Current research suggests a link between childhood sexual abuse and risky sexual behaviors (RSBs) in emerging adults. However, previous studies neglect evaluating the influence of high levels of cumulative childhood victimization. The present study examined the relationships among polyvictimization, six aggregate categories of childhood victimization, and RSB in college women. This study first examined the relative contributions of polyvictimization and individual categories of childhood victimization in predicting RSB and then tested whether polyvictimization contributes any unique variance, beyond that accounted for by the combination of all six aggregate categories in a sample of 321 college women in a Southern state. Regression analyses reveal that (a) polyvictimization accounts for a significant proportion of variability in scores for RSB, beyond that accounted for by any of the six categories of childhood victimization alone; (b) the categories of childhood victimization contribute little to no variability beyond that accounted for by polyvictimization; and (c) polyvictimization accounts for a significant proportion of variability in RSB, beyond that already accounted for by the simultaneous entry of all six categories as predictor variables. Results suggest treatment providers working with college students should assess polyvictimization in relation to RSB and inform their prevention efforts given this link.