Pseudogap Phenomena Research Articles

Microscopic theory of novel pseudogap phenomena and Bose-liquid superconductivity and superfluidity in high-$$T_c$$ cuprates and other systems

Microscopic theory of novel pseudogap phenomena and Bose-liquid superconductivity and superfluidity in high-$$T_c$$ cuprates and other systems

Phase fluctuations in two-dimensional superconductors and pseudogap phenomenon

We study the phase fluctuations in the normal state of generic two-dimensional superconducting systems with $s$-wave pairing. The effect of phase fluctuations of the pairing fields can be dealt with perturbatively using disorder averaging, after we treat the local superconducting order parameter as a static disordered background. It is then confirmed that the phase fluctuations above the two-dimensional Berezinskii-Kosterlitz-Thouless transition lead to a significant broadening of the single-particle spectrum, giving birth to the pseudogap phenomenon. Quantitatively, the broadening of spectral weights near the BCS gap is characterized by the ratio of the superconducting coherence length and the spatial correlation length of the superconducting pairing order parameter. Our results are tested on the fermionic attractive-$U$ Hubbard model on the square lattice, using the unbiased determinant quantum Monte Carlo method and stochastic analytic continuation.

Pseudogap formation due to charge-transfer transition and Kondo effect

We investigate the doping evolution of the electronic state of the three-band t-J-U model considering the normal state of the hole-doped high- superconducting cuprate. In our model, when some number of holes are doped into the undoped state, the d electron exhibits the charge-transfer (CT)-type Mott-Hubbard transition along with a chemical potential jump. A reduced CT gap is formed from the p band and the coherent component of the d band, and it shrinks due to charge fluctuations as more holes are doped as in the pseudogap (PG) phenomenon. This trend is reinforced as the d-p band hybridization is increased, and a Fermi liquid state is retrieved as in the Kondo effect. These suggest that the PG in the hole-doped cuprate emerges due to the CT transition and the Kondo effect.

Topological spin texture in the pseudogap phase of a high-Tc superconductor.

An outstanding challenge in condensed-matter-physics research over the past three decades has been to understand the pseudogap (PG) phenomenon of the high-transition-temperature (high-Tc) copper oxides. A variety of experiments have indicated a symmetry-broken state below the characteristic temperature T* (refs. 1-8). Among them, although the optical study5 indicated the mesoscopic domains to be small, all these experiments lack nanometre-scale spatial resolution, and the microscopic order parameter has so far remained elusive. Here we report, to our knowledge, the first direct observation of topological spin texture in an underdoped cuprate, YBa2Cu3O6.5, in the PG state, using Lorentz transmission electron microscopy (LTEM). The spin texture features vortex-like magnetization density in the CuO2 sheets, with a relatively large length scale of about 100 nm. We identify the phase-diagram region in which the topological spin texture exists and demonstrate the ortho-II oxygen order and suitable sample thickness to be crucial for its observation by our technique. We also discuss an intriguing interplay observed among the topological spin texture, PG state, charge order and superconductivity.

Pseudogap suppression by competition with superconductivity in La-based cuprates

We carried out a comprehensive high-resolution angle-resolved photoemission spectroscopy (ARPES) study of the pseudogap interplay with superconductivity in La-based cuprates. The three systems La2−xSrxCuO4, La1.6−xNd0.4SrxCuO4, and La1.8−xEu0.2SrxCuO4 display slightly different pseudogap critical points in the temperature versus doping phase diagram. We studied the pseudogap evolution into the superconducting state for doping concentrations just below the critical point. In this setting, near optimal doping for superconductivity and in the presence of the weakest possible pseudogap, we uncover how the pseudogap is partially suppressed inside the superconducting state. This conclusion is based on the direct observation of a reduced pseudogap energy scale and re-emergence of spectral weight suppressed by the pseudogap. Altogether these observations suggest that the pseudogap phenomenon in La-based cuprates is in competition with superconductivity for antinodal spectral weight.Received 27 April 2022Accepted 30 August 2022DOI:https://doi.org/10.1103/PhysRevResearch.4.043015Published by the American Physical Society under the terms of the Creative Commons Attribution 4.0 International license. Further distribution of this work must maintain attribution to the author(s) and the published article's title, journal citation, and DOI.Published by the American Physical SocietyPhysics Subject Headings (PhySH)Research AreasElectronic structurePhysical SystemsCupratesTechniquesAngle-resolved photoemission spectroscopyCondensed Matter, Materials & Applied Physics

Phase separation in high-T c cuprates

We develop a minimal non-BCS model for the CuO2 planes with the on-site Hilbert space reduced to only three effective valence centers CuO4 with different charge, conventional spin, and orbital symmetry, combined in a charge triplet, to describe the low-energy electron structure and the phase states of HTSC cuprates. Using the S = 1 pseudospin algebra we introduce an effective spin-pseudospin Hamiltonian which takes into account local and nonlocal correlations, one- and two-particle transport, and spin exchange. The T-n phase diagrams of the complete spin-pseudospin model for the CuO2 planes were reproduced by means of a site-dependent variational approach within effective field approximation typical for spin-magnetic systems. Limiting ourselves to two-sublattice approximation and nn-couplings we arrived at several Néel-like phases in CuO2 planes for parent and doped systems with a single nonzero local order parameter: antiferromagnetic insulator, charge order, glueless d-wave Bose superfluid phase, and unusual metallic phase. However, the Maxwell’s construction shows the global minimum of free energy is realized for phase separated states which are bounded by the third-order phase transition line T*(n), which is believed to be responsible for the onset of the pseudogap phenomenon.

Projected BCS theory for the unification of antiferromagnetism and strongly correlated superconductivity

A close connection between antiferromagnetism and superconductivity is at the core of high-temperature superconductivity. Here, we put forward the projected BCS theory for the unification of antiferromagnetism and strongly correlated superconductivity. Specifically, it is shown that, with the $d$-wave pairing symmetry, the projected BCS theory can provide excellent trial states at general doping for the exact ground states of the $t\text{\ensuremath{-}}J$ model in the square lattice, generating a unified theory of high-temperature superconductivity as a continuous function of hole concentration. A key to the success of the projected BCS theory is an accurate treatment of the strong correlation between Cooper pairs, which not only causes the breakdown of superconductivity itself at half filling but also defines the precise nature of strongly correlated superconductivity at moderate doping. Also, via the proper incorporation of particle number fluctuations, the projected BCS theory allows direct computation of the superconducting order parameter, shedding important light on the pseudogap phenomenon.

Unconventional spectral signature of Tc in a pure d-wave superconductor.

In conventional superconductors, the phase transition into a zero-resistance and perfectly diamagnetic state is accompanied by a jump in the specific heat and the opening of a spectral gap1. In the high-transition-temperature (high-Tc) cuprates, although the transport, magnetic and thermodynamic signatures of Tc have been known since the 1980s2, the spectroscopic singularity associated with the transition remains unknown. Here we resolve this long-standing puzzle with a high-precision angle-resolved photoemission spectroscopy (ARPES) study on overdoped (Bi,Pb)2Sr2CaCu2O8+δ (Bi2212). We first probe the momentum-resolved electronic specific heat via spectroscopy and reproduce the specific heat peak at Tc, completing the missing link for a holistic description of superconductivity. Then, by studying the full momentum, energy and temperature evolution of the spectra, we reveal that this thermodynamic anomaly arises from the singular growth of in-gap spectral intensity across Tc. Furthermore, we observe that the temperature evolution of in-gap intensity is highly anisotropic in the momentum space, and the gap itself obeys both the d-wave functional form and particle-hole symmetry. These findings support the scenario that the superconducting transition is driven by phase fluctuations. They also serve as an anchor point for understanding the Fermi arc and pseudogap phenomena in underdoped cuprates.

Microscopic Theory of Novel Pseudogap Phenomena and Bose-Liquid Superconductivity and Superfluidity in High-Tc Materials and Other Systems

Microscopic Theory of Novel Pseudogap Phenomena and Bose-Liquid Superconductivity and Superfluidity in High-Tc Materials and Other Systems

Ubiquitous Charge Order Correlations in High-Temperature Superconducting Cuprates

The presence of charge order in high-transition-temperature copper oxides (high-Tc cuprates) was identified a decade ago. Now it is a universally observed order like the antiferromagnetic and the superconducting orders of the cuprates. The charge order shows up in various forms depending on materials, and it overlaps other orders in the phase diagram. Because of this diversity and complexity it has been far from clear whether or not the charge order has a direct relevance to superconductivity and to the mysterious pseudogap phenomenon. However, the research development in the last few years has been successful in revealing universal aspects of the charge order and its fluctuations. It turns out that the charge order is compatible with superconductivity, and that its fluctuations have high onset temperature and high energy scale comparable to those of the pseudogap. The charge order correlations might be indispensable for creating the pseudogap and possibly generating high-Tc superconductivity by collaborating with spin and pairing correlations.

Spin texture in a bilayer high-temperature cuprate superconductor

We investigate the possibility of spin texture in the bilayer cuprate superconductor $\rm Bi_2Sr_2CaCu_2O_{8+\delta}$ using cluster dynamical mean field theory (CDMFT). The one-band Hubbard model with a small interlayer hopping and a Rashba spin-orbit coupling is used to describe the material. The $d$-wave order parameter is not much affected by the presence of the Rashba coupling, but a small triplet component appears. We find a spin texture circulating in the same direction around $\mathbf{k}=(0,0)$ and $\mathbf{k}=(\pi,\pi)$ and stable against the superconducting phase. The amplitude of the spin structure, however, is strongly affected by the pseudogap phenomenon, more so than the spectral function itself.

Microscopic evidence for the intra-unit-cell electronic nematicity inside the pseudogap phase in YBa2Cu4O8

Understanding the nature of the mysterious pseudogap phenomenon is one of the most important issues associated with cuprate high-Tc superconductors. Here, we report 17O nuclear magnetic resonance (NMR) studies on two planar oxygen sites in stoichiometric cuprate YBa2Cu4O8 to investigate the symmetry breaking inside the pseudogap phase. We observe that the Knight shifts of the two oxygen sites are identical at high temperatures but different below Tnem ∼ 185 K, which is close to the pseudogap temperature T*. Our result provides a microscopic evidence for intra-unit-cell electronic nematicity. The difference in quadrupole resonance frequency between the two oxygen sites is unchanged below Tnem, which suggests that the observed nematicity does not directly stem from the local charge density modulation. Furthermore, a short-range charge density wave (CDW) order is observed below T ≃ 150 K. The additional broadening in the 17O-NMR spectra because of this CDW order is determined to be inequivalent for the two oxygen sites, which is similar to that observed in case of nematicity. These results suggest a possible connection between nematicity, CDW order, and pseudogap.

Unconventional superconductivity as a quantum Kuramoto synchronization problem in random elasto-nuclear oscillator networks

We formulate the problem of unconventional d − wave superconductivity, with phase fluctuations, pseudogap phenomenon, and local Cooper pairs, in terms of a synchronization problem in random, quantum dissipative, elasto-nuclear oscillator networks. The nodes of the network correspond to localized, collective quadrupolar vibrations of nuclei-like, elastic inhomogeneities embedded in a dissipative medium. Electrons interacting with such vibrations form local Cooper pairs, with a superfluid d − wave pseudogap Δ PG , due to an effective, short range attractive interaction of character. Phase coherent, bulk superconductivity, with a d − wave gap Δ, is stabilized when the oscillator network is asymptotically entangled in a nearly decoherence-free environment. Phase coherence will in turn be destroyed, at T c , when the thermal noise becomes comparable to the coupling between oscillators, the superfluid density K. The 2Δ/k B T c ratio is a function of Kuramoto’s order parameter, , for the loss of synchronization at K c , and is much larger than the nonuniversal 2Δ PG /k B T * ratio, where T * is the temperature at which Δ PG is completely destroyed by thermal fluctuations. We discuss our findings in connection to the available data for various unconventionally high-temperature superconductors.

Mott and pseudogap localization in pressurized NbO2

We present a detailed study of correlation-induced electronic reconstruction in baddeleyite-type ${\mathrm{NbO}}_{2}$, a distorted ${\mathrm{ZrO}}_{2}$-type structure that is found at pressures above 8.0 GPa. Based on density-functional plus dynamical mean-field theory (DFT$+$DMFT), we stress the importance of multiorbital Coulomb interactions in concert with first-principles band-structure calculations for a consistent understanding of emergent Mottness and pseudogap behavior in pressurized ${\mathrm{NbO}}_{2}$ and related ${d}^{1}$ systems. After a proper treatment of multiorbital electron-electron interactions, we find a nearly universal Mott behavior for the peak position of the lower Hubbard band that is independent of crystal- and band-structure details. We explain the nature of the metal-pseudogap-insulator transition to be seen in experiment, showing a first-order transition between two metallic states: a correlated metal and a pseudogap state with a deep density of states at the Fermi level. This emergent pseudogap phenomena is expected to play a central role toward quantum criticality in pressurized ${\mathrm{NbO}}_{2}$.

Unusual Dynamic Charge Correlations in Simple-Tetragonal HgBa2CuO4+δ

The charge-density-wave (CDW) instability in the underdoped, pseudogap part of the cuprate phase diagram has been a major recent research focus, yet measurements of dynamic, energy-resolved CDW correlations are still in their infancy. We report a high-resolution resonant inelastic X-ray scattering (RIXS) study of the underdoped cuprate superconductor HgBa$_{2}$CuO$_{4+\delta}$ ($T_c = 70$ K). At $T=250$ K, above the CDW order temperature $T_\mathrm{CDW} \approx 200$ K, we observe significant dynamic CDW correlations at about 40 meV. This energy scale is comparable to both the superconducting gap and the previously reported low-energy pseudogap. At $T = T_c$, a strong elastic CDW peak appears, but the dynamic correlations around 40 meV remain virtually unchanged. In addition, we observe a new feature: dynamic correlations at significantly higher energy, with a characteristic scale of about 160 meV. A similar scale was previously identified in other experiments as a high-energy pseudogap. The existence of three distinct features in the charge response is highly unusual for a CDW system, and suggests that charge order in the cuprates is closely related to the pseudogap phenomenon and more complex than previously thought. We further observe the paramagnon dispersion along [1,0], across the two-dimensional CDW wavevector $\boldsymbol{q}_\mathrm{CDW}$, which is consistent with magnetic excitations measured by inelastic neutron scattering. Unlike for some other cuprates, our results point to the absence of a discernible coupling between CDW and magnetic excitations.

Superfluidity and pairing phenomena in ultracold atomic Fermi gases in one-dimensional optical lattices. I. Balanced case

The superfluidity and pairing phenomena in ultracold atomic Fermi gases have been of great interest in recent years, with multiple tunable parameters. Here we study the BCS-BEC crossover behavior of balanced two-component Fermi gases in a one-dimensional optical lattice, which is distinct from the simple three-dimensional (3D) continuum and a fully 3D lattice often found in a condensed matter system. We use a pairing fluctuation theory which includes self-consistent feedback effects at finite temperatures, and find widespread pseudogap phenomena beyond the BCS regime. As a consequence of the lattice periodicity, the superfluid transition temperature $T_c$ decreases with pairing strength in the BEC regime, where it approaches asymptotically $T_c = \pi an/2m$, with $a$ being the $s$-wave scattering length, and $n$ ($m$) the fermion density (mass). In addition, the quasi-two dimensionality leads to fast growing (absolute value of the) fermionic chemical potential $\mu$ and pairing gap $\Delta$, which depends exponentially on the ratio $d/a$. Importantly, $T_c$ at unitarity increases with the lattice constant $d$ and hopping integral $t$. The effect of the van Hove singularity on $T_c$ is identified. The superfluid density exhibits $T^{3/2}$ power laws at low $T$, away from the extreme BCS limit. These predictions can be tested in future experiments.

Superfluidity and pairing phenomena in ultracold atomic Fermi gases in one-dimensional optical lattices. II. Effects of population imbalance

In this paper, we study the effect of population imbalance and its interplay with pairing strength and lattice effect in atomic Fermi gases in a one-dimensional optical lattice. We compute various phase diagrams as the system undergoes BCS-BEC crossover, using the same pairing fluctuation theory as in Part I of this work [Phys. Rev. A 101, 053617 (2020)]. We find widespread pseudogap phenomena beyond the BCS regime and intermediate temperature superfluid states for relatively low population imbalances. The Fermi surface topology plays an important role in the behavior of ${T}_{\mathrm{c}}$. For large $d$ and/or small $t$, which yield an open Fermi surface, superfluidity can be readily destroyed by a small amount of population imbalance $p$. The superfluid phase, especially in the BEC regime, can exist only for a highly restricted volume of the parameter space. An open Fermi surface often leads to destruction of the superfluid ground state in the BEC regime. Due to the continuum-lattice mixing, population imbalance gives rise to a new mechanism for pair hopping, as assisted by excessive majority fermions, which may lead to significant enhancement of ${T}_{\mathrm{c}}$ on the BEC side of the Feshbach resonance, and also render ${T}_{\mathrm{c}}$ approaching a constant asymptote in the BEC limit, when it exists. Furthermore, we find that not all minority fermions will be paired up in BEC limit, unlike the 3D continuum case. These predictions can be tested in future experiments.

Unusual Destruction and Enhancement of Superfluidity of Atomic Fermi Gases by Population Imbalance in a One-Dimensional Optical Lattice**Supported by the National Natural Science Foundation of China (Grant Nos. 11774309 and 11674283) and the Natural Science Foundation of Zhejiang Province of China (Grant No. LZ13A040001).

We study the superfluid behavior of a population imbalanced ultracold atomic Fermi gases with a short range attractive interaction in a one-dimensional (1D) optical lattice, using a pairing fluctuation theory. We show that, besides widespread pseudogap phenomena and intermediate temperature superfluidity, the superfluid phase is readily destroyed except in a limited region of the parameter space. We find a new mechanism for pair hopping, assisted by the excessive majority fermions, in the presence of continuum-lattice mixing, which leads to an unusual constant Bose-Einstein condensate (BEC) asymptote for Tc that is independent of pairing strength. In result, on the BEC side of unitarity, superfluidity, when it exists, may be strongly enhanced by population imbalance.

Extent of Fermi-surface reconstruction in the high-temperature superconductor HgBa2CuO4+δ.

High magnetic fields have revealed a surprisingly small Fermi surface in underdoped cuprates, possibly resulting from Fermi-surface reconstruction due to an order parameter that breaks translational symmetry of the crystal lattice. A crucial issue concerns the doping extent of such a state and its relationship to the principal pseudogap and superconducting phases. We employ pulsed magnetic-field measurements on the cuprate [Formula: see text]Cu[Formula: see text] to identify signatures of Fermi-surface reconstruction from a sign change of the Hall effect and a peak in the temperature-dependent planar resistivity. We trace the termination of Fermi-surface reconstruction to two hole concentrations where the superconducting upper critical fields are found to be enhanced. One of these points is associated with the pseudogap endpoint near optimal doping. These results connect the Fermi-surface reconstruction to both superconductivity and the pseudogap phenomena.

Nonequilibrium strong-coupling theory for a driven-dissipative ultracold Fermi gas in the BCS-BEC crossover region

We theoretically investigate strong-coupling properties of an ultracold Fermi gas in the BCS-BEC crossover regime in the non-equilibrium steady state, being coupled with two fermion baths. By developing a non-equilibrium strong-coupling theory based on the combined $T$-matrix approximation with the Keldysh Green's function technique, we show that the chemical potential bias applied by the two baths gives rise to the anomalous enhancement of Fulde-Ferrell-Larkin-Ovchinnikov (FFLO) type pairing fluctuations (although the system has no spin imbalance), resulting in the re-entrant behavior of the non-equilibrium superfluid phase transition in the BCS-unitary regime. These pairing fluctuations are also found to anomalously enhance the pseudogap phenomenon. Since various non-equilibrium phenomena have recently been measured in ultracold Fermi gases, our non-equilibrium strong-coupling theory would be useful to catch up this experimental development in this research field.