Pulse Duration Research Articles

Comparing optical deposition and drop casting for enhanced tunability in Q-switched fiber lasers using a biogenic AgNPs-CS saturable absorber

This study presents the successful synthesis and characterization of silver nanoparticles (AgNPs) using Camellia sinensis (CS) leaf extract as a biogenic saturable absorber (SA) for tunable Q-switched applications. The AgNPs-CS SA was fabricated through optical deposition and drop casting methods into a fiber ferrule. The nonlinear optical properties of AgNPs-CS as SA were investigated, revealing a modulation depth of 24.37% and a saturation intensity of 0.15 MW cm−2. Q-switching based on optical deposition exhibited a pump power of 213.40 mW, a 3-dB bandwidth of 3.20 nm, a pulse repetition rate of 78.74 kHz, and a pulse duration of 2.38 μs. Meanwhile, the drop casting method showed a 3-dB bandwidth of 2.0 nm, a pulse repetition rate of 53.05 kHz, and a pulse duration of 5.53 μs for the Q-switched pulse. Additionally, the tunability of wavelength in Q-switching using AgNPs-CS SA was investigated. The drop casting method achieved a tuning range of 32.00 nm, covering the S-band to C-band, while the optical deposition technique resulted in a tuning range of 54.20 nm, spanning from the C-band to L-band. Notably, this work represents the first utilization of AgNPs synthesized with leaf extract as a biogenic SA in the tunability of Q-switched lasers, employing two distinct fabrication techniques for the SA.

Power scaling of intra-cavity Nd:YAG/LBO laser at 532 nm by birefringence compensation

We report an effective method to reduce the impact of polarization state changes caused by thermal birefringence in intra-cavity frequency-doubled laser. The laser consists of a diode side pumped Nd:YAG module, an acousto-optic modulator Q-switch, and an LBO crystal used for SHG generation in 532 nm laser. The effect of thermal birefringence originated by the Nd:YAG rod with concave-shape end surfaces on SHG efficiency is compensated by the insertion of a λ/8 plate into the cavity. At the repetition frequency of 9 kHz, the 532 nm laser achieves a maximum output power of 23.8 W, a pulse duration of 60 ns (FWHM), and a beam quality factor of Mx 2 × My 2 = 1.52 × 1.43. Compared with the λ/4 plate and without plate, the maximum average power of the laser with the λ/8 plate has increased by 22.7% and 66.4%, respectively, the beam quality factor has also been greatly improved correspondingly. This method provides a new solution for lasers to compensate thermally induced birefringence.

Numerical and experimental study of thermography parameters for inspection of composites repaired by CFRP patches

ABSTRACT Considering the ever-increasing importance of composite patches applied to repair or reinforce composite structures, radical health monitoring of these patches seems inescapable. Thermography method is one of the most influential non-destructive methods applied to inspect the repaired structures. Since there are many parameters influencing defects detection in repaired composite structures, extracting the most influential method to determine these parameters is significantly important. In the present study, a repaired carbon fiber reinforced plastic (CFRP) composite structure having defects of different dimensions, types and features located in different depths, is investigated by experiment and finite element simulations to assess the influence of the experimental parameters, like the thermal excitation pulse duration and the best image frame. In thermal simulation, two criteria, maximum thermal variations versus time and path length, are developed to derive the most optimum heating duration and the best thermal frames. The obtained results are validated through defining direct and diagonal paths passing through defects demonstrated on thermography images and thermal map images. The average error of thermal variations on different paths displayed on thermography and simulation images is less than 4.5 percent which confirms the correspondence of obtained results of both mentioned methods.

Electric Field Generated at the Millisecond Pulse-Polarized Interface Facilitates the Electrolytic Conversion of SO2 into H2S.

Interfacial electric field holds significant importance in determining both the polar molecular configuration and surface coverage during electrocatalysis. This study introduces a methodology leveraging the varying electric dipole moment of SO2 under distinct interfacial electric field strengths to enhance the selectivity of the SO2 electroreduction process. This approach presented the first attempt to utilize pulsed voltage application to the Au/PTFE membrane electrode for the control of the molecular configuration and coverage of SO2 on the electrode surface. Remarkably, the modulation of pulse duration resulted in a substantial inhibition of the hydrogen evolution reaction (HER) (FEH2 < 3%) under millisecond pulse conditions (ta = 10 ms, tc = 300 ms, Ea = -0.8 V (vs Hg/Hg2SO4), Ec = -1.8 V (vs Hg/Hg2SO4)), concomitant with a noteworthy enhancement in H2S selectivity (FEH2S > 97%). A comprehensive analysis, incorporating in situ Raman spectroscopy, electrochemical quartz crystal microbalance, COMSOL simulations, and DFT calculations, corroborated the increased selectivity of H2S products was primarily associated with the inherently large dipole moment of the SO2 molecule. The enhancement of the interfacial electric field induced by millisecond pulses was instrumental in amplifying SO2 coverage, activating SO2, facilitating the formation of the pivotal intermediate product *SOH, and effectively reducing the reaction energy barrier in the SO2 reduction process. These findings provide novel insights into the influences of ion and molecular transport dynamics, as well as the temporal intricacies of competitive pathways during the SO2 electroreduction process. Moreover, it underscores the intrinsic correlation between the electric dipole moment and surface-molecule interaction of the catalyst.

Pilot Experiment on Non-Invasive Non-Thermal Disintegration of Human Mucinous Breast Carcinoma Ex Vivo Using Boiling Histotripsy.

We present the results of a pilot study demonstrating the feasibility of non-invasive non-thermal disintegration of human mucinous carcinoma of the breast ex vivo using sequences of high-intensity focused ultrasound pulses in boiling histotripsy regimen. The target volume was sonicated by focusing ultrasound pulses (n=20) of 1.5 MHz frequency, 10-msec duration and 1-sec pulse repetition period, 517 W acoustic power within the pulse, and 103 MPa shock front amplitude at the focus into each node of a volumetric grid 4×4×1 mm. Sonication was visualized and controlled using B-mode ultrasound imaging, total time of the treatment was 21 min. Histological hematoxylin and eosin and Masson's trichrome staining revealed the absence of tumor elements in the treated region confirming destruction of cancer cells and their nuclei after boiling histotripsy procedure.

Steady motion of 80-nm-size skyrmions in a 100-nm-wide track

The current-driven movement of magnetic skyrmions along a nanostripe is essential for the advancement and functionality of a new category of spintronic devices resembling racetracks. Despite extensive research into skyrmion dynamics, experimental verification of current-induced motion of ultra-small skyrmions within an ultrathin nanostripe is still pending. Here, we unveil the motion of individual 80 nm-size skyrmions in an FeGe track with an ultrathin width of 100 nm. The skyrmions can move steadily along the track over a broad range of current densities by using controlled pulse durations of as low as 2 ns. The potential landscape, arising from the magnetic edge twists in such a geometrically confined system, introduces skyrmion inertia and ensures efficient motion with a vanishing skyrmion Hall angle. Our results showcase the steady motion of skyrmions in an ultrathin track, offering a practical pathway for implementing skyrmion-based spintronic devices.

First-principles simulations of high-order harmonics generation in thin films of wide bandgap materials [Invited

High-order harmonics generation (HHG) is the only process that enables tabletop-sized sources of extreme ultraviolet (XUV) light. The HHG process typically involves light interactions with gases or plasma––material phases that hinder wider adoption of such sources. This motivates the research in HHG from nanostructured solids. Here, we employ the time-dependent density function theory (TDDFT) to investigate material platforms for HHG at the nanoscale using first-principles supercomputer simulations. We reveal that wide bandgap semiconductors, aluminum nitride (AlN) and silicon nitride (Si3N4), are highly promising for XUV light generation when compared to silicon, one of the most common nonlinear nanophotonic materials. In our calculations, we assume excitation with a 100 fs pulse duration, 1×1013W/cm2 peak power, and 800 nm central wavelength. We demonstrate that in AlN material the interplay between the crystal symmetry and the incident light direction and polarization can enable the generation of both even and odd harmonics. Our results should advance the development of high-harmonics generation of XUV light from nanostructured solids.

Evolution of level population in Ar interacting with XFEL pulses: impact of resonant absorptions

Abstract Theoretical exploration of the population dynamics at fine-structure levels of Ar atoms interacting with ultrafast ultraintense x-ray free electron laser (XFEL) pulses is conducted. A time-dependent rate equation based on a detailed-level accounting approach is applied for tracking population levels, encompassing microscopic atomic processes such as photoexcitation, radiative decay, photoionization and Auger decay. A Monte Carlo algorithm is implemented to solve large-scale rate equations efficiently. The primary investigation centers on generating Ar17+ through resonant absorption by the second-harmonic radiation of the x-ray pulse. The calculated population ratios of Ar17+ to Ar16+ align well with the experimental measurements [LaForge A. C. et al. Phys. Rev. Lett. 127, 213202 (2021)]. In comparison to the transition energy of the strongest line, (1s2)0- (1s1⁄22p3⁄2)1 of Ar16+, there is a distinct ~25 eV red shift in the peak ratio, which is attributed to the presence of intricate resonant channels in the lower ionization stages. The results demonstrate the sensitivity of the population ratio Ar17+/Ar16+ to the laser pulse parameters such as x-ray pulse duration, bandwidth and the contribution of second-harmonic radiation, indicating their potential as diagnostic tools in future experiments.

Controlling the spectral persistence of a random laser

Random lasers represent a relatively undemanding technology for generating laser radiation that displays unique characteristics of interest in sensing and imaging. Furthermore, they combine the classical laser’s nonlinear response with a naturally occurring multimode character and easy fabrication, explaining why they have been recently proposed as ideal elements for complex networks. The typical configuration of a random laser consists of a disordered distribution of scattering centers spatially mixed into the gain medium. When optically pumped, these devices exhibit spectral fluctuations from pulse to pulse or constant spectra, depending on the pumping conditions and sample properties. Here, we show clear experimental evidence of the transition from fluctuating (uncorrelated) to persistent random laser spectra, in devices in which the gain material is spatially separated from the scattering centers. We interpret these two regimes of operation in terms of the number of cavity round trips fitting in the pulse duration. Only if the cavity round-trip time is much smaller than the pulse duration are modes allowed to interact, compete for gain, and build a persisting spectrum. Surprisingly this persistence is achieved if the pumping pulse is long enough for radiation in the cavity to perform some 10 round trips. Coupled-mode theory simulations support the hypothesis. These results suggest an easy yet robust way to control mode stability in random lasers and open the pathway for miniaturized systems, as, for example, signal processing in complex random laser networks.

Microchanneling and ultrasonic delivery of gold and platinum nanoparticles for selective photothermolysis of sebaceous follicles in the treatment of acne: a pilot study using porcine skin.

Several treatment options for acne vulgaris are limited by their associated adverse effects. An innovative approach involves introducing light-absorbing nanoparticles into sebaceous follicles before destroying the follicles using selective photothermolysis. We aimed to investigate efficient methods for introducing gold and platinum nanoparticles into sebaceous follicles and to identify suitable laser equipment and parameters for the effective destruction of these follicles. We used porcine skin as the experimental model. We compared the efficacies of a thulium laser, ultrasound, and manual massage and evaluated the optimal method for delivering nanoparticles in close proximity to sebaceous follicles. Subsequently, a 1064-nm-wavelength neodymium-doped yttrium aluminum garnet (Nd: YAG) laser was employed to induce selective photothermolysis. We compared different parameters to identify the optimal pulse duration and fluence of the Nd: YAG laser. The extent of penetration and destruction of sebaceous follicles was assessed using hematoxylin and eosin (H&E) staining, and a numerical evaluation was conducted. H&E staining showed that irradiation with a long-pulsed Nd: YAG laser following a combination of thulium laser and sonophoresis effectively destroyed sebaceous follicles, with destruction rates exceeding 50%. These results were valid with a long pulse duration and a high fluence of the Nd: YAG laser. This study demonstrated that sebaceous follicles can be effectively destroyed through a mixture of gold and platinum nanoparticle delivery by a combination of microchanneling and sonophoresis, followed by selective thermal damage induced by a 1064-nm long-pulsed high-fluence Nd: YAG laser.

Amorphization and Ablation of Crystalline Silicon Using Ultrafast Lasers: Dependencies on the Pulse Duration and Irradiation Wavelength

AbstractUsing lasers to achieve controlled crystallographic phase changes in silicon with high spatial precision promises new manufacturing solutions in semiconductor technologies, including silicon photonics. Recent demonstrations of improved amorphization thicknesses position ultrafast lasers as an optimum tool to meet current challenges. Here, the literature on silicon transformations is reviewed and complemented with new experimental data. This includes amorphization and ablation response as a function of pulse duration (τ = 13.9 to 134 fs at λ = 800 nm) and laser wavelength (λ = 258 to 4000 nm with τ = 200 fs pulses). For pulse duration‐dependent studies on Si(111), the amorphization fluence threshold decreases with shorter durations, emphasizing the significance of non‐linear absorption in the range of considered conditions. For wavelength‐dependent studies, the amorphization threshold increases sharply from λ = 258 to 1030 nm, followed by near‐constant behavior up to λ = 3000 nm. Conversely, the ablation threshold fluence increases in these specified ranges. Differences in the obtained amorphization thicknesses on Si(111) and Si(100) are also discussed, identifying an anomalously large fluence range for amorphization at λ = 258 nm. Finally, the question of the lateral resolution, shown as independent of the interaction nonlinearity is addressed.

Quick methylene blue dye elimination via SDS-Ag nanoparticles catalysts

Methylene blue dye, being toxic, carcinogenic and non-biodegradable, poses a serious threat for human health and environmental safety. The effective and time-saving removal of such industrial dye necessitates the use of innovative technologies such as silver nanoparticle-based catalysis. Utilizing a pulsed Nd:YAG laser operating at the second harmonic generation of 532 nm with 2.6 J energy per pulse and 10 ns pulse duration, Ag nanoparticles were synthesized via an eco-friendly method with sodium dodecyl sulphate (SDS) as a capping agent. Different exposure times (15, 30, and 45 min) resulted in varying nanoparticle sizes. Characterization was achieved through UV–Vis absorption spectroscopy, scanning electron microscopy (SEM) imaging, and energy dispersive X-ray (EDX). Lorentzian fitting was used to model nanoparticle size, aligning well with SEM results. Mie’s theory was applied to evaluate the absorption, scattering, and extinction cross-sectional area spectra. EDX revealed increasing Ag and carbon content with exposure time. The SDS-caped AgNPs nanoparticles were tested as catalyst for methylene blue degradation, achieving up to 92.5% removal in just 12 min with a rate constant of 0.2626 min−1, suggesting efficient and time-saving catalyst compared to previously reported Ag-based nanocatalysts.

Physical start-up of the Nuclear Subcritical Facility “Neutron Source” of NSC KIPT

National Science Center “Kharkov Institute of Physics and Technology” jointly with the Argonne National Laboratory developed, designed and constructed the Subcritical Nuclear Facility “Neutron source based on the subcritical assembly driven by electron linear accelerator”. The article presents the main results obtained during the physical start-up of the plant, the program of which involved the staged loading of fuel assemblies into the core with subsequent measurements of its neutron-physical characteristics. In total, 37 fuel assemblies of WWR-M2 type were loaded into the facility core. The values o f the effective neutron multiplication factor keff and reactivity ρ of the subcritical assembly were measured after each loading step using the multiplication and area ratio methods. In addition, the neutron flux to electron current ratio method was tested for on-line reactivity monitoring. The investigations were performed when the accelerator was operated with 100 MeV electron beam energy, 2.7 μs electron pulse duration, 20 Hz pulse repetition rate and ≤ 40 mA beam pulse current. The obtained results were analyzed in terms of ensuring the facility nuclear safety at the next stage of its commissioning which is the pilot operation.

Simulation of femtosecond laser-induced periodic surface structures on fused silica by considering intrapulse and interpulse feedback

The formation of laser-induced periodic surface structures (LIPSSs) on fused silica upon irradiation with plane wave, double pulse, spot processing, and scanning processing (pulse duration tp = 35 fs, center wavelength λ = 800 nm, low repetition rate ≈1 kHz) is studied theoretically with an improved three-dimensional finite-difference time-domain plasma model. The model covers both intrapulse feedback under single shot and interpulse feedback under multi-shots, thus enabling better prediction of transient responses during laser–material interaction and the evolution of the ablated morphology and accumulated defects’ density with more shots. In simulations of a single plane wave, a double pulse can modulate LIPSS periodicity. In simulations of spot processing with Gaussian beam, an increase in the number of shots results in a noticeable ablation pattern where high-spatial-frequency LIPSS surrounds low-spatial-frequency LIPSS at a fluence of 2.8 J/cm2. Moreover, simulations of scanning processing with Gaussian beam showcase the broad applicability of this model, revealing that the orientation of the LIPSS depends on the polarization direction rather than the scanning path. This new model provides a powerful tool to simulate the formation of LIPSS on silica, particularly when temporally modulated laser is involved or predicting the evolution of morphology dependent on the number of shots.

Brillouin expanded time-domain analysis based on dual optical frequency combs

Brillouin Optical Time-Domain Analysis (BOTDA) is a widely-used distributed optical fiber sensing technology employing pulse-modulated pump waves for local information retrieval of the Brillouin gain or loss spectra. The spatial resolution of BOTDA systems is intrinsically linked to pulse duration, so high-resolution measurements demand high electronic bandwidths inversely proportional to the resolution. This paper introduces Brillouin Expanded Time-Domain Analysis (BETDA) as a modified BOTDA system, simultaneously achieving high spatial resolution and low detection bandwidth. Utilizing two optical frequency combs (OFCs) with different frequency intervals as pump and probe, local Brillouin gain spectra are recorded by their spectral beating traces in an expanded time domain. A 2-cm-long hotspot located in a 230 m single-mode fiber is successfully measured in the time domain with a detection bandwidth of less than 100 kHz using dual OFCs with tailored spectral phase, line spacing, and bandwidth.

Guidelines for element size and type selection for the finite element simulation of laser-induced elastic waves in thermoelastic laser ultrasonic testing

This paper explores spatial discretization within finite element simulations of laser-induced elastic waves within the context of Laser Ultrasonic Testing (LUT). Motivated by discrepancies and oscillations detected in temperature and displacement results in the literature, we traced these issues back to spatial discretization challenges. These challenges originate from rapid localized heating and the generation and propagation of high-frequency waves across a relatively large domain. This study effectively addresses and rectifies these inaccuracies, offering guidance for selecting the appropriate element size and type. We examined two element types: four-node quadrilaterals (Q4) employing first-order Lagrange and nine-node quadrilaterals (Q9) using second-order Lagrange shape functions. Our analysis encompasses mesh refinement strategies, exploration of time and frequency domain plots for temperature and displacement, as well as an evaluation of different pulse durations. Our findings demonstrate that Q9 elements attain accuracy with grids four times larger than Q4 elements for temperature and wave propagation analyses. Furthermore, we observe that lower frequency waves exhibit reduced sensitivity to element size, emphasizing the relationship between element size and elastic wave frequency. Pulse durations in the 6 to 30 ns range affect the required element size in the heat-affected zone but exert minimal influence on wave frequency and spatial discretization in the remainder of the domain. Finally, we present a new formula for element size selection based on the dominant frequency. This study provides a comprehensive guideline for selecting element size and type, enabling the attainment of accurate results while effectively managing computational costs.

Methodology for Measuring the Dose Rate of Pulsed Bremsstrahlung Radiation using Gamma Radiation Dosimeters with Geiger-Muller Counter

Introduction. Industrial monitoring of pulsed bremsstrahlung radiation is associated with a number of challenges. Russia produces only three dosimeters that can be used for measuring pulsed bremsstrahlung radiation with a pulse duration of less than 10 gs. These dosimeters, in addition to being rather expensive, have a number of significant restrictions on the energy range (10 MeV) and the minimum pulse duration (10 ns). The DKG-RM1621 dosimeter with a Geiger-Muller counter can be used for dosimetry of photon radiation with energies up to 20 MeV. However, this device is not intended for dosimetry of pulsed radiation.Aim. Development of a methodology for conducting radiation monitoring of pulsed bremsstrahlung radiation sources using dosimeters with Geiger-Muller counters.Materials and methods. In 2021, measurements of the dose rate of pulsed bremsstrahlung radiation with a maximum energy of 3.0 MeV at pulse repetition rates of 50, 100, 150, 200, 250, 300, and 400 Hz were carried out using DKS- AT1123 (as a reference) and MKS-AT117M dosimeters with a Geiger-Muller counter.Results. A technique was developed for correcting the results of measuring the dose rate of pulsed bremsstrahlung radiation by a dosimeter equipped with a Geiger-Muller counter, which allows the dose rate of pulsed bremsstrahlung radiation to be measured with an additional error of less than 15 % in a practically significant range of dose rates. For the MKS- AT117M dosimeter at a pulse repetition rate of 400 Hz, this value was 320 gSv/h, which is sufficient for most practical tasks in radiation monitoring.Conclusion. The feasibility and possibility of successful application of dosimeters with Geiger-Muller counters for dosimetry of pulsed bremsstrahlung radiation using the proposed measurement technique with a limitation on the maximum measured dose rate is shown.

Transient heating of Pd nanoparticles studied by x-ray diffraction with time of arrival photon detection.

Pulsed laser heating of an ensemble of Pd nanoparticles, supported by a MgO substrate, is studied by x-ray diffraction. By time-resolved Bragg peak shift measurements due to thermal lattice expansion, the transient temperature of the Pd nanoparticles is determined, which quickly rises by at least 100 K upon laser excitation and then decays within 90 ns. The diffraction experiments were carried out using a Cu x-ray tube, giving continuous radiation, and the hybrid pixel detector Timepix3 operating with single photon counting in a time-of-arrival mode. This type of detection scheme does not require time-consuming scanning of the pump-probe delay. The experimental time resolution is estimated at 15 ± 5 ns, which is very close to the detector's limit and matches with the 7 ns laser pulse duration. Compared to bulk metal single crystals, it is discussed that the maximum temperature reached by the Pd nanoparticles is higher and their cooling rate is lower. These effects are explained by the oxide support having a lower heat conductivity.

Beam characterization of mid-infrared free electron laser to drive high-harmonic generation

The maximum energy of photons from high-harmonic generation (HHG) increases with the wavelength of the driving laser. A free electron laser (FEL) is a continuously tunable light source in the mid-IR wavelength range and it is useful for investigating the extension of the accessible photon energy in HHG. Recently, the undulator magnets of the IR FEL at the Laboratory for Electron Beam Research and Application (LEBRA), Nihon University, have been replaced, and then the output power of the FEL has increased. Here, we evaluate the pulse duration and focal beam size of the FEL and show that the LEBRA FEL with 2 and 3 μm laser wavelengths under a 44 MHz bunch repetition mode can drive HHG.

Compact hard x-ray flash radiography device based on wire-shorted low-impedance rod pinch diode.

A rod pinch diode (RPD) is a feasible load configuration to generate a high-brightness, small-size hard x-ray radiation source. In this paper, the radiography performance of a wire-shorted low-impedance RPD on a compactly designed table-top driver (WRPD-1) is demonstrated for the first time. The driver consists of four high-power discharge branches connected in parallel, with each branch consisting of two metal-film capacitors and one multigap field-distortion switch in series. The four branches are triggered synchronously to generate a fast-rising current pulse: the inductance of the load section at the short circuit is ∼10 nH, and the short-circuit current amplitude is ∼325kA at ±90kV charging voltage, with a 10%-90% rise time of 110ns. With a low-impedance RPD shorted by an 18-µm-diameter aluminum wire, a quasi-spherical x-ray focal spot with diameter <0.6mm (width of the half-maximum grayscale) and a pulse duration of ∼25ns (half-width of the radiation pulse) is obtained at ±70kV charging voltage, and the imaging resolution excels 10 lp/mm under 1.56× magnification. According to the transmission-absorption x-ray spectrum estimation, the average emitted photon energy is ∼30keV with a distinct peak in the 10-15keV range that corresponds to the L-lines of tungsten, and the total energy of photons >10keV reaches ∼1.16J. The present results show that the device can serve well for the flash radiography diagnosis and potentially as an efficient light source for dynamic x-ray diffraction.