The development of heat transfer models for proton exchange membrane water electrolysis (PEMWE) cells is necessary to enhance their efficiency, durability, and safety. Although modeling efforts have indicated that the heat transfer to fluids is significant, the magnitude of the heat transfer and mechanism have not been adequately studied. To fill this knowledge gap, we quantified the amounts of heat transferred in a thermally insulated cell and associated system. We found that heat transfer to the inflow water accounted for the majority of heat transfer to the fluids, and the rise of the membrane (CCM + PTL) temperature was due mainly to deterioration of the distribution of water at high current density. The sensible heat transfer and the resistive heat were directly proportional to each other, and the quantity of latent heat transfer could be influenced by resistive heating and kinetic factors. This study was the first to provide detailed experimental insights into the factors that mainly affect heat transfer to fluids in PEM water electrolysis cells.
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