Radiocarbon Analysis Research Articles

Late Glacial and Holocene history of climate, vegetation landscapes and fires in South Taiga of Western Siberia based on radiocarbon dating and multi-proxy palaeoecological research of sediments from Shchuchye Lake

Abstract To investigate long-term relationships between climate, vegetation, landscape geochemistry and fires in the boreal forest zone of Western Siberia, a sediment core of 345 cm was collected from Shchuchye Lake (located in south taiga zone of southeast part of West Siberian plain) and investigated by spore-pollen, radiocarbon, LOI and charcoal analyses. Quantitative palaeoclimate was reconstructed based on pollen data. Investigation revealed 13.2 cal ka history of vegetation, climate, landscapes and fires. In the dry climate of Late Glacial, the landscape was treeless. Continuous permafrost existed in the soil. In the middle of the YD cooling 12.4–12.2 cal ka BP, our data showed warming that caused degradation of permafrost in soils and settlement of spruce in moist places. Later, thawing and accumulation of moisture in a local lowering in relief increased and a lake was formed. With the beginning of the Holocene, the climate sharply changed to warmer and wetter. Intensified surface flow caused accumulation of mineral and carbonate fraction in the lake. Dense birch forests spread on drylands. As a result, the leaching regime initiated the formation of podzols in the soil. At about 10.0 cal ka BP, Scots pine (Pinus sylvestris) quickly spread in the area of investigation. Fires became more frequent and more intense during the dry Late Glacial time, sharply decreasing with increased precipitation in the Early Holocene, and again moderately increasing with spread of pine forests in the mid Holocene. With the transition to Late Holocene (after 6.0 cal ka BP), the intensity of regional background fires and number of local fires decreased.

Isolation of Methane from Ambient Water and Preparation for Source-Diagnostic Natural Abundance Radiocarbon Analysis.

A key challenge in climate change research is apportioning the greenhouse gas methane (CH4) between various natural and anthropogenic sources. Isotopic source fingerprinting of CH4 releases, particularly with radiocarbon analysis, is a promising approach. Here, we establish an analytical protocol for preparing CH4 from seawater and other aqueous matrices for high-precision natural abundance radiocarbon measurement. Methane is stripped from water in the optionally field-operated system (STRIPS), followed by shore-based purification and conversion to carbon dioxide (CO2) in the CH4 Isotope Preparation System (CHIPS) to allow Accelerator Mass Spectrometry analysis. The blank (±1σ) of the combined STRIPS and CHIPS is low (0.67 ± 0.12 μg C), allowing natural sample sizes down to 10 μg C-CH4 (i.e., 30 L samples of 40 nM CH4). The full-system yield is >90% for both CH4-spiked seawater and ambient samples from CH4 hotspots in the Baltic Sea and the Arctic Ocean. Furthermore, the radiocarbon isotope signal of CH4 remains constant through the multistage processing in the STRIPS and the CHIPS. The developed method thus allows for in-field sampling and sample size reduction followed by precise and CH4-specific radiocarbon analysis. This enables powerful source apportionment of CH4 emitted from aquatic systems from the tropics to the polar regions.

The archaeology of eastern Lutruwita (Tasmania)

ABSTRACTFifty years have passed since the first systematic archaeological surveys and excavations were conducted in Lutruwita (Tasmania). Despite numerous Late Pleistocene archaeological discoveries in the southwest region, no indisputable pre‐Holocene sites have been found in eastern Tasmania. This profound difference raises questions about how Aboriginal people utilised the Lutruwita landscape; first as a projecting peninsula into the Southern Ocean and then as an island cut off by rising seas c.14000 years ago.To examine the difference between east and west further, legacy data excavated by one of us (RJ) in 1964 at the Oatlands OL1 site and stored at the Tasmanian Museum and Art Gallery (TMAG) has been analysed. The results of pXRF chemical analysis of artefact raw material, radiocarbon dating and studies of faunal remains have produced information that highlights the Holocene interaction between people in eastern Lutruwita. Despite the current lack of Late Pleistocene evidence from eastern Lutruwita, this pattern appears to be different from land use models for Late Pleistocene southwestern Lutruwita. With new information from the OL1 rock shelter site we can now contrast the Late Pleistocene hunting economics with the exceptionally well‐preserved faunal remains found in the Holocene site, OL1.

Rapid, effective screening of tar seep fossils for radiocarbon and stable isotope analysis

Tar seeps trap and preserve diverse fossil assemblages that reflect unique environmental histories. While the macro preservation of the fossils is usually good, preservation of organic bone collagen is often variable. Radiocarbon dating and stable isotope analysis of tar seep taxa can reveal distinct paleoecological insights but are complicated by the contamination from tar infiltration. Additionally, the removal of tar is complex and time-consuming. Therefore identifying fossils with preserved collagen prior to further investigation minimizes unnecessary damage to fossil collections and improves success rates for analyses that require organic preservation.We used tar pit fossils where the collagen preservation state was independently known to test non-destructive (visual inspection) and minimally-destructive (infrared spectroscopy; FTIR) methods to determine the most reliable methods to identify bones with well preserved collagen. We found that while collagen is less often preserved in heavily weathered bones, visual cues alone are not a reliable indicator. Instead, the Water-Amide-on-Phosphate FTIR index is highly sensitive and specific at identifying fossils suitable for radiocarbon dating and stable isotope analysis. While our protocol and analysis code were developed using fossils from two California tar seep localities (McKittrick and Rancho La Brea), they are likely to be broadly applicable to other tar seep localities that have yielded fewer fossils, thus requiring even greater care when selecting specimens for further analysis.

The Late Middle and Early Upper Palaeolithic in Crimea (Ukraine)—A Review of the Neanderthal Refugium Hypothesis

The Crimean Peninsula contains numerous important Palaeolithic sites. It has been considered a potential Neanderthal refugium in Eurasia prior to their disappearance or assimilation, and subsequent replacement by Homo sapiens. This understanding is primarily drawn from lithic technological analysis and radiocarbon dating. However, recent developments in the latter suggest that many of the previously obtained radiocarbon dates from Crimean sites may be too young. The chronological sequence from the site of Kabazi II is a case in point, where differences between dates of bulk collagen and those of single amino acids range up to 10,000 radiocarbon years. These discrepancies are argued to arise from sample contamination and its lack of removal in bulk collagen dating. In this paper, we undertake a critical re-evaluation of results from seven Palaeolithic archaeological sites in the Crimean Peninsula: Kabazi II, Siuren I, Buran-Kaya III, Zaskalnaya V and Zaskalnaya VI, Kabazi V and Starosel’e. Our analysis of radiocarbon results from various sites supports the view that radiocarbon dates obtained so far tend to be too young, which has been indicated in the stratigraphy and lithic assemblages. By harnessing robust radiocarbon protocols in future chronometric work, such as the extraction of hydroxyproline, ninhydrin derivatisation or the purification of amino acids using XAD-2 resin, there is potential for constructing accurate chronologies. Furthermore, improved dating accuracy holds the promise of significant additional insights into the prehistoric sequence of the Crimean Peninsula and its potential role as a refugium for Neanderthals prior to their disappearance.

Radiocarbon dating of illegal ivory confirmed by Milos Forman’s Hair

Abstract Illegal poaching brought elephant species to the brink of extinction; therefore, international trade in ivory has become regulated by the Convention on International Trade in Endangered Species of Flora and Fauna (CITES). However, the trade is still allowed for antique items, standing for ivory from a period before 1947 within the European Union. This could serve as a loophole for the laundering of modern ivory. In the described case of the Happy Fisherman statuette, the traded item was declared to be antique, but radiocarbon analysis proved a modern provenance, and the statuette was confiscated. The radiocarbon analysis was later confirmed by information from a Chinese newspaper found inside the statuette. Based on the findings, we strongly recommend careful consideration of each individual ivory piece offered for sale, with a thorough inspection of the items and related documentation carried out by a relevant CITES authority. Any exemption of the commercial ban should be granted only to those applicants who meet the criteria of proper evidence in the form of scientific analysis or reliable and trustworthy documentation.

Characterization and analysis of a Commiphora species germinated from an ancient seed suggests a possible connection to a species mentioned in the Bible

A seed recovered during archaeological excavations of a cave in the Judean desert was germinated, with radiocarbon analysis indicating an age of 993 CE– 1202 calCE. DNA sequencing and phylogenetic analysis identified the seedling as belonging to the angiosperm genus Commiphora Jacq., sister to three Southern African Commiphora species, but unique from all other species sampled to date. The germinated seedling was not closely related to Commiphora species commonly harvested for their fragrant oleoresins including Commiphora gileadensis (L.) C.Chr., candidate for the locally extinct “Judean Balsam” or “Balm of Gilead” of antiquity. GC-MS analysis revealed minimal fragrant compounds but abundance of those associated with multi-target bioactivity and a previously undescribed glycolipid compound series. Several hypotheses are offered to explain the origins, implications and ethnobotanical significance of this unknown Commiphora sp., to the best of our knowledge the first identified from an archaeological site in this region, including identification with a resin producing tree mentioned in Biblical sources and possible agricultural relationship with the historic Judean Balsam.

Growth characterization of mesophotic rhodoliths in the northern Gulf of Mexico using radiocarbon dating

Boxwork rhodoliths are characterized by a multitaxonomic composition and excessive void spaces, and they are distributed from intertidal to mesophotic depths. Growth rates and patterns in rhodoliths from shallower depths and simpler morphologies have been assessed using incremental and geochemical analyses, but rhodoliths from mesophotic depths have been harder to access and require more studies. Boxwork rhodoliths have proved too structurally complex for age and growth rate assessment techniques such as stable oxygen isotopes profiling or elemental mapping. We therefore utilized sequential radiocarbon analysis for growth characterization of mesophotic boxwork rhodoliths. Rhodoliths were collected from the Flower Garden Banks National Marine Sanctuary in the northern Gulf of Mexico from one location at 48–72 m and another at 103 m. Specimens were extensively sampled for radiocarbon concentrations from predicted nucleation points and along growth axes. From depths of 48–72 m, nucleation ages ranged from 795 ± 20 to 3270 ± 25 14C yr B·P. From depths of 103 m, nucleation ages ranged from 8960 ± 110 to 13,050 ± 150 14C yr B.P., dating back to the end of the Pleistocene in some cases. Several rhodoliths contained evidence of growth hiatuses, with deeper samples displaying age reversals that complicated the apparent growth history. We define age reversals to be non-sequential ages within a sampling sequence, typically a singular age before the return to normal age sequence. The research presented here includes the oldest known living rhodoliths, with the oldest rhodoliths grown before and after Holocene sea-level stabilization. These results have implications for the use of rhodoliths as paleoenvironmental indicators, and provide better understanding of the range and volume of carbonate production in these habitats.

Climate Factor in Cultural Transformations of Eurasia in the Mid-4Th – Mid-3Rd Millennia BC, and Possibilities of Creating an Absolute Chronology

Climate changes were the most important factor that stimulated migration in antiquity. It was they which led to the appearance of monuments of the megalithic tradition in the Northwestern Black Sea region (Usatovo), in the North Caucasus (Novosvobodnaya), in the Urals, and in Central Asia (Chemurchek) in the 4th – 3rd millennia B.C. This also caused the spread of the tradition of Yamnaya culture to Central Europe, the appearance of the Corded Ware cultures and many other changes. However, the general process of climate change could not be a trigger for migrations. These were short-term drastic climatic changes, which are recorded by dendrochronology. The latter can also be used as chronological markers, making it possible to create the Eurasian chronology independent of radiocarbon analyses, which have too wide confidence intervals. This approach made it possible to determine the date of the Yamnaya migration to the Carpathian Basin and the formation of the Corded Ware cultures ca. 2850 B.C., and the date of the Fatyanovo migration from Europe to the east ca. 2564 B.C. Unfortunately, the dates of the appearance of megaliths in the east are not determined with a similar accuracy, due to the impossibility to verify this with alternative sources. Their appearance can be dated to ca. the mid-4th millennium B.C. in Eastern Europe, in the last quarter of the 4th millennium B.C. in the Urals, and in the 24th century B.C. in Central Asia.

Low-Invasive Sampling Method with Tape-Disc Sampling for the Taxonomic Identification of Archeological and Paleontological Bones by Proteomics.

Collagen from paleontological bones is an important organic material for isotopic measurement, radiocarbon analysis, and paleoproteomic analysis to provide information on diet, dating, taxonomy, and phylogeny. Current paleoproteomic methods are destructive and require from a few milligrams to several tens of milligrams of bone for analysis. In many cultures, bones are raw materials for artifacts that are conserved in museums, which hampers damage to these precious objects during sampling. Here, we describe a low-invasive sampling method that identifies collagen, taxonomy, and post-translational modifications from Holocene and Upper Pleistocene bones dated to 130,000 and 150 BC using dermatological skin tape discs for sampling. The sampled bone micropowders were digested following our highly optimized enhanced filter-aided sample preparation protocol and then analyzed by MALDI FTICR MS and LC-MS/MS for identifying the genus taxa of the bones. We show that this low-invasive sampling does not deteriorate the bones and achieves results similar to those obtained by more destructive sampling. Moreover, this sampling method can be carried out at archeological sites or in museums.

A tree-ring cellulose extraction device adapted to radiocarbon analysis

AbstractTree-ring cellulose is a commonly used material for radiocarbon analysis. Extracting cellulose is labor-consuming and several devices that enable batchwise extraction have been developed. However, these devices bear the risk of sample contamination. The present study describes a new device which improves upon two aspects of currently available devices. First, to prevent cross-sample-contamination, we redesigned the drainage module to enable independent removal of chemical waste from each individual sample funnel. Second, we added covers to the sample funnels to reduce the risk of external contamination. Cellulose purity (i.e., holocellulose) was confirmed by Fourier Transform Infrared (FTIR) Spectroscopy. Furthermore, accuracy of the radiocarbon analysis was confirmed by results of 14C-blank samples and samples of known age. In conclusion, while maintaining labor-saving, our modified device significantly reduces the risk of sample contamination during extraction of tree-ring cellulose.

Compound-specific radiocarbon analysis of sedimentary fatty acids: Potential as a dating tool for lake sediments of Mt. Fuji volcanic region, Japan

Compound-specific radiocarbon analysis (CSRA) is a promising tool for dating sediment sequences where traditional dating methods are impractical. However, the applicability of CSRA of short-chain fatty acids as a dating tool remains poorly understood, especially in lacustrine settings. Accordingly, we determined the radiocarbon content (Δ14C) of individual fatty acids in sediments of Lake Yamanaka (central Japan), as well as their stable carbon and hydrogen isotope ratios, to evaluate the potential of CSRA as a dating tool in volcanic lake environments. We found that the Δ14C values of plant-derived (C24, C26, and C28) n-fatty acids (–99‰ to –149‰) were considerably lower than the Δ14C of charred plants (139‰) within the sediments and those of living aquatic plants (–52‰ to –58‰) in Lake Yamanaka, suggesting that contributions from pre-aged terrestrial and aquatic plant materials likely affect these acids. Similarly, the Δ14C of C16n-fatty acid (–95‰) in surface sediments was much lower than the Δ14C of modern aquatic plants (–52‰ to –58‰), as well as the Δ14C of dissolved organic carbon (DIC) in surface water (–48‰). Together with the stable isotope results, we conclude that in addition to autochthonous aquatic sources, contributions from pre-aged terrestrial carbon sources significantly affect the Δ14C of C16n-fatty acids. Comparing fatty acid Δ14C and concentration data across lakes within the Mt. Fuji region suggests that CSRA of the C16 acid provides valid chronological information only when the C16 originates exclusively from autochthonous aquatic sources, with minor allochthonous terrestrial input.

Anthropogenic and biogenic pollutants in a forested environment: SPRUCE-22 campaign overview

The SPRUCE-22 field campaign was conducted during July 2022 on a remote mountainous forested site in Greece to assess interactions of biogenic and anthropogenic pollutants in the Eastern Mediterranean. Particle chemical composition and size distributions along with concentrations of organic and inorganic gases were measured at high temporal resolution, while samples were collected and analyzed off-line. PM1 had a surprisingly high average concentration of 13 μg m−3 consisting primarily of organics (57%), followed by sulfate (30%), ammonium (9%), and black carbon (2%). Nitrates (both inorganic and organic) were less than 1% of the PM1 despite the relatively high NOx emissions in the Balkans. The PM2.5 concentrations at this remote site were similar and even higher than those in major cities across Greece including Athens, indicating the importance of regional transport for summertime pollution in the Eastern Mediterranean. The relatively constant average diurnal profiles of major anthropogenic pollutants are consistent with only minimal effects from local sources. Sulfates are not any more the dominant component of fine PM in Greece due to the reduction of SO2 emissions of coal-burning powerplants. The organic aerosol (OA) was quite oxidized with an average oxygen to carbon ratio (O:C) equal to 0.83. The average concentration of isoprene was 0.6 ppb, of monoterpenes 0.5 ppb, while the biogenic secondary organic aerosol factor (obtained through source apportionment analysis) was estimated to contribute 22% of the OA. Additional biogenic secondary organic aerosol (SOA) may be part of the two oxygenated OA (OOA) factors that were also identified. Radiocarbon analysis indicated that the non-fossil carbon was approximately equal to the sum of the biogenic and the more oxidized oxygenated OA, implying that the less oxidized OOA in this study was mostly associated to anthropogenic fossil fuel combustion. The biogenic SOA was quite aged (O:C equal to 0.63) and was also mostly transported to the site. Nearby new particle formation events occurred during 20 % of the days, with an average SO2 concentration of 0.3 ppb. The oxidative potential of the PM per unit of mass was quite high. The source attribution of the fine PM and the interactions among its anthropogenic and biogenic components are also discussed.

Lipid biomarkers and stable isotopes uncover paleovegetation changes in extremely species-rich forest-steppe ecosystems, Central Europe

The historical development of the vegetation of semi-dry grasslands in Central Europe is not satisfactorily understood. Long-term continuity of open vegetation or, conversely, deep-past forest phases are considered possible sources of the current extreme species diversity of these ecosystems. We aimed to reveal the trajectory of paleovegetation development in these ecosystems through detailed analysis of terrestrial in-situ soil geoarchives. We measured the bulk soil carbon and nitrogen contents, lipid molecular distribution, and compound-specific stable carbon and hydrogen isotopic signatures of mid- and long-chain n-alkanes extracted from soil and modern plant material tissues (i.e., deciduous and Pinus leaves and grass/herbaceous species).The C23–C33 n-alkane homologues were identified in soils with different abundances. Normally, C27 and C29 n-alkanes were the most abundant homologues in tree-leaf samples, while grass-derived n-alkanes were mostly C31 and C33 homologues. Soils were largely dominated by C29 and C31 n-alkanes. Odd-numbered C27–C33 soil n-alkane δ13C values ranged from −36.2‰ to −23.2‰, whereas their δ2H values showed a wider range of variability that fluctuated from −224‰ to −172‰. Molecular distribution in combination with radiocarbon analysis of soil organic matter (SOM) and δ13C and δ2H values of n-alkanes revealed a large contribution of C3 trees (both deciduous and coniferous trees/pine trees) as the main source of n-alkanes between the late Pleistocene and early Holocene (ca 15,000–8200 calibrated year before present/cal year BP). A clear shift toward more grassy/herbaceous vegetation was observed from the early Holocene (ca 11,700–8200 cal year BP) onwards. Distribution patterns of lipids and soil geochemical parameters showed that plants are the main source of SOM and that biodegradation and kinetic isotope fractionation are not the main reasons for 13C enrichment in soil profiles. Past C3 vegetation shifts as well as paleoclimate changes (i.e., aridity) can have played a role in the observed 13C depth profiles.

San Isidro, Sonsonate, El Salvador: Development of a Preclassic Settlement in Chronological and Geographic Context

ABSTRACT This paper presents a study of the San Isidro archaeological site in El Salvador, providing significant insights into the development of Preclassic settlements in the region. Through analysis of ceramic sequences, radiocarbon dating, and excavations, the study traces the site’s evolution and its contextual significance within Mesoamerican and Isthmo-Colombian spheres. We report on the discovery of over 50 mounds constructed around 400 b.c., indicating the emergence of a complex social structure at that time. The unearthed artifacts, including jade objects and Bolinas-type figurines, suggest cultural exchange with often distant regions of Mesoamerica and the Isthmo-Colombian area. This research not only contributes to understanding the chronological and geographic development of San Isidro but also highlights the site’s role in broader Preclassic Mesoamerican cultural dynamics. Our findings challenge existing perceptions of cultural peripherality and emphasize the need for nuanced regional studies in reconstructing ancient Central American history.

Characterisation of urban aerosol size distribution by radiocarbon and PIXE analyses in a middle-European urban environment for source identification: a pilot study

This study, conducted in Debrecen, Hungary, aimed to analyse atmospheric particulate matter (APM or PM) through radiocarbon and PIXE analyses during the winter smog (23–25 January) and spring (15–18 May) seasons. The information presented in this pilot study aims to provide insight into the importance of utilising detailed characteristics of the mass size distributions of fossil carbon (ff) and contemporary carbon (fC) content. Additionally, it seeks to compare these characteristics with the size distributions of various elements to enable even more accurate PM source identification. In winter, APM concentrations were 86.27 μg/m3 (total), 17.07 μg/m3 (fC) and 10.4 μg/m3 (ff). In spring, these values changed to 29.5 μg/m3, 2.64 μg/m3 and 7.01 μg/m3, respectively. Notably, differences in mass size distribution patterns were observed between the two seasons, suggesting varied sources for contemporary carbon. Biomass burning emerged as a crucial source during the smog period, supported by similar MMAD (Mass Median Aerodynamic Diameter) values and a strong correlation (r = 0.95, p < 0.01) between potassium and fC. In spring, a significant change in the concentration and distribution of fC occurred, with a broad, coarse mode and a less prominent accumulation mode. Ff was found to have similar distributions as PM, with nearly the same MMADs, during both periods. Finally, a comprehensive comparison of modal characteristics identified specific sources for the various components, including biomass burning, vehicle exhaust, coal and oil combustion, vehicle non-exhaust, road dust, tyre abrasion, mineral dust and biogenic emission. This study showcases how using radiocarbon and PIXE analysis in size distribution data can enhance our understanding of the sources of PM and their effects on different size fractions of PM.

Microbial Communities Degrade Ancient Permafrost‐Derived Organic Matter in Arctic Seawater

AbstractThe Arctic is experiencing rapid warming, which among other processes results in increasing erosion of coastal permafrost and the release of ancient organic carbon (OC) into the Arctic Ocean, which in turn might result in greenhouse gas emissions following its decomposition. Supply of terrigenous organic matter to the ocean affects near‐shore nutrient concentrations and the composition of microbial communities—highlighting the need to understand the fate of permafrost‐derived carbon in this fragile ecosystem. We incubated material from coastal Yedoma permafrost for 85 days in seawater collected during the Arctic Century expedition. During this experiment, 2.8 ± 1.4% of OC from coastal Yedoma was respired to CO2. Radiocarbon analysis revealed that 88 ± 15% of the released CO2 originated from ancient material (∼40,000 years), indicating that degradation of permafrost OC reintroduces old carbon into the short‐term carbon cycle. Hence, the permafrost climate feedback may be enhanced in the coming decades when coastal erosion accelerates. Additionally, 0.9 ± 0.3% of Yedoma OC was leached as dissolved OC. The observed net production of inorganic nitrogen during the incubation could potentially provide a negative feedback by stimulating primary production. Bacterial community analysis showed a succession of primary responders to biolabile substrates (e.g., Psychrobacter and Colwellia) followed by secondary consumers of less biolabile substrates (e.g., Maribacter and Pseudohongiella), plus a potential establishment of permafrost associated‐bacteria on particles. Overall, our data show that OC input from thawing permafrost stimulates bacterial dynamics, with likely implications for regional biogeochemical cycles and the Earth's climate.

Otolith radiocarbon signatures provide distinct migration history of walleye pollock around Hokkaido, Japan in the North-Western Pacific.

Trace elements and stable isotope ratios in otoliths have been used as proxies for the migration history of teleosts; however, their application in oceanic fishes remains limited. This study reports the first use of radiocarbons in otoliths to evaluate the horizontal migration histories of an oceanic fish species, the walleye pollock Gadus chalcogrammus. We conducted radiocarbon analyses of three stocks sourced from Hokkaido, Japan. The radiocarbon concentrations from the outermost portion of the otoliths from the Japanese Pacific, Northern Japan Sea (JS), and Southern Okhotsk Sea (OS) stocks were in general agreement with the seawater radiocarbon concentration of the sampling region, suggesting that pollock of all three stocks generally inhabited the within the sea region where each pollocks were sampled throughout their life cycle. However, the radiocarbon signals also provided some indications that some JS and OS stocks may be migrating between different sea regions. The proposed novel approach of reconstructing the individual migration history of marine fish using radiocarbon in otoliths may help examine fish migration with a higher temporal and spatial resolution that could not be achieved by trace elements and stable isotope ratios.

Source apportionment of fine particulate matter in middle Indo-Gangetic Plain by coupled radiocarbon –molecular organic tracer method

Despite significant emissions of fine particulate matter (FPM) from the Indo-Gangetic Plain (IGP) that affect the climate and air quality in the region, the sources of these emissions are not adequately addressed. This research uses a combined radiocarbon-molecular organic tracer technique to investigate the degree of contamination, seasonal fluctuations, and contribution of FPM in the middle IGP (Patna), India. The findings indicated levoglucosan (L) as the single primary BB tracer chemical, ranging from 149 ng/m3 to 490 ng/m3 (median 282 ng/m3). Winter (median 462 ng/m3) showed a 2–3 times higher level of L than the monsoon season (median 180 ng/m3). A significant association of L with other organic tracers such as galactosan (G), mannosan (M), vallinic acid, syringic acid, p-hydroxybenzoic acid (pHA) and dehydroabietic acid (DHAA)(r = 0.53 to 0.89, p < 0.05), and moderate connection with Cl− (r = 0.21, p < 0.05), SO42− (r = 0.29, p < 0.05), and NO3- (r = 0.22, p < 0.05) indicated significant BB contribution. However, non-sea salt (nss-K+) was not related to L. Based on seven days of air mass back trajectories and MODIS active fire counts analysis, we conclude that OAs composition is not the local origin but is also impacted by long-range atmospheric transport from Pakistan/Afghanistan, followed by the Bay of Bengal and the Arabian Sea. Chemical analysis of organic tracers and positive matrix factorization (PMF) modeling study identified three unique sources, i.e., biomass burning, secondary aerosols formation, and mixed type (fossil fuels and construction dust) as the primary source of FPM in Patna, accounted for 46.1 %, 28.9 %, and 24.9 %, of total emissions, respectively. The radiocarbon (14 C) analysis of total carbon (TC) samples further supported this conclusion. The results of the 14 C study indicated that emissions from BB, such as wood and stubble, were responsible for 57% of the TC concentration.

Morphodynamics and morpotectonics of the varzuga river mouth area (terskiy coast of the white sea) in the late glacial and holocene

The Late- and post-glacial history of the development of the White Sea coastal zone in the area of the Varzuga River mouth is considered as a result of the interaction of endogenous and exogenous factors of coastal morpholithogenesis. Based on geomorphological investigations, study of Holocene deposits by lithostratigraphic, diatom and radiocarbon analyses, as well as collection and analysis of published data, new results on the area’s relief development for ~13 cal ka BP have been obtained. The features of the regional hierarchical morphostructure and local post-glacial tectonics of the territory — the spatial relationships of blocks and the speed of vertical movements – were determined. The superimposed linear Nizhnevarzugskaya depression, which determined the configuration of the Varzuga River estuary in the late and postglacial time, was identified for the first time. The influence of the spatial ratio of blocks and differentiated postglacial uplift on the coastal morpholithogenesis was established. The course of changes in the relative sea level (RSL), development conditions and morphodynamics of the open coast and the estuary of the Varzuga River were reconstructed and new data on the rhythms of coastal morpholithogenesis processes (coastal, estuarine, and aeolian) obtained. Three stages of the coastal zone development were identified, corresponding to regional rhythms of changes in the relative sea level and climate: (I) Late Glacial transgression and Early Holocene regression (~12–9.8 cal ka BP), (II) Middle Holocene Tapes transgression (7.8–4.9 cal ka BP), (III) Late Holocene regression (after 4.9 cal ka BP). The upper marine boundary of the Late Glacial transgression is traced at the elevation of ~54–55 m a. s. l. to the west of the Nizhnevaruzgskaya depression, — ~39–40 m a. s. l. to the east of it, and — 22–25 m a. s. l. in the depression. The shores of lower morphostructural blocks were probably blocked by dead ice up until ~10.2–9.8 cal ka BP. During the Tapes transgression, the RSL reached a maximum (~7.8–7.6 cal ka BP; ~20 m a. s. l.), and by 4.9 cal ka BP fall to ~15 m a. s. l. The prevailing directions of sediment fluxes, winds and wave approach became similar to those of today. However, the main source of the coastal zone sedimentary supply was the erosion of glaciofluvial sediments and the input of sands from the seabed. In the interval of ~4.9–1.7 cal ka BP, the RSL decreased to ~5 m a. s. l. The sediment runoff of the Varzuga River became the main source of feeding the coastal zone.