Pseudo-second Order Kinetic Model Research Articles

Fabrication of tannic acid-incorporated polyvinylpyrrolidone/polyvinyl alcohol composite hydrogel and its application as an adsorbent for copper ion removal.

An effective tannic acid-incorporated polyvinylpyrrolidone/polyvinyl alcohol composite hydrogel with high-potential sorption capacity was developed for the removal of copper from aqueous solution. The composite hydrogel exhibited pH-dependent swelling, in which swelling and shrinking occurred reversibly with adjustment of the pH of the medium. At pH 4, the maximal adsorption capacity for copper at 30°C was 297.0mg g-1, and the adsorbent dose was 4g L-1. The adsorption kinetics were best fitted with a pseudo-second order kinetic model. The adsorption behavior was well predicted by the Freundlish isotherm. The thermodynamics parameters indicated a spontaneous and exothermic reaction with an increase in the entropy of the system. The chemical changes in the film structure before and after adsorption treatment were characterized by Scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and X-ray absorption spectroscopy (XAS). The FTIR, XPS and XAS results confirmed that Cu bound to the oxygens in the -OH, C = O and N-(C = O)- functional groups on the T-HD. XAS analysis revealed the chemical composition and molecular geometry of the adsorbed copper ions. The single-solute adsorption and coadsorption mechanisms, which provide insight into cobalt-copper, nickel-copper, or nickel-cobalt-copper complex solutions, were investigated. The composite hydrogel exhibited excellent regeneration ability in EDTA solution. Notably, the adsorbent retained an adsorption efficiency exceeding 87% even after five regeneration cycles. On the basis of both adsorbent characteristics and adsorption performance, it was determined that the composite hydrogel has the potential to be used as a platform for developing materials to treat wastewater containing high levels of metal contaminants such as those from the electroplating industry.

In Situ Potentiometric Monitoring of Nitrate Removal from Aqueous Solution by Activated Carbon and Ion Exchange Resin

A nitrate selective electrode was used for real-time in situ potentiometric monitoring of a batch nitrate removal process using activated carbon and ion exchange resin. A plasticized polymeric membrane consisting of polyvinyl chloride, 2-nitrophenyl octyl ether and tridodecyl methyl ammonium chloride was incorporated into an ion-selective electrode body. First, the dynamic potential response of the electrode to nitrate was investigated. Two commercial activated carbons with different physical properties were then tested. Nitrate removal with these carbons was monitored potentiometrically using several nitrate concentrations. The extreme turbidity of the solutions was not a drawback during potentiometric monitoring of the process, which is a clear advantage over other methods such as optical monitoring. The potential versus time recordings were converted into nitrate concentration versus time plots, which were evaluated with different adsorption kinetic models. A pseudo-second order kinetic model for nitrate adsorption on both activated carbons was found to fit the experimental data very well. The values of the kinetic parameters were very different between the two activated carbons. The proposed methodology was also satisfactorily applied to the study of nitrate removal by an ion exchange resin. In this case, the experimental results clearly follow a pseudo-first order kinetic model. Potential applications of the proposed methodology for monitoring nitrate removal in real water samples are discussed.

Utilizing Waste Biomass from Agricultural and Forestry Sustainable Resources: Biomass Conversion to Functional Adsorbent Material for Efficient Removal of Total Phosphate in Practical Water.

The promotion of the utilization of waste agricultural and forestry resources (AFRs) as a means of combating environmental pollution represents an advanced and necessary development approach with the potential to achieve sustainable development. In this work, an advanced adsorbent with a functional Mg-Al bimetallic layer was prepared using waste sawdust biomass (WSD) as a raw material. The layer serves as the primary active component for adsorbing total phosphate from both simulated and real wastewater. The hierarchical structure of the Mg-Al bimetallic hydroxide-modified waste sawdust biomass (MA@WSD) has an abundance of nanosheets on its surface, providing ample binding sites and an enhanced specific surface area of 175.99 m2/g. Under the optimal conditions, the maximum removal efficiency toward phosphate can reach 99.99%. The adsorption of phosphate by MA@WSD follows the pseudo-second order kinetic (PSOK) model, indicating that chemisorption is the rate-determining step. Moreover, the thermodynamic data demonstrate the spontaneous nature of the adsorption process, indicating the favorable characteristics of the developed material. The adsorption mechanism can be summarized as the collaboration of physical adsorption, electrostatic interaction, and chemical adsorption. The results of the regeneration process indicate that MA@WSD exhibits a retention of 50.3% of its initial adsorption performance following the fifth testing cycle, thereby suggesting its potential for comparable reusability. The MA@WSD performs well in adsorbing total phosphate in real river water, and the removal efficiency of MA@WSD is evidently superior to commercial activated carbon, which is at least 70% higher than that of the commercial activated carbon. Besides, the 5-time average removal efficiency toward total phosphate by MA@WSD is 62.9%, evidently higher than the 29.1% of commercially available activated carbon, indicating its potential as an alternative for treating phosphorus-containing wastewater. The research provides theoretical support for harmless treatment, resource utilization, carbon sequestration, and emission reduction of waste biomass.

Exploring the adsorption of Catechol and Resorcinol onto Croton caudatus activated carbon: An integrated experimental and theoretical approach

The present work aimed to examine the process for adsorption of Catechol (CT) and Resorcinol (RS) onto activated carbon that was obtained from Croton caudatus biomass (CAB). Using a batch method, the maximum removal efficiencies of 99.23 % for CT and 98.68 % for RS was achieved at adsorbent dosage-0.2 g L-1, reaction time-60 min; concentration-100 mgL-1 CT and 80 mgL-1 RS; and pH 6.0 CT and pH 4.0 RS, respectively. A maximum equilibrium adsorption of 56.05 mgg-1 and 61.85 mgg-1 was achieved at pH 6.0 and pH 4.0 for CT and RS. The adsorption behavior of both adsorbates on activated carbon were best described by the Langmuir model (correlation coefficients (R2) = 0.996 for CT and 0.995 for RS) and the pseudo-second order kinetic model. The values of ΔG, ΔS, and ΔH suggest that the adsorption process is spontaneous and endothermic. Additionally, the adsorption process is easily reversible, enabling the reuse of the adsorbate even after fifth cycle. Further, density functional theory (DFT) simulations demonstrated that the CT and RS adsorption onto the AC adsorbent is favorable. Among the oxygen functional groups analysed, the carboxyl group showed the greatest effect on the adsorption process, exhibiting the most negative adsorption energy at -44.869 (CT) and -45.082 kJmol-1 (RS), respectively. Therefore, the activated carbon derived from CAB has significant potential for effectively removing phenolic contaminants from wastewater.

Adsorptive removal of ppb levels of boron trichloride using N-doped porous carbon materials

The removal of trace boron impurities (BCl3) in chlorosilane represents a significant challenge in polysilicon production. In this study, we employed the high-temperature ammonia etching method to fabricate nitrogen-doped porous carbon (NPC) adsorbents derived from lignite. The as-prepared NPCs were tested and evaluated as potential adsorbents for efficient removal of BCl3. Furthermore, a systematic investigation was conducted to assess the impact of contact time, initial concentration, adsorbent dose, and temperature. It was found that the adsorbent (NPC900) obtained at 900 °C exhibited an excellent efficacy in removing BCl3 (R% = 98.9 %), with a residual concentration of BCl3 in the solution was 1.65 ppb, which met the industrial requirements. This can be primarily attributed to its porous structure and high pyridinic-N content. Furthermore, the adsorption of BCl3 on NPC900 was better followed by Pseudo-second order kinetic model and the Langmuir isotherm model. Thermodynamic studies showed that the adsorption process was spontaneous and exothermic. The interactions between BCl3 and different nitrogen forms was analysis through the utilizing density functional theory (DFT) calculation. The findings indicate that pyridinic-N exhibits a stronger interaction with BCl3 (Eads = −102.35 kJ/mol), primarily due to the easier electron transfer from the nitrogen atom on pyridinic-N to BCl3.

Effectiveness of Musa Balbisiana bract toward chromium removal from industrial tannery effluent: optimization, kinetics, isotherms, regeneration, and cost estimation

Eradicating chromium from industrial effluent is essential for environmental security and economic reasons. This study investigates the potency of activated Musa balbisiana bract biomass as a biosorbent to remove hexavalent chromium (Cr6+) from real industrial tannery effluent (ITE). The characterization study exemplifies the existence of irregular structures and excessive cavities, and the occurrence of functional groups (hydroxyl, carboxyl, esters, and alkynes) are benefitting the deposition of Cr6+ on the biosorbent. A maximum biosorption capacity of 42.75 ± 0.21mg/g was observed at an optimum pH of 6.5, biosorbent dosage of 0.3g, initial Cr6+ concentration of 50mg/L, and contact time of 120min. The validation experiment confirmed the removal efficiency of total chromium, trivalent chromium, and Cr6+ 92.56 ± 0.80%, 98.63 ± 0.20%, and 96.21 ± 0.50%, respectively. Among the models, Langmuir isotherm (R2: 0.9992) and pseudo-second order (R2: 0.9999) kinetic models greatly correlate with the equilibrium data. A 2-tier membrane module was examined for continuous study and reached 88.23 ± 0.60% Cr6+ removal. Statistical analysis was performed to confirm the significance of adsorption results. The likelihood of the desorption and regeneration of the treated biosorbent was investigated. The estimated cost per volume of ITE treated and unit of pollutant removal from ITE employing Musa balbisiana bract biosorbent is around $3.08/m3 and $3.75/kg.

Enhanced cationic/anionic dyes removal in wastewater by green nanocomposites synthesized from acid-modified biomass and CuFe2O4 nanoparticles: Mechanism, Taguchi optimization and toxicity evaluation

This article addresses the nanoadsorption mechanisms of rhodamine B (RB), crystal violet (CV), and Congo red (CR) using acid-treated C.edulis (ATCE)/CuFe2O4 (ATCE@CuFe2O4) from an aqueous solution. The physical and chemical characterizations of nanobiomass were studied using different techniques. The specific surface areas of the ATCE and ATCE@CuFe2O4 composites were 15.88 and 337.81 m2/g, respectively, indicating a significant specific surface area of ​​the ATCE@CuFe2O4 nanocomposite. A number of functional groups were determined, which promote the binding of the dye to the adsorbent. The SEM also shows that the adsorbent has a homogeneous texture with deep voids and significant porosity, which likely explains the retention and binding of dye ions on the surface of the adsorbent. In fact, the Langmuir isotherm with a correlation coefficient of 99 % for CV, RB and CR, respectively, represents the most suitable model to explain the adsorption mechanism. The maximum adsorption amount is 666.6 mg/g for CV, 645.16 mg/g for RB and 434.71 mg/g for CR at 308 °K. The adsorption kinetic processes were predicted by the pseudo-second order kinetic model. The thermodynamic properties showed that the adsorption on ATCE@CuFe2O4 was possible and spontaneous. The ATCE@CuFe2O4 recycling and elimination CV, RB, and CR were 74.23 %, 72.75 %, and 67.84 %, respectively, after seven cycles. The design, modeling and optimization of the adsorption parameters were carried out using the Taguchi experimental design. The maximum removal efficiency of CV, RB and CR dyes in optimal operating conditions were 99.96, 98.29 and 97.76 %, respectively. Which at the optimal conditions of 1 g/L, 90 min, 20 mg/L, 298 °K, pH 10 for CV and RB dyes and 1 g/L, 90 min, 20 mg/L, 308 °K, pH 4 for CR. This research demonstrated the performance of ATCE@CuFe2O4 in bean seed germination test and its effectiveness in removing dyes from wastewater.

Sustainable Management of Agro-Food Wastes Derived from the Olive Mill and Sugar Industry and Clinoptilolite to Produce Novel Adsorptive Materials

Novel sorbents were produced using sustainable and eco-friendly methods, aimed at minimizing environmental impact while utilizing industrial by-products and natural minerals. Olive stones and molasses derived from olive mill and sugar industries, respectively, and an abundant, natural and low-cost mineral, clinoptilolite, were combined in the following proportions: 80/20 clinoptilolite/stone, 80/10/10 clinoptilolite/stone/molasses, 50/50 stone/molasses, w/w. Then, physical carbonization (CL80OL20C, CL80OL10M10C, OL50M50C) or chemical activation (CL80OL20A, CL80OL10M10A, OL50M50A) took place. The adsorbents were characterized through Raman, FT-IR, BET and SEM-EDS analysis. The CL80OL20A material presents the highest ratio of C/O in EDS analysis and the lowest ID/IG in Raman spectroscopy. The increase in the specific surface area is as follows: OL50M50C < OL50M50A < CL80OL10M10C < CL80OL20C < CL80OL20A < CL80OL10M10A. Three applications were conducted: two with dyes (methylene blue and methyl red) in aqueous means and one in olive mill wastewaters for the removal of total phenols and their addition to rice, increasing the total phenolic content and producing novel foods. The well-fitted application of the pseudo-second order kinetic model to the experimental data has shown that chemisorption is the prevailing mechanism. The adsorbed amount of the recovered phenols to rice ranges from 0.14 to 0.93 mg/g. Consequently, olive and sugar by-products can be used as filters either to adsorb dangerous organic compounds or to recover bioactive compounds from wastewater, preventing their disposal in the environment, which could otherwise lead to severe negative effects on the ecosystems.

Artificial Neural Network Modeling of the Removal of Methylene Blue Dye Using Magnetic Clays: An Environmentally Friendly Approach

In this study, the effectiveness of Fe3O4-based clay as a cost-effective material for removing methylene blue (MB) dye from aqueous solutions was evaluated. The structural properties of the clay and Fe3O4-based clay were analyzed using SEM, XRF, BET, XRD, FTIR, and TGA techniques. In this research, the effects of various aspects, such as adsorbent amount, contact time, solution pH, adsorption temperature, and initial dye concentration, on the adsorption of Fe3O4-based clay are investigated. The experiments aimed at understanding the adsorption mechanism of Fe3O4-based clay have shown that the adsorption kinetics are accurately described by the pseudo-second order kinetic model, while the equilibrium data are well represented by the Langmuir isotherm model. The maximum adsorption capacity (qm) was calculated as 52.63 mg/g at 25 °C, 53.48 mg/g at 30 °C, and 54.64 mg/g at 35 °C. All variables affecting the MB adsorption process were systematically optimized in a controlled experimental framework. The effectiveness of the artificial neural network (ANN) model was refined by modifying variables such as the quantity of neurons in the latent layer, the number of inputs, and the learning rate. The model’s accuracy was assessed using the mean absolute percentage error (MAPE) for the removal and adsorption percentage output parameters. The coefficient of determination (R2) values for the dyestuff training, validation, and test sets were found to be 99.40%, 92.25%, and 96.30%, respectively. The ANN model demonstrated a mean squared error (MSE) of 0.614565 for the training data. For the validation dataset, the model recorded MSE values of 0.99406 for the training data, 0.92255 for the validation set, and 0.96302 for the test data. In conclusion, the examined Fe3O4-based clays offer potential as effective and cost-efficient adsorbents for purifying water containing MB dye in various industrial settings.

Removal of cefuroxime from aqueous solution by biochars derived from antibiotic mycelial residue.

In China, antibiotic mycelial residue is categorized as hazardous waste. To achieve the harmless and resourceful disposal of cephalosporin, three types of biochars from cephalosporin mycelia residues, namely non-activated carbon (BC1), ZnCl2-activated carbon (BC2), and KOH-activated carbon (BC3), were respectively fabricated by high-temperature pyrolysis carbonization technology. These three kinds of biochars were characterized via iodine value, FTIR, and SEM, and the adsorption performance of the prepared biochars was investigated using cefuroxime (CXM) as the adsorption target. The results indicated that BC3 biochar possesses the most well-developed pores and the highest iodine value of 1367.41 mg/g; The most suitable dosage is 1.6 g/L, and the lower the pH, the more favorable the adsorption effect. The investigation of adsorption kinetics revealed that it conformed to the kinetic model of pseudo-second order, as well as the process of adsorption was governed by the chemical adsorption mechanism, the rate of adsorption was affected by the collective impact of the quantity of active sites present and the interaction strength between the CXM molecules and the biochar. The exploration of adsorption thermodynamics revealed that it aligned with the Langmuir model, the surface of biochar was relatively uniform, and the adsorption was mainly of low coverage; The calculation of thermodynamic parameters demonstrated that the adsorption was exothermic and spontaneous.

Eco-friendly copper nanoparticles for acetamiprid pesticide mitigation in water effluents

Water pollution by pesticides is a significant environmental concern, given their extensive use in agriculture to meet food production demands. This study focuses on evaluating the effectiveness of biosynthesized copper nanoparticles in removing the pesticide acetamiprid (AMP). The degradation process is tracked by measuring the absorbance at 245 nm (AMP λmax) while considering variables such as adsorbent dosage, pH, and time. It provides valuable insights into the design and preparation of CuO nano adsorbents and their efficiency in purifying and remediating aquatic environments. The research investigated the ability of CuO nanoparticles, with an average size of 60 nm, to eliminate acetamiprid at very low concentrations (0.0005–0.01 mg/ml). The results showed that the nanoparticles could remove up to 97.5 % of AMP (0.01 mg/ml GT-CuO) after 90 min of contact time. Additionally, the study used the Langmuir isotherm model (R2 = 0.99125) and the pseudo-second order kinetic model (R2 = 0.98303) to model the adsorption of AMP on CuO NPs. Overall, CuO NPs derived from Glochidium tomentosum (GT) could offer a promising approach for adsorbing AMP pesticides.

Synthesis and characterization of allyl mannitol cross-linker based novel hydrogel for capturing of toxic metal ions from aqueous solution

ABSTRACT Three grades of allyl-mannitol cross-linker-based hydrogel (AMCLHs hydrogel) have been synthesized with the help of acrylic acid and acrylamide monomers using a free radical co-polymerization technique. The three prepared grades of AMCLHs hydrogel have been referred to as AMCLHs-1, AMCLHs-2, and AMCLHs-3, respectively. The prepared AMCLHs hydrogels have been characterized by several analytical techniques viz. Fourier transform infrared (FTIR) spectroscopy, thermogravimetric (TG) analysis, point of zero charge (ΔpHPZC), analysis, and scanning electron microscope (SEM) analysis, respectively. The synthesized hydrogels have been utilized for the elimination of Cu2+ and Co2+ ions from wastewater. The properties of prepared AMCLHs hydrogels, i.e. swelling and water retention ratio have been studied in distilled water under optimized conditions. The maximum swelling ratio of the best grade of hydrogel (AMCLHs-1) has been found to be 400.5 g/g with the water retention ratio of 75.09% during 24 h. These findings indicate the AMCLHs-1 hydrogel has remarkable swelling and water retention capacity. The maximum metal ion removal efficiency of AMCLHs-1 hydrogel from aqueous solutions has been found to be 96.6% for Cu2+ and 94.2% for Co2+ ions under optimum conditions. The experimental data fitted well with the Langmuir and Freundlich adsorption models, revealing maximum adsorption capacities of 431.03 mg/g for Cu2+ ions and 414.93 mg/g for Co2+ ions, respectively. In addition, the rate for the adsorption of Cu2+ and Co2+ ions onto AMCLHs-1 hydrogel follows both Pseudo first and second-order kinetic models. The negative ΔG values indicate that the adsorption process occurs spontaneously, while positive ΔH values suggest that the adsorption process is exothermic in nature. The prepared AMCLHs hydrogel is reusable and exhibits high desorption efficiency with 87.63% for Cu2+ and 85.21% for Co2+ metal ions even after the fourth cycle. Overall, AMCLHs hydrogel is a cost-effective and reusable adsorbent that possesses a significant potential for heavy metal ion removal from aqueous solutions.

Modeling of adsorptive treatment of lead (II) ions contaminated effluents using cashew nut shell alkali activated carbon: Batch kinetic, isothermal and thermodynamic studies

The numerical study of the decontamination of lead(II) ions-rich effluent employing activated carbon derived from cashew nut shell was the central focus of this work. Chemical activation with zinc chloride (ZnCl2) was used to produce powdered activated carbon at optimized activation conditions of impregnation ratio (0.531), activation temperature (1083 K) and activation time (63min). The physiochemical properties of raw and activated cashew nut shell were determined using Fourier transform infrared spectroscopy, scanning, X-ray diffractor (XRD), scanning electron microscopy (SEM), and Brunauer-Emmet-Teller (BET) analyses. Batch adsorption experiments were performed at varied process conditions of temperature (303–323) K, contact time (5–80min), and initial lead(II) ion concentrations (100–400 mg.L−1). The adsorption behavior of the batch–type operation was mathematically described in the form of non-linear parabolic partial differential equations (PDE’S) incorporating film, pore and surface diffusion mechanisms. The batch mathematical model was solved by implementing a custom MATLAB program-OkiyNwabannebatch and calibrated to predict the desired response (percentage removal) using measured adsorption data. The equilibrium adsorption, kinetics and thermodynamics of lead(II) ions adsorption onto activated cashew nut shell were also assessed using nonlinear isotherm, kinetic and thermodynamic models. Sensitivity analysis unveiled that temperature with sensitivity value of 37.31 % had a predominant effect on the model performance. The simulated equilibrium data was well explicated by the Freundlich model for lead(II) ions adsorption onto activated cashew nut shell. The pseudo-second order kinetic model best reproduced the simulated adsorption data for lead(II) ions uptake by cashew nut shell adsorbent. Likewise, the kinetic data followed Boyd model, indicating that the adsorption process is controlled by external (film) diffusion for the uptake of lead(II) ions by alkali activated cashew nut shell. Thermodynamic analysis using the Gibbs and Van’t Hoff’s models indicated that lead(II) ions adsorption by modified cashew nut shell is spontaneous and exothermic. The physical nature of the adsorption process was elucidated from the low values of the isosteric heats of adsorption (ΔHX) evaluated (<80 kJ mol−1). This study showed that zinc chloride activated cashew nut shell has good potential to be used as a cost-effective and efficient adsorbent for the uptake of lead(II) ions from aqueous solution.

Harnessing Moringa oleifera root powder (MORP) for the sustainable remediation of heavy metal contaminated water.

Heavy metal environmental pollution is rapidly increasing due to the increase in industrialization and urbanization. Industrial processes, such as paint production, mining, and raw materials producing industries release effluents rich in heavy metals, like Pb2+, Cd2+, Cu2+, and Cr3+. These heavy metals are dangerous because they persist in nature, are non-biodegradable and they have high tendency to accumulate in the environment and in living organisms who are exposed to them. This work studied the removal of heavy metals (Cu, Pb, Cr, and Cd) from aqueous solution using Moringa oleifera root powder (MORP) as the adsorbent. The MORP was characterized by SEM, FTIR, BET, and XRD. Batch adsorption experiments carried out investigated the effects of adsorbate concentration, adsorbent dosage, agitation time, pH and temperature on adsorption. The optimum parameters are: contact time (90 min); pH (9); adsorbent dose (0.6); metal ion concentration (30 mg L-1) for Cr and 40 mg L-1 for the rest; and temperature (50 °C) for Cu and Pb, and 70 °C for Cr and Cd. These experimental data were analyzed with 5 isotherm models (Temkin, Flory-Huggins, Langmuir, D-R and Freundlich). The result obtained fitted best to Temkin isotherm in comparison to others. Kinetic studies revealed that the pseudo-second order kinetic model best described the adsorption (with high R2 values ranging from 0.9810-0.9976) compared to pseudo-first order and intra-particle diffusion kinetics model. Results of the thermodynamic study showed that the sorption process was endothermic for Cu and Pb, but exothermic for Cd and Cr. The adsorbent showed good adsorptive tendencies toward the ions studied, and could be applied on an industrial scale for the remediation of metal contaminated water.

Efficient phosphate removal from water using ductile cast iron waste: a response surface methodology approach.

Water scarcity is a critical issue worldwide. This study explores a novel method for addressing this issue by using ductile cast iron (DCI) solid waste as an adsorbent for phosphate ions, supporting the circular economy in water remediation. The solid waste was characterized using XRD, XRF, FTIR, and particle size distribution. Wastewater samples of different phosphate ion concentrations are prepared, and the solid waste is used as an adsorbent to adsorb phosphate ions using different adsorbent doses and process time. The removal percentage is attained through spectrophotometer analysis and experimental results are optimized to get the optimum conditions using Design Expert V13. The pseudo-second order (PSO) kinetics model and Langmuir isotherm were fitted with the experimental results with maximum adsorption capacity (qmax = 0.28mg/g). The thermodynamic analysis indicated that this adsorption process was spontaneous based on the negative value of Gibbs free energy (∆G). Additionally, the positive values of enthalpy (∆H) indicated the endothermic nature of this adsorption system. It was able to reach the highest adsorption percentage of 98.9 (%) for phosphate ions from aqueous solutions using response surface methodology (RSM) with optimum conditions of 10mg/L phosphate ion concentration, pH = 8, normal room temperature, 9min adsorption, and 0.5g/L adsorbent dosage.

One-step green synthesis of melamine-modified cellulose nanofiber composite aerogels for efficient removal of Pb(II) and Cu(II): Experiments and DFT calculations

A composite aerogel (CGMA) with high porosity (98.32 %) and multiple active sites was prepared for the adsorption of Pb(II) and Cu(II) by sol-gel combined with freeze-drying process using melamine and (3-Glycidyloxypropyl)trimethoxysilane as cellulose nanofiber modifying materials. Characterized by SEM-EDS, XPS, FTIR, BET, MIP and TG, CGMA has a hierarchical pore structure and abundant adsorption sites. At pH = 6, the adsorption reached equilibrium within 120 min, following the Pseudo second-order kinetic model and the Langmuir model, with maximum capacities of 268.1 mg/g for Pb(II) and 152.6 mg/g for Cu(II). The process was primarily governed by homogeneous chemisorption. The coexisting ion, organic matter, and water quality experiments confirmed the excellent anti-interference properties of CGMA. Competitive adsorption experiments showed that CGMA has excellent selective adsorption performance for Pb(II). After 5 cycles, Pb(II) and Cu(II) adsorption performance decreased to 79.21 % and 83.40 %, respectively. FTIR, XPS, DFT and RDG analysis showed that amino groups and oxygen-containing groups were the main sites of adsorption. CGMA forms coordination bonds and complexes with Pb(II) and Cu(II) via amine and oxygen groups and adsorbs via electron transfer, hydrogen bonding, and van der Waals forces, with Pb(II) being more selective. CGMA has good prospects for application in heavy metal ion treatment.

Sorption properties of a new modified flax fibre sorbent

The purpose of this study is to develop a modified sorbent of flax waste and investigate its sorption properties towards Cu (II) ions. The authors conducted the modification in two steps. The first step was oxidation of flax fibre cellulose with sodium metaperiodate to dialdehyde cellulose, the second one was the addition of taurine to increase the sorption characteristics of the modified sorbent. The paper presents the conditions for the periodate oxidation reaction of flax fibre and the treatment of the resulting dialdehyde cellulose with taurine. We determined the sorption characteristics of the modified sorbent in comparison with the original flax fibre. Kinetic studies allowed us to establish the time of reaching sorption equilibrium in the heterophase system ‘aqueous solution of metal salt-sorbent’ and determine the reaction order using pseudo first and pseudo-second order kinetics models. The authors processed the sorption isotherms obtained during the experiments using the Langmuir model. The maximum sorption capacity increased by 3 times compared to the original flax fibre. IR spectroscopy confirmed the improvement of equilibrium and kinetic characteristics of flax fibre occuring as a result of the appearance of new sorption centres in its structure.

Comparison of adsorption potential of methylene blue and 17β-stradiol on biochar, activated biochar and catalytic biochar from lignocellulosic waste

This work compares the adsorption capacity of methylene blue (MB) and 17β-stradiol (17β-S) onto biochar (B), activated biochar (AB) and catalytic biochar (CB), obtained through pyrolysis of residual lignin of the second-generation (2G) ethanol production process from a sugarcane industry. K2CO3 was used as activating agent and catalyst. Biochars were characterized by the techniques of point of zero charge, nitrogen adsorption and desorption, SEM and FTIR. Kinetic, isothermal and thermodynamic adsorption studies were carried out. Biochars behaved according to the pseudo-second order (PSO) kinetic model, with similar removal percentages of MB using AB and CB. In contrast, AB showed significantly higher removal percentages of 17β-S than CB. The Sips model agreed to isothermal adsorption data of 17β-S onto all biochars. For MB adsorption, Freundlich model agreed to data using B and AB, and Langmuir model was more suitable for CB. The process was viable, spontaneous, endothermic and showed increase in entropy, except for 17β-S adsorption onto CB. Consequently, the activated and catalytic pyrolysis processes increased the adsorptive potential of biochar derived from 2G lignocellulosic residue. Finally, CB and AB obtained significant removal percentage values of MB (85.8–99.3 %) and 17β-S (37.6–76.7 %), where CB is favorable due to its simpler preparation steps.

Biochar-alginate beads derived from argan nutshells for effective methylene blue removal: A sustainable approach to wastewater treatment

This study explores the use of biochar derived from Argan Nutshells as a core component in alginate beads for the removal of methylene blue (MB) from aqueous solutions. The characterization of BC/Alg composite was conducted using techniques like Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-Ray diffraction (XRD), and size distribution to assess its structural properties and confirm the strong interaction between both components. The adsorbent exhibited surface functional groups characteristic of both biochar and alginate, and SEM confirmed the spherical morphology of the beads. A response surface methodology (RSM) was used to optimize the adsorption process by evaluating the effects of key parameters including pH, temperature, adsorbent mass, and dye concentration. The results showed that the BC/Alg effectively removed 96.4 % of MB. The pseudo-second order (PSO) kinetic model best described the MB removal process (R2 = 0.9990), while the Langmuir isotherm model accurately represented the adsorption equilibrium (R2 = 0.96879). After four cycles of regeneration trials, BC/Alg retained 82 % MB removal efficiency, indicating high reusability and stability. The remarkable adsorption capability of BC/Alg showed that it may be employed as an economical and environmentally friendly adsorbent in aqueous solutions, strengthening the case for employing Argan nutshells for water treatment.

A CIRCULAR ECONOMY APPROACH TO PRODUCE LOW-COST BIODIESEL USING AGRO-INDUSTRIAL AND PACKING WASTES FROM MEXICO: VALORIZATION, HOMOGENEOUS AND HETEROGENEOUS REACTION ROUTES AND PRODUCT CHARACTERIZATION

This manuscript describes a circular economy approach to produce low-cost biodiesel using Tetra Pak (TP) and Mexican biomass wastes. Lipids were extracted from non-edible biomass with hexane. Corozo seeds contained 53 wt% lipids, while remaining biomass had <5 wt%. Corozo seed oil was selected to produce biodiesel with both homogeneous and heterogeneous reaction systems. A heterogeneous catalyst was synthesized from TP and its performance was compared with KOH in homogeneous systems using corozo and soybean oils. The best reaction conditions were identified through the Signal/Noise ratio analysis. TP catalyst achieved biodiesel yields of 12.7-98.11% (corozo) and 87.0-98.4% (soybean), while KOH systems showed 7.2-96.3% and 64.6-98.5%, respectively. These reactive systems were endothermic and fit to pseudo-second order kinetic model. Activation energies for KOH-catalyzed systems were 86.89 (corozo) and 43.72 (soybean) kJ/mol, while TP-catalyzed systems showed 78.31 and 105.68 kJ/mol, respectively. TP catalyst reuse was tested, and the loss of catalytic activity was attributed to active sites poisoning. Biomass, catalysts, and reaction products were characterized (e.g., FTIR, ICP, XRD, EDX-SEM, WDXRF, XPS, basicity and nitrogen adsorption isotherms). The TP catalyst showed competitive performance with respect to KOH, contributing to a sustainable biodiesel production chain viable for commercial implementation in Mexico.