Protected Designation Of Origin Wines Research Articles

Development of two-level Design of Experiments for the optimization of a HS-SPME-GC-MS method to study Greek monovarietal PDO and PGI wines

Aroma is a key element in the description of wine's hedonistic character and commercial value. The volatile compounds that compose a wine's aroma belong to various very different chemical groups and their concentration varies from ppt to ppm. Therefore, the development of an analytical method able to cover such variability is a challenging task. In the present work, arduous method development was applied to reach optimal headspace solid-phase microextraction (HS-SPME) conditions, for the characterization of wine volatilome, by using a two-level screening-to-modelling Design of Experiments (DoE) approach. The optimized and comprehensive HS-SPME-GC-MS protocol was then used for the analysis of seventy wine samples of six monovarietal Greek Protected Designation of Origin (PDO) and Protected Geographical Indication (PGI) white and red wine cultivars (Moschofilero, Assyrtiko, Savvatiano, Malagouzia, Agiorgitiko and Xinomavro). One hundred volatile metabolites were identified and semi-quantified in several concentration ranges according to variety. Fatty acids and their corresponding ethyl esters were found in higher concentrations in the white wines, while higher alcohols were characteristic for the red wines. Differences between the cultivars were evaluated through multivariate statistical analysis and PCA and OPLS-DA models. The results demonstrated that Moschofilero is a very aromatic and floral variety, as it is very rich in terpenic compounds, while Malagouzia and Agiorgitiko were characterized by isoamyl alcohol and ho-trienol, respectively.

Development of a Descriptive Profile and References for the Assessment of Taste and Mouthfeel Descriptors of Protected Designation of Origin Wines.

Producers of PDO (Protected Designation of Origin) wines must submit to the EU authorities’ technical specifications that include the specific sensory description of each product typology, to be subsequently checked by the competent authority in each country. Unfortunately, there is no consensual and standardized approach for the development of sensory control methods for PDO wines. The aim of this work was to develop a sensory profile for the taste and mouthfeel descriptors that allows the characterization of wines from 11 existing PDOs in Catalonia (Spain), and with the purpose of advancing the process of harmonization of the official sensory analysis of wines. This paper includes the selection process of tasters, the procedure used for the definition and grouping of descriptors, and the development of references for the selected attributes. The use of this analytical tool should allow PDO/PGI product certification and control authorities to verify compliance with their specifications (descriptive and quantitative) based on objectively evaluated results.

A geospatial inventory of regulatory information for wine protected designations of origin in Europe

The Wine Protected Designation of Origin (PDO) label is a European quality scheme that protects high quality wines by linking them to legally defined geographic areas and a set of specific production practices. Because of the tight relation between PDO wines and the specifications defined in the official regulatory documents, these products are highly susceptible to changes in climatic, environmental, or socioeconomic conditions. However, the content of these regulatory documents has never been systematically analysed and summarized in a single dataset. Here, we present the first geospatial inventory that organizes regulatory information about the 1177 wine PDO in Europe based on the documents from the official EU geographical indication register. It includes essential legal information that defines the wine PDO such as the geographic boundaries, authorized cultivars and maximum yields. This inventory opens new possibilities for researchers to accurately assess, compare and map the regulatory information in each wine region at an unprecedented level of detail, supporting decision makers in developing adaptation strategies for the preservation of PDO wine regions.

Managerial capabilities and generic business strategies in the wineries of the 'Cava' protected designation of origin

Aim of study: Cava is Spain’s largest wine exporter. However, in the last 20 years, the growth of exports from Cava protected designation of origin (PDO) wineries has been lower than that of other Spanish PDO wines, and Cava’s domestic market share has fallen. From the point of view of strategic management, it could be said that it seems that the wineries of the Cava PDO are losing their competitive advantage. It is therefore fundamental to perform an analysis of the wineries that maintain a better performance to understand the elements that give them a competitive advantage. In this article, to analyse competitive advantage, both management capabilities and Robinson and Pearce’s generic business strategies are studied. The objective is twofold; on the one hand, we pursue the level of the managerial capabilities in the wineries of Cava PDO, while on the other hand, we seek to know the influence of the managerial capabilities and the strategies as reflected in their business performance.Area of study: Spanish wineries of the Cava PDO.Material and methods: Sixty-six wineries were analyzed using the Mann-Whitney U Test and Bayesian regression to determine the relationship between the managerial capabilities, strategy, and business performance.Main results: The results show a lower level of managerial capabilities in Cava PDO wineries as compared with Rioja PDO wineries, a strong relationship between management capabilities and performance.Research highlights: These results are highly applicable since they show what resources and what strategies should be promoted to achieve a competitive advantage.

Volatile and Non-Volatile Characterization of White and Rosé Wines from Different Spanish Protected Designations of Origin

The quality of wines has often been associated with their geographical area of production, as well as the grape variety used in their elaboration. Many research studies have been carried out to characterize and differentiate between red wines labeled with Protected Designation of Origin (PDO) from different geographical areas, but very few have been carried out on white and rosé wines. The objective of this work was to characterize white and rosé PDO wines from different geographical areas of Spain very close to each other elaborated with different grape varieties and select the variables that most contribute to their differentiation. Analysis of variance (ANOVA) and principal component analysis (PCA) were used as statistical methods. The ethanol content was the nonvolatile variable that most contributed to differentiating between some of the white and rosé wines according to their PDO. The white wines from RD (Ribera del Duero) and BI (Bierzo) were characterized by a high terpenic content (floral notes) while the wines from RU (Rueda), TO (Toro) and CI (Cigales)by a high content of ethyl esters and alcohol acetates (fruity aromas). The rosé wines elaborated with the Mencía grape variety from BI were characterized by their highest polysaccharidic content, which could have a positive sensory effect on the mouthfeel. The rosé wines from CI were characterized by their volatile profile complexity, having the highest content of volatile compounds from the oak wood, terpenes and C6 alcohols which provide pleasant woody, floral and herbaceous aromas. On the contrary, the RD wines were richest in alcohol acetates responsible for fruity aromas.

Assessment of UV–visible spectroscopy as a useful tool for determining grape-must caramel in high-quality wine and balsamic vinegars

The addition of E-150d caramel, known as grape-must caramel in vinegars, is a legal but without limitation practice in Spanish wine vinegars, as those with a protected designation of origin (PDO), for unifying the final colour of different batches and barrels. It is also used in the production of ‘Balsamic vinegar of Modena’ vinegars, with a maximum addition fixed at 2% v/v by law. Although its quantification in vinegars was studied by other techniques, there is still not any official method for it. Therefore, UV–vis spectroscopy was assessed as a quick analytical method able to quantify grape-must caramel in Balsamic vinegars of Modena and Spanish PDO wine vinegars. Univariate and multivariate calibrations were assessed for this quantification. Results demonstrated the ability of UV–vis spectroscopy coupled with multivariate calibration in the quantification of grape-must caramel, predicting caramel amounts under 2% v/v in both Balsamic and PDO wine vinegars.

Characterization of the aroma profile and key odorants of the Spanish PDO wine vinegars

The aroma profiles of Spanish wine vinegars with Protected Designation of Origin (PDO) were described and compared for the first time by gas chromatography–mass spectrometry–olfactometry (GC–MS–O), odor-active values (OAVs) and quantitative descriptive analysis (QDA). Vinagre de Jerez Reserva (JRE) showed higher percentage of ‘grassy-vegetal’ impact odorants, while ‘spicy’ compounds highlighted the Pedro Ximénez category (JPX). Vinagre de Montilla-Moriles Reserva (MRE) had ‘buttery-lactic’ impact odorants, while ‘empyreumatic’ and ‘sweet’ aromas stood out for Pedro Ximénez category (MPX). Vinagre de Condado de Huelva Reserva (CRE) showed a stronger percentage of ‘chemical’ impact odorants. The key odorants were ethyl propionate, ethyl octanoate, propanoic acid and 4-ethylphenol for JRE, diacetyl and methional/furfural for JPX, acetoin for MRE, ethyl phenylacetate and vanillin for MPX and acetaldehyde diethyl acetal, isobutyl acetate, ethyl isovalerate and guaiacol for CRE. A good relation among the impact odorants and the sensory descriptors was observed.

Molecular characterization of wine grape cultivars from Calabria

The wine sector is one of the most active and profitable in Italy; Italy is the largest wine producer in the world, followed by Spain and France. For this reason, it is subject to extensive legislative discipline. Calabria ranks sixteenth among Italian regions for wine production; however, in recent years, much effort has been made to promote the wine sector in this region. Nine Calabrian wines are designated as PDO (protected designation of origin) and ten wines as PGI (protected geographical indication). Among the PDO wines, Terre di Cosenza and Ciro are the most famous. Fraud prevention is necessary for consumer protection and for product valorization and promotion. Microsatellite marker analysis represents a reliable and effective tool for varietal characterization, allowing the detection of adulteration in the winemaking process. We sampled 20 grapevine cultivars from different areas of Calabria commonly used for production of the PDO wine Terre di Cosenza and 20 cultivars from other Italian regions in order to carry out a molecular characterization. The analysis was performed through six simple sequence repeat (SSR) markers proposed by the International Organization of Vine and Wine (OIV), VVSS2, VVMD5, VVMD7, VVMD27, VrZAG62, and VrZAG79. Some of the cultivars showed the same molecular profile, revealing the presence of synonymies and incorrect name assignment.

Sampling methods for the study of volatile profile of PDO wine vinegars. A comparison using multivariate data analysis

High-quality wine vinegars have been registered in Spain under protected designation of origin (PDO): “Vinagre de Jerez”, “Vinagre de Condado de Huelva” and “Vinagre de Montilla-Moriles”. The raw material, production and aging processes determine their quality and their aromatic composition. Vinegar volatile profile is usually analyzed by gas chromatography–mass spectrometry (GC–MS), being necessary a previous extraction step. Thus, three different sampling methods (Headspace solid phase microextraction “HS-SPME”, Headspace stir bar sorptive extraction “HSSE” and Dynamic headspace extraction “DHS”) were studied for the analysis of the volatile composition of Spanish PDO wine vinegars. Multivariate curve resolution (MCR) was used to solve chromatographic problems, improving the results obtained. Principal component analysis (PCA) showed that not all the sampling methods were equally suitable for the characterization and differentiation between PDOs and categories, being HSSE the technique that made able the best vinegar characterization.

Characterization and authentication of Spanish PDO wine vinegars using multidimensional fluorescence and chemometrics.

This work assesses the potential of multidimensional fluorescence spectroscopy combined with chemometrics for characterization and authentication of Spanish Protected Designation of Origin (PDO) wine vinegars. Seventy-nine vinegars of different categories (aged and sweet) belonging to the Spanish PDOs "Vinagre de Jerez", "Vinagre de Montilla-Moriles" and "Vinagre de Condado de Huelva", were analyzed by excitation-emission fluorescence spectroscopy. A visual assessment of fluorescence landscapes pointed out different trends with vinegar categories. PARAllel FACtor analysis (PARAFAC) extracted the potential fluorophores and their values in the PDO vinegars. This information, coupled with different classification methods (Partial Least Square Discrimination Analysis "PLS-DA" and Support Vectors Machines "SVM"), was able to discriminate the wine vinegar category within each PDO, for which SVM models obtained better results (>92% of classification). In each category, SVM also allows the differentiation between PDOs. The proposed methodology could be used as an analysis method for the authentication of Spanish PDO wine vinegars.

A Multivariate Methodological Approach to Relate Wine to Characteristics of Grape Composition: The Case of Typicality

Typicality is defined as the characteristics of a Protected Designation of Origin (PDO) wine related to a terroir. In the context of a PDO, a typicality assessment can be used to assess the global quality of a PDO wine. This study used a two-phase method to identify the distinctive characteristics of a PDO wine and then apply those findings to a case study of Chianti Montespertoli DOCG wine, where DOCG is the Italian acronym for PDO. A panel of wine professionals evaluated the typicality of a series of selected PDO wine samples, and a partial least squares (PLS) regression model was used to associate wine typicality and chemical composition. The model was used to predict wine typicality from the chemical composition of experimental wines (2009, 2010, and 2011 vintages) produced from grapes growing in the PDO area. Finally, regression coefficients of the PLS model were analyzed to select which grape chemical parameters were significant in describing the typicality of the wine. These highlight the most important factors to manage during winemaking to ensure the typicality of this wine.

Drivers of high-involvement consumers' intention to buy PDO wines: Valpolicella PDO case study.

This study investigates whether different sensory profiles of wines belonging to the same Protected Designation of Origin (PDO) are perceived as different products by consumers. It identifies the drivers of consumers' intention to buy preferred wines. Descriptive sensory analysis, consumer tests and consumer interviews were conducted to reach research aims. To perform the consumer tests and interviews, 443 consumers participated in the survey. The tasted wines comprised five samples representative of Valpolicella PDO wine. Analysis of variance tests, principal component analysis and linear and logit regressions were employed to verify the research hypotheses. The results demonstrated: (1) different sensory profiles exist within the Valpolicella PDO wine; (2) these sensory profiles result in consumers having the perception of diversified products; (3) the perception of differences was less marked for consumers than for trained assessors due to the different weight attributed to visual, aroma and the taste/mouthfeel hedonic dimensions; and (4) consumers' liking, as well as general perceptions, attitudes, preferences, wine knowledge and experience, contribute to consumers' intentions to buy more than the socio-demographic characteristics of consumers. The analysis of the drivers of consumers' intention to buy certain PDO wines provides new marketing insights into the roles of intrinsic quality, preferences and consumers' subjective characteristics in market segmentation. © 2015 Society of Chemical Industry.

An analytical approach to Sr isotope ratio determination in Lambrusco wines for geographical traceability purposes

Geographical origin and authenticity of food are topics of interest for both consumers and producers. Among the different indicators used for traceability studies, 87Sr/86Sr isotopic ratio has provided excellent results. In this study, two analytical approaches for wine sample pre-treatment, microwave and low temperature mineralisation, were investigated to develop accurate and precise analytical method for 87Sr/86Sr determination. The two procedures led to comparable results (paired t-test, with t<tcrit). Furthermore, the precision of the whole analytical procedure was evaluated by using a control sample (wine sample), processed during each sample batch (calculated Relative Standard Deviation, RSD%, equal to 0.002%. Lambrusco PDO (Protected Designation of Origin) wines coming from four different vintages (2009, 2010, 2011 and 2012) were pre-treated according to the best procedure and their isotopic values were compared with isotopic data coming from (i) soils of their territory of origin and (ii) wines obtained by same grape varieties cultivated in different districts. The obtained results have shown no significant variability among the different vintages of wines and a perfect agreement between the isotopic range of the soils and wines has been observed. Nevertheless, the investigated indicator was not enough powerful to discriminate between similar products. To this regard, it is worth to note that more soil samples as well as wines coming from different districts will be considered to obtain more trustworthy results.

Use of Production Practices and Sensory Attributes to Characterize Loire Valley Red Wines

Quality wines are typically the product of soil, climate, and wine production practices. Sensory attributes are increasingly used to distinguish among Protected Designation of Origin (PDO) wines. Since 2010, the International Organization of Vine and Wine (OIV) is now taking all such parameters into account in the official ‘terroir’ definition. However, links between production practices and sensory attributes in geographically circumscribed PDO areas have not yet been investigated. This paper assesses production practices and sensory attributes of distinct PDO wines, within the same area. The study also identifies relationships between production practices and sensory attributes of these PDO wines. A survey was conducted to characterize production practices of thirty-three commercially produced PDO wines from the Loire Valley, France. Vineyard training systems, viticulture, harvest timing, winemaking and aging practices were studied. Descriptive sensory analysis was conducted to characterize the significant sensory attributes of these same wines. PDO wines were separated from one another by classical statistical analyses. About 25 percent of the analyzed production practices and less than fifty percent of the analyzed sensory attributes could differentiate PDO wines produced in the same area: respectively, percentage of Cabernet franc, time of leaf removal, harvest date, yield, duration of fermentation, duration of aging and use of oak, color intensity, viscosity, cloudiness, blackcurrant, prune, spicy, moldy, animal, bitterness and astringency. The study also identified links between some production practices and sensory attributes. The results of the study demonstrate that, under similar climatic conditions and soil characteristics, production practices and sensory attributes can distinguish PDO wines in well-defined geographic areas.

Antecedents of Consumer Commitment to a PDO Wine: An Empirical Analysis of Spanish Consumers

The purpose of this paper is to examine the antecedents of consumer commitment to a food product with a Protected Designation of Origin (PDO). We analyse the influence of intrinsic and extrinsic perceived quality on consumer satisfaction, consumer trust and consumer commitment. The data were collected through a structured questionnaire given to Spanish consumers of PDO wine from Somontano. After the fieldwork, a PLS model was applied to analyse the relations proposed. The findings confirm that satisfaction and trust are the main drivers of consumer commitment to the PDO. In addition, satisfaction is found to be determined by the intrinsic attributes of quality and trust by the extrinsic attributes of the product. However, no direct influence has been found of extrinsic attributes on satisfaction or of intrinsic attributes on trust. This influence has been found to be mediated by consumer satisfaction.