Quartz Optically Stimulated Luminescence Research Articles

Further investigation of spatially resolved single grain quartz OSL and TL signals

The use of luminescence signals from single mineral grains for optical dating has become a valuable and frequently utilised tool in Quaternary Geochronology. Single grain luminescence dating is particularly beneficial in complex depositional settings, however the ability to measure single grain signals also offers the opportunity to assess intrinsic luminescence properties of individual mineral grains. The use of spatially resolved luminescence technologies such as an electron multiplier charge coupled device is of benefit when making luminescence measurements at single grain scales because they allow stimulation with light emitting diodes, and this offers a number of key benefits related to stimulation power when it comes to the assessment of characteristics such as optically stimulated luminescence (OSL) decay rate and the calculation of parameters such as the fast ratio and photo ionisation cross-sections. In this paper, the intra- and inter-sample variability of sensitised single grain thermoluminescence (TL) and OSL signals is considered. A comparison between TL and OSL signals is undertaken, as well as calculation of the fast ratio, OSL component photo ionisation cross-sections, thermal stability, and characteristic dose for a suite of quartz samples from a range of geographic locations and depositional settings. For these heated signals, key findings include the lack of relationship between OSL signal intensity and dominance of the fast component, the fitting of two components (a fast and slow component) is the most common fit for single grain OSL signals, characteristic doses from fast dominated signals suggesting saturation at c. 150 Gy, and the identification of the ultrafast OSL component. Intra-sample variability across all measured parameters is observed, suggesting that for this suite of samples, variability is the norm rather than the exception, and that the intrinsic luminescence characteristics of quartz are variable and diverse.

Multi-method luminescence dating of young aeolian dunes in the central Tibetan plateau

The environment of the Tibetan Plateau (TP) is extremely sensitive to global climate change, and the frequent aeolian activity on the central TP generates large amounts of dust with the result that the region has a major impact on regional and global environmental change. The extensive aeolian dunes on the central TP provide a direct and valuable archive of aeolian activity; however, the age and sediment deposition processes of these dunes are still poorly understood. Optically stimulated luminescence (OSL) dating, an effective method for dating aeolian sediments, has been used sparingly in the region. In this study, we applied quartz single-aliquot regenerative-dose (SAR) OSL, K-feldspar post-infrared infrared-stimulated luminescence (pIRIR), and single-grain K-feldspar pIRIR methods to determine the ages of two well-preserved sand dunes in the Lunpola (LD) and Tuotuohe (TTH) river basins in the central TP. Our results showed that the quartz OSL signal of the TTH dune was dim, while the LD dune quartz exhibited a higher OSL sensitivity than that of the TTH dune. The high recuperation observed could be attributed to the low signal-to-noise ratio of the OSL signals. The K-feldspar signal was bright and the pIR50IR170 signal could be used to date young dune samples in the central TP, whereas it could be affected by the residual dose, or incomplete bleaching in the TTH profile, resulting in age overestimation. The single-grain K-feldspar protocol had a good potential for dating the young TP dunes. Multi-method luminescence dating is recommended for the cross-checking of young dune samples with low OSL sensitivity in the TP. Our luminescence dating reveals that aeolian dunes in the central TP formed approximately 385 to 330 a and persisted to the present, possibly in response to climate change since the late stage of Little Ice Age (1400−1850 CE).

Single grain pIRIR dating of glacigenic deposits in the Yuzhu Peak area of Kunlun Mountains of Tibetan Plateau revealed the glaciations during Holocene period

The variations of glaciers in the Kunlun Mountains of the northern Tibetan Plateau are influenced by the complex interaction of the East Asia summer monsoon (EASM), Indian summer monsoon (ISM) and Westerlies, as well as human activity during the Holocene period. Consequently there is ongoing debates regarding the evolution of glaciers and the factors driving their changes. The reconstruction of glacial evolutions in these regions has been hindered by insufficient chronological data for moraines and other glacial landforms. In this study, glacial sediment samples were collected from five moraine sequences located on the southern and northern slopes of the Yuzhu Peak in the Kunlun Mountains. These poorly bleached moraine samples were dated using the single-grain quartz optically stimulated luminescence (OSL) and K-feldspar post-infrared infrared stimulated luminescence (pIRIR) dating methods. The luminescence characteristics analysis of quartz grains shows that single grain quartz OSL dating cannot be used to date Holocene moraine samples due to the low brightness of quartz OSL signals. Various tests were conducted to assess the reliability of K-feldspar pIR50IR170 dating, including anomalous fading tests, dose recovery, and residual dose tests. The K-feldspar pIR50IR170 ages, determined using the Minimum Age Model (MAM), indicate that during the early Holocene, glaciations have expanded by ∼800 m in length at ∼ 8 ka, and during the end of the Neoglacial period, they extended by ∼200 m in length at ∼ 1 ka. The strengthened ISM precipitation and northward movement of ISM boundary likely contributed to the glacial expansion in the early Holocene. During the end of the Neoglacial period, the increase in westerlies precipitation and cold events may have played a role in the advancement of glaciers.

Optical dating of charcoal kiln remains from WWII: A test of accuracy

The majority of relic charcoal kilns in Europe are more recent than 1650 CE and cannot be precisely dated using radiocarbon dating (14C). Quartz-based optically stimulated luminescence (OSL) dating of the sediments associated with the kiln remains has been suggested as a viable alternative. Owing to the lack of reliable and sufficiently precise independent age information, however, it remains to be established whether OSL dating can yield accurate ages for post-1650 CE features. This is explicitly investigated in this study by applying a commonly adopted quartz OSL methodology to three relic charcoal kilns which are known to have been constructed and operated between December 1941 and March/April 1942 CE.We first document the quartz luminescence characteristics and show through procedural tests that the adopted single-aliquot regenerative dose procedure should be appropriate for equivalent dose determination. Four samples collected from the uppermost part of the charcoal-rich layers in the three features yield the youngest optical ages and are considered coeval. Their average age is 1928 ± 13 CE (95% probability), which matches the independent age reasonably well. The precision associated with the individual OSL ages ranges between 7 and 14% (1 sigma total uncertainty) and it might ideally be possible to establish relative chronologies with a higher time resolution. Finally, we briefly discuss our entire set of OSL ages in relation to future strategies for sampling charcoal kilns remains. In general, we conclude that OSL dating can be particularly advantageous to help resolving chronometric issues that pertain to post-1650 CE relic charcoal kilns.

Tracing uplift and erosion in orogenic settings using quartz luminescence sensitivity: Insights from the Northern Andes uplift

The optically stimulated luminescence (OSL) sensitivity of the fast component in quartz has been increasingly used in provenance analysis of Quaternary sediments. Quartz OSL natural sensitization is thought to be mainly controlled by the formation conditions of the source bedrock and surface processes occurring mainly in sediment source areas. Thus, quartz OSL sensitivity can be linked to distinct sediment source regions, based on their tectonic setting and erosion conditions. In this way, changes in quartz OSL sensitivity within siliciclastic successions would track variations in sediment provenance. So far, few works evaluated how the OSL sensitivity of quartz sand grains varies in sedimentary successions that experienced long-term cycles of deep burial, exhumation, and erosion. Therefore, this work aims to characterize the sensitivity of the fast OSL component of quartz sand grains retrieved from the Cenozoic sedimentary rocks of the Northern Andes basins and assess its spatiotemporal changes. We found that quartz grains with the lowest OSL sensitivity are sourced by crystalline and volcanic rocks related to the Andean Continental Arc emplaced in the Colombian Central Cordillera, reflecting the onset of denudation in orogenic sources during the Paleocene. Subsequently, increasing trends in OSL sensitivity are related to the sedimentary recycling during the Andean orogeny, reaching maximum values as a result of the progressive unroofing of Cretaceous rocks in the Colombian Eastern Cordillera, originally sourced from the low-relief Amazon Craton. Changes in quartz OSL sensitivity measured in the Cenozoic sedimentary basin-fill sequences of the Northern Andes vary according to the shifts in sediment provenance related to the orogenic construction and sediment recycling of the Andean range.

Dating the Neanderthal environment: Detailed luminescence chronology of a palaeochannel sediment core at the Palaeolithic site of Lichtenberg in the Lower Saxony, northern Germany

Northern Germany is famous for its numerous Neanderthal (Middle Palaeolithic) archaeological sites and well-preserved palaeoclimate records. Nevertheless, our understanding of how hominins responded to climate fluctuations and adapted to changing environments in this region remains limited because there are only a few reliable, highly-resolved chronological frameworks of long stratigraphic successions. Most of the Middle Palaeolithic sites in this region lack a reliable chronostratigraphy beyond the radiocarbon dating range. In this study, we present a high-resolution optically stimulated luminescence (OSL) chronology derived from a ∼21 m long sediment core (Li-BPa) that was drilled in close proximity to the known Neanderthal site of Lichtenberg. Quartz OSL dating was applied to the upper 6.5 m of the core. Subsequently, the obtained quartz OSL ages were compared with feldspar post-infrared (IR) IRSL (pIRIR) measured at 290 °C (pIRIR290), pulsed IR50 (pre-pIRIR225), and pulsed pIRIR225 ages to select a suitable feldspar signal to date older samples. A comparison of the quartz and feldspar ages indicates that only fading-corrected pulsed IR50 (pre-pIRIR225) and pIRIR225 ages agree well with quartz OSL ages. Finally, the age framework of the sediment sequence was established based on the 11 quartz OSL ages and 23 fading-corrected pulsed IR50 (pre-pIRIR225) and pulsed pIRIR225 ages. The resulting Bacon age-depth model agrees with litho- and biostratigraphic designations, indicating that the whole sequence was deposited between ca. 275 ka and ca. 24 ka, corresponding to the Saalian to Weichselian periods.

Using quartz OSL signals from SAR cycles for sediment provenance studies

Quartz optically stimulated luminescence (OSL) sensitivity is varied and related to Earth surface processes and, thus, it has been shown to be a useful tool for appraising sediment recycling and provenance investigations. These investigations are mainly based on OSL data purposely measured for sensitivity calculations. However, it has been recently shown that the relative sensitivity of the quartz OSL fast component (%BOSLF) from the first test dose (Tn) signal from an OSL dating measurement using the Single Aliquot Regenerative-dose (SAR) protocol can be used to discriminate sediment sources. Here, we investigate the possibility of characterizing %BOSLF for provenance purposes using not only Tn signals but all other OSL signals obtained over SAR protocol cycles from OSL dating measurements. We address the %BOSLF behaviour over SAR cycles (if conservative or not), the %BOSLF dependency on dose-size, differences between %BOSLF values given by natural/regenerative and test dose signals, and %BOSLF application for provenance studies. Quartz sand grains data from twenty Late Quaternary sediment samples, representing orogenic and cratonic sources and diverse depositional contexts from South America, Africa, and Asia, are included in the analysis. All calculations were performed using data that have been previously obtained for equivalent dose estimation. The key finding is that the averaged %BOSLF of all SAR signals was representative of the samples' characteristic sensitivity and could satisfactorily discriminate samples from known sources, mainly in the case of high-sensitivity samples. We could distinguish sediment source areas by averaging the %BOSLF of OSL signals from SAR natural/regenerative and test doses together. Likewise, laboratories worldwide could produce regional/global sediment provenance fingerprinting reference data using their dating measurements accumulated throughout the last decade.

Not too old to rock: ESR and OSL dating reveal Quaternary activity of the Periadriatic Fault in the Alps

The Periadriatic Fault system (PAF) ranks among the largest post-collisional structures of the European Alps. Recent geodetic data suggest that a fraction of the Adria–Europe convergence is still being accommodated in the Eastern Alps. However, the historical seismicity records along the easternmost segment of the PAF are ambiguous, and instrumental records indicate that seismotectonic deformation is mostly concentrated in the adjacent Southern Alps and Dinarides. Both electron spin resonance (ESR) and optically stimulated luminescence (OSL) dating methods can be used to date coseismic slip (with a combined range covering a few decades to a couple of million years) in slowly deforming fault zones, such as the PAF. Since the saturation doses of the quartz ESR signals are larger than quartz and feldspar OSL, ESR enables establishing a maximum age of the last resetting event of the system, while OSL allows constraining their minimum age when the signal is in saturation. We collected fault gouge samples from three localities along the easternmost segment of the PAF. For ESR, we measured the signals from the Al center in quartz comparing the results from the single aliquot additive dose (SAAD) and single aliquot regenerative (SAR) dose protocols. For OSL, we recorded the infrared stimulated luminescence signal at 50°C (IR50) and post-infrared infrared-stimulated luminescence signal at 225 °C (pIRIR225). Our dating results indicate that the studied segment of the PAF system accommodated seismotectonic deformation during the Quaternary, with a maximum age for the last resetting event of the system ranging from 1075 ± 48 to 552 ± 26 ka (ESR SAR) and minimum ages in the range from 196 ± 12 to 281 ± 16 ka (saturation of pIRIR225). The obtained ages suggest that the studied segment of the PAF could be considered at least as a potentially active fault.Graphical abstract

Chronology of late Holocene sediments related to the Qicheng ruins in central China

The Qicheng city wall is located in Puyang, Henan Province, China, and it is an important archaeological site from the Neolithic period in the North China Plain region. A trench across the northwest corner of the city wall revealed an 11 m thick sediment sequence, closely associated with human activities, which provides valuable records for the dating and environmental evolution of the site. In this study, we have applied field geological investigation, grain size analysis, optically stimulated luminescence (OSL) dating, and radiocarbon (14C) dating to reveal the history and changes in the site. The ancient city wall was built on the sedimentary sequence (U1) of the high terrace of the Ancient Yellow River. The upper 11 m thick sedimentary sequence (U2) recorded early moat sedimentation (U2L) and was followed by three cycles of paleosol-flooding deposits (U2U). The quartz OSL signals of the U2 silts are extremely bright, indicating high sensitivity. Partial bleaching was observed as well. The quartz OSL single-grain SAR dating results are consistent with that of charcoal 14C dating and are closer to the ‘true’ burial ages of the sediments than those obtained with multiple grains. By using a Bayesian statistical model, a chronological framework for the U2 sedimentary sequence was established. The earliest construction date of the Qicheng city wall is dating to 2100–1300 BC, during the late Longshan period, which is consistent with archaeological evidence (Li et al., 2015). The Qicheng city was not significantly affected by paleo-flooding prior to 870–960 AD, but experiences frequent flooding thereafter.

A formation record of modern Nitraria tangutorum nebkhas on the Ordos Plateau of northern China based on optically stimulated luminescence dating

Nebkhas, as special biologically mediated aeolian landforms, play an important role in indicating regional aeolian activities and aeolian environmental changes. The Ordos Plateau is located in arid and semiarid regions of northern China that have a wide distribution of Nitraria tangutorum nebkhas. There are few chronological records of nebkha formation, so the history of the formation and evolution of nebkhas in the plateau is still unclear. In addition, the optically stimulated luminescence (OSL) dating method, which has been widely used in the dating of Holocene aeolian sediments, has not yet been applied to the dating of nebkha sediments in the Ordos Plateau. In this study, OSL methods were used to discuss the formation age and relevant aeolian activities of Nitraria tangutorum nebkhas in the Ordos Plateau. The results demonstrated that (1) the coarse-grained quartz OSL signals of nebkha sediments were insensitive and thus were inapplicable by the single aliquot regenerative (SAR) protocol. (2) The luminescence characteristics of the K-feldspar fraction and internal checks of the post-infrared infrared-stimulated (pIRIR) dating indicated that the pIR50IR170 protocol with 200 °C of preheating was applicable for De determinations of nebkha sediments. (3) The residual doses of the pIRIR170 signals ranging from 0.02 to 0.14 Gy should be considered when calculating De values. (4) Bayesian age-depth models were used for the Nitraria tangutorum nebkha sedimentary sequences. The formation of nebkhas occurred during a relatively dry climate period accompanied by strong aeolian activity. That ∼0.38 ka was the main growth period of Nitraria tangutorum nebkhas. This study is the first report of the formation age of nebkhas of more than one hundred years in the region.

Chronology by luminescence and radiocarbon on core sediments from the northeastern pearl river plain and implications for delta process

Accurate dating is the basis for deciphering eustatic and climatic changes on deltaic sedimentary processes. In the Pearl River Delta (PRD) plain of south China, scarce robust chronology hinders the detailed interpretation of sedimentary history. In this study, quartz optically stimulated luminescence (OSL) (21 samples), feldspar post-IR IRSL (pIRIR) (4 samples) and radiocarbon (14C) (2 samples) dating were applied to obtain detailed chronological framework of core SXG06 (23-m long to bedrock) from the northeastern PRD. SXG06 consists an upper marine unit (M1) and a lower marine unit (M2), separated by a terrestrial unit (mottled clay, T1). For M1, quartz OSL and 14C samples yielded ages from 5.2 ± 0.3 to 0.32 ± 0.02 ka. The sample on top of T1 produced a quartz OSL age of 35 ± 2 ka. For other 12 samples in T1 and M2, quartz OSL signals reached saturation and generated minimum ages (>51 ka). For these the saturated quartz OSL samples, feldspar pIR50IR250 provides an age range of 123 ± 7–105 ± 7 ka. The compilation of all the above ages and previous sedimentology data reveals that: (1) M2 was formed during marine transgression of Marine Isotope Stage (MIS) 5; (2) A hiatus with an age gap of between ∼35 ka and ∼5 ka was observed, which might be due to the low sea level and resultant weathering scouring; (3) Initial M1 deposits from the northeastern PRD postdated the central and southern PRD by ∼3 ka, indicating delayed delta development in the northeastern PRD during the Holocene. (4) SXG06 experienced slow deposition 0.3 m/ka in ∼5–3 ka because of the coevally decreased sediment supply, followed by accelerated deposition rate of 3 m/ka after ∼3 ka associated with strengthen human activity.

Chronology of core sediments from the south coastal Bohai Sea of eastern Asia and its implications for sedimentary history

The Shandong Peninsula along the coastal Bohai Sea in China is a vast alluvial plain formed by the Yellow River. It is an ideal place for investigating the evolution of landform in a river–sea interaction area where chronology is key. However, detailed optically stimulated luminescence (OSL) chronology studies of cores are still limited and have mainly concentrated on the Yellow River Delta, while they are scarce on the south coast of the Bohai Sea. In this study 16 OSL samples were collected from the upper 32 m of core DZK01 (192 m in depth) to establish a chronological framework using quartz OSL. Results indicated that the quartz OSL ages ranged from 217 ± 19 ka to 1.63 ± 0.14 ka, and we believe they were the minimum ages when De > ca. 200 Gy owing to OSL signal saturation. Our dating results reveal two sedimentary hiatuses with age gaps of 71–37 ka and 37–9.5 ka. Holocene sediments are located above a depth of 11.8 m with an onset age of approximately 9.5 ± 0.6 ka. Based on the sedimentary facies and dating results, no transgression sediment has been observed during marine isotopic stage (MIS) 3. This sedimentary sequence pattern is consistent with global sea-level change. We also summarized the extents of three transgressions around the Bohai Sea, and found very different patterns for different part of the coasts, e.g., in the north, the west, and the south. This requires further investigation.

High-resolution luminescence-dated sediment record for the last two glacial-interglacial cycles from Rodderberg, Germany

The Rodderberg Volcanic Complex (RVC) is well-known for the long climate record archived in its crater basin, which lasts for several glacial-interglacial cycles. However, a detailed chronological framework is still lacking. Here, we perform high-resolution luminescence dating on a 72.8 m-long sediment core with the optically stimulated luminescence (OSL) signal from fine-grained (4–11 μm) quartz and three kinds of post-infrared infrared (pIRIR) stimulated luminescence signals from fine-grained polymineral fractions. Together with magnetic susceptibility, grain size and quartz OSL sensitivity measurements, a numerical age framework is built for the upper half of the sediment core. Quartz OSL ages align well with pIRIR ages for the last 45 ka, but they underestimate in relation to pIRIR ages for ages beyond 45 ka. The three pIRIR signals, including the pIRIR signal at 225 °C (pIRIR225), the pulsed pIRIR signal at 150 °C (pulsed pIRIR150) and the multi-elevated-temperature pIRIR at 250 °C (MET-pIRIR250), yield consistent ages up to ca. 250 ka at a sediment depth of 37.5 m. Below that depth, dating limits of the protocols are reached. Nevertheless, our results indicate that sediments below 37.5 m predate Marine Isotope Stage (MIS) 7. Altogether, obtained ages reveal continuous dust accumulation during MIS 7 and MIS 6. One erosional event happened at the end of the Eemian (MIS 5e), which eroded the Eemian soil. The sedimentation rate during the Weichselian glacial period is tenfold lower compared to the sedimentation rate observed during MIS 7–6. This low sedimentation rate likely arises from the cessation of slope wash effects and the occurrence of various wind erosional events alternating with dust deposition as the basin is filled by dust. A notably high sedimentation rate is observed at the transition from MIS 6 to the Eemian, marked by the deposition of a 7 m-thick loess layer between 135 and 129 (±5) ka. This high sedimentation rate could be attributed to intensified slope wash and solifluction processes resulting from the thawing of permafrost at the time of deglaciation. Alternatively, it might be a signature of Heinrich event 11, during which strong winds brought large amounts of dust into the basin within a short time.

Investigations on single and multi-grain optically stimulated luminescence (OSL) sensitivity and electron spin resonance (ESR) signals in quartz derived from sandstones: Insights on provenance of quartz in ancient depositional systems

Trapped charge techniques of luminescence and electron spin resonance (ESR) are classic tools for dating Quaternary deposits. Over the past decade, these techniques have been routinely applied to investigate provenance and/or the sedimentary history of quartz grains based on their different luminescence and ESR characteristics. Of these, optically stimulated luminescence (OSL) sensitivity is one of the most widely investigated parameter for luminescence-based provenance approach. A majority of studies on this parameter are based on evaluation of multi-grain quartz OSL sensitivity of the samples. This is particularly concerning because single-grain quartz luminescence studies have shown that the luminescence signal of a multi-grain aliquot is contributed by less than ∼1–10% of the total grains. Since the sole criteria for discrimination of sources based on luminescence sensitivity relies on its intensity, therefore the results based on multi-grain analysis will most likely be skewed depending on the ‘proportion’ and ‘brightness’ of a few grains. This demands a need to evaluate the potential of single-grain quartz OSL sensitivity in provenance studies. In this study, we investigate single and multi-grain quartz OSL sensitivity from compositionally different sandstones with well-characterised sources based on U–Pb zircon ages. We further complement this analysis with characterisation of ESR centres commonly used in quartz provenance, namely E′1 and [AlO4]0 centres. Our study shows that single-grain quartz OSL sensitivity can help distinguish between sediments that have a predominant input from a single source as compared to those with contribution from multiple sources, which otherwise cannot be inferred from multi-grain studies. Moreover, our results on characterisation of quartz-based ESR intensity of E′1 and saturated [AlO4]0 centres successfully differentiates between sandstones and further complements the luminescence-based characterisation.

Correlations between quartz OSL dose-response curve and TL glow curve characteristics, and their implications for equivalent dose estimation

Optically stimulated luminescence (OSL) dating of quartz using the single-aliquot regenerative-dose (SAR) procedure requires construction of dose-response curves (DRCs). The shapes of DRCs and their characteristic saturation doses (D0 values) are well-known to be highly variable between samples and among individual grains from the same sample, but the factors that control DRC characteristics are imperfectly understood. Here we report correlations between OSL DRC shapes and thermoluminescence (TL) glow curve characteristics for a sample of quartz from northern Australia. Individual grains were measured using the SAR procedure and one of two preheat temperatures (160 °C and 260 °C), and grouped according to similarities in their DRC shapes. Grains from each DRC group were then physically transferred onto a separate disc for TL measurement as a multi-grain aliquot. A strong correlation was observed between DRC group and laboratory-irradiated TL glow curve shapes, along with some differences between the two preheats. Irrespective of the selected preheat, earlier saturating DRC groups are associated with the most intense 110 °C TL signal, and the least intense 325 °C TL signal, which corresponds to the main OSL trap. Later saturating DRC groups generally show the opposite trend. There are also trends within other regions of the glow curve and DRC group, such as prominent TL responses at 140–160 °C, 220–240 °C and 390–410 °C. We assessed the effect on the accuracy of equivalent dose (De) estimation using an associated radiocarbon age as an independent cross-check of the OSL ages for the DRC groups. De over- and under-estimates were obtained for some DRC groups. Most notably, grains preheated to 160 °C displayed a pattern of De values which decreased with an increase in D0. We relate this to variable concentrations of charge at the ∼230 °C TL trap prior to regenerative dose OSL measurements. OSL ages for most DRC groups preheated to 260 °C are close to the radiocarbon age, as are those of later saturating DRC groups preheated to 160 °C; the latter DRC groups have the smallest TL signals at ∼230 °C relative to the TL peak at 325 °C. The results of this study suggest that correlations between single-grain De and D0 values can occur due to underlying differences in the TL characteristics of grains with different DRC shapes. In the absence of independent age control and prior to measuring multi-grain aliquots of quartz, we recommend that OSL dating practitioners screen their samples for any single-grain patterns of De as a function of DRC shape, to determine the optimal SAR measurement conditions and data-analysis procedures for De estimation.

Underestimated single-aliquot quartz OSL ages of Late-Pleistocene sediments due to the dominance of medium component

Optically stimulated luminescence (OSL) dating technique has increasingly been employed to establish chronologies for coastal deposits since the Late Pleistocene. However, the commonly used single-aliquot quartz OSL dating method may yield inaccurate ages due to factors such as partial bleaching, luminescence characteristics, and the age limit of quartz. In this study, taking the Yangtze River Delta (YRD) as an example, single-aliquot and single-grain OSL dating using varying grain-sized quartz and K-feldspar were cross-checked to establish appropriate dating method for Late-Pleistocene sediments in coastal areas. The quartz OSL signals of the upper 24 m Holocene sediments were dominated by the fast component, and the ages obtained through OSL and AMS 14C ages agree. Conversely, the lower 24–91 m section, representing the last glacial-interglacial cycle, reveals a notable underestimation of quartz OSL ages, with a maximum underestimation of 250%, attributed to the influence of signal components. For samples within the dating limit of quartz (less than 70 ka), the single-grain method effectively mitigates the issue associated with the signal component. Single-grain K-feldspar technique proves valuable for accurately determining the age of those older sediments exceeding 70 ka. Through cross-checking between different OSL dating methods, sediments initially attributed to marine isotope stage (MIS) 3 (36–60 ka) are re-identified as deposited during MIS 5 (80–130 ka). This study highlights the necessity of assessing the variability in luminescence characteristics before applying a single OSL dating protocol to all samples from different sedimentary facies within a single core.

Post-glacial small delta process uncovered by luminescence and radiocarbon chronology of core sediments from coastal South China Sea

Reliable chronology is crucial for reconstructing delta processes. The past decades witnessed a boost of dating works on the most economically influential large deltas (i.e., subaerial area >1000 km2), but chronology remains lacking on many small deltas (i.e., subaerial area <1000 km2) that are also densely populated and economically active. Luohe River Delta (LRD) in the coastal South China Sea is such a small delta, whose evolution concerns hundreds of thousands of people, and literally no reliable dating results have been reported to support research of its processes. Herein, dating work combining radiocarbon (14C) on mollusk shells and quartz Optically Stimulated Luminescence (OSL) methods were performed on core LFZK06 from LRD, to test applicability of both methods by age comparison and to establish a chronological framework, using Bayesian age-depth models, of LRD for the first time. 14C ages are systematically c. 0.5–1 ka younger than OSL ages from the same depths. Such young bias of 14C ages in LRD contrasts with previously observed overestimated 14C results in the nearby Pearl River Delta (PRD), likely due to the distinction in bedrock types between Luohe River (granites and sandstones only) and Pearl River (limestone prevalence causing hardwater effect) drainages. Ages of core LFZK06 span from 57 ± 7 ka to 3.42 ± 0.05 cal ka BP and contain a hiatus between 57±7–11.9 ± 1.7 ka. Holocene deltaic sequence of the core shows three-stage sedimentary processes: (1) rapid deposition of prodelta/delta front sediments at 10.2‐0.4+0.5 ka–7.7‐0.3+0.4 ka related to rapid sea level rise, (2) hiatus during 7.7‐0.3+0.4 ka–5.7‐0.8+0.5 ka likely due to reduced sediments input or river channel migration, (3) rapid accumulation of delta plain sediments during 5.7‐0.8+0.5 ka–3.42‐0.85+0.42 ka reflecting depocenter shift toward core location. Moreover, changes of quartz OSL sensitivity were detected, indicative of sediment provenance transition. A change in sediment source from nearby granite weathering towards fluvial long-transported materials occurred at a depth of 24.7 m, with low quartz OSL sensitivity in the gravelly layer below (11.9 ± 1.7 ka) and one magnitude higher quartz OSL sensitivity in prodelta deposits above (10.2‐0.4+0.5 ka).

Stratigraphy and OSL chronology of the Middle–Upper Pleistocene sedimentary sequence and vegetation history during Late MIS6–MIS5e in the Neva Lowland (St. Petersburg region, Russia)

ABSTRACTThe quarry of the Sverdlov (Etalon) Factory stands out as a unique site in the northwest of the East European Plain since it exposes an almost complete Upper Pleistocene stratigraphic succession. Previous investigations have revealed a sequence of marine sediments deposited during the whole Mikulino Interglacial [Eemian, Marine Isotope Stage (MIS)5e], but the chronology of the Late Pleistocene deposits remains incomplete and requires further update. We present a study of the Middle–Upper Pleistocene units exposed in the Sverdlov Factory quarry by using geological methods, optically stimulated luminescence (OSL) dating and pollen analysis. The lower part of the Sverdlov Factory section comprises glaciomarine/glaciolacustrine varves, which accumulated during degradation of the Late Moscow (Late Saalian, Late MIS6) glaciation and correspond to pollen zone M1 (lower peak of Picea). They are covered by interglacial marine clayey silt that includes all Mikulino regional pollen zones M2–M8. According to a Bayesian model based on K‐rich feldspar luminescence ages, the interglacial marine deposition started 133 ± 8 ka ago and ended 109 ± 7 ka ago. The marine sediments are overlain by lacustrine silt with a K‐rich feldspar age of 119 ± 7 ka, lacustrine/alluvial sand with plant detritus formed 47–41 ka ago, and lacustrine sand and silt without organic matter accumulated ~39 ka ago. The upper part of the section is composed of subglacial till formed during the Late Valdai (Late Weichselian, MIS2) under the Scandinavian Ice Sheet and glaciolacustrine varved deposits of the Baltic Ice Lake. Two ages were acquired using quartz OSL from these varves, 16.9 ± 1.6 and 15.7 ± 1.0 ka, which are assumed to slightly overestimate the true age.

Revisiting a proof of concept in quartz-OSL bleaching processes using sands from a modern-day river (the Séveraisse, French Alps)

Conditions of sediment transport and deposition in highly dynamic fluvio-glacial environments enhance incomplete bleaching of luminescence signals during sunlight exposure. Whatever the geomorphic context or application, partial bleaching has been widely reported and remains a methodological limitation for application of Optically Stimulated Luminescence (OSL) dating methods, potentially resulting in sediment-burial age overestimation. This study focuses on the highly dynamic Séveraisse River (SW French Alps) where modern-day alluvial sands of a braided reach were sampled to assess the degree of quartz-OSL partial bleaching associated with superficial pre- and post-deposition geomorphic processes. Our original approach combines (i) a photogrammetry-based survey, (ii) sediment grain-size analysis, and (iii) measurements of both portable OSL luminescence signals and conventional quartz OSL equivalent doses in modern superficial (from 0.1 to 1 cm) and sub-surface (up to 30 cm) alluvial sands exposed to sunlight for at least 19 days. Our results show high but spatially variable residual luminescence signals at the surface, measured in all grain-size fractions with both the portable luminescence reader (≥5 x106 cts/g) and conventional quartz-OSL doses (≥80 Gy), even within the uppermost millimetres of the exposed alluvial surface. Our data thus highlight poor luminescence bleaching in the Séveraisse's modern sands, during both pre-depositional transport and post-depositional exposure. In addition, our study reveals, for the first time, the significant sunlight attenuation over a few millimetres within modern alluvial sediments, perhaps conditioned by dark sand grains, and/or by superficial blanketing by silts (i.e. waning flow stage) that leads to a porosity decrease and very low sunlight penetration. We suggest the occurrence of a critical sediment layer (i.e. only a few mm thick) that could play a key role in bleaching processes for alluvial surfaces, with strong implications for our understanding of residual doses in braided systems' sandy deposits and the dynamics of such alluvial surfaces.

Combined optically stimulated luminescence and radiocarbon dating of aeolian dunes in Arctic Sweden

AbstractMultiple parabolic sand dune fields formed in Arctic Sweden after the last deglaciation, facilitated by an abundance of loose glaciofluvial sediment, limited vegetation cover and strong winds. Following initial stabilisation, these dunes underwent repeated reworking after fire events, as evidenced by the presence of buried soils, charcoal layers and redeposited sands in the dune stratigraphy. These reworking events may be driven by wider climate forcing; however, to date, no chronological framework exists for this activity in Sweden. As such, here, we apply quartz optically stimulated luminescence (OSL) dating of Arctic Swedish sand dunes using two dunes at the sites of Vastakielinen and Jorggástat. Resultant double‐SAR (single aliquot regenerative dose) quartz OSL ages are in good agreement with independent ages provided by 14C dating of charcoal fragments recovered from charcoal layers within the dunes, and we conclude that the chosen protocol is generally well suited for dating aeolian reworking of dune sediments in Arctic Sweden. While feldspar contamination limits precise age assignment for initial dune movement, our results nonetheless suggest repeated and long‐lasting aeolian activity in Arctic Sweden throughout the Holocene and, although there are differences in detail, further suggest some general trends in terms of dune stability and reworking over Arctic Fennoscandia.