Properties Of Castings Research Articles

Temperature gradient mechanism in the heterogeneous nucleation of inoculated alloy: A quantitative phase-field study

The grain size of solidification microstructure has a significant influence on the mechanical properties of castings. Generally, smaller grain size makes the strength of castings higher. Therefore, inoculation is an effective strategy to reduce grain size and improve casting performance. In this work, the phase-field method combined with the free growth model is employed to simulate the solidification of inoculated aluminum alloy with temperature gradient. The simulations indicate that a higher temperature gradient slows the progression of already nucleated grains into impingement growth and enhances the undercooling of the melt ahead of the solid-liquid interface. Hence, more inoculants have chance to get the corresponding nucleation undercooling, promoting grain nucleated sequentially along the gradient direction. These results are consistent with previous real-time observed experiments. This work may provide guidance on improvement of the theoretical models for predicting grain size of inoculated alloys and the optimization of casting process to obtain refined grains in inoculated ingots.

Studies on the Influence of Methane Gas Bubbling of Metal Alloys on the Casting Properties

Abstract The purpose of using bubbling in the case of metal alloys was to increase the mechanical resistance, to improve the casting properties as well as to observe the changes brought by gases on the structure. During bubbling, especially hydrogen and oxygen are removed, which obviously leads to the improvement of metal alloys. The influence of bubbling on the casting properties is explained by the structural changes that occur in the cast alloys. Therefore, bubbling with methane gas is a safe means of improving the quality of cast parts, ensuring at the same time the increase of casting properties of alloys.

The effect of pre-dehydrated magnesium-silicate-hydrate on the properties of the castables bonded with hydrable magnesium carboxylate

This study investigates the effect of pre-dehydrated magnesium-silicate-hydrate (PMSH) on the properties of HMC-bonded castables (HMCC), aiming to enhance the medium-temperature mechanical performance of HMCC through the structural memory characteristics of PMSH. The results indicate that adding M-S-H-300 (PMSH treated at 300 °C) improves the mid-temperature mechanical properties of HMCC. Specifically, the cold modulus of rupture (CMOR) for the samples 300MSH increases by 605.9% at 500 °C and 582.6% at 800 °C compared to control samples due to the excellent thermal stability of M-S-H-300 and a 38.3% improvement in castable sintering performance. Additionally, M-S-H-300 improves the thermal shock resistance and setting properties of HMCC, extending the castable's setting time by 19%. The conductivity test results indicate that the addition of M-S-H-300 inhibits the ionization of HMC, thereby delaying its hydration process. Castables with M-S-H-300 demonstrate higher CMOR and residual strength ratio before and after thermal shock. Further testing reveals that adding M-S-H-300 increased the castable's elastic modulus by 482.6% and fracture toughness by 35.6% after sintering at 1500 °C, enhancing resistance to microcrack propagation during thermal shock. Furthermore, adding M-S-H-300 reduces the aspect ratio of HMC hydration products, optimizing microstructure and reducing porosity. However, this modification slightly decreases the mechanical properties of the green body.

Effect of rotational speed on friction stir welding microstructure and properties of cast and rolled (ZrB2 + Al3Zr) particle-reinforced aluminum matrix composites

Effect of rotational speed on friction stir welding microstructure and properties of cast and rolled (ZrB2 + Al3Zr) particle-reinforced aluminum matrix composites

An experimentally validated thermomechanical model for a parametric study on reducing residual stress in cast iron repair welding

Remarkable casting properties and superior mechanical characteristics of cast iron make it an ideal material for a wide range of industrial applications. However, the production of cast iron components may result in the formation of cracks and defects, posing a significant threat to their structural integrity. Repair welding is a promising solution to resolve cast iron production defects. However, repair welding cast iron components poses unique challenges that stem from residual stress (RS) formation and the possibility of cracking during the repair process. Moreover, research on cast iron repair is scarce. To overcome these challenges, this paper presents a thermo-mechanical model validated by experiments to reduce RS in cast iron repair welding through the optimization of welding parameters and weld sequences as well as the geometry of the repair area. An experimental bead-on-plate weld is set up in order to validate the developed thermo-mechanical model. The temperature distribution in the weld is measured using thermocouples placed around the weld line. An X-ray diffraction technique is used to measure the axial and transverse RS at different points around the weld line. The developed finite element model is employed to simulate the repair welding process and analyze the effect of inter-pass temperature, the number of welding passes, welding sequences, and groove geometry on the RS. The numerical approach applied in this study provides a framework for repair welding optimization of cast iron and other materials, fostering the development of more efficient and reliable repair methods for industrial applications.

Effects of carbon content and heat treatment on wear-resistance and impact properties of novel cast steels with bainitic and martensitic structure

Abstract The traditional material for caterpillar boards is mainly Hadfield steel. The wear resistance of the Hadfield steel cannot be fully exerted due to insufficient work hardening during the operation of the caterpillar board. The effects of carbon content and heat treatment on the wear-resistant and impact properties of a novel caterpillar board cast steels with bainitic and martensitic structures have been investigated. The microstructural observation of worn surface topography was performed by scanning an electronic microscope, and the impact toughness was carried out by an impact tester, in a bid to improve the wear-resistant properties and its impact toughness. The results demonstrate that the hardness and wear-resistant properties of cast steels increase with the increase of carbon content, whereas the impact properties reduce because the brittle phases, such as the carbide precipitation and the martensite, are more. The heat treatment temperature of steels can change the relative ratio of bainitic and martensitic structures, thus affecting the wear-resistant properties of the steels. By controlling the carbon content and heat treatment processing of the steels, the optimal combination of toughness and wear-resistant properties can be achieved. The wear mechanism of dual-phase cast steel was analyzed through wear resistance tests, and it also shows that dual-phase cast steel with bainitic and martensitic structures had better wear-resistance properties compared to the Hadfield steel at low-impact wear conditions.

Effect of hot rolling process on the microstructure and mechanical properties of a high-strength strip casting microalloyed steel

A novel Nb–V–Mo microalloyed steel with 1 GPa yield strength and high ductility was developed by strip casting. The effects of hot rolling on the microstructure and mechanical properties of the Nb–V–Mo microalloyed steel were investigated using scanning electron microscopy, electron backscatter diffraction, transmission electron microscopy, atom probe tomography and tensile tests. Both the as-cast and hot-rolled specimens exhibit a microstructure characterized by lath-like bainite and (Nb, V, Mo)C clusters, while the bainite lath was refined after hot rolling. Tensile test results show obvious improvements in the yield strength, tensile strength, and elongation of the hot-rolled specimen (1008 MPa, 1075 MPa, 20.1 %, respectively), compared to that of the as-cast ones (879 MPa, 978 MPa, 19.0 %, respectively). Additionally, the hot-rolled specimen displays a similar dislocation multiplication and storage capacity to the as-cast specimen, resulting in a comparable work-hardening capability during plastic deformation.

Effect of La on the Microstructures and Mechanical Properties of Al-5.4Cu-0.7Mg-0.6Ag Alloys.

The effects of the rare earth element La on the microstructure and mechanical properties of cast Al-5.4Cu-0.7Mg-0.6Ag alloys have been investigated through metallographic observation, scanning electron microscopy analysis, transmission electron microscopy, X-ray diffraction, and tensile testing. The present form and action mechanism of La have been analyzed. The findings indicate that the inclusion of trace amounts of La markedly diminishes the grain size in the Al-Cu-Mg-Ag alloy. Furthermore, as the La content increases, the alloy's strength is significantly improved. When the La concentration reaches 0.4 wt.%, the mechanical properties of the alloy, both at room temperature and at 350 °C, surpass those of the alloy lacking rare earth elements. When the added rare earth La content exceeds 0.2 wt.%, the emergence of the Al6Cu6La phase causes the alloy structure to exhibit a skeletal morphology, altering the morphology and distribution of excess second phases along grain boundaries, thereby impacting the alloy's overall performance. Incorporating La leads to a reduction in the size of the strengthening precipitate phase Ω while also enhancing its precipitation density, but an excess of La leads to the emergence of Al6Cu6La, depleting the available Cu and suppressing the precipitation of the Ω phase, ultimately affecting the mechanical properties of the alloy.

The impact of small Zr addition to Al–Ni cast alloy for elevated temperature applications

Most aluminium casting alloys are based on the eutectic system Al–Si, which has weak thermal properties. Alloys from the eutectic Al–Ni system on the other hand have higher thermal stability and good casting properties and are therefore promising for casting applications. Using casting simulations, a copper mold was designed to achieve cooling rates above 100 K/s with the aim of producing a Zr-rich supersaturated solid solution. Microstructural analysis revealed that the addition of Zr leads to notable changes in the microstructure characterised by the formation of primary Al3Zr and αAl dendrites. Subsequent heat treatment revealed that Zr-enriched alloys undergo significant age hardening, which showed an improvement in microhardness due to effective Al3Zr precipitation.

Adaptive neuro-fuzzy inference system approach for tensile properties prediction of LPDC A357 aluminum alloy

This study is based on the desire of aluminum casting foundries to understand the influence of minor changes, within the specification limits, in the alloy chemistry. In order to ensure the casting of A357 Al alloys within the framework of the casting standards and to minimize the quality problems that may arise during casting; the estimation of ultimate tensile strength (UTS), yield strength (YS) and elongation (ε) due to very small changes among the alloying elements, although they are in the standard range, by using machine learning method (ML), were studied. The dataset of chemical composition and tensile properties of Low-Pressure Die Cast (LPDC) A357 Al alloy were experimentally established. The relationship between five input variables in the A357 alloy, namely the main alloying elements Si and Mg together with the most common impurity contents Fe, Ti and Cu were selected and three outputs (i.e UTS, YS and ε) were linked by Adaptive Neuro Fuzzy Inference System (ANFIS). The ANFIS model predicted that the most detrimental element affecting tensile properties was Fe content. According to this model, the order of the relative importance on UTS, YS and ε revealed as Si, Mg and Ti content respectively after the Fe content of the alloy.

Effect of Al or Cu Content on Microstructure and Mechanical Properties of Zn Alloys Fabricated Using Continuous Casting and Extrusion

The effect of Al or Cu content on the microstructure and mechanical properties of continuous casting and extrusion Zn alloys has been studied by a room temperature tensile test, X-ray diffraction, and scanning electron microscope. With the increase in Al content, the microstructure of continuous casting and extrusion Zn alloys slightly coarsens, and the lamellar eutectic structure increases. The changes in the above structural factors result in a slight decrease in strength and a significant increase in the elongation of Zn-Al alloys. The strength of Zn alloys increases as the Cu content increases due to the increased content and size of the second phase in the Zn alloys. This means that the mechanical properties of Zn alloys can be adjusted by a continuous casting and extrusion process, and the improvement of equipment capacity can improve the structure and morphology of the alloys.

Revisiting class: A feminist political analysis of the Indian Time Use Survey

AbstractThe literature on agrarian change in India has largely employed class categories based upon data on land, assets and occupational status, which collapse women's class relations into those of (mostly male) households heads. In this paper, we interrogate this understanding of class building on the work of Carmen Diana Deere. Employing the first ever national time use survey conducted in India in 2019, we interrogate class as a labour process that intersects with caste and gender. Our analysis of the data using a Marxist‐feminist framework suggests the following. First, there exist intra‐household gendered differences in class locations. This calls to question theoretical frameworks that assign a cohesive class location to all household members that underlie data collection in India and elsewhere. Second, individuals participate in multiple labour processes depending on their caste and gender. Hence, they may be subsumed to capital in varied and sometimes contradictory ways. Finally, we find that both men and women engage in reproductive labour in addition to other forms of labour, which varies by caste categories. This finding further underscores and supports previous research on the importance of an expanded conception of work that includes reproductive labour. In sum, we argue for a more complex understanding of class in India, one that incorporates its caste and gender dimensions.

Effects of Alumina Bubble Addition on the Properties of Corundum-Spinel Castables Containing Cr2O3.

Purging plugs made of corundum-spinel castables containing Cr2O3 have been widely utilized in secondary refining process. However, their poor thermal shock resistance has greatly limited the improvement of their service life. Aiming to enhance their properties, we introduced alumina bubbles (ABs) to corundum-spinel castables, and the effects of the AB addition on the properties of the castables are studied in this manuscript. The results indicate that the apparent porosity, permanent linear change, cold strength, and hot strength all increased with an increasing AB amount. The thermal shock resistance of the samples with the AB addition was improved; the residual strength and residual strength ratio of the sample with 4 wt% ABs was the best. The effects of ABs on the tabular alumina aggregate distribution and relationship between the cold strength of the samples and the AB content was evaluated via the box dimension method. With the increments of AB content, the box dimension value of the tabular alumina within the samples significantly decreased, indicating that the tabular alumina aggregate distribution was related to the amount of ABs. In addition, the relationship between the box dimension and the strength was also established.

Properties of tape cast (Na, K, Li) (Nb, Sb, Ta)O3 -based ceramics sintered in reduced atmosphere and its application in triaxial piezoelectric accelerometer

In this study, we utilized the tape-casting method to produce Pb-free (Na0·52K0·4425Li0.0375) (Nb0·8925Sb0·07Ta0.0375)O3 + 2 mol% MnCO3 + y mol% LiF (y = 0 to 3) piezoelectric ceramics. We investigated the impact of LiF sintering in a reduced atmosphere on microstructure, dielectric properties, impedance spectroscopy, and piezoelectric performance. By analyzing the degree of diffuse phase transition, we observed increased density and enhanced long-range order in the sample doped with 1 mol% LiF, which exhibited optimal piezoelectric properties (d33 = 265 pC/N and kp = 0.437) and a minimal diffusion parameter. Moreover, LiF doping enabled sintering at 1020 °C under low PO2, facilitating potential co-firing with Cu inner electrodes to further enhance the piezoelectric performance. Using the optimized parameters, we fabricated a cross-type triaxial piezoelectric accelerometer, demonstrating sensitivities of 2.33, 2.44, and 10.6 mV/g along the X, Y, and Z axes, respectively, with a resonance frequency of ∼2600 Hz and frequency range of ∼1300 Hz. This accelerometer holds promise for vibration measurements in low-frequency mechanical systems.

The effect of ultra-fast surface hardening and strengthening on microstructure and mechanical properties of cast (9Cr–3Co–3W) heat-resistant steel

The effect of ultra-fast surface hardening and strengthening on microstructure and mechanical properties of cast (9Cr–3Co–3W) heat-resistant steel

Effect of TiB2 particles on the microstructure and properties of cast Al-5Cu-0.3Mg-0.1Ag alloy

The influence of TiB2 particles on the microstructure and properties of cast Al-5Cu-0.3Mg-0.1Ag alloy is investigated in this study using techniques such as optical microscopy (OM), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), mechanical property testing, and mathematical calculations. It has been observed that the addition of a small amount of TiB2 particles significantly enhances the mechanical properties of the cast alloy (maximum strength increased from 185.27 MPa to 276.1 MPa). Additionally, a small amount of Ag was detected at the Al/TiB2 interface. The distribution of particles within the matrix plays a crucial role in determining the microstructure and properties of the alloy, which is primarily influenced by particle size and supersaturation. Among various strengthening mechanisms resulting from particle addition, thermal mismatch strengthening and grain-refinement strengthening exhibit more pronounced effects (13.95 MPa and 3.49 MPa, respectively).

Flexural behavior of SS316-based metal matrix composite prepared through microwave heating

SS316 is the most commonly used material among the existing stainless steels. SS316-based composite materials provide tailor-made stuff to the various automotive and machinery components due to their competent properties. In the current work, SS316, EWAC, and Cr7C3 powders have been selected for the development of cast specimens in the domestic microwave applicator. The cast of the SS316+15EWAC+5Cr7C3, SS316+15EWAC+10Cr7C3, and SS316+15EWAC+15Cr7C3 compositions has been prepared using a novel technique of microwave hybrid heating. The sample size of 30 × 6 mm2 has been used for flexural strength analysis. The flexural modulus, flexural strength, maximum load, strain at break, and strain at peak load have been tested on a universal testing machine. The maximum values of flexural strength, flexural modulus, peak load, and microhardness were found 469.86 MPa, 10,2321.79 MPa, 4510.65 N, and 585.93 ± 203.33 HV respectively for SS316+15EWAC+15Cr7C3 cast, and maximum strain at peak load and the maximum strain at breaking load were 3.07 and 4.29% respectively for SS316+15EWAC+10Cr7C3 cast. The highest microhardness of 615 HV has been obtained at the carbide phase in the case of SS316+15EWAC+15Cr7C3 cast. The XRD presented the leading peaks of σ-Fe, μ-Fe3Ni2, τ-Cr23C6, α-MoNi4, γ-Mo2C, and β-Fe5C2. The microstructural morphology of the composite casting revealed the proper coalescence of the matrix, homogeneous dispersion of reinforcements, dendrites formation, and equiaxed grain growth. Overall the metallurgical and mechanical properties of the composite cast were improved.

Microstructure and mechanical properties of cast, eutectic Al-Ce-Ni-Mn-Sc-Zr alloys with multiple strengthening mechanisms

The effects of Ni additions on microstructure and microhardness of near-eutectic Al-9Ce-xNi-0.75Mn-0.18Sc-0.12Zr (x = 2.5, 3.2, and 3.9 wt.%) alloys are investigated for various cooling rates. The as-cast microstructure consists of fine, micron-scale Al11Ce3 and Ni-rich phases formed during eutectic solidification. Two Ni-rich phases are observed: (i) Al27Ce3Ni6 at higher Ni contents and slower solidification rates, and (ii) Al9(Ni,Mn,Fe)2 at lower Ni contents and faster solidification rates. While these Ni-containing alloys have higher microhardness than a Ni-free control alloy, varying the Ni concentration in the 2.5–3.9 wt.% range does not significantly affect the microhardness, indicative of competing strengthening and weakening effects from adding Ni. The alloy with intermediate Ni content (3.2 wt.%) is selected for further microstructural and mechanical characterization. It contains four coarsening-resistant strengthening constituents: (i) micron-scale Al11Ce3 and (ii) Al27Ce3Ni6 or Al9(Ni,Mn,Fe)2 platelets, all formed during eutectic solidification, (iii) L12-Al3(Sc,Zr) nanoprecipitates formed on aging, and (iv) Mn atoms in solid solution in the α-Al matrix. The combined strengthening mechanisms impart high strength at ambient and elevated temperatures, as measured by microhardness (as a function of aging time), by compression and tensile experiments, and by compressive creep measurements. Alloys previously reported in the literature - with various combinations of one, two or three of these four strengthening phases - show lower hardness and creep resistance, indicating that cumulative strengthening can be achieved when combining mechanisms; the present alloy containing all four phases shows a remarkably high creep threshold stress of 62 MPa at 300 °C.

Microstructure and Phase Composition of Novel Crossover Al-Zn-Mg-Cu-Zr-Y(Er) Alloys with Equal Zn/Mg/Cu Ratio and Cr Addition

The effect of 0.2%Cr addition on the structure, phase composition, and mechanical properties of the novel cast and wrought Al-2.5Zn-2.5Mg-2.5Cu-0.2Zr-Er(Y) alloys were investigated in detail. Chromium is distributed between primary crystals (5.7–6.8%) of the intermetallic phase and the aluminum solid solution (0.2%) (Al). The primary crystals contain for the main part Cr, Ti, Er(Y). The experimental phase composition is in good correlation with the thermodynamic computation data. The micron-sized solidification origin phases (Al8Cu4Er(or Y) and Mg2Si) and supersaturated (Al) with nano-sized Al3(Zr,Ti) and E (Al18Mg3Cr2) precipitates are presented in the microstructure of the novel alloys after solution treatment. The nucleation of η (MgZn2) (0.5%), S (Al2CuMg) (0.4%), and T (Al,Zn,Mg,Cu) (8.8%) phase precipitates at 180 °C, providing the achievement of a maximum hardness of 135 HV in the Al2.5Zn2.5Mg2.5CuYCr alloy. The corrosion potential of the novel alloy is similar to the Ecor of the referenced alloy, but the corrosion current density (0.68–0.98 µA/sm2) is still significantly lower due to the formation of E (Al18Mg3Cr2) precipitates and S phase precipitates of the aging origin, in addition to the T phase. The formation of E (Al18Mg3Cr2) precipitates under the solution treatment provides a lower proportion of recrystallized grains (2.5–5% vs. 22.4–25.1%) and higher hardness (110 HV vs. 85–95 HV) in the Cr-rich alloys compared to the referenced alloys. Solution treated, hot and cold rolled, recrystallized, water quenched and aged at 210 °C alloys demonstrate an excellent microstructure stability and tensile properties: YS = 299–300 MPa, UTS = 406–414 MPa, and El. = 9–12.3%.

Al and A356 Alloy Foam Castings Modified with Low Concentrations of Nano-Sized Particles: Structural Study and Compressive Strength Tests

Aluminum and A356 alloy foam castings are produced using a melt-foaming method. Prior to foaming, the melt is modified with nano-sized particles (SiC, TiN, or Al2O3). The nano-sized particles are mixed with micro-sized Al particles, which are ultrasonically treated and hot-extruded. Thus, the so-called “modifying nano-composition” is obtained. The resulting compositions are introduced into the melt of the Al foam at the following mass concentrations of nanoparticles: SiC: 0.038 wt. %; TiN: 0.045 wt. %; and Al2O3: 0.046 wt. %. For the A356 foam, we use the following concentrations: SiC: 0.039 wt. %; TiN: 0.052 wt. %; and Al2O3: 0.086 wt. %. The macrostructure of the foam castings is investigated by CT scanning and 3D analysis. The pore size distributions and accumulative fraction dependencies are determined for all samples. The microstructure of the foam castings is investigated by SEM-EDS analysis. The results confirmed the presence of individual nano-sized particles, as well as clusters of particles in foam walls. The conducted compression tests show a significant increase in the plateau stress (up to 237%) of the modified aluminum foam castings compared to non-modified castings. However, a similar effect of the nano-compositions on A356 alloy foam castings is not observed. The obtained results show that the above-indicated concentrations of nanoparticles can positively influence the mechanical properties of aluminum foam castings. The novelty of the current study is two-fold: (1) such low concentrations of added nanoparticles have never been used before to alter Al foam’s properties, and (2) an original method of introducing the nanoparticles into the melt is applied in the form of nano-compositions.