Proximity-induced Interactions Research Articles

Optical spectrum of n-type and p-type monolayer MoS2 in the presence of proximity-induced interactions

In this paper, we examined the effects of proximity-induced interactions such as Rashba spin-orbit coupling and effective Zeeman fields (EZFs) on the optical spectrum of n-type and p-type monolayer (ML)-MoS2. The optical conductivity is evaluated using the standard Kubo formula under random-phase approximation by including the effective electron–electron interaction. It has been found that there exist two absorption peaks in n-type ML-MoS2 and two knife shaped absorptions in p-type ML-MoS2, which are contributed by the inter-subband spin-flip electronic transitions within conduction and valence bands at valleys K and K′ with a lifted valley degeneracy. The optical absorptions in n-type and p-type ML-MoS2 occur in THz and infrared radiation regimes and the position, height, and shape of them can be effectively tuned by Rashba parameter, EZF parameters, and carrier density. The interesting theoretical predictions in this study would be helpful for the experimental observation of the optical absorption in infrared to THz bandwidths contributed by inter-subband spin-flip electronic transitions in a lifted valley degeneracy monolayer transition metal dichalcogenides system. The obtained results indicate that ML-MoS2 with the platform of proximity interactions make it a promising infrared and THz material for optics and optoelectronics.

Subgap states and quantum phase transitions in one-dimensional superconductor–ferromagnetic insulator heterostructures

We theoretically study the spectral properties of a one dimensional semiconductor-superconductor-ferromagnetic insulator (SE-SU-FMI) hybrid nanostructure, motivated by recent experiments where such devices have been fabricated using epitaxial growing techniques. We model the hybrid structure as a one-dimensional single-channel semiconductor nanowire under the simultaneous effect of two proximity-induced interactions: superconducting pairing and a (spatially inhomogeneous) Zeeman exchange field. The coexistence of these competing mechanisms generates a rich quantum phase diagram and a complex subgap Andreev bound state (ABS) spectrum. By exploiting the symmetries of the problem, we classify the solutions of the Bogoliubov-de Gennes equations into even and odd ABS with respect to the spatial inversion symmetry $x\ensuremath{\rightarrow}\ensuremath{-}x$. We find the ABS spectrum of the device as a function of the different parameters of the model: the length $L$ of the coexisting SU-FMI region, the induced Zeeman exchange field ${h}_{0}$, and the induced superconducting coherence length $\ensuremath{\xi}$. In particular we analyze the evolution of the subgap spectrum as a function of the length $L$. Interestingly, we generically find spin-polarized ABS emerging in the subgap region, which, depending on the ratio ${h}_{0}/\mathrm{\ensuremath{\Delta}}$, can eventually cross below the Fermi energy at certain critical values ${L}_{c}$, and induce spin- and fermion parity-changing quantum phase transitions. We argue that this type of device constitute a promising highly-tunable platform to engineer subgap ABS.

Terahertz optical Hall effect in p-type monolayer hexagonal boron nitride on fused silica substrate.

We demonstrate for the first time, to the best of our knowledge, that the optical Hall effect (OHE) can be observed in p-type monolayer (ML) hexagonal boron nitride (hBN) on a fused silica substrate by applying linearly polarized terahertz (THz) irradiation. When ML hBN is placed on fused silica, in which the incident pulsed THz field can create local and transient electromagnetic dipoles, proximity-induced interactions can be presented. The Rashba spin-orbit coupling can be enhanced, and the in-plane spin component can be induced, along with the lifting of valley degeneracy. Thus, in the presence of linearly polarized THz radiation, the nonzero transverse optical conductivity (or Hall conductivity) can be observed. We measure the THz transmission through ML hBN/fused silica in the temperature range from 80 to 280 K by using THz time-domain spectroscopy in combination with an optical polarization examination. The Faraday ellipticity and rotation angle, together with the complex longitudinal and transverse conductivities, are obtained. The temperature dependence of these quantities is examined. The results obtained from this work indicate that ML hBN is a valleytronic material, and proximity-induced interactions can lead to the observation of OHE in the absence of an external magnetic field.

Spin polarization in monolayer MoS2 in the presence of proximity-induced interactions

When monolayer (ML) MoS2 is placed on a substrate, the proximity-induced interactions such as the Rashba spin-orbit coupling (RSOC) and exchange interaction (EI) can be introduced. Thus, the electronic system can behave like a spintronic device. In this study, we present a theoretical study on how the presence of the RSCO and EI can lead to the band splitting, the lifting of the valley degeneracy and to the spin polarization in [Formula: see text]- and [Formula: see text]-type ML MoS2. We find that the maxima of the in-plane spin orientation in the conduction and valence bands in ML MoS2 depend on the Rashba parameter and the effective Zeeman field factor. At a fixed Rashba parameter, the minima of the split conduction band and the maxima of the split valence band along with the spin polarization in ML MoS2 can be tuned effectively by varying the effective Zeeman field factor. On the basis that the EI can be induced by placing the ML MoS2 on a ferromagnetic substrate or by magnetic doping in ML MoS2, we predict that the interesting spintronic effects can be observed in [Formula: see text]- and [Formula: see text]-type ML MoS2. This work can be helpful to gain an in-depth understanding of the basic physical properties of ML MoS2 for application in advanced electronic and optoelectronic devices.

Terahertz optical Hall effect in monolayer MoS2 in the presence of proximity-induced interactions

The effect of proximity-induced interactions such as Rashba spin-orbit coupling (SOC) and exchange interaction on the electronic and optical properties of n-type monolayer (ML) ${\mathrm{MoS}}_{2}$ is investigated. We predict and demonstrate that the Rashba SOC can induce an in-plane spin splitting with terahertz (THz) energy, while the exchange interaction lifts the energy degeneracy in different valleys. Thus, spin polarization can be achieved in an n-type ML ${\mathrm{MoS}}_{2}$ and valley Hall or optical Hall effect can be observed using linearly polarized THz radiation. In such a case, the transverse optical conductivity ${\ensuremath{\sigma}}_{xy}(\ensuremath{\omega})$ results from spin-flip transition within spin-split conduction bands and from the fact that contributions from electrons with different spin orientations in different valleys can no longer be canceled out. Interestingly, we find that for fixed effective Zeeman field (or exchange interaction) the lowest spin-split conduction band in ML ${\mathrm{MoS}}_{2}$ can be tuned from one in the $K$ valley to another one in the ${K}^{\ensuremath{'}}$ valley by varying the Rashba parameter ${\ensuremath{\lambda}}_{R}$. Therefore, by changing ${\ensuremath{\lambda}}_{R}$ we can turn the sign of the spin polarization and $\mathrm{Im}{\ensuremath{\sigma}}_{xy}(\ensuremath{\omega})$ from positive to negative. Moreover, we find that the dominant contribution of the selection rules to ${\ensuremath{\sigma}}_{xx}(\ensuremath{\omega})$ is from electrons in the $K$ valley and to ${\ensuremath{\sigma}}_{xy}(\ensuremath{\omega})$ is from electrons in the ${K}^{\ensuremath{'}}$ valley. These important and interesting theoretical findings can be helpful to experimental observation of the optical Hall effect in valleytronic systems using linearly polarized THz radiation fields.

Colorimetric Detection of Aliphatic Alcohols in β-Cyclodextrin Solutions.

The sensitive, selective, and practical detection of aliphatic alcohols is a continuing technical challenge with significant impact in public health research and environmental remediation efforts. Reported herein is the use of a β-cyclodextrin derivative to promote proximity-induced interactions between aliphatic alcohol analytes and a brightly colored organic dye, which resulted in highly analyte-specific color changes that enabled accurate alcohol identification. Linear discriminant analysis of the color changes enabled 100% differentiation of the colorimetric signals obtained from methanol, ethanol, and isopropanol in combination with BODIPY and Rhodamine dyes. The resulting solution-state detection system has significant broad-based applicability because it uses only easily available materials to achieve such detection with moderate limits of detection obtained. Future research with this sensor system will focus on decreasing limits of detection as well as on optimizing the system for quantitative detection applications.

Covariant Conservation Laws and the Spin Hall Effect in Dirac-Rashba Systems.

We present a theoretical analysis of two-dimensional Dirac-Rashba systems in the presence of disorder and external perturbations. We unveil a set of exact symmetry relations (Ward identities) that impose strong constraints on the spin dynamics of Dirac fermions subject to proximity-induced interactions. This allows us to demonstrate that an arbitrary dilute concentration of scalar impurities results in the total suppression of nonequilibrium spin Hall currents when only Rashba spin-orbit coupling is present. Remarkably, a finite spin Hall conductivity is restored when the minimal Dirac-Rashba model is supplemented with a spin-valley interaction. The Ward identities provide a systematic way to predict the emergence of the spin Hall effect in a wider class of Dirac-Rashba systems of experimental relevance and represent an important benchmark for testing the validity of numerical methodologies.

Approaching quantum anomalous Hall effect in proximity-coupled YIG/graphene/h-BN sandwich structure

Quantum anomalous Hall state is expected to emerge in Dirac electron systems such as graphene under both sufficiently strong exchange and spin-orbit interactions. In pristine graphene, neither interaction exists; however, both interactions can be acquired by coupling graphene to a magnetic insulator as revealed by the anomalous Hall effect. Here, we show enhanced magnetic proximity coupling by sandwiching graphene between a ferrimagnetic insulator yttrium iron garnet (YIG) and hexagonal-boron nitride (h-BN) which also serves as a top gate dielectric. By sweeping the top-gate voltage, we observe Fermi level-dependent anomalous Hall conductance. As the Dirac point is approached from both electron and hole sides, the anomalous Hall conductance reaches ¼ of the quantum anomalous Hall conductance 2e2/h. The exchange coupling strength is determined to be as high as 27 meV from the transition temperature of the induced magnetic phase. YIG/graphene/h-BN is an excellent heterostructure for demonstrating proximity-induced interactions in two-dimensional electron systems.

Interaction proximity effect at the interface between a superconductor and a topological insulator quantum well

A material whose electrons are correlated can affect electron dynamics across the interface with another material. Such a ``proximity effect'' can have several manifestations, from order parameter leakage to generated effective interactions. The resulting combination of induced electron correlations and their intrinsic dynamics at the surface of the affected material can give rise to qualitatively new quantum states. For example, the leaking of a superconducting order parameter into certain Rashba spin-orbit-coupled materials has been recently identified as a path to creating ``topological superconductors'' that can host Majorana particles of use in quantum computing. Here we analyze the other aspects of the superconducting proximity effect. The proximity-induced interactions are a promising path to incompressible quantum liquids with non-Abelian fractional quasiparticles in topological insulator quantum wells, which could also find applications in topological quantum computing. We discuss the operational and design principles of a heterostructure device that could realize such states. We apply field-theoretical methods to characterize the properties of induced interactions via the electron-phonon coupling and Cooper pair tunneling across the interface. We argue that bound-state Cooper pairs can be stabilized by the interaction proximity effect inside a topological insulator quantum well at experimentally observable energy scales. The condensation of spinful triplet pairs, enabled by the Rashba spin-orbit coupling and tunable by gate voltage, would lead to novel superconducting states and fractional topological insulators.