Properties Of AZ31 Magnesium Alloy Research Articles

Effects of PEO and BN-PVD coatings on the wear, corrosion, and surface properties of AZ31 magnesium alloy

This study investigates the effects of Plasma Electrolytic Oxidation (PEO) and subsequent Boron Nitride (BN) coatings applied via Physical Vapor Deposition (PVD) on the wear, corrosion, and surface properties of AZ31 magnesium alloy. The AZ31 alloy samples were first coated using the PEO process, forming a ceramic-like layer that enhances surface properties. However, inherent microcracks and pores in PEO coatings can compromise corrosion resistance. To mitigate these issues, a BN layer was applied over the some of PEO coating using RF-PVD, significantly improving wear resistance, corrosion protection, and surface integrity. The coatings were characterized using x-ray diffraction (XRD), scanning electron microscopy (SEM), x-ray photoelectron spectroscopy (XPS), and electrochemical testing. The results indicate that the PEO-BN coatings provide the highest wear resistance, lowest friction coefficient, and most effective barrier against corrosion among the samples tested. These findings highlight the potential of PEO-BN coatings to enhance the durability and performance of magnesium alloys, making them suitable for demanding applications.

Effect of Ceramic Coating on Mechanical Properties of AZ31 Magnesium Alloy

Effect of Ceramic Coating on Mechanical Properties of AZ31 Magnesium Alloy

Improving the mechanical and wear properties of AZ91 magnesium alloy via laser cladded (AlCu)3.5CoCrNiSnx (x = 0 and 1) high entropy alloy coatings

(AlCu)3.5CoCrNiSnx (x = 0 and 1) high entropy alloy (HEA) coatings were prepared on AZ91 magnesium alloy substrate by laser cladding technology. Both the HEA coatings consisted of FCC phase and BCC phase. The addition of Sn could lead to an increase in the relative proportion of the BCC phase and the formation of coarse dendritic structure in the HEA coating. The average microhardness and average wear weight loss of the (AlCu)3.5CoCrNi coating (612.2 HV and 2.9 mg) and (AlCu)3.5CoCrNiSn coating (562.1 HV and 3.9 mg) were both higher and lower than those of the AZ91 substrate (70.5 HV and 5.5 mg), indicating that the prepared HEA coatings could significantly improve the properties of the substrate. The (AlCu)3.5CoCrNi coating showed better performance than the (AlCu)3.5CoCrNiSn coating due to the grain refinement effect.

Research on stamping formability and process simulation of AZ31 magnesium alloy based on deep learning

To study the formability of AZ31 magnesium alloy under different temperature conditions and improve the forming quality of its parts, this paper aims to solve the minimization problem of pursuing the “maximum thinning rate”. This study obtained the mechanical properties of AZ31 magnesium alloy at 25 °C, 150 °C, 250 °C, and 350 °C through uniaxial tensile tests and explored the stamping formability of AZ31 magnesium alloy mobile phone cases using the finite element inverse calculation method (MSTEP). Based on the hot stamping of AZ31 magnesium alloy at 250 °C, the Monte Carlo Simulation (MCS) method was used to randomly sample the blank holder force, stamping speed, friction coefficient, and resistance coefficient, and then simulate to obtain the corresponding “maximum thinning rate”. In addition, a hybrid prediction model optimized by Genetic Algorithm (GA) and Dung Beetle Optimization (DBO) based on the Back Propagation Neural Network (BPNN) - Random Forest (RF) was used to explore the nonlinear relationship between blank holder force, stamping speed, friction coefficient, resistance coefficient, and the “maximum thinning rate”. The results show that the plasticity of AZ31 magnesium alloy enhances with the temperature increase, especially exhibiting the best stamping formability at 250 °C. Feature importance indicates that the resistance coefficient and stamping speed have a greater impact on the maximum thinning rate, while the influence of blank holder force and friction coefficient is relatively smaller. Mean Square Error (MSE) shows that the predictive capability of the hybrid model is significantly superior to that of the single BP neural network and Random Forest model, displaying optimal efficiency. The predicted maximum thinning rate by the model is 15.39 %, with an error rate of only 0.32 % compared to the DYNAFORM finite element software simulation results, confirming the correctness, accuracy, and effectiveness of the prediction model. Overall, this study provides practical optimization strategies for metal stamping forming processes, with significant practical application value.

Effect of Co-addition of Sn, Traces of RE and Ca on the Mechanical and Micro Structural Properties of As-cast AZ80 Alloy

In this study, the effect of co-addition of tin (0, 6 and 9 wt.%), cerium (0, 0.3 and 0.6 wt.%), gadolinium (0, 0.6 and 0.9 wt.%) and calcium (0, 0.6 and 0.9 wt.%) on the mechanical and microstructural properties of AZ80 magnesium alloy is investigated. The results indicate that the mechanical properties are improved for all the as-cast alloys when compared to base alloy except for one alloy which is due to the presence of Mg-Sn-Ca phase in high volume fraction. Also, it is found that the existence of Al2Ca, Mg2Ca, Al2RE, MgSnRE and Mg2Sn phases have a significant impact on the mechanical and microstructural characteristics of the as-cast AZ80 alloys. It is observed that without the addition of Sn content, the best room temperature tensile properties are obtained for the alloy containing 1.5 wt.% of RE and 0.9 wt.% of Ca. With the addition of Sn, it is found that the best room temperature tensile properties are obtained for the alloy containing 6 wt.% of Sn, 0.9 wt.% of RE and 0.5 wt.% of Ca.

Effects of T6 treatment on the microstructure and mechanical properties of az80 magnesium alloy

The mechanical and microstructure properties of the AZ80 magnesium alloy in deformed and T6 states were evaluated and analyzed by tensile testing and metallographic analysis. The results showed that the grain size of the magnesium alloy increased after T6 treatment, whereas the number of deformed grains decreased considerably. These changes were accompanied by a transformation of the β-Mg17Al12 phase from a discontinuous point-like morphology to a continuous lath-like morphology. After T6 treatment, the tensile strength and yield strength of the material were significantly improved. These findings indicated that the microstructure of the AZ80 magnesium alloy was altered through T6 treatment, and its mechanical properties were markedly enhanced.

Effect of Polytetrafluoroethylene Coating on Corrosion Wear Properties of AZ31 Magnesium Alloy by Electrophoretic Deposition

In this study, we aim to enhance the corrosion and wear resistance of AZ31 magnesium alloy using electrophoretic deposition (EPD) technology to apply a hydrophobic polytetrafluoroethylene (PTFE) coating. Polyethyleneimine (PEI) serves as a charged dispersant, facilitating uniform deposition of PTFE particles on the alloy surface. Results demonstrate a significant reduction in corrosion current density (from 67.5 μA/cm2 to 5.2 μA/cm2) and improved wear resistance (wear volume decreased from 0.24167 mm3 to 0.00167 mm3) in a 3.5 wt% NaCl solution compared to uncoated alloy. Moreover, the friction coefficient of the coated sample decreases. These findings underscore the potential of nano-PTFE coatings prepared via EPD in enhancing AZ31 magnesium alloy’s corrosion and wear resistance, providing a foundation for future protective coating design and optimization.

Effect of Stretch Bending on the Microstructure and Mechanical Properties of AZ31 Magnesium Alloy

Effect of Stretch Bending on the Microstructure and Mechanical Properties of AZ31 Magnesium Alloy

Microstructural Evolution and Mechanical Properties of AZ31 Magnesium Alloy Processed through Constrained Groove Pressing at Different Deformations and Temperatures

Microstructural Evolution and Mechanical Properties of AZ31 Magnesium Alloy Processed through Constrained Groove Pressing at Different Deformations and Temperatures

Effect of Zinc and Severe Plastic Deformation on Mechanical Properties of AZ61 Magnesium Alloy.

This study investigates the effects of zinc (4 wt.%) and severe plastic deformation on the mechanical properties of AZ61 magnesium alloy through the stir-casting process. Severe plastic deformation (Equal Channel Angular Pressing (ECAP)) has been performed followed by T4 heat treatment. The microstructural examinations revealed that the addition of 4 wt.% Zn enhances the uniform distribution of β-phase, contributing to a more uniformly corroded surface in corrosive environments. Additionally, dynamic recrystallization (DRX) significantly reduces the grain size of as-cast alloys after undergoing ECAP. The attained mechanical properties demonstrate that after a single ECAP pass, AZ61 + 4 wt.% Zn alloy exhibits the highest yield strength (YS), ultimate compression strength (UCS), and hardness. This research highlights the promising potential of AZ61 + 4 wt.% Zn alloy for enhanced mechanical and corrosion-resistant properties, offering valuable insights for applications in diverse engineering fields.

STUDY ON EPOXY RESIN/MULTI-WALLED CARBON NANOTUBES CONDUCTIVE COATING ON AZ31 MAGNESIUM ALLOY AFTER MICRO-ARC OXIDATION

After micro-arc oxidation, the surface properties of AZ31 magnesium alloy have been improved. However, micro-arc oxidation treatment leads to high insulation, which limits its application in electronic devices. To increase conductivity, a conductive coating was developed by adding multi-walled carbon nanotubes (MWCNTs) to the epoxy resin. The microstructure and performance of the coating were tested by SEM, thermogravimetric analyzer, four-probe conductivity meter, high-temperature friction and wear tester, and electrochemical workstation. The results indicate that the optimal conductivity with a resistivity of 303[Formula: see text][Formula: see text]m is obtained when the MWCNT content is at 4[Formula: see text]wt%. In addition, MWCNTs are filled with a network structure of epoxy resin, which increases the density of the coating and enhances their wear and corrosion resistance.

Grain refinement and strengthening mechanism of AZ31 magnesium alloy formed by pre-upsetting alternating forward extrusion

The pre-upsetting deformation process was added before the alternating forward extrusion forming, which can significantly refine the grains and improve the mechanical properties while reducing the load. The effects of 14%, 25%, 36% pre-upsetting deformation on the microstructure and mechanical properties of AZ31 magnesium alloy were investigated. The results show that the pre-upsetting alternating forward extrusion (UAFE) process can achieve significant grain refinement from 31.1 µm to 2.9–3.5 µm. With the increase of pre-upsetting deformation, the elongation at break tends to decrease and the tensile strength tends to increase. The comprehensive mechanical properties of U2AFE are the best, the yield strength and tensile strength are 203.1 MPa and 299.0 MPa respectively, and the elongation at break is 12.5%. The enhancement of the pre-upsetting deformation process not only makes the basal plane of grains in the billet randomly distributed and weakens the basal plane texture, but also stores a large amount of strain energy and dislocation inside the billet, which accelerates the subsequent continuous dynamic recrystallization (CDRX) process of alternating extrusion. This provides scientific guidance and technical support for the research of high-performance magnesium alloy extrusion forming technology.

Enhanced mechanical properties of AZ91 magnesium alloy by asynchronously large-strain high-efficiency rolling with bimodal grain structure

The study describes large strain high-speed asynchronous rolling process to process AZ91 magnesium alloy sheets with an overall thickness reduction of 84 % via two-pass rolling at 350 °C. Rolling speed ratios of 1.0, 1.1, 1.2, and 1.3 were used to obtain bimodal grain structure with different organizational states. Microstructural analysis unraveled that the formation of the bimodal structure was a consequence of combined effect of precipitation-strengthening and the Zener pinning effect. The R3 exhibiting an asynchronous ratio of 1.2 exhibited an optimized bimodal grain structure characterized by smaller recrystallized grains and a more homogeneous distribution. This phenomenon underscored the beneficial impact on enhancing strength and alleviating the anisotropic behavior.

Recrystallization and Anisotropy of AZ31 Magnesium Alloy by Asynchronous Rolling

In this study, the microstructure and mechanical properties of AZ31 magnesium alloy were investigated through asynchronous rolling. The results demonstrate that the rolled sample exhibits a refined grain structure with a significant presence of continuous dynamic recrystallization. Notably, as the roll speed ratio increases, the grain refinement becomes more apparent. For the sample with a roll speed ratio of 1.3, the tensile strength in the rolling direction (RD) reaches 273 MPa, while the elongation measures 20.2%. Similarly, in the transverse direction (TD), the tensile strength reaches 282 MPa, accompanied by an elongation of 18.9%. These values indicate a substantial improvement in elongation compared to conventional rolling processes. The enhanced elongation can be attributed to two primary factors. Firstly, recrystallization contributes to a grain refinement recrystallization ratio of 86%, promoting improved mechanical properties. Secondly, the recrystallized grains induce a favorable Schmidt factor, further supporting elongation. Overall, the findings of this research highlight the benefits of asynchronous rolling in refining the microstructure and enhancing the mechanical properties of AZ31 magnesium alloy.

Deformation localization behavior research of AZ31 magnesium alloy under impact load

The dynamic mechanical properties of AZ31 magnesium alloys were analyzed under different strain rates by using a separated Hopkinson pressure bar system. The microstructure of the specimens was observed by optical microscopy. The results show that the dynamic yield strength of AZ31 magnesium alloy is insensitive to the strain rate. The compressive strength is increasing and shear deformation localization behavior is more obvious with the increase in the strain rate. Meanwhile, the temperature within the shear band is about 241 k and meets the twinning dynamic recrystallization temperature. Temperature rise promotes the grain refining effect.

Modeling the correlation between texture characteristics and tensile properties of AZ31 magnesium alloy based on the artificial neural networks

This work is aimed to investigate the relationship between the texture and tensile properties of the AZ31 Mg alloy by the machine learning method. The texture characteristics parameters, namely the maximum pole intensity (Imax), texture dispersion (D), and texture directivities along the longitudinal direction (PLD) and transverse direction (PTD), are extracted from the (0002) pole figures of the AZ31 Mg alloy. An artificial neural networks (ANN) model to describe the relationship between the texture characteristic parameters and tensile properties is constructed and trained by the data collected from the literature. To validate the reliability and generalization performance of the ANN, 6 samples with different texture characteristics are prepared, and their textures and tensile properties are evaluated through electron backscattered diffraction (EBSD) measurement and uniaxial tensile test, respectively. The results indicate that the ANN model exhibits good prediction performance in yield strength and elongation of the AZ31 Mg alloy when it is applied to the new cases. The correlations between the texture characteristics and tensile properties are analyzed according to the ANN-predicted results. The maximum pole intensity and texture dispersion significantly influence the tensile properties of the AZ31 Mg alloy. With increasing the Imax or decreasing the D, the strength is increased but the elongation is reduced. As increasing the texture directivity along the LD, the tensile properties of the AZ31 Mg alloy show non-monotonic changes. This research presents a correlation model between the texture and mechanical properties of the Mg alloy, which contributes to the development of high-performance Mg alloys.

Microstructure and mechanical properties of AZ91 magnesium alloy fabricated by multi-layer and multi-pass CMT based WAAM technique

The block sample of AZ91 magnesium alloy was fabricated via multi-layer and multi-pass wire and arc additive manufacturing (WAAM) based on cold metal transfer (CMT) technique, and the dimension of the sample could better meet the requirement of actual production compared with the thin-walled sample prepared by the multi-layer and single-pass process. The sample was composed of equiaxed grains. The grain size was homogeneous in the deposited passes, while there was an obvious difference of grain size in the junction area of the deposited passes. The average tensile strength and elongation of the sample in the traveling direction were 246.7 MPa and 19.4%, respectively, while those in the pass overlap direction perpendicular to the traveling direction were 127.1 MPa and 11.6%, respectively, due to the formation of defects and brittle second phases.

Effect of Plasma Argon Pretreatment on the Surface Properties of AZ31 Magnesium Alloy

Climate change has evidenced the need to reduce carbon dioxide emissions into the atmosphere, and so for transport applications, lighter weight alloys have been studied, such as magnesium alloys. However, they are susceptible to corrosion; therefore, surface treatments have been extensively studied. In this work, the influence of argon plasma pretreatment on the surface properties of an AZ31 magnesium alloy focus on the enhancement of the reactivity of the surface, which was examined by surface analysis techniques, electrochemical techniques, and gravimetric measurements. The samples were polished and exposed to argon plasma for two minutes in order to activate the surface. Contact angle measurements revealed higher surface energy after applying the pretreatment, and atomic force microscopy showed a roughness increase, while X-Ray photoelectron spectroscopy showed a chemical change on the surface, where after pretreatment the oxygen species increased. Electrochemical measurements showed that surface pretreatment does not affect the corrosion mechanism of the alloy, while electrochemical impedance spectroscopy reveals an increase in the original thickness of the surface film. This increase is likely associated with the high reactivity that the plasma pretreatment confers to the surface of the AZ31 alloy, affecting the extent of oxide formation and, consequently, the increase in its protection capacity. The weight loss measurements support the effect of the plasma pretreatment on the oxide thickness since the corrosion rate of the pretreated AZ31 specimens was lower than that of those that did not receive the surface pretreatment.

Effect of multi-pass continuous screw twist extrusion process on microstructure evolution, texture, and mechanical properties of AZ31 magnesium alloy

Effect of multi-pass continuous screw twist extrusion process on microstructure evolution, texture, and mechanical properties of AZ31 magnesium alloy

Effect of Squeeze Casting and Combined Addition of Calcium and Strontium on Microstructure and Mechanical Properties of AZ91 Magnesium Alloy

Effect of Squeeze Casting and Combined Addition of Calcium and Strontium on Microstructure and Mechanical Properties of AZ91 Magnesium Alloy