Pulse Current Method Research Articles

Characterisation and evaluation of paint-coated marine corrosion in carbon steel based on pulsed eddy current thermography and BEMD noise-reducing method

ABSTRACT Eddy current pulsed thermography (ECPT) technique has been investigated for steel corrosion detection and evaluation. However, the random interference was not considered and disposed adequately, which bedims the original thermal images and reconstructed feature ones. This paper applied bidimensional empirical mode decomposition (BEMD) method which used to denoise the thermal image sequences, and the contrast between corroded and uncorroded regions in the skewness reconstructed images of 6-months and 12-months samples was improved by 19% and 28%, respectively. By this means, the skewness of the temperature response curve of each pixel was extracted to reconstruct the feature image. Furthermore, the differential skewness and the contrast of reconstructed skewness image are utilised for distinguishing the early corrosion and the moderate corrosion. The results demonstrate that the method provides higher sensitivity and accuracy in corrosion detection with ECPT.

20 Seconds to fabricate high-performance NiFe-based anode for seawater electrolysis via bidirectional pulse current method

Direct electrolysis of seawater to produce green hydrogen has attracted great attention. While the development of efficient and rapid manufacturing processes for high-performance electrodes, particularly for the oxygen evolution reaction (OER), remains trail. Here, we introduce an innovative approach to fabricate high-performance NiFe-based OER electrodes using an ultrafast and eco-friendly bidirectional pulse current (BPC) method, which remarkably shortens the production time to only 20 s. Our BPC method alternates oxidation and reduction currents within a single period, promoting the in-situ formation of porous NiFe(oxy)hydroxide nanosheets through dissolution/deposition processes. Moreover, this methodology creatively utilizes the “Cl− induced effect”, typically a hindrance in other electrochemical systems involving seawater or brine, to enhance the synthesis of electrodes from NaCl-based electrolyte devoid of additional Ni/Fe cations. The prepared NiFe-based electrode (NFF O-R 20 s) demonstrates remarkable OER catalytic activity, with optimal overpotentials (ηj) of 272, 308 and 367 mV at current densities (j) of 10, 100 and 1000 mA cm−2, respectively. Impressively, it maintains a low cell voltage of 1.59 V after enduring 1000 h of operation under the industrially current density of 300 mA cm−2, with a direct current energy consumption of 3.8 kWh Nm−3 H2 for overall alkaline seawater electrolysis. Our BPC preparation approach provides a promising path to construction high-catalytic activity, good-stability electrode, and low-energy consumption direct seawater electrolyzer.

Binder-free copper manganese sulfide nanoflake arrays electrodeposited on reduced graphene oxide-wrapped nickel foam as an efficient battery-type electrode for asymmetric supercapacitors

In the current study, 2D interconnected copper manganese sulfide (CMS) nanoflake arrays are successfully electrodeposited on nickel foam (NF) and reduced graphene oxide-coated NF (NF/rGO). A pulsed current electrodeposition method is used to prepare a uniform and homogeneous coverage of rGO on NF. By using rGO as a conductive carbon-based template, an ultrathin nanoflake structure of CMS with smaller dimensions and higher electrochemically active surface area (ECSA) is achieved. The results reveal the battery-type behavior of the as-synthesized CMS electroactive materials. At a current density of 5 A g−1 this electrode delivers a significant specific capacity of 667 C g-1 and maintained a considerable proportion of its initial capacity, with a retention value of 83.2 % even after undergoing 3000 charge/discharge cycles. In addition, an asymmetric supercapacitor is fabricated by setting up the synthesized NF/rGO/CMS sample as the positive electrode and activated carbon as the negative electrode. The constructed device not only delivers an impressive energy density of 63.3 Wh kg-1 accompanied by an outstanding power density of 11214.5 W kg−1, but also exhibits a considerable cycling durability, enduring only a 12 % decline in specific capacitance after 3000 charge/discharge cycles at a current density of 5 A g−1.

Computational study of pulse current and thermal stress on thermoelectric cooler

The thermal performance of a Peltier thermoelectric cooler (TEC) can be enhanced by multi-staging, modifying the geometry of the thermoelement, and using new material with improved thermoelectric properties. This study utilizes COMSOL multiphysics to simulate thermomechanical analyses of various geometries of thermoelectric coolers under pulse current conditions. This investigation explores the influence of pulse current parameters, such as pulse width, pulse ratio, and hot-side convective heat transfer coefficient, on a thermoelectric cooler with different leg geometries. Additionally, the impact of the TEC cold-side temperature, hot-side temperature, and thermal stress on both sides is discussed. The results indicate that TEC leg shapes, such as pin and trapezoid, exhibit the minimum cold-side temperature. Increasing the pulse ratio leads to a decrease in the cold-side temperature and an increase in the hot-side temperature. A notable improvement in the cold-side temperature is also observed with higher pulse ratios, with the pin geometry achieving a minimum cold-side temperature of 276 K. Furthermore, the cooling load affects the temperature on both sides of the TEC. These findings provide valuable insights for optimizing thermoelectric coolers for electronic cooling applications using pulse current methods.

Comparative Study on Multiple Methods for Partial Discharge Detection of Gap Defect in Medium Voltage Switchgear

Abstract The medium voltage switchgear is a key equipment in the distribution network of the power system, which directly faces users. Once a fault occurs, it will cause huge economic losses and adverse social impacts. Partial discharge measurement is an important means to ensure the safe operation of switchgear. The physical quantities measured by different partial discharge detection methods are different, so the detection effects by different methods for the same defect are also different. This paper takes the common internal air gap defects of solid insulation in switchgear as the research object, and conducts partial discharge detection tests on real switchgear equipment. At the same time, radio frequency method, ultrasonic method, transient earth voltage (TEV) method, and pulse current method are used to detect and analyze the partial discharge generated by the defect. The results show that the radio frequency method, TEV method, and pulse current method have good detection sensitivity for air gap defects, but the ultrasonic method cannot detect this type of defect. Comparing the amplitudes of the three electrical signals, it can be found that the correlation between the TEV method and the pulse current method is relatively high, while the correlation between the radio frequency method and the two is relatively low. As the applied voltage increases, the amplitude of the radio frequency method changes linearly, which can more sensitively reflect the degree of defect change.

Research on discharge characteristics of synthetic ester-paper insulation under power frequency and low frequency

Abstract Synthetic ester insulating oil transformer has broad application prospects in offshore wind power low-frequency power transmission. This paper carried out discharge tests on synthetic ester-paper insulated used sharp plate electrodes at a power frequency of 50 Hz and a low frequency of 17 Hz based on the pulse current method. The research results show that some basic characteristics do not change under 50 Hz and 17 Hz, that is, the discharge is distributed near the voltage peak in a peak shape. The main differences are that the positive peak characteristics at 17 Hz tend to be blurred; the positive maximum discharge amount, and discharge times show an overall downward trend; the phase-resolved partial discharge pattern (PRPD) and the statistical map (n-φ, n-q) have the same overall shape, but different distribution ranges. The test results can be used as a reference for partial discharge pattern identification and insulation design in synthetic ester low-frequency transformers.

Transformer Fault Diagnosis Based on Intelligent Algorithm and Partial Discharge

Abstract As an important part of power transmission and transformation equipment and power systems, transformers’ operating conditions will have a direct impact on the stability and reliability of the power system. In view of the problems of high diagnosis cost and low accuracy of diagnosis results in existing fault diagnosis technology, this paper uses the pulse current method to detect the pulse signal generated by the discharge model based on the partial discharge experimental platform data, analyzes and studies the discharge characteristics of different discharge defects, and draws For the partial discharge phase distribution (PRPD) spectrum of each defect type, the statistical characteristic parameters characterizing the characteristics of the spectrum were extracted. The partial discharge statistical characteristics were used as classification feature quantities and input into three network models: RBF, GRNN, and PSO-GRNN. The results show that PSO-GRNN has a good recognition effect and is suitable for partial discharge type identification. It has important practical significance and application value for the all-round health management of power transformers.

Experimental Study on the Current Pretreatment-Assisted Free Bulging of 304 Stainless Steel Sheets

In order to further improve the microplastic deformation ability and forming performance of metal sheets, a pulse current pretreatment-assisted micro-forming method was proposed. Firstly, a 304 stainless steel sheet was pretreated with current (0–25 A), and the microstructure changes in the sheet under the action of current were analyzed. Then, a current-assisted bulging experiment was carried out from three aspects as follows: current size, mold structure size, and material properties, to explore the influence of different process parameters on the micro-bulging of the sheet. Finally, the forming quality was analyzed and evaluated from the two perspectives of bulging depth and wall thickness uniformity. The research results show that when the current intensity increases from 0 to 25 A, the fibrous distribution in the thickness direction of the sheet is alleviated, the structure is more uniform, the bulging depth shows an increasing trend, and the thinning rate and wall thickness uniformity are improved. When the current intensity reaches 25 A, the bulging depth increases from the original 463 μm to 503 μm, and the thinning rate drops from the most serious 48.52% to 19.4%. At the same time, as the mold size increases, the single-channel aspect ratio (W/H) also increases accordingly. When the mold groove width (W) is 2 mm, the ratio reaches 0.4, the sheet deforms significantly, and the filling effect is better. In addition, the larger the roundness of the convex and concave molds, the more uniform the wall thickness distribution of the bulging parts. Under the same experimental conditions, the bulging depth of the 304 stainless steel sheet is higher than that of TC4 titanium alloy, and it is less prone to springback and is more conducive to plastic deformation.

Characterization of Co–Ni–TiO2 coatings prepared by combined sol-enhanced and pulse current electrodeposition methods

Abstract This research comprehensively explores the synthesis of Co–Ni–TiO2 coatings employing a hybrid methodology that integrates sol-enhanced and pulse current electrodeposition techniques. The investigation examined the surface morphology and intrinsic properties of Co–Ni–TiO2 coatings, revealing the significant influence of pulse duty cycle variations on the characteristics of coatings. A detailed analysis indicates that a pulse duty cycle of 0.4 optimized the coating’s performance, offering superior attributes compared to other duty cycle settings. The study elucidates that lower duty cycles foster hydrogen evolution reactions on the cathode surface, culminating in the formation of a porous, needle-like coating structure. Conversely, higher duty cycles are found to mitigate the effects of material replenishment, thereby affecting the coating’s quality and performance. The findings of this investigation not only shed light on the critical relationship between the pulse duty cycle and the properties of Co–Ni–TiO2 coatings but also lay a foundational framework for the further refinement and optimization of these coatings for advanced applications.

Electrodeposition of nanocrystalline Ni and NiCr alloy coatings: Effects of Cr content on microhardness and wear resistance improvement

The safety and reliability of high-speed trains depend on the brake disc. In order to improve the lifetime of brake disc and reduce the waste of resources, a coating with higher microhardness and well wear resistance is urgently needed. The effect of chromium content on the microstructure, microhardness and wear resistance of NiCr coating has been studied. Nano-crystalline Ni and NiCr coatings with superior mechanical properties were successfully prepared on the 30CrNiMo steel substrate by pulse current electrodeposition method. The inclusion of formic acid and sodium citrate was found to significantly expedite the co-deposition of Ni and Cr. The NiCr coatings with various Cr contents were prepared at current densities ranging from 200 to 300 mA/cm2. These coatings significantly enhance microhardness and wear resistance of the substrate. The microhardness of the NiCr coating increased to 603 HV, outperforming pure Ni coating by 119 HV. Additionally, the wear rate of the NiCr coating decreased by 50% at a load of 10 N in comparison to the Ni coating. The high microhardness is attributed to grain refinement and solution strengthening. This study successfully addresses the challenges associated with electrodepositing Ni-based coatings on 30CrNiMo steel substrate and lays a theoretical foundation for the utilization of Ni-based coatings to enhance the tribological properties of materials used in high-speed train brake disc.

Influence of magnetic field upon electrode kinetics and ionic transport

Performance properties in lithium-ion, sodium-ion, and zero excess metal batteries are currently limited by the sluggish ion diffusion and inhomogeneity of the transport ion flux, resulting in poor formation, low rates, and short cycle lives. In this work, a magnetic field is applied to the cell by the incorporation of a NdFeB magnetic spacer, and the effect upon the kinetics and transport properties at each electrode is studied using galvanic charge and discharge, electrochemical impedance spectroscopy, and intermittent titration techniques. Stabilization of the anode-free or zero excess sodium and lithium metal cells is achieved during formation, and upon cycling. Reduced cell overpotential is observed with resulting higher areal capacities, with improved ionic diffusion through the electrode. Upon cycling metallic dendritic structures are suppressed due to the inhomogeneity of ion flux, and the likely competing kinetics of plating at a metallic tip and the surrounding surface. At the NMC electrode, improved kinetics are observed with lower charge-transfer resistance (Rct) due to the reshaped and aligned domain in the ferromagnetic Ni of NMC cathode. Pulsed current methods further confirm enhanced cationic diffusion in the anode graphite materials, particularly at high mass loading of 4 mA h cm−2 and high C rates. Consequently, the combination of enhanced reaction kinetics on the ferromagnetic cathode and improved diffusion kinetics in the porous anode leads to excellent full-cell performance compared to control groups. This study highlights the potential of magnetic fields in enhancing diffusion and reaction kinetics for rechargeable batteries (Li, Na, K, Mg, etc.), and may provide routes for extending cycle life, reconditioning cells, and improving formation protocols.

Comparison of EV Fast Charging Protocols and Impact of Sinusoidal Half-Wave Fast Charging Methods on Lithium-Ion Cells

In electric vehicle fast charging systems, it is important to minimize the effect of fast charging on the grid and it is also important to operate the charging system at high efficiencies. In order to achieve these objectives, in this paper, a sinusoidal half-wave DC current charging protocol and a sinusoidal half-wave pulsed current charging protocol are proposed for the fast charging of Li-ion batteries. A detailed procedure is presented for implementing the following proposed methods: (a) a pre-defined half-sine wave current function and (b) a pulsed half-sine wave current method. Unlike the conventional full-wave sinusoidal ripple current charging protocols, the proposed study does not utilize any sinusoidal full-wave ripple. The performance of these new charging methods on Ni-Co-Al-type Li-cells is studied and compared with the existing constant current and positive pulsed current charging protocols, which have been discussed in the existing literature. In addition, the changes in the electrochemical impedance spectrograph of each cell are examined to study the effects of the applied charging methods on the internal resistance of the Li cell. Finally, the test results are presented for 250 life cycles of charging at 2C (C: charging rate) and the degradation in cell capacities are compared among the four different methods for the Ni-Co-Al-type Li cell.

An innovative pulsed current arc welding technology for armor steel: Processes, microstructure, and mechanical properties

This study presents a novel pulsed current arc welding technology, specifically pulsed current gas tungsten arc welding (PC-GTAW), single and double pulse gas metal arc welding (SP/DP-GMAW), and dual process welding (D-process). This study aims to investigate the effectiveness of these welding techniques for armor steel weldments. This research focused on investigating the welding processes, resulting microstructures, and mechanical properties of welded joints. Based on the macrography analysis, it was determined that the weldments exhibit no signs of porosity, inclusions, or inadequate penetration. This finding substantiates the optimum settings for the weldment production process. The weldment optical microstructure, fusion, and heat-affected zone were examined in the weld interface. The microstructural properties of the FZ include δ-ferrite, austenite, bainite, and acicular martensite. The HAZ has a bainite-untempered martensite microstructure. The chemical composition and variations across the weldment (base, weld and HAZ) were identified. The grain borders contained greater quantities of Cr, Ni, Mn, Si, and Mo than those of the grain cores. EBSD revealed average weld zone grain sizes of 17.7 µm, 32.6 µm, 30.8 µm, and 24.6 µm for PC-GTAW, SP-GMAW, DP-GMAW, and D-Process, respectively.Furthermore, the hardness measurements showed a progressive transition across different regions. Additionally, the D-Process-fabricated material exhibited a maximum ultimate tensile strength of 872 MPa and an elongation of 4%. The mechanical properties exhibited by this new process variant exceed those of other weldments, indicating its potential for fabricating armor steel. The impact toughness demonstrated superior performance in all the weldments. Within this context, the new use of pulsed current advanced welding methods has shown the ability to generate welded parts of exceptional quality.

Distinguishing evaluation of plastic deformation and fatigue damage using pulsed eddy current testing

The vessels and pipes of nuclear power structures are subjected to complex forces. The structures suffer sudden loads that lead to plastic deformation and cyclic loads that result in fatigue damage. In practice, two types of microscopic damage may occur simultaneously. The effect of plastic deformation on material fatigue properties remains unclear, and there is a lack of effective methods to distinguish plastic deformation and fatigue damage. To address these issues, the fatigue life curve of 304 stainless steel is experimentally measured, and the influence of fatigue life due to the presence of plastic deformation under a certain load is investigated. It's identified that preset plastic deformation below 15% will increase the fatigue life of the structure. Additionally, a pulsed eddy current signal processing and reconstruction method based on the empirical modal decomposition (EBD) method is proposed. Finally, the pulsed eddy current signal characteristics of plastic deformation and fatigue damage are analyzed, and a distinguishing evaluation method of fatigue damage with preset plastic deformation is established.

Characterization and Corrosion Resistance Behavior Study of Pure Ni Coatings and Ni–V2O5 Nanocomposite Coatings Developed by Direct Current and Pulse Current Methods of Electrodeposition

Characterization and Corrosion Resistance Behavior Study of Pure Ni Coatings and Ni–V2O5 Nanocomposite Coatings Developed by Direct Current and Pulse Current Methods of Electrodeposition

Current Pulse-Based Measurement Technique for Zinc–Air Battery Parameters

Zinc–air batteries possess advantages such as high energy density, low operational costs, and abundant reserves of raw materials, demonstrating broad prospects for applications in areas like stationary power supplies and emergency power sources. However, despite significant advancements in zinc–air battery technology, a comprehensive measurement model for zinc–air battery parameters is still lacking. This paper utilizes a gas diffusion model to separately calculate the concentration polarization of zinc–air batteries, decoupling it from electrochemical polarization and ohmic polarization, simplifying the equivalent circuit model of zinc–air batteries into a first-order RC circuit. Subsequently, based on the simplified equivalent circuit model and gas diffusion model, a zinc–air battery parameter measurement technique utilizing current pulse methods is proposed, with predictions made for the dynamic voltage response during current pulse discharges. Validation of this method was conducted through single current pulses and step current pulses. Experimental results demonstrate the method’s capability to accurately measure zinc–air battery parameters and predict the dynamic voltage response.

Discharge Characteristics of Needle Plate Electrode in Transformer Oil Under Low-frequency AC Voltage

Low-frequency transformer is the key equipment of flexible low-frequency AC transmission systems for offshore wind power. As the low-frequency voltage is applied, the transformer has significantly different insulation characteristics from those of the conventional transformer, it is necessary to study the typical characteristics of partial discharge of oil-paper insulation under such voltage. In this dissertation, the characteristics of discharge of needle plate electrodes in transformer oil under power frequency to low-frequency voltage are experimentally researched by adopting the pulse current method, and the discharge statistics, discharge atlas as well as feature parameters are analysed. With the decreasing of voltage frequency, the inception voltage (IV) value of partial discharge slightly increases, the extinction voltage (EV) phases of positive half-cycle (PHC) voltage waveform, as well as negative half-cycle (NHC) voltage waveform appear earlier, and the maximum discharge (MD), average discharge (AD), and pulse repetition rate (PRR) all show a downward trend.

Rapid microstructure modification of laser powder-bed fused superalloy IN718 using high-density pulsed electric current

A novel high-density pulsed electric current (HDPEC) method is developed to modify the grain-scale microstructure of laser powder-bed fused Ni-based superalloy IN718, which has not been reported in other studies. Rapid micro-residual stress relief and micro-segregation alleviation were achieved without significant grain coarsening which is common in conventional heat treatment. This technique can be an alternative energy-saving post-treatment method for additively manufactured metallic materials, enabling rapid and efficient annealing and solution treatment.

Enhanced Methanol Oxidation in Alkaline Media on Electrodeposited Ni Electrodes by Morphological and Crystallographic Evolution

This research aims at exploiting the electrocatalytic behaviour of nano-crystalline nickel electrodes electrodeposited by different techniques including direct current (DC), pulse current (PC), or pulse reversal current (PRC) for methanol electrooxidation in alkaline solutions. We understand that PC electrodeposition forms pyramidal shaped grains with a preferential Bragg diffraction peak of (111), whereas PRC produced refined spherical grain morphology with a strong (200) diffraction peak. However, DC electrodeposition exhibits an intermediate morphology and crystalline structure. Cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS) show that PRC electrodeposition develops Ni electrodes with better electrocatalytic activity for methanol electrooxidation than other two nickel electrodes. Based on the CV curve, the current density for Ni prepared by PRC electrodeposition methods is about 75.26 mA.cm−2, which is higher than those of DC and PC methods. This higher activity of PRC electrodeposited nickel is attributed to the low charge transfer resistance confirmed by Nyquist plots. We attributed this behavior to the (200)-oriented crystallographic texture, spherical grain morphology, and consequently the high electrochemical active surface area of this nickel electrode. This work reveals the importance of surface morphology and crystallography on the electrocatalytic behaviour of nickel electrodes for electrochemical energy devices.

Low-frequency experimental method for measuring the electric double-layer capacitances of multi-cell electrolysis stacks based on equivalent circuit model

In recent years, the green hydrogen production via water electrolysis has acquired significant attention, and the dynamic operation of electrolysis stacks has become a crucial research area. The electric double-layer capacitance (EDLC) is the primary factor indicating the performance of the stack and affecting the dynamic behavior of the electrolysis stack. High-frequency testing methods are commonly used to measure the EDLCs of electrolysis cells in laboratory, but these methods are not suitable for cost-efficiency and a bottleneck of the engineering power electronic devices. This study proposes a novel square-wave pulse current (SPC) method for determining the EDLCs of multi-cell electrolysis stacks using industrial rectifiers. The response of the stack subjected to SPC is analyzed based on a semi-empirical equivalent circuit (SEEC) model. The feasibility of the proposed method is verified through experiments on a 2 Nm3/h alkaline water electrolysis stack, and an accuracy of 2.67% is obtained.