion parameters were obtained within reasonable ranges by using a genetic algorithm optimization method. With these optimized parameters, the local oxygen distribution profiles in the samples at different inlet oxygen concentrations were simulated. The results indicate that oxygen diffusion can lead to large oxygen concentration differences within the coal samples, exceeding 63% of the inlet oxygen concentration. These oxygen differences can impact the local chemistry throughout the sample, and lead to fundamental errors in analyzing global kinetic analyses, if the transport effects are not considered. Altogether, this study delivers new insights into a potentially rate-limiting phenomenon that is relevant in progressing knowledge on many fire problems and engineering applications.

Integrated aerobic-anaerobic digestion of highly solids-loaded corn stover and swine manure under dynamic aeration: Temperature rise, physicochemical characteristics, and methane production

This research aimed to design an integrated aerobic-anaerobic reactor with dynamic aeration that was automatically regulated based on real-time oxygen concentration and investigate the aerobic pretreatment and subsequent dry co-anaerobic digestion (co-AD) characteristics of highly solids-loaded corn stover and swine manure in terms of temperature rise, physiochemical characteristics, and methane production. The high-temperature feedstocks from the aerobic pretreatment phase rapidly entered the AD phase without transportation and effectively improved the start-up and methane production of the co-AD. Oxygen concentration range, aeration rate, and pretreatment time affected the cumulative aeration time, temperature rise, and organic matter removal interactively during aerobic pretreatment, and a low aeration rate was relatively preferable. Although the lignocellulose removal increased with the increase in pretreatment duration, the maximal lignin elimination efficiency only reached 1.30%. The inoculum injection in the transition phase from aerobic pretreatment to co-AD and the leachate reflux during co-AD were also critical for producing methane steadily apart from aerobic pretreatment. The cold air weakened the temperature rise of aerobic pretreatment, and the low-temperature leachate reduced the methane production in the co-AD process. An oxygen concentration range of 13%–17%, aeration rate of 0.10 m3/(min·m3), pretreatment time of 84 h, inoculum loading of 40%, leachate refluxing thrice per day, and double-layer inoculation were optimum for improving the integrated aerobic-anaerobic digestion system's ability to resist low temperatures and achieving high methane production. The maximal cumulative and volatile solids (VS) methane yields of corn stover and swine manure reached 444.58 L and 266.30 L/kg VS.

Seven white dwarfs with circumstellar gas discs II: tracing the composition of exoplanetary building blocks

ABSTRACT This second paper presents an in-depth analysis of the composition of the planetary material that has been accreted on to seven white dwarfs with circumstellar dust and gas emission discs with abundances reported in Rogers et al. The white dwarfs are accreting planetary bodies with a wide range of oxygen, carbon, and sulphur volatile contents, including one white dwarf that shows the most enhanced sulphur abundance seen to date. Three white dwarfs show tentative evidence (2–3$\sigma$) of accreting oxygen-rich material, potentially from water-rich bodies, whilst two others are accreting dry, rocky material. One white dwarf is accreting a mantle-rich fragment of a larger differentiated body, whilst two white dwarfs show an enhancement in their iron abundance and could be accreting core-rich fragments. Whilst most planetary material accreted by white dwarfs display chondritic or bulk Earth-like compositions, these observations demonstrate that core-mantle differentiation, disruptive collisions, and the accretion of core-mantle differentiated material are important. Less than 1 per cent of polluted white dwarfs host both observable circumstellar gas and dust. It is unknown whether these systems are experiencing an early phase in the disruption and accretion of planetary bodies, or alternatively if they are accreting larger planetary bodies. From this work there is no substantial evidence for significant differences in the accreted refractory abundance ratios for those white dwarfs with or without circumstellar gas, but there is tentative evidence for those with circumstellar gas discs to be accreting more water rich material which may suggest that volatiles accrete earlier in a gas-rich phase.

Chromogenic Approach for Oxygen Sensing Using Tapered Coreless Optical Fibre Coated with Methylene Blue

In this paper, a Methylene Blue (MB)-coated tapered coreless (TCL) optical fibre sensor is proposed and experimentally investigated for oxygen sensing in the near-infrared (NIR) wavelength range of 993.5 nm. The effect of TCL diameter and MB sol–gel coating thickness on the sensitivity of the sensor was also investigated. A maximum sensitivity of 0.19 dB/O2% in the oxygen concentration range of 0–37.5% was achieved for a TCL fibre sensor with a 2 µm taper waist diameter and a 0.86 µm MB sol–gel coating thickness, with a response time of 4 min. The sensor provides reproducible results even after 7 days and is shown to be highly selective to oxygen compared to argon and ethanol at the same concentration.

Dissolved oxygen affinities of hundreds of benthic foraminiferal species

Over the past decades, fossil assemblages of benthic foraminifera have been used to reconstruct the variability of oxygen-depleted areas, including oxygen minimum zones. These areas currently represent almost a tenth of the global oceans' surface area, and further expansion is expected due to global warming; with major impacts on marine ecosystems, biodiversity, and fisheries. To predict their future evolution, accurate estimates and quantification of past oceanic oxygenation are needed, and thus consistent calibration of the O2 estimation transfer functions is required.Here, we combine the BENFEP database that compiles all the benthic foraminiferal census data published for the East Pacific Ocean, with dissolved oxygen data interpolated from the WOA18 and GLODAPV2.2022 databases, to describe the oxygen affinities of the 1526 benthic foraminiferal taxa from the BENFEP database among 1691 samples. The affinities of the most common 202 species of the database are detailed here. For each of these taxa, the range of oxygen concentration, average O2 value where the species is usually found, and O2 value associated with its peak in relative abundance are listed and used to assign each taxon to the oxygen categories anoxic, dysoxic, suboxic, low oxic, and high oxic.Finally, using the relative abundance of each of these five oxygen assemblages and their associated taxa, transfer function indices of dissolved oxygen estimation were refined. The new BFAex extends the range of applicability of the formerly published BFA index, here updated using all the available samples BFAup and extended from 0.04 to 2.58 mL L−1 to 0.02–6.62 mL L−1.

Crystal structure, oxygen nonstoichiometry and properties of Pr1-xSrxCoO3-δ

The crystal structure, oxygen content and homogeneity range of Pr1-xSrxCoO3-õ solid solutions from room temperature (RT) up to 1100 °C in air were studied. It has been shown that an increase in temperature and Sr content causes an Orthorhombic → Rhombohedral → Cubic transformation of the crystal structure. The heterovalent substitution of Sr2+ for Pr3+ is compensated by an increase in the mean oxidation state of Co ions (zCo) and the formation of oxygen vacancies. The temperature dependences of thermal expansion and conductivity of Pr1-xSrxCoO3-õ solid solutions are explained from the point of view of crystal and defect structure. The diagram of phase relation in the PrCoO3 – “SrCoOz” cross section has been constructed.

Early Diagenetic Controls on Sedimentary Iodine Release and Iodine‐To‐Organic Carbon Ratios in the Paleo‐Record

AbstractIodine cycling in the ocean is closely linked to productivity, organic carbon export, and oxygenation. However, iodine sources and sinks at the seafloor are poorly constrained, which limits the applicability of iodine as a biogeochemical tracer. We present pore water and solid phase iodine data for sediment cores from the Peruvian continental margin, which cover a range of bottom water oxygen concentrations, organic carbon rain rates and sedimentation rates. By applying a numerical reaction‐transport model, we evaluate how these parameters determine benthic iodine fluxes and sedimentary iodine‐to‐organic carbon ratios (I:Corg) in the paleo‐record. Iodine is delivered to the sediment with organic material and released into the pore water as iodide (I−) during early diagenesis. Under anoxic conditions in the bottom water, most of the iodine delivered is recycled, which can explain the presence of excess dissolved iodine in near‐shore anoxic seawater. According to our model, the benthic I− efflux in anoxic areas is mainly determined by the organic carbon rain rate. Under oxic conditions, pore water dissolved I− is oxidized and precipitated at the sediment surface. Much of the precipitated iodine re‐dissolves during early diagenesis and only a fraction is buried. Particulate iodine burial efficiency and I:Corg burial ratios do increase with bottom water oxygen. However, multiple combinations of bottom water oxygen, organic carbon rain rate and sedimentation rate can lead to identical I:Corg, which limits the utility of I:Corg as a quantitative oxygenation proxy. Our findings may help to better constrain the ocean's iodine mass balance, both today and in the geological past.

A multilayer microfluidic system for studies of the dynamic responses of cellular proteins to oxygen switches at the single-cell level.

Oxygen levels vary in the environment. Oxygen availability has a major effect on almost all organisms, and oxygen is far more than a substrate for energy production. However, less is known about related biological processes under hypoxic conditions and about the adaptations to changing oxygen concentrations. The yeast Saccharomyces cerevisiae can adapt its metabolism for growth under different oxygen concentrations and can grow even under anaerobic conditions. Therefore, we developed a microfluidic device that can generate serial, accurately controlled oxygen concentrations for single-cell studies of multiple yeast strains. This device can construct a broad range of oxygen concentrations, [O2] through on-chip gas-mixing channels from two gases fed to the inlets. Gas diffusion through thin polydimethylsiloxane (PDMS) can lead to the equilibration of [O2] in the medium in the cell culture layer under gas cover regions within 2min. Here, we established six different and stable [O2] varying between ~0.1 and 20.9% in the corresponding layers of the device designed for multiple parallel single-cell culture of four different yeast strains. Using this device, the dynamic responses of different yeast transcription factors and metabolism-related proteins were studied when the [O2] decreased from 20.9% to serial hypoxic concentrations. We showed that different hypoxic conditions induced varying degrees of transcription factor responses and changes in respiratory metabolism levels. This device can also be used in studies of the aging and physiology of yeast under different oxygen conditions and can provide new insights into the relationship between oxygen and organisms. Integration, innovation and insight: Most living cells are sensitive to the oxygen concentration because they depend on oxygen for survival and proper cellular functions. Here, a composite microfluidic device was designed for yeast single-cell studies at a series of accurately controlled oxygen concentrations. Using this device, we studied the dynamic responses of various transcription factors and proteins to changes in the oxygen concentration. This study is the first to examine protein dynamics and temporal behaviors under different hypoxic conditions at the single yeast cell level, which may provide insights into the processes involved in yeast and even mammalian cells. This device also provides a base model that can be extended to oxygen-related biology and can acquire more information about the complex networks of organisms.

"Three Zones" Division of Spontaneous Combustion in Goaf of Y-type Ventilation Fully Mechanized Mining Face

The goaf of coal mine is accompanied by residual coal, and the possibility of spontaneous combustion determines whether the mine can work safely. Therefore, the division of "three zones" of spontaneous combustion in goaf under different working conditions is of great significance. This paper takes the 3154 fully mechanized coal face of Longmen Xianan Coal Mine as the research background to explore the "three belts" distribution under the Y-type ventilation mode. Based on the laboratory measured coal related spontaneous combustion characteristic parameters, the division standard of "three zones" is determined. Combined with the daily monitoring of the temperature and gas collection devices deployed on the site and the numerical simulation of the wind speed in the goaf, the comprehensive division of "three zones" in the goaf is realized. The results show that the range of "three zones" divided by temperature is similar to the range of oxygen concentration. The average width of heat dissipation zone and oxidation zone in the transport lane is 34.7m and 48.8m respectively. The asphyxiation zone is located at an average distance of more than 83.4m from the working face; The average width of the heat dissipation zone of the return air lane is 30.6m, the average width of the oxidation zone is 42.7m, and the average distance from the working face is more than 73.3m. In the numerical simulation, the width of the heat dissipation zone of the transport roadway is 35.0m, the width of the oxidation zone is 50m, and the asphyxiation zone is more than 85m from the working face. The width of the heat dissipation zone of the return air lane is 30m, the width of the oxidation zone is 40m, and the asphyxiation zone is more than 75m from the working face. The simulation results are close to the measured range of "three zones" of spontaneous combustion, and the width of "three zones" of return air roadway with Y-type ventilation is obviously different from that of transport roadway.

An improved semi-global intrinsic kinetics model for high temperature carbon oxidation

Measurements of the oxidation rates of various forms of carbon (soot, graphite, coal char) have often shown an unexplained attenuation with increasing temperatures in the vicinity of 2000 K, even when accounting for diffusional transport limitations and gas-phase chemical effects (e.g. CO2 dissociation). With the development of oxy-fuel combustion approaches for pulverized coal utilization with carbon capture, high particle temperatures are readily achieved in sufficiently oxygen-enriched environments. In this work, a new semi-global intrinsic kinetics model for high temperature carbon oxidation is created by starting with a previously developed 5-step mechanism that was shown to reproduce all major known trends in carbon oxidation, except for its high temperature kinetic falloff, and incorporating a recently discovered surface oxide decomposition step. The predictions of this new model are benchmarked by deploying the kinetic model in a steady-state reacting particle code (SKIPPY) and comparing the simulated results against a carefully measured set of pulverized coal char combustion temperature measurements over a wide range of oxygen concentrations in N2 and CO2 environments. The results show that the inclusion of the spontaneous surface oxide decomposition reaction step significantly improves predictions at high particle temperatures. Furthermore, the simulations reveal that O atoms released from the oxide decomposition step enhance the radical pool in the near-surface region and within the particle interior itself. Incorporation of literature rates for O and OH reactions with the carbon surface results in a reduction in the predicted radical pool concentrations and a very minor enhancement of the overall carbon oxidation rate.

Reverse combustion propagation in an oxygen-limited and -enriched N2/O2 flow for a bed packed with rice husk

Propagation characteristics of reverse combustion significantly impact the conversion of solid fuels in packed beds, especially under variable reaction atmosphere conditions. In this study, the propagation of reverse combustion was experimentally studied in an oxygen-limited and -enriched O2/N2 flow with an oxygen concentration range of 21–100 % for a bed packed with rice husk. The temperature profile measured by thermocouples along the bed height was processed to appreciate the driving mechanism of combustion front, as well as the reaction structure inside the bed. Besides, the contribution of volatiles gas-phase oxidation and char surface oxidation to reverse combustion was also evaluated. Results show that compared to the air case, an oxygen-enriched condition broadens the operating range of oxygen flow rate for the oxygen-limited reverse combustion. Under high oxygen concentration conditions, the low-temperature oxidation of rice husk inside the reaction front becomes enhanced. Such chemical reaction effect widens the whole reaction front thickness and thereby reduces the oxidation intensity in local regions, resulting in a faster ignition rate and a lower temperature for combustion front. It is found that this process is dominated by the gas-phase oxidation of volatiles, of which oxygen consumed is above 60 % of the supplied. As oxygen concentration increases, the gas-phase oxidation of volatiles becomes further enhanced. Correspondingly, the oxidation ratio of char is gradually approaching a limit, about 12 %, especially at the oxygen concentration above 50 %. These findings will facilitate a better fundamental understanding of driving mechanism of this special combustion process and thereby provide an important theoretical basis for efficient thermal conversion of solid fuels.

Alternating ventilation accelerates the mineralization and humification of food waste by optimizing the temperature-oxygen-moisture distribution in the static composting reactor

Traditional unidirectional ventilation often leads to the loss of heat and moisture during composting, disrupting the favorable microenvironment required for aerobic microbes. This study developed a pulse alternating ventilation composting reactor and investigated the effects of alternating ventilation on composting efficiency compared with upward ventilation and downward ventilation. The results demonstrated that alternating ventilation stabilized the moisture content at approximately 60 % while reducing the temperature and oxygen concentration range within the reactor. Moreover, it extended the duration of high-temperature (>50 °C) by 31 % and 75 % compared to other two groups. It improved the microbial cooperation intensity and stimulated the core microbe (Tepidimicrobium). Seed germination index (GI) of the compost was improved (GI = 91.27 %), and the humic acid content was 1.23 times and 1.37 times higher than other two groups. These results showed that alternating ventilation can be used for efficient resource disposal of food waste.

Understanding the effect of char oxidation on wood temperature profiles for varying heating and oxygen conditions

The use of mass timber framing as a sustainable material, particularly in high-rise buildings, requires detailed structural fire performance calculations. Thermal models describing only the solid phase are cost-effective alternatives to provide information to structural behavior models. Their accuracy depends on an adequate description of drying, pyrolysis, charring and eventually flaming phenomena. While in recent years there have been considerable contributions to the development of such models, there are still open questions. This work proposes a thermal model which incorporates char oxidation, describing both the kinetic- and diffusion-controlled regimes. The model was used to replicate two sets of experimental results which used standard fire calorimeters to study the ignition of thick wood specimens within a range of incident heat fluxes and oxygen concentrations, respectively. The model yields adequate temperature predictions in the early heating stages, but fails to replicate the behavior at later stages, when the effect of the surface combustion is noticeable. In terms of mass loss rates, a poorer performance is observed. To change from one oxidation regime to another, a Damköhler number is proposed, based on char oxidation reaction rates. It is found that for compartment fire conditions, char oxidation will mostly occur develop under diffusion-controlled conditions.

Iodine-to-calcium ratios in deep-sea scleractinian and bamboo corals

The distribution of dissolved iodine in seawater is sensitive to multiple biogeochemical cycles, including those of nitrogen and oxygen. The iodine-to-calcium ratio (I/Ca) of marine carbonates, such as bulk carbonate or foraminifera, has emerged as a potential proxy for changes in past seawater oxygenation. However, the utility of the I/Ca proxy in deep-sea corals, natural archives of seawater chemistry with wide spatial coverage and radiometric dating potential, remains unexplored. Here, we present the first I/Ca data obtained from modern deep-sea corals, specifically scleractinian and bamboo corals, collected from the Atlantic, Eastern Pacific, and Southern Oceans, encompassing a wide range of seawater oxygen concentrations (10–280 μmol/kg). In contrast to thermodynamic predictions, we observe higher I/Ca ratios in aragonitic corals (scleractinian) compared to calcitic corals (bamboo). This observation suggests a strong biological control during iodate incorporation into deep-sea coral skeletons. For the majority of scleractinian corals, I/Ca exhibits a covariation with local seawater iodate concentrations, which is closely related to seawater oxygen content. Scleractinian corals also exhibit notably lower I/Ca below a seawater oxygen threshold of approximately 160 μmol/kg. In contrast, no significant differences in I/Ca are found among bamboo corals across the range of oxygen concentrations encountered (15–240 μmol/kg). In the North Atlantic, several hydrographic factors, such as temperature and/or salinity, may additionally affect coral I/Ca. Our results highlight the potential of I/Ca ratios in deep-sea scleractinian corals to serve as an indicator of past seawater iodate concentrations, providing valuable insights into historical seawater oxygen levels.

Role of Biogeochemical Processes during Groundwater Deferrization

The paper is devoted to the biogeochemical aspects of the treatment of iron-bearing groundwater, which are associated with the formation of biofouling in the pore space around wells after aeration of the aquifer and on technological equipment. Structure and activity characteristics of microbial complexes as a result of pumping groundwater from production and observation wells under changing redox conditions are presented. Scanning electron microscopy was used to study the microstructure and elemental composition of biofilm growths. It has been established that the accumulation of iron and manganese by microbial biomass occurs due to the encrustation of the surface of bacterial cells immersed in a polymer matrix represented by a constant base of three elements: Al, Si, and Ca. The survival of microbial complexes in biofouling is due to the high natural potential and ability to carry out biogeochemical processes in a wide range of oxygen concentrations (aerobic and anaerobic conditions).

Low‐Power and Fast‐Response Limiting Current‐Type Oxygen Microsensor with a Wide Range Oxygen Concentration

In this study, we fabricated limiting current‐type oxygen microsensors capable of sensing a wide range of oxygen concentrations. The oxygen microsensors consist of yttria‐stabilized zirconia thin films on spiral Ta2O5 diffusion layers and high‐temperature micro‐hotplates. At temperatures above 575 °C, we observed a clear limiting current that increased proportionally with oxygen concentration between 0.4% and 94%. This wide‐range linearity is attributed to the Knudsen diffusion of the oxygen gas passing through the small gap in the spiral Ta2O5 diffusion layer. © 2023 Institute of Electrical Engineer of Japan and Wiley Periodicals LLC.

Sustainability of hydrogen-enriched methane MILD combustion over a wide range of hydrogen-blending ratios in a strongly heat-extracted well-stirred reactor

Moderate or intense low-oxygen dilution (MILD) combustion of methane blended with hydrogen offers a potential solution for gas-fired industrial furnaces and even boilers to realize rapid decarbonization while maintaining ultra-low NO emissions. In this work, the combustion mode map for identifying MILD combustion when burning CH4/H2 mixtures from pure methane to pure hydrogen is proposed, and then the sustainability of hydrogen-enriched methane MILD combustion over a wide range of hydrogen-blending ratios from 0 to 100% under strongly heat-extracted conditions is revealed. Results show that, there exists a threshold oxygen mole fraction (XO2*) below which hydrogen-enriched methane MILD combustion can be achieved as long as the inlet temperature (Tin) is above the self-ignition temperature of reactants. As the hydrogen-blending ratio increases from 0 to 100%, XO2* is reduced from 9.3 to 6.5% and thus the unconditional MILD combustion region is concentrated, implying that hydrogen addition requires a larger oxygen dilution level to sustain MILD combustion. Interestingly, the sustainable operating range of oxygen concentration to sustain hydrogen-enriched methane MILD combustion can be extended by increasing the heat extraction ratio (HER) properly, e.g., XO2* up to 13.2% at HER = 30% for pure hydrogen fuel. However, methane MILD combustion would become unstable and even extinguished once HER exceeds about 49%, whereas MILD combustion of methane blended with a high percentage of hydrogen could be sustained even under highly heat-extracted conditions, e.g., a maximum allowable HER of about 91% for pure hydrogen fuel. In pure hydrogen MILD combustion, heat extraction can further reduce NO emissions, mainly due to less NO production via the N2O-intermediate, NNH, and thermal pathways, and NO reduction by H radicals tends to be weakened with heat extraction. In conclusion, high-percentage hydrogen co-firing makes it possible to achieve stable MILD operation with low NO emissions under strongly heat-extracted conditions encountered in boilers.

NO/SO2/HCl emissions from solid waste combustion via oxygen-carrier-aided combustion in rotary kiln

Rotary kiln incineration technology has become an important approach to achieve the harmless, reduced, and resourceful solid waste (SW) due to its wide range of fuel adaptability and high treatment efficiency. SW incineration through oxygen carrier (OC) aided combustion in the rotary kiln shows significant advantages in improving SW conversion and reducing CO emission. However, the impacts of introducing OC into the rotary kiln on the emissions of NO, SO2, and HCl, are still unknown. This research objective was to investigate the effects of OCs on the emission characteristics of NO, SO2, and HCl. Natural manganese and ilmenite ores as OCs, are added to a continuous-feeding rotary kiln during the combustion of biomass SW and hazardous SW. The results show that the introduction of OCs can significantly improve the uniformity of oxygen distribution in the furnace, and promotes the conversion of fuel N to NO. At high temperatures and low oxygen concentrations range, the reduction rate of NO by high-concentration CO or catalytic reduction by char and ash is faster than the oxidation of fuel N by OCs, which decreases NO concentration. Moreover, at high temperatures, when OCs are distributed in the bed of the rotary kiln, the fuel in the oxygen-poor zone can obtain O2 or lattice oxygen from the OCs, which promotes the decomposition and oxidation of S-containing compounds in fuels and increase the SO2 concentration. In addition, OCs in the bed provide more reaction sites for fuel conversion and promote the release of Cl as HCl at high temperatures. Specifically, during the oil sludge combustion at 900 °C, compared with the inert reference case, the addition of ilmenite ore increased the concentrations of NO, SO2, and HCl by 47.44%, 64.87%, and 20.28%, respectively, which is attributed to the better reactivity and redox cycle stability of ilmenite ore. This study highlights the potential of OC-aided combustion in rotary kilns as an approach to regulate SW combustion and offers a foundation for the future related research.

Radiochemical Oxygen Depletion Depends on Chemical Environment and Dose-Rate: Implications for FLASH Effect

FLASH (dose rates > 40 Gy/s) radiotherapy (RT) protects normal tissues from radiation damage, compared with conventional RT (∼Gy/min). Radiation-chemical oxygen depletion (ROD) has been the leading and most-studied mechanism to explain FLASH. Previous studies have reported low ROD values of ∼0.35 µM/Gy, however, they do not accurately model (utilizing water or oxidized substrates such as albumin) the intracellular environment. It has been proposed that the intracellular environment may support higher ROD values due to its specific chemical makeup. As chemical reducing agents, which play a critical role in the cell, may promote ROD, we measured ROD for several well-known cellular reducing agents. Precision polarographic oxygen sensors were used to measure ROD over a ∼100-0 µM oxygen concentration range in solutions containing various types of intracellular reducing agents, either alone or combined with glycerol (1M; to simulate the intracellular hydroxyl-radical-scavenging capacity). A Cs irradiator and a research proton beamline were used for radiation beam generation over a 10,000-fold (0.0085 to 100 Gy/s) dose rate range. Reagents were grouped generally into primary free-radical scavengers (glycerol & lysozyme) and reducing agents (cysteamine, cysteine, glutathione, dextrin-conjugated linoleic acid, NAD(P)H, ascorbate and uric acid). Reducing agents at 1 mM significantly altered ROD values. ROD, at 0.1 Gy/s varied from greater than 1 µM/Gy for NADPH to less than 0.1 µM/Gy for uric acid. Even higher RODs were found at lower dose rates and/or higher reducing agent concentrations. Although most greatly increased ROD, ascorbate and uric acid decreased ROD and additionally imposed an oxygen dependence of ROD at low oxygen concentrations. Interestingly, all agents having high rates of ROD at low dose rates show a decrease at FLASH dose rates and this seems to be a proportional response (i.e., the greater the ROD at low dose rate, the greater the inhibition by FLASH). At FLASH dose rates our data for a simple mixture of glycerol and glutathione showed the same trend as recent studies that, in general, FLASH had ∼25% lower ROD rates than conventional demonstrating agreement between polarographic sensors and optical phosphorescence decay methods. ROD was greatly augmented by some intracellular reducing agents but others effectively reversed this effect. Ascorbate had its greatest impact at low oxygen concentrations. ROD decreased with increasing dose rate and in all cases was less than 1 µM/Gy at 100 Gy/s, potentially posing a fundamental limit of max ROD for FLASH.