Analyzing the spatiotemporal changes and influencing factors of carbon emissions generated by land use is of great importance for improving land use structure and promoting regional low-carbon economic development. This study, based on remote sensing and statistical yearbook data from 1995 to 2020, calculated the carbon emissions from land use in Jiangxi Province, China. Multiple spatial analysis methods and the logarithmic mean Divisia index were used to elucidate the spatiotemporal evolution and driving factors of carbon emissions, and the findings revealed the following: (1) The spatiotemporal changes in land use in Jiangxi Province during 1995–2020 were substantial as forest land accounted for 65% of the entire land area, while construction land increased by 98.1%. Cultivated land decreased the most, followed by forest land. (2) There was a fourfold rise in carbon emissions in Jiangxi Province, driven primarily by construction land, and northern areas produced higher carbon emissions compared with central and southern regions. Forest land was the main carbon sink. (3) Economic development (257.36%) and the impact of the proportion of construction land (211.31%) were the primary factors contributing to the increase in carbon emissions from land use, while other factors had inhibitory effects. This study transformed the macroscale low-carbon development strategy of cities into targeted local policies, and the research theories and methods adopted could provide scientific reference for other regions in urgent need of carbon reduction worldwide.