Coupled quantum dots (QDs), referred to as quantum dot molecules (QDMs), have attracted much attention in recent years [1]. Besides the electronic coupling or superradiance effects [2], the properties of QDMs are affected by phonon-related phenomena. In particular, many experiments have shown phonon-assisted excitation transfer [3] between the QDs. For moderate separations between the dots (6 nm) tunneling is exponentially suppressed and the energetically lowest states correspond to spatially direct excitons localized in individual QDs [4]. Such states are bound by the Coulomb interaction via interband dipole moments [5], i.e., by the Forster interaction [6]. Signatures of such coupling were indeed found in a photon-correlation experiment [7]. In this paper we derive a quantum-kinetic description of the evolution of an exciton in a QDM, including the effect of the carrier–phonon coupling. We show that, depending on the parameters, the system can show different dynamical scenarios, ranging from partial pure dephasing to an almost exponential transfer. As we shall see, the transfer may be very fast (on the timescales of several picoseconds), that is, 2–3 orders of magnitude faster than suggested by the existing perturbative estimates [8].
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