Pure Absorption Research Articles

Assessment of Changes in Selected Features of Pine and Birch Wood after Impregnation with Graphene Oxide.

In this work, pine and birch wood were modified by graphene oxide using a single vacuum impregnation method. The research results indicate that the impregnation of wood with graphene oxide increases the crystallinity of cellulose in both pine and birch wood, and the increase in crystallinity observed in the case of birch was more significant than in the case of pine. FT-IR analyses of pine samples impregnated with graphene oxide showed changes in intensity in the absorption bands of 400-600, 700-1500 cm-1, and 3200-3500 cm-1 and a peak separation of 1102 cm-1, which may indicate new C-O-C connections. In the case of birch, only some differences were noticed related to the vibrations of the OH group. The proposed modification also affects changes in the color of the wood surface, with earlywood containing more graphene oxide than latewood. Analysis of scanning electron microscope images revealed that graphene oxide adheres flat to the cell wall. Considering the differences in the anatomical structure of both wood species, the research showed a statistically significant difference in water absorption and retention of graphene oxide in wood cells. Graphene oxide does not block the flow of water in the wood, as evidenced by the absorbability of the working liquid at the level of 580-602 kg/m3, which corresponds to the value of pure water absorption by wood in the impregnation method using a single negative pressure. In this case, higher graphene oxide retention values were obtained for pine wood.

Approximating Rayleigh Scattering in Exoplanetary Atmospheres using Physics-informed Neural Networks (PINNs)

Abstract This research introduces an innovative application of physics-informed neural networks (PINNs) to tackle the intricate challenges of radiative transfer (RT) modeling in exoplanetary atmospheres, with a special focus on efficiently handling scattering phenomena. Traditional RT models often simplify scattering as absorption, leading to inaccuracies. Our approach utilizes PINNs, noted for their ability to incorporate the governing differential equations of RT directly into their loss function, thus offering a more precise yet potentially fast modeling technique. The core of our method involves the development of a parameterized PINN tailored for a modified RT equation, enhancing its adaptability to various atmospheric scenarios. We focus on RT in transiting exoplanet atmospheres using a simplified 1D isothermal model with pressure-dependent coefficients for absorption and Rayleigh scattering. In scenarios of pure absorption, the PINN demonstrates its effectiveness in predicting transmission spectra for diverse absorption profiles. For Rayleigh scattering, the network successfully computes the RT equation, addressing both direct and diffuse stellar light components. While our preliminary results with simplified models are promising, indicating the potential of PINNs in improving RT calculations, we acknowledge the errors stemming from our approximations as well as the challenges in applying this technique to more complex atmospheric conditions. Specifically, extending our approach to atmospheres with intricate temperature-pressure profiles and varying scattering properties, such as those introduced by clouds and hazes, remains a significant area for future development.

Assessing the residual biases in high-resolution transit absorption spectra correction

Context. In recent years it has become common practice to divide observed transit absorption spectra by synthetic absorption spectra computed for the transit of an atmosphere-less planet. This action supposedly corrects the observed absorption spectrum, leaving the sole atmospheric absorption signature free from the biases induced by stellar rotation and centre-to-limb variations. Aims. We aim to show that while this practice is beneficial, it does not completely correct the absorption spectrum from the stellar distortions and that some residual biases remain, leaving a possibly altered atmospheric signature. Methods. By reducing the problem to its most basic form, we show that dividing the observed absorption spectrum by a synthetic absorption spectrum of the planet does not isolate the pure atmospheric absorption signature. We also used simulated synthetic transit observations to assess the magnitude of these residual biases in typical transit observations. Results. We show that dividing the observed absorption spectrum by the planetary absorption spectrum results in an atmospheric signature modulated by the ratio of the flux behind the atmosphere and the flux behind the planet. Depending on the non-homogeneity of the stellar spectrum, this leads to distorted atmospheric signatures. Eventually, directly analysing these biased signatures will lead to wrong estimates of planetary atmosphere properties.

Spectroscopy in Nanoscopic Cavities: Models and Recent Experiments.

The ability of nanophotonic cavities to confine and store light to nanoscale dimensions has important implications for enhancing molecular, excitonic, phononic, and plasmonic optical responses. Spectroscopic signatures of processes that are ordinarily exceedingly weak such as pure absorption and Raman scattering have been brought to the single-particle limit of detection, while new emergent polaritonic states of optical matter have been realized through coupling material and photonic cavity degrees of freedom across a wide range of experimentally accessible interaction strengths. In this review, we discuss both optical and electron beam spectroscopies of cavity-coupled material systems in weak, strong, and ultrastrong coupling regimes, providing a theoretical basis for understanding the physics inherent to each while highlighting recent experimental advances and exciting future directions.

Carbon microspheres/carbon sheets as efficient electromagnetic wave absorbers

To address the issue of weak absorption intensity and narrow frequency band in pure dielectric electromagnetic wave (EMW) absorbing materials, this study adopts a simple method to successfully prepare a pure dielectric EMW absorption material by modifying acrylonitrile–methylmethacrylate copolymer carbon microspheres (co-AN-MMA@CS) with capsaicin-like 3,5-dimethylphenol derivative (DMPD). The introduction of DMPD into the carbon microspheres increases the heteroatoms (N, O) in the carbon material, thus resulting in functional groups (-C-N, –NO, and C–O) that enable energy loss through dipole polarization. Additionally, the special morphology of carbon microspheres attached or embedded in carbon sheets derived from DMPD increases the inhomogeneous interfaces, thereby increasing the interface polarization relaxation and further attenuating EMWs. The resulting carbon material with the optimal structure (denoted as CNO-2) exhibits superior EMW absorption properties. At a thickness of 2.50 mm, the minimum reflection loss (RLmin) reaches −63.10 dB at 13.14 GHz, whereas the maximum effective absorption bandwidth (EABmax) reaches 6.81 GHz (8.95–15.76 GHz). CNO-2 has excellent EMW absorption capabilities due to the controllable complex dielectric constant and multiple attenuation mechanisms, including interfacial polarization, dipole polarization, and conduction loss. The CNO absorbers prepared in this study can be used as efficient microwave absorbers for electromagnetic protection applications.

Water-vapor absorption database using dual comb spectroscopy from 300 to 1300 K part I: Pure H2O, 6600 to 7650 cm-1

We present broadband dual frequency comb laser measurements of pure H2O absorption (natural isotopic abundance of 99.7 % H216O) from 6600 to 7650 cm−1 (1307–1515 nm) with a spectral point spacing of 0.0068 cm−1. Twenty-nine absorption spectra were collected at temperatures between 300 and 1300 K (±0.81 % average uncertainty) and pressures ranging from 0.5 to 16 Torr (±0.27 %) with an average residual absorbance noise of 7.4E-4 across the spectrum for all measurements. We fit measurements using a quadratic speed-dependent Voigt profile to determine 17,030 absorption parameters for 5986 transitions found in HITRAN2020. The measured parameters include line strength, line center, self-broadening, and self-shift, along with their power-law temperature-dependence exponents, and speed-dependent self-width parameters. A second version of the retrieved parameters with fits that do not include speed-dependence is also presented. We explore various trends to enable parameter extrapolation for weak transitions that were not covered in this work. We measured line parameters for an additional 614 features not presently catalogued in the HITRAN2020 database. In aggregate, these updates improved RMS absorbance error by a factor of 2.6 on average, and the remaining residual is predominantly spectral noise. This updated database improves high-temperature spectroscopic knowledge across the 6600–7650 cm−1 region of H2O absorption. An accompanying paper (Part II) describes similar measurements and a new database for air-broadened H2O absorption.

Investigation of Broadband Optical Nonlinear Absorption and Transient Dynamics in Orange IV Containing Azobenzene.

Broadband reverse saturable absorption is systematically investigated via Z-scan, transient absorption spectrum (TAS). The excited state absorption and negative refraction of Orange IV are observed in the Z-scan experiment at 532 nm. Meanwhile, two-photon-induced excited state absorption and pure two-photon absorption are observed at 600 nm and 700 nm with the pulse width of 190 fs, respectively. An ultrafast broadband absorption in the visible wavelength region is observed via TAS. The different nonlinear absorption mechanisms at multiple wavelengths are discussed and interpreted from the results of TAS. In addition, the ultrafast dynamics of negative refraction in the excited state of Orange IV are investigated via a degenerate phase object pump-probe, from which the weak long-lived excited state is extracted. All studies indicate that Orange IV has the potential to be further optimized into a superior broadband reverse saturable absorption material and also has certain reference significance for the study of optical nonlinearity in organic molecules containing azobenzene groups.

Measurements of Nonlinear Absorption and Refraction Coefficients of Pure and Nd Doped Calcium Lanthanum Borate Glasses

Measurements of Nonlinear Absorption and Refraction Coefficients of Pure and Nd Doped Calcium Lanthanum Borate Glasses

Study of the Mechanism and Increasing Crystallinity in the Self-Templated Growth of Ultrathin PbS Nanosheets.

Colloidal 2D semiconductor nanocrystals, the analogue of solid-state quantum wells, have attracted strong interest in material science and physics. Molar quantities of suspended quantum objects with spectrally pure absorption and emission can be synthesized. For the visible region, CdSe nanoplatelets with atomically precise thickness and tailorable emission have been (almost) perfected. For the near-infrared region, PbS nanosheets (NSs) hold strong promise, but the photoluminescence quantum yield is low and many questions on the crystallinity, atomic structure, intriguing rectangular shape, and formation mechanism remain to be answered. Here, we report on a detailed investigation of the PbS NSs prepared with a lead thiocyanate single source precursor. Atomically resolved HAADF-STEM imaging reveals the presence of defects and small cubic domains in the deformed orthorhombic PbS crystal lattice. Moreover, variations in thickness are observed in the NSs, but only in steps of 2 PbS monolayers. To study the reaction mechanism, a synthesis at a lower temperature allowed for the study of reaction intermediates. Specifically, we studied the evolution of pseudo-crystalline templates toward mature, crystalline PbS NSs. We propose a self-induced templating mechanism based on an oleylamine-lead-thiocyanate (OLAM-Pb-SCN) complex with two Pb-SCN units as a building block; the interactions between the long-chain ligands regulate the crystal structure and possibly the lateral dimensions.

Low-Frequency NARS (LF NARS) by the use of a superheterodyne EPR spectrometer

In this article, the possibilities of recording EPR spectra by the non-adiabatic rapid sweep (NARS) method on a superheterodyne spectrometer are investigated. This method allows recording the pure EPR absorption spectrum of the object under investigation without the need for lineshape–lineheight compromise, while increasing sensitivity by suppressing low-frequency noise. In the NARS method, a low-amplitude sinusoidal modulation of a magnetic field is not used, and an oscillating triangular-shaped bipolar magnetic field is superimposed on the main permanent magnetic field. The triangular field repetition rate should be higher than that of the undesirable noise, and the amplitude is such that the rate of field change satisfies the Bloch non-adiabaticity criterion. The EPR absorption signal is digitized by a fast ADC and accumulated over a large number (n) of triangular field periods. In this case, for low-frequency noise, the spectrum of which is located below the repetition frequency of the triangular field, an accumulation process occurs with an increase in the signal-to-noise ratio (SNR) in proportion to n. A remarkable property of a superheterodyne spectrometer is that the frequency below which low-frequency noise prevails over white noise is significantly lower for it than for a homodyne spectrometer. This allows the use of a low repetition rate (LF NARS), which makes it much easier to obtain a highly linear triangular field of significant amplitude even in microwave resonators with a massive metal case since the harmful effects of eddy currents are reduced. The conditions of non-adiabaticity become easily feasible. At the same time, the noise suppression effect during accumulation turns out to be so significant that the SNR of the LFNARS spectrum exceeds that of the traditional spectrum with magnetic field modulation, with the same recording time, by more than 10 times.

Synthesis and Properties of Octet NiCr Alloy Lattices Obtained by the Pack Cementation Process

NiCr alloys with different components were obtained by pack chromation and homogenization heat treatment of octet Ni lattice. The microstructure, alloy composition, microhardness and quasi-static compression properties of the NiCr lattice were tested. The results showed that after homogenization heat treatment, the NiCr alloy lattice had an austenitic structure with uniform composition. Compared with the pure nickel lattice, the microhardness, compressive strength, elastic modulus and energy absorption of the NiCr lattice increased with the increase of chromium content. The microhardness, specific strength, specific modulus and specific energy absorption of the Ni-45Cr alloy were 363 HV, 11.1 MP/(g/cm3), 1169.1 MP/(g/cm3) and 10 J/g, respectively, which were attributed to the solid solution strengthening provided by chromium and the increase in density. NiCr alloy lattices have high strength and toughness and may have potential applications in high-temperature filters or heat exchangers.

The Low-redshift Lyman Continuum Survey: Optically Thin and Thick Mg ii Lines as Probes of Lyman Continuum Escape

The Mg ii λλ2796, 2803 doublet has been suggested as a useful indirect indicator for the escape of Lyα and Lyman continuum (LyC) photons in local star-forming galaxies. However, studies to date have focused on small samples of galaxies with strong Mg ii or strong LyC emission. Here, we present the first study of Mg ii to probe a large dynamic range of galaxy properties, using newly obtained high-signal-to-noise, moderate-resolution spectra of Mg ii, for a sample of 34 galaxies selected from the Low-redshift Lyman Continuum Survey. We show that the galaxies in our sample have Mg ii profiles ranging from strong emission to P-Cygni profiles to pure absorption. We find that there is a significant trend (with a possibility of spurious correlations of ∼2%) that galaxies that are detected as strong LyC emitters (LCEs) show larger equivalent widths of Mg ii emission, while non-LCEs tend to show evidence of more scattering and absorption features in Mg ii. We then find that Mg ii strongly correlates with Lyα in both equivalent width and escape fraction, regardless of whether emission or absorption dominates the Mg ii profiles. Furthermore, we show that, for galaxies that are categorized as Mg ii emitters, one can use the information of Mg ii, metallicity, and dust to estimate the escape fraction of LyC within a factor of ∼3. These findings confirm that Mg ii lines can be used as a tool for selecting galaxies as LCEs and thus serve as an indirect indicator for the escape of Lyα and LyC.

CO2 capture enhancement by encapsulation of nanoparticles in metal–organic frameworks suspended in physical absorbents

In this study, CO2 nanoabsorbents composed of encapsulated Fe3O4 nanoparticles in metal-organic frameworks (MOFs) and methanol, are developed to overcome the limitations of conventional CO2 sorbents. The polyvinylpyrrolidone-functionalized Fe3O4 nanoparticles encapsulated in (Zn)MOF-74 [Zn2(DOBDC), DOBDC = 2, 5-dihydroxyterephthalic acid] are dispersed in the methanol. Compared with pure methanol, CO2 absorption and regeneration performances of Fe3O4 @ (Zn)MOF-74/methanol are improved by 13.07% and 16.25% (Abs.: 0.84 g-CO2/L-solvent and reg.: 0.77 g-CO2/L-solvent), respectively, at optimum conditions of 0.01 wt%. Cyclic stability experiments exhibit that the performance of Fe3O4 @ (Zn)MOF-74/methanol can preserve 93.76% of their initial capacities. It is finally concluded that the absorption performance is improved by hydrodynamic and shuttle effects while the CO2 sorbent regeneration performance is enhanced by metal-organic heat carriers (MOHCs) and nucleation from the surface of nanoparticles by introducing Fe3O4 @ (Zn)MOF-74 nanoparticles.

Operational islands and black hole dissipation in JT gravity

In this work, we revisit the problem of finding entanglement islands in 2d Jackiw-Teitelboim (JT) gravity. We implement the following adjustments to the traditional setup: (1) we do not explicitly couple to a non-gravitating system, instead we implement only pure absorption into a fiducial detector, (2) we utilise the operationally defined renormalised matter entanglement entropy, as defined by the boundary observer’s wordline. We show that this leads to a unitary Page curve that we explicitly compute, with an island outside of the event horizon. Next, we extend the analysis to a charged and/or supersymmetric black hole. We find that in a certain regime the charged black hole grows first as it emits superradiation before eventually dissipating. We obtain similar results when embedding the system in a supersymmetric setting.

Bathymetry Retrieval Algorithm Based on Hyperspectral Features of Pure Water Absorption From 570 to 600 nm

Current efforts for improving the hyperspectral optimization processing exemplar (HOPE) model include further testing of remote-sensing reflectance (Rrs) features containing useful information for bathymetry retrieval via the minimization of the interference stemming from the variability in inherent optical properties and benthic reflectance. In this paper, we found a novel feature originating from the pure water absorption within the narrow spectral region of 570–600 nm. In most coastal regions of clear water, for example, in a coral reefs environment, pure water accounts for the majority of the total absorption in this spectral range. In addition to the depth variation, the spectral behavior of Rrs(570–600) is primarily dominated by a steep increase in pure water absorption with wavelength, whereas the influence of other optical properties such as phytoplankton/CDOM absorption, particle backscattering, and benthic reflectance can be simplified using the spectrally constant shape model. A HOPE pure water (HOPE-PW) algorithm using this feature was developed based on Rrs measurements with a spectral resolution of near 3.5 nm, wherein only four unknown parameters must be resolved. The validation from LiDAR data and comparison with HOPE-BRUCE using PRISM data at 15 sites located in five distinct regions of Palau, Guam, Great Barrier Reef, Hawaiian Islands and Florida Key, confirmed that the HOPW-PW yielded a considerable performance and provided adequate transferability to other sites with varying bottom and water environments. The sensitivity analysis based on Hydrolight-simulated datasets showed that HOPE-PW was less effected by bottom type variations but still had limitations in retrieving water optical properties.

The Collaboration between the Lecturer’s Community Service and Student’s Community Service for Disaster-Resilient in Pondok Aren District, South Tangerang, Indonesia

This study investigated the effectiveness of the collaboration program between the Lecturer's Community Service (PKM) and Student's Community Service (KKN) of the State College of Meteorology Climatology and Geophysics (STMKG) for disaster-resilient in Pondok Aren District, South Tangerang, Indonesia. Community participatory methods have been applied during this program which elaborates the role of lecturers, students and the community in enhancing the disaster awareness community. Some activities have been done during this program, such as providing the spatial information maps, designing the earthquake's evacuation route, planting the bio pure absorption hole technology (LRB), installing the Automatic Rain Gauge (ARG), counselling to school and Forum Group Discussion (FGD). As the result, Pondok Aren district appreciated STMKG, which has chosen their office as the target of program. The improving knowledge about the disaster vulnerability in Pondok Aren district has formed during the program which the pre- and post-questioners of FGD can evaluate. The collaboration-community service program proved more effective in activities, funding and time consumption than the conventional program. Furthermore, the causes of floods disaster in the Pondok Aren district also can be listed during this program.

Engineering polarization surface of hierarchical ZnO microspheres via spray-annealing strategy for wide-frequency electromagnetic wave absorption

• Hierarchical ZnO microspheres were successfully synthesized via spray-annealing strategy. • Pure dielectric loss ZnO materials were assembled by nanorods and nanoparticles with adjusting different aspect ratios, defects and polar faces. • Hierarchical ZnO-1 materials shown the widest efficient absorption region from 9.9 to 18.0 GHz at 2.4 mm. Regulating orientation growth plays a dominant role in enhancing dielectric properties for the electromagnetic (EM) functional materials, which faces a huge challenge in the synthesis method. By spray-annealing strategy, hierarchical ZnO microspheres assembled by ZnO nanorods and nanoparticles were successfully fabricated. With confined microsphere space and controlling crystal growth, oriented ZnO nanorods possess rich defects, Zn-polar, O-polar faces, and high permittivity. Meanwhile, temperature-dependency of exposed polarization surfaces is discovered in the semiconductor ZnO nanoparticles with evolved aspect ratios. As pure dielectric EM wave absorption material, the hierarchical ZnO microsphere exhibits adjustable complex permittivity and polarization behaviors. When the thickness is 2.4 mm, the hierarchical ZnO-1 absorber shows the widest efficient absorption (RL ≤ –10 dB) region from 9.9 to 18.0 GHz (8.1 GHz, ∼50.6% testing frequency). The minimum reflection loss (RL) of ZnO-1 can reach –31.5 dB at only 2.0 mm. Because of the outstanding dielectric loss ability and wide absorption frequency, large-scale hierarchical ZnO microspheres can be a potential EM absorption candidate.

High resolution ALMA imaging of H2O, and SiO, and SO2 masers in the atmosphere of the AGB star W Hya

AbstractThe mass-loss mechanism in asymptotic giant branch (AGB) stars is not yet fully understood. We present 20-milliarcsecond resolution ALMA imaging of the well-studied AGB star W Hya in multiple molecular lines at 250–269 GHz, including masers from SiO, H2O, and SO2. The images show complex plumes, arcs, and clumps over the stellar disk and in the atmosphere extending to several stellar radii. We detected prominent emission components over the stellar disk—instead of pure absorption as expected—in some Si17O, 30SiO, H2O, and SO2 lines. The surface emission seen in the Si17O and vibrationally excited H2O lines is particularly strong, indicating maser actions. The masers seen over the stellar disk indicate radial amplification.

Structures and performance of alcohol activated thin film composite polyamide (TFC-PA) nanofiltration (NF) membranes prepared with and without Co(II) modulation

Structures and NF performance of TFC-Co and TFC membranes activated with 50 % alcohol solutions were studied. Methanol and glycol solution activation increased water flux 2–4 times without trading off salt rejection while glycerin solution activation increased water flux 3–4 times with reduced salt rejection and increased dye/salt retention selectivity. The Stokes radius of TFC-Co membrane changed from 0.77 nm to 0.66, 0.78 and 0.92 nm while the TFC membrane changed from 0.54 nm to 0.55, 0.65 and 0.70 nm after activation with methanol, glycol and glycerin solutions, respectively. Capillary pore filling models were developed from pure alcohol absorption experiments including the stages of initial pore filling, pore expansion, pore relaxation and pore adjustment, while most Stokes radius after 50 % solutions activation were found to be close to the relaxed pore radius values (rrx) or half of the expanded pore radius values (rex) from pure alcohol absorption experiments.

Optical characterization of liquid phantoms in 500–1000 nm using an improved single integrating sphere system

This paper reports on optical characterization (absorption coefficient μa and reduced scattering coefficient μs′) of liquid phantoms in the wavelength range of 500–1000 nm using an improved single integrating sphere system. 54 liquid optical phantoms (18 pure absorption, pure scattering and mixed samples each) with known optical properties were first prepared. The overall performance of a laboratory-established single integrating sphere system was then evaluated, and the results indicated that the system has perfect stability, repeatability, and accuracy in optical property measurement. After that, effect of cuvette size (i.e., optical path and wall thickness) on optical property measurement was investigated. The experimental results showed that the discrepancies of the measured optical properties for the pure absorption and scattering phantoms held by different cuvettes with varying optical paths and wall thicknesses were within 8.76 %. Finally, the effect of different concentrations of absorber and scatterer on optical property determination of mixed liquid phantoms were explored. It was found the measured optical properties of the mixed liquid phantoms had a considerable difference from those of the pure absorption and pure scattering phantoms. We guessed that the addition of the absorber (scatterer) would dilute the concentration level of scatterer (absorber), and also brought about interaction between the two particles, and thus resulting in an offset for the measured optical properties. Future work needs to test our conjecture from the micro level, like monitoring the dynamic change of the absorption and scattering particle distribution and interaction, when optically characterizing the mixed liquid phantoms.