Proton Events Research Articles

Copper(I)‐Catalyzed Asymmetric 1,4‐Hydroarsination of α,β‐Unsaturated Compounds

Herein, a copper(I)‐catalyzed asymmetric 1,4‐hydroarsination of β‐substituted α,β‐unsaturated esters is achieved in moderate to excellent yields with high to excellent enantioselectivity, based on the proposed nucleophilic [Cu]‐AsPh2 species. As for α‐substituted α,β‐unsaturated esters, a 1,4‐hydroarsination/enantioselective protonation event occurs smoothly in satisfying results. Furthermore, β‐substituted α,β‐unsaturated ketone, α,β‐unsaturated amide, and α,β‐unsaturated phosphine sulfide are well applied in the present catalytic system. Finally, some control experiments show that HAsPh2 is activated through coordination with the copper(I) catalyst and HAsPh2 exhibits inferior soft Lewis basicity to HPPh2 in the presence of a copper(I)‐bisphosphine complex.

Copper(I)‐Catalyzed Asymmetric 1,4‐Hydroarsination of α,β‐Unsaturated Compounds

Herein, a copper(I)‐catalyzed asymmetric 1,4‐hydroarsination of β‐substituted α,β‐unsaturated esters is achieved in moderate to excellent yields with high to excellent enantioselectivity, based on the proposed nucleophilic [Cu]‐AsPh2 species. As for α‐substituted α,β‐unsaturated esters, a 1,4‐hydroarsination/enantioselective protonation event occurs smoothly in satisfying results. Furthermore, β‐substituted α,β‐unsaturated ketone, α,β‐unsaturated amide, and α,β‐unsaturated phosphine sulfide are well applied in the present catalytic system. Finally, some control experiments show that HAsPh2 is activated through coordination with the copper(I) catalyst and HAsPh2 exhibits inferior soft Lewis basicity to HPPh2 in the presence of a copper(I)‐bisphosphine complex.

Predicting the Energetic Proton Flux with a Machine Learning Regression Algorithm

The need for real-time monitoring and alerting systems for space weather hazards has grown significantly in the last two decades. One of the most important challenges for space mission operations and planning is the prediction of solar proton events (SPEs). In this context, artificial intelligence and machine learning techniques have opened a new frontier, providing a new paradigm for statistical forecasting algorithms. The great majority of these models aim to predict the occurrence of an SPE, i.e., they are based on the classification approach. This work is oriented toward the successful implementation of onboard prediction systems, which is essential for the future of space exploration. We present a simple and efficient machine learning regression algorithm that is able to forecast the energetic proton flux up to 1 hr ahead by exploiting features derived from the electron flux only. This approach could be helpful in improving monitoring systems of the radiation risk in both deep space and near-Earth environments. The model is very relevant for mission operations and planning, especially when flare characteristics and source location are not available in real time, as at Mars distance.

Optimization of the Electron Spectrometer Telescope geometry for the PRESET satellite through Monte Carlo simulation

The Electron Spectrometer Telescope (EST) aboard the PRESET satellite mission aims to measure the pitch angle distribution of 0.3–4 MeV electrons in the outer Van Allen belts. The PRESET satellite is planned to launch into a sun-synchronous low Earth orbit in Q2, 2026. We present comprehensive Monte Carlo simulations to optimize the design and response of the EST instrument. The EST consists of a stack of silicon strip detectors and a collimator to take pitch-angle dependent electron spectral measurements with a target angular resolution of 6° while rejecting the proton, heavy ion and gamma detection events. Various collimator designs and detector stacking configurations are investigated using the Geant4 code to deduce an optimal design and configuration. For validation of the Geant4 simulations, a benchmark test spectrometer was set up using a stack of four silicon detectors and a good agreement between the measured and simulated responses was found for a beta spectrum from a 90Sr/90Y source. The collimator design was optimized by adjusting total length, aperture size, number of view-ports and collimator materials. The optimum aperture size and the number of view-ports were determined by varying them and selecting the best cases that meet the angular resolution and the geometric factor requirements. Moreover, to address the under-utilization of the front position-sensitive detector encountered in a typical pin-hole collimator, two offset collimators with tilted axes were employed. Extensive simulations were carried out by varying the number of silicon detectors and the thickness of each detector to optimize the configuration of the silicon detector stack. An optimum thickness of the front detector was found to be 140 µm, which can minimize the perturbation counts caused by the proton detection events. For the other detectors, a stack of four 1.5 mm thick detectors was chosen to achieve a good sensitivity to low energy electrons at a tolerable complexity of the system. The angular response simulated for the optimum design of the EST showed a resolution of 5.5°, which is slightly better than the target resolution of 6°. The response matrices of the final design simulated for isotropic electron and proton fields showed a high geometric factor, which is expected to produce an average electron counting rate of 230 cps within the trapped region with a negligible contamination of the electron spectrum by protons except for a mild contamination by the 1.0–1.1 MeV protons.

Impact Pattern of Energetic Particle Precipitation on Polar Mesospheric Ozone

AbstractThe upper atmosphere of polar regions exhibits two distinct patterns of energetic particle precipitation that can lead to ozone destruction by ionizing the atmosphere: one is the energetic proton precipitation in the polar cap region during solar proton events (SPEs), and the other is the energetic electron precipitations (EEPs) in the auroral oval region from the radiation belt. In this study, we conduct case studies and statistical analyses of ozone observations from the Aura satellite to present the quantitative difference in the impact patterns of SPEs and EEPs on polar mesospheric ozone. According to our statistical analysis of 13 SPEs and 19 EEPs during the MLS time frame, the magnitude of ozone depletion during SPEs is greater than during EEPs. The ozone depletion during SPEs is more pronounced at higher geomagnetic latitudes and negatively correlates with the proton flux, while during EEPs the ozone depletion is more in favor of the geomagnetic latitude band of 60–70° but independent of the electron count rates. In addition, hydroxyl enhancement also exhibits different patterns during SPEs and EEPs, similar to that of ozone depletion. This study further validates the physical link between the magnetosphere and atmosphere and promotes our understanding of the solar influence on Earth's climate.

The Mean Free Path of 13–64 MeV Protons Derived from Statistical Results of Solar Energetic Particle Events

A recent study by Wang et al. investigated gradual solar proton events with energies >10 MeV, as observed by STEREO-A, STEREO-B, and the Solar and Heliospheric Observatory spacecraft. For each event, the spacecraft with the best magnetic connection to the source region among the three spacecraft was identified, and energetic proton intensities observed by the spacecraft were analyzed through fitting. The fitting process produced two parameters, b and c, for four energy channels (13–16 MeV, 20–25 MeV, 32–40 MeV, and 40–64 MeV) in each event. Parameters b and c govern the rise and decay of particle intensities, respectively. Statistical analysis revealed a power-law correlation between b and c, expressed as c ∼ b −γ . In this study, in order to explain the relation between the two parameters, we investigate the model of particle diffusion coefficients in the interplanetary space. In our simulations, the radial mean free path is modeled as a power function of radial distance, successfully reproducing the b–c relation. Consequently, the observations demonstrate that the radial mean free path varies with radial distance in a power law. In future research, the model of diffusion coefficients holds promise in determining the mean free path of energetic protons.

A treatment of the all-clear problem for solar energetic particle events and subsequent decision making

We discuss the relatively overlooked problem of All Clear in Solar Energetic Particle (SEP) event prediction. These proton and heavier ion events are injected in major solar eruptions, propagate directionally into the heliosphere at relativistic speeds and threaten equipment and personnel at low-Earth orbit and beyond. SEPs are rare to extreme events associated with solar flares and coronal mass ejections (CMEs), with one SEP event detected in-situ every several hundreds of flares and CMEs observed remotely. This abysmal overall association improves drastically to below 1:2 for fast (i.e., shock-fronted) and halo (i.e., propagating mainly along the Sun–Earth line) CMEs. All Clear implies an assessment of tolerable conditions within a preset prediction window. Relying on one of the most comprehensive data sets for SEP events, we implement a methodology that provides an All Clear for events of NOAA severity S1 and above (S1+) and identify the minimal eruption attributes (flare size and CME speed) that could give rise to such SEP events from source locations in the Sun. The results correspond to and reflect settings of minimum complexity, giving rise to different attributes for different longitudinal zones in the earthward solar hemisphere. This work presents proof of concept; complexity can be increased at will for more demanding All Clear definitions, subject only to sufficient statistics due to the scarcity of the phenomenon. At this point, feedback is desired from stakeholders on what fits their definition of All Clear (we expect different definitions from different operators), so that to define the precise settings on which to run this and similar exercises.

Criteria for Forcast of Proton Events by Real-Time Solar Observations

The sequence of overcoming threshold values of a number of physical characteristics for proton event forecast in real time is discussed. Each characteristic adds a new physical meaning that refines the forecast. To take into account all the characteristics, the following continuous patrol observations are necessary: 1) the magnetic field of the active region (ascent of the flux) and the general magnetic field of the Sun, which can predict the onset of flare activity several days before the main events; 2) soft X-ray radiation in two channels to calculate the temperature (T) and the measure emission of plasma, which can show the preheating to T 10 MK required to begin proton acceleration (the first minutes before the start of hard X-ray (HXR) radiation with energies 100 keV); 3) HXR radiation 100 keV or microwave radiation (3 GHz), which indicate the intensity and duration of operation of the electron accelerator (units and tens of minutes before the arrival of protons with energies 100 MeV); 4) radio emission at plasma frequencies ( 1000 MHz), showing the development of the flare process upward into the corona and leading to a coronal mass ejection (CME) several minutes before the onset of radio bursts of types II and IV (the first tens of minutes before the appearance of a CME in the field of view of the coronagraph); 5) the direction and speed of CME propagation, which determine the conditions for the release of accelerated protons into the heliosphere. These stages of solar proton flares are illustrated by observations of proton events on August 2—9, 2011. To quantitatively predict the onset time, maximum and magnitude of the proton flux, as well as its fluence, it is necessary to create statistical regression models based on all of the listed characteristics of past solar proton events.

Characterizing High-Energy Solar Proton Events with Energies Below and Above 100 MeV

We analyzed 58 high-energy proton events that occurred during the years 1996 – 2022. In 32 out of the 58 (55%) events, the proton energies extended up to ∼68\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$\\sim 68$\\end{document} MeV but did not reach 100 MeV. In the remaining 26 events, the proton energies exceeded 100 MeV. We studied the differences in the characteristics of these proton events and their associations with solar and interplanetary phenomena to improve understanding proton sources and acceleration processes.The coronal mass ejections (CMEs) associated with >100\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$>100$\\end{document} MeV proton events appeared to be, on average, more energetic than those associated with <100\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$< 100$\\end{document} MeV proton events. The peak and integrated fluxes (fluence) of the soft X-ray (SXR) flares were higher in > 100 MeV proton events, but there was almost no difference in the rise times of the flares. In a major part of the >100\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$> 100$\\end{document} MeV proton events, protons were released over the rise phase of the SXR flares, whereas in most of the <100\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$<100$\\end{document} MeV events the proton releases occurred after the peak of the SXR flares. We established limits for the CME speed VCME and SXR peak flux Fpk or total fluence Fi, which helped us to distinguish the events in the two groups. Solar eruptions with VCME>1000\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$> 1000$\\end{document} km s−1 and F>pk5⋅10−5\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$_{\\mathrm{pk}} > 5 \\cdot 10^{-5} $\\end{document} W m−2 had a high probability to produce proton events of >100\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$> 100$\\end{document} MeV. On the other hand, eruptions with V>CME900\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$_{\\mathrm{CME}} > 900$\\end{document} km s−1 and F<i5⋅10−4\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$_{i} <5 \\cdot 10^{-4} $\\end{document} J m−2 and eruptions with V<CME900\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$_{ \\mathrm{CME}} < 900$\\end{document} km s−1 irrespective of the SXR total fluence were very likely to produce proton events of <100\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$< 100$\\end{document} MeV.All proton events were associated with decametric Type III radio bursts, and most of them had Type II bursts associations either in metric or decametric–hectometric (DH) wavelengths or both. Both metric- and DH-Type II emissions were observed in 50% of <100\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$<100$\\end{document} MeV proton events while they were observed in 88% of >100\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$>100$\\end{document} MeV events. Our analysis showed that protons in most of the >100\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$>100$\\end{document} MeV events were released low in the corona (≤3.0\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$\\leq 3.0$\\end{document} R⊙) before the onsets of the DH-Type II radio bursts. Conversely, protons in most of the <100\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$<100$\\end{document} MeV events were released higher in the corona (>3\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$>3$\\end{document} R⊙) and after the DH-Type II onsets.We conclude that protons in most of the >100\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$> 100$\\end{document} MeV events are accelerated either by the flare reconnection processes or by shocks low in the corona and could undergo reacceleration higher in the corona in CME shocks manifested in DH-Type II radio emission. In the <100\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$<100$\\end{document} MeV events, protons are mainly accelerated in CME shocks at coronal heights >3\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$>3$\\end{document} R⊙.

The “SEP Clock”: A Discussion of First Proton Arrival Times in Wide-Spread Solar Energetic Particle Events

This work analyzes the appearance of wide-spread deka-MeV solar energetic proton (SEP) events, in particular the arrival of the first protons within ≈ 4.5 – 45 MeV measured at Earth–Sun L1, and their relationship with their relative solar source longitude. The definition of “wide-spread SEP event” for this study refers to events that are observed as a 25 MeV proton intensity increase at near 1 AU locations that are separated by at least 130∘ in solar longitude. Many of these events are seen at all three of the spacecraft, STEREO (Solar-Terrestrial Relations Observatory) A, STEREO B, and SOHO (Solar and Heliospheric Observatory), and may therefore extend far beyond 130∘ in longitude around the Sun. A large subset of these events have already been part of a study by Richardson et al. (Solar Phys., 289, 3059, 2014). The event source region identifications draw from this study; more recent events have also been added. Our focus is on answering two specific questions: (1) What is the maximum longitude over which SEP protons show energy dispersion, i.e., a clear sign of arrival of higher-energy protons before those of lower energy? (2) What implications can be drawn from the ensemble of events observed regarding either direct magnetic connectivity to shocks and/or cross-field transport from the site of the eruption in the onset phase of the event?

Electrodes Modified with Overlayers for Enhanced CO2 Reduction Selectivity

Like many electrocatalytic reactions involving the transfer of multiple protons and electrons, the CO2 reduction reaction frequently exhibits poor selectivity among many possible products. In this presentation, I will describe our laboratory’s efforts to design electrochemical platforms that enable the control over proton transfer dynamics to electrocatalysts using molecular and polymeric overlayers with the goal of increasing product selectivity and understanding reaction mechanism. This platform is generally applicable to both molecular and metallic systems, and we demonstrate how it can be used to improve the selectivity of nonprecious metal O2 reduction and NO3 - reduction catalysts.For the CO2 reduction reaction, this strategy as applied to metal electrodes is also broadly germane and is used to modulate catalyst reactivity such that it results in the selective production of ethylene, ethanol, methanol, carbon monoxide, and methane, with examples for each with Faradaic efficiencies in excess of 70%. A common theme is that the hydrophobicity of the metal-overlayer interface frequently controls product selectivity and can steer the site of protonation events at intermediates. In this manner, for example, the selectivity of catalysts between the C2 products ethanol and ethylene can be dictated. To aid in mechanistic understanding and catalyst characterization, the majority of these studies are conducted on nominally flat metal electrodes. However, we will also describe ongoing efforts to nanostructure these CO2 reduction systems to develop selective catalysts that operate at high current densities.

Mesospheric Ozone Depletion during 2004–2024 as a Function of Solar Proton Events Intensity

Solar proton events (SPEs) affect the Earth’s atmosphere, causing additional ionization in the high-latitude mesosphere and stratosphere. Ionization rates from such solar proton events maximize in the stratosphere, but the formation of ozone-depleting nitrogen and hydrogen oxides begins at mesospheric altitudes. The destruction of mesospheric ozone is associated with protons with energies of about 10 MeV and higher and will strongly depend on the intensity of the flux of these particles. Most studies investigating the impact of SPEs on the characteristics of the middle atmosphere have been based on either simulations or reanalysis datasets, and some studies have used satellite observations to validate model results. We study the impact of SPEs on cold-season ozone loss in both the northern and southern hemispheres using Aura MLS mesospheric ozone measurements over the 2004 to 2024 period. Here, we show how strongly SPEs can deplete polar mesospheric ozone in different hemispheres and attempt to evaluate this dependence on the intensity of solar proton events. We found that moderate SPEs consisting of protons with an energy of more than 10 MeV and a flux intensity of more than 100 pfu destroy mesospheric ozone in the northern hemisphere up to 47% and in the southern hemisphere up to 33%. For both hemispheres, the peak of winter ozone loss was observed at about 76 km. In the northern hemisphere, maximum winter ozone loss was observed on the second day after a solar proton event, but in the southern hemisphere, winter ozone depletion was already detected on the first day. In the southern hemisphere, mesospheric ozone concentrations return to pre-event levels on the ninth day after a solar proton event, but in the northern hemisphere, even on the tenth day after a solar proton event, the mesospheric ozone layer may not be fully recovered. The strong SPEs with a proton flux intensity of more than 1000 pfu lead to a maximum winter ozone loss of up to 85% in the northern hemisphere, and in the southern hemisphere winter, ozone loss reaches 73%.

A Real‐Time Prediction System of the Intensity of Solar Energetic Proton Events Based on a Solution of the Diffusion Equation

AbstractIn this study, based on solar energetic particle (SEP) events classification and a solution of the diffusion equation, we present an efficient system, HITSEP, to predict the intensities in different energy channels (P4 15.0–44.0 MeV, P5 40.0–80.0 MeV, and P6 80.0–165.0 MeV) of energetic proton events observed by GOES spacecraft. The system can predict the rising phase (especially the peak time and peak intensity) of the energetic proton events using only a small amount of data at the beginning of the solar energetic proton events. Among the events that meet the conditions for the use of our prediction system from 2003 to 2017, for P4, P5, and P6 channels, the median Warning Times are 3.70, 2.52, and 1.69 hr; the median Error of the Intensity for events are 0.43, 0.23, 0.34 orders of magnitude; the median Error of the Peak Time for events are 2.53, 0.55, 0.43 hr, respectively. Our system is based on physical mechanisms and has a high accuracy in forecasting the peak intensity with a strict definition of the error. The HITSEP system has huge potential to apply in the space weather forecast. The application of the HITSEP system in space weather forecasting is very promising.

Numerical Simulation of Equal Ratio Relations for the Peak Intensities of >10 MeV Energetic Protons

Previous studies have highlighted the significance of perpendicular diffusion in the decay phase of particle intensities for >10 MeV energetic protons. Recently, an observational study has indicated that the peak intensity ratios across different energy channels (13−64 MeV protons) remain almost constant as the spacecraft location varies in many solar proton events. This interesting phenomenon is referred to as equal ratio relations. These findings suggest that perpendicular diffusion not only affects particle intensity during the decay phase but also throughout the rising phase. In this study, we perform numerical simulations of >10 MeV energetic proton events observed by STEREO A, STEREO B, and the Solar and Heliospheric Observatory. Our findings demonstrate that perpendicular diffusion strongly affects the entire time profile of particle intensity for spacecraft not magnetically connected to the source region. The numerical simulation results indicate that in order to reproduce observations, we need to include perpendicular diffusion near the source region and in interplanetary space. Perpendicular diffusion leads to nearly uniform peak ratios at different locations and contributes to the formation of the reservoir phenomenon during the decay phase. Consequently, these numerical results support the significant role of perpendicular diffusion in the formation of the longitudinal distribution of >10 MeV proton events.

Neutrino oscillations with atmospheric neutrinos at large liquid argon TPCs

We propose to study atmospheric neutrino interactions with a unique event topology to distinguish neutrinos and anti-neutrinos using a liquid argon time projection chamber in an experiment such as DUNE. The detection of charged-current 1 proton (CC1P) and charged-current no proton (CC0P) events will allow us to access neutrino oscillation physics complementary to accelerator-based beam neutrinos. Assuming maximal CP violation (δCP= π/2) as the true hypothesis, our analysis shows that it is possible to disfavour CP conservation δCP=0 (or π) with more than 2σ (≈ 1.6σ) with a data sample of 140 kt-yr of atmospheric neutrinos in the DUNE detector. Our analysis also shows that assuming normal mass-ordering as the true hypothesis, the sensitivity to the opposite mass-ordering can be disfavoured with a significance close to 4σ and an octant of θ23 sensitivity with more than 2σ both for a true lower octant (θ23=41∘) and higher octant (θ23=49∘) value.

The solar cycle 25 multi-spacecraft solar energetic particle event catalog of the SERPENTINE project

Context. The solar energetic particle analysis platform for the inner heliosphere (SERPENTINE) project, funded through the H2020-SPACE-2020 call of the European Union’s Horizon 2020 framework program, employs measurements of the new inner heliospheric spacecraft fleet to address several outstanding questions on the origin of solar energetic particle (SEP) events. The data products of SERPENTINE include event catalogs, which are provided to the scientific community. Aims. In this paper, we present SERPENTINE’s new multi-spacecraft SEP event catalog for events observed in solar cycle 25. Observations from five different viewpoints are utilized, provided by Solar Orbiter, Parker Solar Probe, STEREO A, BepiColombo, and the near-Earth spacecraft Wind and SOHO. The catalog contains key SEP parameters for 25–40 MeV protons, ~1 MeV electrons, and ~100 keV electrons. Furthermore, basic parameters of associated flares and type II radio bursts are listed, as are the coordinates of the observer and solar source locations. Methods. An event is included in the catalog if at least two spacecraft detect a significant proton event with energies of 25–40 MeV. The SEP onset times were determined using the Poisson-CUSUM method. The SEP peak times and intensities refer to the global intensity maximum. If different viewing directions are available, we used the one with the earliest onset for the onset determination and the one with the highest peak intensity for the peak identification. We furthermore aimed to use a high time resolution to provide the most accurate event times. Therefore, we opted to use a 1-min time resolution, and more time averaging of the SEP intensity data was only applied if necessary to determine clean event onsets and peaks. Associated flares were identified using observations from near Earth and Solar Orbiter. Associated type II radio bursts were determined from ground-based observations in the metric frequency range and from spacecraft observations in the decametric range. Results. The current version of the catalog contains 45 multi-spacecraft events observed in the period from November 2020 until May 2023, of which 13 events were found to be widespread (observed at longitudes separated by at least 80° from the associated flare location) and four could be classified as narrow-spread events (not observed at longitudes separated by at least 80° from the associated flare location). Using X-ray observations by GOES/XRS and Solar Orbiter/STIX, we were able to identify the associated flare in all but four events. Using ground-based and space-borne radio observations, we found an associated type II radio burst for 40 events. In total, the catalog contains 142 single event observations, of which 20 (45) have been observed at radial distances below 0.6 AU (0.8 AU). It is anticipated that the catalog will be extended in the future.

Radioactivity soundings of the upper atmosphere in Finland 1962-2022

Radioactivity soundings have been performed in Finland since the early 1960s to measure radiation and radioactivity levels in the atmosphere up to the altitude of almost 40 km. A sonde package based on a Geiger‐Müller (GM) tube is carried up to the stratosphere by a balloon filled with hydrogen or helium. En route the GM tube count rate values are sent to the ground station with a radio transmitter. These radioactivity soundings revealed the presence of abnormal radioactivity in the stratosphere over Finland due to Soviet atmospheric nuclear tests in 1962. Between 1964 and 1980 artificial radioactivity in the stratosphere originating from the Chinese nuclear tests were observed too. The radioactivity soundings have brought information on cosmic radiation even if the main motivation has been the surveillance of artificial radioactivity in the upper atmosphere. The effects of the solar cycle, geomagnetic latitude and solar proton events on the radiation environment of the upper atmosphere have been measured. The produced vertical ionization profiles may also be useful in studies concerning ion‐induced or ion‐mediated new particle formation events in the atmosphere.

A novel acidic pH-dependent metacaspase governs defense-response against pathogens in tomato

The importance of metacaspases in programmed cell death and tissue differentiation is known, but their significance in disease stress response, particularly in a crop plant, remained enigmatic. We show the tomato metacaspase expression landscape undergoes differential reprogramming during biotrophic and necrotrophic modes of pathogenesis; also, the metacaspase activity dynamics correlate with the disease progression. These stresses have contrasting effects on the expression pattern of SlMC8, a Type II metacaspase, indicating that SlMC8 is crucial for stress response. In accordance, selected biotic stress-related transcription factors repress SlMC8 promoter activity. Interestingly, SlMC8 exhibits maximum proteolysis at an acidic pH range of 5–6. Molecular dynamics simulation identified the low pH-driven protonation event of Glu246 as critical to stabilize the interaction of SlMC8 with its substrate. Mutagenesis of Glu246 to charge-neutral glutamine suppressed SlMC8's proteolytic activity, corroborating the importance of the amino acid in SlMC8 activation. The glutamic acid residue is found in an equivalent position in metacaspases having acidic pH dependence. SlMC8 overexpression leads to heightened ROS levels, cell death, and tolerance to PstDC3000, and SlMC8 repression reversed the phenomena. However, the overexpression of SlMC8 increases tomato susceptibility to necrotrophic Alternaria solani. We propose that SlMC8 activation due to concurrent changes in cellular pH during infection contributes to the basal resistance of the plant by promoting cell death at the site of infection, and the low pH dependence acts as a guard against unwarranted cell death. Our study confirms the essentiality of a low pH-driven Type II metacaspase in tomato biotic stress-response regulation.

The role of Tyr34 in proton-coupled electron transfer of human manganese superoxide dismutase.

Human manganese superoxide dismutase (MnSOD) plays a crucial role in controlling levels of reactive oxygen species (ROS) by converting superoxide (O2 ●-) to molecular oxygen (O2) and hydrogen peroxide (H2O2) with proton-coupled electron transfers (PCETs). The reactivity of human MnSOD is determined by the state of a key catalytic residue, Tyr34, that becomes post-translationally inactivated by nitration in various diseases associated with mitochondrial dysfunction. We previously reported that Tyr34 has an unusual pKa due to its proximity to the Mn metal and undergoes cyclic deprotonation and protonation events to promote the electron transfers of MnSOD. To shed light on the role of Tyr34 MnSOD catalysis, we performed neutron diffraction, X-ray spectroscopy, and quantum chemistry calculations of Tyr34Phe MnSOD in various enzymatic states. The data identifies the contributions of Tyr34 in MnSOD activity that support mitochondrial function and presents a thorough characterization of how a single tyrosine modulates PCET catalysis.

The Role of Deposition of Cosmogenic 10Be for the Detectability of Solar Proton Events

AbstractThe manifestation of extreme solar proton events (SPEs) in Beryllium‐10 (10Be) ice core data contains valuable information about the strength and incidence of SPEs or local characteristics of the atmosphere. To extract this information, the signals of enhanced production of cosmogenic 10Be due to the SPEs have to be detected, hence distinguished from the variability of the background production by galactic cosmic rays (GCRs). Here, we study the transport and deposition of 10Be from GCRs, using the ECHAM/MESSy Atmospheric Chemistry climate model, and discuss the detectability of extreme SPEs (similar to the CE 774/775 SPE) in 10Be ice core data depending on the ice core location, seasonal appearance of the SPE, atmospheric aerosol size distribution and phase of the 11‐year solar cycle. We find that sedimentation can be a major deposition mechanism of GCR generated 10Be, especially at high latitudes, depending on the aerosols to which 10Be attaches after production. The comparison of our results to four ice core records of 10Be from Greenland and Antarctica shows good agreement for both 10Be from GCRs and solar energetic particles (SEP). From our results we deduce that the location of detection and the season of occurrence of the SPE have a considerable effect on its detectability, as well as the aerosol size distribution the produced cosmogenic nuclides meet in the atmosphere. Furthermore, we find that SPEs occurring in the phase of highest activity during the 11‐year solar cycle are more detectable than SPEs that arise in the phase of lowest activity.