Prominent Minimum Research Articles

Nonequilibrium switching of segmental states can influence compaction of chromatin.

Knowledge about the dynamic nature of chromatin organization is essential to understand the regulation of processes like DNA transcription and repair. The existing models of chromatin assume that protein organization and chemical states along chromatin are static and the 3D organization is purely a result of protein-mediated intra-chromatin interactions. Here we present a new hypothesis that certain nonequilibrium processes, such as switching of chemical and physical states due to nucleosome assembly/disassembly or gene repression/activation, can also simultaneously influence chromatin configurations. To understand the implications of this inherent nonequilibrium switching, we present a block copolymer model of chromatin, with switching of its segmental states between two states, mimicking active/repressed or protein unbound/bound states. We show that competition between switching timescale Tt, polymer relaxation timescale τp, and segmental relaxation timescale τs can lead to non-trivial changes in chromatin organization, leading to changes in local compaction and contact probabilities. As a function of the switching timescale, the radius of gyration of chromatin shows a non-monotonic behavior with a prominent minimum when Tt ≈ τp and a maximum when Tt ≈ τs. We find that polymers with a small segment length exhibit a more compact structure than those with larger segment lengths. We also find that the switching can lead to higher contact probability and better mixing of far-away segments. Our study also shows that the nature of the distribution of chromatin clusters varies widely as we change the switching rate.

Sedimentary evolution and lake level fluctuations of Urmia Lake (north‐west Iran) over the past 50 000 years; insights from Artemia faecal pellet records

AbstractA 25 m long sediment core from hypersaline Urmia Lake (north‐west Iran) was studied for the Late Quaternary depositional history and palaeoclimate variations using the abundance and compositional characteristics of Artemia faecal pellets. Sediment analysis is supported by scanning electron microscopy – energy dispersive X‐ray spectroscopy, organic and inorganic carbon content measurements, and stable isotopes (δ13C and δ18O) from faecal pellet carbonates. The imprecise chronology of the core back to 50 kyr bp is supported by ten radiocarbon ages from faecal pellets and bulk sediments. The palaeoenvironmental record is subdivided into four periods: (i) During much of Marine Isotope Stage 3, a period of lake level lowering is characterized by a decreasing amount of faecal pellets, and an increasing amount of coated grains, sulphate minerals and reworked shell fragments. (ii) During late Marine Isotope Stage 3 and early Marine Isotope Stage 2 a lake level lowstand and a lake floor exposure is interpreted based on the relatively low abundance of pellets, which are multicoloured and appear together with volcanic lithics and rounded sulphate minerals. (iii) During late Marine Isotope Stage 2 the record is devoid of pellets but dominated by large sulphate crystals suggesting a prolonged low lake level. (iv) During Marine Isotope Stage 1 a relative lake level highstand is rapidly established with sediments that are highly abundant in fresh pellets. The modern lake level lowstand is represented by a salt crust. The δ13C and δ18O records measured from faecal pellet carbonates suggest a link with the precipitation versus evaporation balance in the lake over time. From bottom to top the linear trend towards more negative delta values illustrates the increasing amount of precipitation arriving at the lake from the Late Pleistocene to the Holocene. Two prominent isotope minima during the Late Pleistocene and one prominent minimum in the early Holocene mark relative high lake levels, which can also be linked to Lake Van in Turkey.

Fluvial and permafrost history of the lower Lena River, north‐eastern Siberia, over late Quaternary time

ABSTRACTArctic warming and permafrost thaw visibly expose changes in the landscape of the Lena River delta, the largest Arctic delta. Determining the past and modern river regime of thick deltaic deposits shaping the Lena River mouth in north‐eastern Siberia is critical for understanding the history of delta formation and carbon sequestration. Using a 65 m long sediment core from the delta apex a set of sedimentological techniques is applied to aid in reconstructing the Lena River history. The analysis includes: (i) grain‐size measurements and the determination of the bedload composition; (ii) X‐ray fluorescence, X‐ray diffractometry, and magnetic susceptibility measurements and heavy mineral analysis for tracking mineral change; (iii) pH, electrical conductivity, ionic concentrations, and the δ18O and δD stable isotope composition from ground ice for reconstructing permafrost formation. In addition; (iv) total and dissolved organic carbon is assessed. Chronology is based on; (vi) radiocarbon dating of organic material (accelerator mass spectrometry and conventional) and is complemented by two infrared – optically stimulated luminescence dates. The record stretches back approximately to Marine Isotope Stage 7. It holds periods from traction, over saltation, to suspension load sedimentation. Minerogenic signals do not indicate provenance change over time. They rather reflect the change from high energy to a lower energy regime after Last Glacial Maximum time parallel to the fining‐up grain‐size trend. A prominent minimum in the ground ice stable isotope record at early Holocene highlights that a river arm migration and an associated refreeze of the underlying river talik has altered the isotopic composition at that time. Fluvial re‐routing might be explained by internal dynamics in the Lena River lowland or due to a tectonic movement, since the study area is placed in a zone of seismic activity. At the southern Laptev Sea margin, onshore continental compressional patterns are bordering offshore extensional normal faults.

Role of the Deglacial Buildup of the Great Barrier Reef for the Global Carbon Cycle

AbstractThe carbon isotope 13C is commonly used to attribute the last deglacial atmospheric CO2 rise to various processes. Here we show that the growth of the world's largest reef system, the Great Barrier Reef (GBR), is marked by a pronounced decrease in δ13C in absolutely dated fossil coral skeletons between 12.8 and 11.7 ka, which coincides with a prominent minimum in atmospheric δ13CO2 and the Younger Dryas. The event follows the flooding of a large shelf platform and initiation of an extensive barrier reef system at 13 ka. Carbon cycle simulations show the coral δ13C decrease was mainly caused by the combination of isotopic fractionation during reef carbonate production and the decomposition of organic land carbon on the newly flooded shallow‐water platform. The impacts of these processes on atmospheric CO2 and δ13CO2, however, are marginal. Thus, the GBR was not contributing to the last deglacial δ13CO2 minimum at ∼12.4 ka.

Hybrid Mapping of the Black Hole Shadow in M87

Abstract We present a reanalysis of the Event Horizon Telescope 228 GHz observations of M87. We apply traditional hybrid mapping techniques to the publicly available network-calibrated data. We explore the impact on the final image of different starting models, including the following: a point source, a disk, an annulus, a Gaussian, and an asymmetric double Gaussian. The images converge to an extended source with a size ∼44 μas. Starting with the annulus and disk models leads to images with the lowest noise, smallest off-source artifacts, and better closure residuals. The source appears as a ring, or edge-brightened disk, with higher surface brightness in the southern half, consistent with previous results. Starting with the other models leads to a surface brightness distribution with a similar size, and an internal depression, but not as clearly ringlike. A consideration of visibility amplitudes versus UV-distance argues for a roughly circularly symmetric structure of ∼50 μas scale, with a sharp edge, based on a prominent minimum in the UV-distribution, and the amplitude of the secondary peak in the UV-plot is more consistent with an annular model than a flat disk model. With further processing, we find a possible modest extension from the ring toward the southwest, in a direction consistent with the southern limb of the jet seen on 3mm VLBI images on a factor of few larger scales. However, this extension appears along the direction of one of the principle sidelobes of the synthesized beam, and hence requires testing with better UV-coverage.

Gravity modeling reveals a Messinian foredeep depocenter beneath the intermontane Fucino Basin (Central Apennines)

Residual gravity anomalies over Central Italy clearly indicate a prominent regional minimum over the Fucino Basin. Here, we forward model this anomaly along seven cross-sections. The modeling results validate the geometries and petrophysical properties of the Plio-Quaternary units previously proposed by reflection seismic data interpretation. Moreover, we suggest that a thick wedge-shaped sequence is present beneath the Plio-Quaternary post-orogenic units. Based on the inferred density and velocity properties, as well as outcrop evidence from around the Fucino Basin, this sequence would likely represent thick (~1700 m) siliciclastic syn-orogenic Messinian foredeep deposits. The proposed model implies a long-lasting tectonic inheritance history for the Fucino area, which originally hosted primary paleogeographic Mesozoic-Miocene boundaries. In the Messinian-Recent time, the Fucino has continuously represented a first-order tectonic depocenter for siliciclastic sediments, despite differences in tectonic regime (syn-orogenic Messinian, post-orogenic Plio-Quaternary) and palaeoenvironments (Messinian marine flysch, Plio-Quaternary alluvial-lacustrine facies). The compaction-corrected sedimentation rate (~0.89 mm yr−1), suggests a foredeep activity possibly spanning the entire pre-evaporitic, evaporitic and post-evaporitic Messinian time and is comparable to the sedimentation rate observed in the larger Pliocene Apennine foredeep, ~100 km northeast of the study area, suggesting a self-similarity of the belt-foreland system across time and space.

Synchronizing Geomagnetic Field Intensity Records in the Levant Between the 23rd and 15th Centuries BCE: Chronological and Methodological Implications

AbstractArcheomagnetic records are an important source of information on the past behavior of the geomagnetic field. Frequently, however, coeval archeomagnetic intensity (archeointensity) datasets from nearby locations display significant discrepancies, hampering precise reconstruction of high‐resolution secular variation curve. This is the case for the time interval between the later phase of the Early Bronze and the early phase of the Late Bronze Ages (23rd–15th centuries BCE) in the Levant and Mesopotamia. We address the problem by cross‐correlating archeointensity datasets from four major multilayered archeological sites in the southern Levant (Hazor and Megiddo), northern Levant (Ebla), and western Upper Mesopotamia (Mari). We report new archeointensity data, obtained using the Thellier‐IZZI‐MagIC and the Triaxe methods, from six strata at Hazor and four radiocarbon‐dated strata at Megiddo. From 39 pottery fragments, 199 specimens passed our selection criteria, from which we calculated the mean archeointensity for each stratum. To strengthen the comparison of these data with previously published data from Mari and Ebla, obtained using the Triaxe method, we conducted a blind test of the methods that resulted in indistinguishable results or a difference of less than 1 μT. The synchronized compilation, constrained by radiocarbon data from Megiddo, displays a V‐shaped pattern with a prominent minimum of at least 200 years centered around the 18th century BCE. The study highlights the importance of stacking archeomagnetic data obtained by different archeointensity methods only after cross‐testing the methods and ensuring that archeological samples were dated in a consistent manner.

Enhanced Poleward Flux of Atmospheric Moisture to the Weddell Sea Region (ODP Site 690) During the Paleocene‐Eocene Thermal Maximum

AbstractEarth's hydrological cycle was profoundly perturbed by massive carbon emissions during an ancient (56 Ma) global warming event referred to as the Paleocene‐Eocene thermal maximum (PETM). One approach to gaining valuable insight into the response of the hydrological cycle is to construct sea‐surface salinity (SSS) records that can be used to gauge changes in the rates of evaporation and precipitation during the PETM in such climatically sensitive areas as the circum‐Antarctic region. Here, we pair oxygen isotope (δ18O) and magnesium‐calcium (Mg/Ca) measurements to reconstruct PETM sea‐surface temperatures (SSTs) and δ18O composition of seawater (δ18Osw) at austral Site 690 (Weddell Sea). Several discrepancies emerge between the δ18O‐ and Mg/Ca‐based SST records, with the latter indicating that the earliest PETM was punctuated by a short‐lived ~4°C increase in local SSTs. Conversion of the δ18Osw values to SSS reveals a ~4 ppt decrease ~50 ka after peak PETM warming at Site 690. This negative SSS (δ18Osw) anomaly coincides with a prominent minimum in the planktic foraminifer δ18O record published for the Site 690 PETM section. Thus, our revised interpretation posits that this δ18O minimum signals a decrease in surface‐ocean δ18Osw fostered by a transient increase in mean annual precipitation in the Weddell Sea region. The results of this study corroborate the view that the poleward flux of atmospheric moisture temporarily increased during a distinctive stage of the PETM.

Black carbon in spring aerosols of Moscow urban background

Air quality in megacities is recognized as the most important environmental problem. Aerosol pollution by combustion emissions is remaining to be uncertain. Measurements of particulate black carbon (BC) were conducted at the urban background site of Meteorological Observatory (MO) MSU during the spring period of 2017 and 2018. BC mass concentrations ranged from 0.1 to 10 μg m–3, on average 1.5±1.3 and 1.1±0.9 µg/m3 , in 2017 and 2018, respectively. Mean BC concentrations displayed significant diurnal variations with poorly prominent morning peak and minimum at day time. BC mass concentrations are higher at night time due the shallow boundary layer and intensive diesel traffic which results in trapping of pollutants. Wind speed and direction are found to be important meteorological factors affected BC concentrations. BC pollution rose identifies the North as the direction of the preferable pollution. A negative correlation between BC concentrations and wind speed confirms the pollution accumulation preferably in stable weather days. Relation of BC pollution to a number of agriculture fires is distinguishable by air mass transportation from South and South-Est of Russia and Western Europe. Mean season ВС concentrations at rural and remote sites in different world locations are discussed.

A hybrid image processing method for measuring 3D bubble distribution using digital inline holography

The paper presents a hybrid bubble hologram processing approach for measuring the size and 3D distribution of bubbles over a wide range of size and shape. The proposed method consists of five major steps, including image enhancement, digital reconstruction, small bubble segmentation, large bubble/cluster segmentation, and post-processing. Two different segmentation approaches are proposed to extract the size and the location of bubbles in different size ranges from the 3D reconstructed optical field. Specifically, a small bubble is segmented based on the presence of the prominent intensity minimum in its longitudinal intensity profile, and its depth is determined by the location of the minimum. In contrast, a large bubble/cluster is segmented using a modified watershed segmentation algorithm and its depth is measured through a wavelet-based focus metric. Our processing approach also determines the inclination angle of a large bubble with respect to the hologram recording plane based on the depth variation along its edge on the plane. The accuracy of our processing approach on the measurements of object size and 3D distributions are assessed through synthetic bubble holograms and oil droplet holograms from an experiment separately. In addition, we evaluate the ability of this algorithm to estimate the bubble inclination with respect to the hologram recording plane through measuring a 3D-printed physical target of pillars with different inclination angles. The holographic measurement technique is further implemented to capture the fluctuation of instantaneous gas leakage rate from a ventilated supercavity generated in a water tunnel experiment. Overall, our paper introduces an inexpensive and compact solution for high resolution characterization of bubbles and other particles in multiphase flows from a broad range of applications.

Integrated influence of melting parameters of rail steel on rail products quality and technical and economic indicators of the production

Analysis of literature and production data has shown that despite the significant improvement in quality of domestic rail products, achieved in the last decade due to fundamental technical re-equipment of rail production, there is a problem of increased rejection of rails for surface defects. Based on studies of influence of rail steel chemical composition on quality of rails produced by «EVRAZ ZSMK», there was established a significant effect of increasing copper content in the range of 0.07 - 0.15 % and of sulfur - in the range of 0.006 - 0.011 % in E76KhF steel to increase rejection caused by rail surface defects. Mechanism of the influence of these elements concentration in rail steel on finished rails quality was revealed. Decisive influence of ratio of pig iron and scrap in metal charge on copper and sulfur content in rail steel was evidenced - higher rate of cast iron in metal charge within 20 - 50 % contributes to decrease of copper concentration and increase of sulfur content. To justify optimal composition of the charge for rail steel melting in regard to rail products quality and technical and economic indicators of production, study of the effect of cast iron (liquid and solid) to scrap ratio in metal charge on basic parameters of furnaces’ operation was conducted. As a result, it was found that with an increase in share of both liquid and solid iron in metal charge, there are linear decrease in specific electricity consumption, increase in specific oxygen consumption according to parabolic law and a linear decrease in manganese content in furnace output. The obtained dependences of melting duration on ratio of charge components in metal charge indicates presence of prominent minimum, when using liquid iron in the range of 35 - 40 %, and when using solid iron - in the range of 30 - 35 %. Based on the regression equations, statistical model was constructed for the influence of metal charge composition on technical and economic performance of the melt charge in rail steel smelting, in which optimization parameters are: total cost, depending on the metal stock composition and performance of the shop for suitable billets produced by continuous casting. Application of the obtained model allows to develop reasonable recommendations on the optimal proportion of iron in the metal for current level of prices for materials and energy used in electric smelting, taking into account changes in the shop productivity.

Dynamics of entangled polymer chains with nanoparticle attachment under large amplitude oscillatory shear

ABSTRACTThis paper presents a nonlinear viscoelastic model for polymer nanocomposites and the computed model response to large amplitude oscillatory shear flow. The model predicts the stress in a mixture of entangled polymer chains, with different convective constraint release (CCR) rates for free chains and nanoparticle‐attached chains, through an averaging scheme which is consistent with double reptation in the Marrucci–Ianniruberto constitutive equation. The nonlinear response of the mixture is evaluated both numerically in terms of Q and by an asymptotic analysis in terms of four frequency dependent parameters of medium amplitude oscillatory shear (MAOS) as well as the intrinsic nonlinearity parameter Q0. In the case of free polymer chains alone, the MAOS signatures are comparable to those of the Giesekus model with the notable difference of a minimum in the elastic parameter [e1] at De >1. The viscous nonlinear parameters of the mixture model depart significantly from those of the free chains, especially in mixtures where the CCR parameter for attached chains is larger than that for the free chains: [v1] has a prominent minimum and [v3] has a prominent maximum near De = 2/c, the low frequency plateau region, along with a higher Q0 compared to the matrix at all Deborah numbers. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019, 57, 62–76

The Controlling Role of Boundary Layer Inertial Oscillations in Meiyu Frontal Precipitation and Its Diurnal Cycles Over China

AbstractConvection‐permitting simulations are used to investigate the key mechanism of Meiyu precipitation diurnal cycle over China. Six days from the 2014 Meiyu season are used to produce a “north” composite rainband over the Yangtze‐Huaihe River Basin and another 6 days used to produce a “south” composite band. Both rainbands have peak rainfall in the early morning, while the south band has a secondary peak in the afternoon. Low‐level ageostrophic winds (AGWs) are found to exhibit diurnal cycles with clockwise rotations and their directions, and magnitudes depend on the background geostrophic monsoon flows. Net moisture flux into a control volume enclosing each rainband is almost purely due to AGWs. For both rainbands, net flux reaches maximum at ~04 LST, about 3–4 hr before morning precipitation peak. For the north band, a prominent minimum occurs at ~19 LST, 4 hr before the precipitation minimum. The moisture fluxes through the southern control volume boundary make the largest contributions to the net flux and its diurnal variations. The diurnal variations of the AGWs and their relationship with the background monsoon flows agree very well with the prediction of Blackadar boundary layer inertial oscillation theory, and the convergence forcing by the AGWs resulting from the inertial oscillations plays a paramount role in modulating the diurnal cycles of Meiyu front precipitation, including the creation of early morning peak and evening minimum. Feedback of latent heat release plays only a secondary role. The commonly recognized diurnal monsoon variability can be explained by the Blackadar inertial oscillation theory.

Holocene Hydroclimate Variability in Central Scandinavia Inferred from Flood Layers in Contourite Drift Deposits in Lake Storsjön

Despite the societal importance of extreme hydroclimate events, few palaeoenvironmental studies of Scandinavian lake sediments have investigated flood occurrences. Here we present a flood history based on lithological, geochemical and mineral magnetic records of a Holocene sediment sequence collected from contourite drift deposits in Lake Storsjön (63.12° N, 14.37° E). After the last deglaciation, the lake began to form around 9800 cal yr BP, but glacial activity persisted in the catchment for ~250 years. Element concentrations and mineral magnetic properties of the sediments indicate relatively stable sedimentation conditions during the Holocene. However, human impact in the form of expanding agriculture is evident from about 1100 cal yr BP, and intensified in the 20th century. Black layers containing iron sulphide appear irregularly throughout the sequence. The increased influx of organic matter during flood events led to decomposition and oxygen consumption, and eventually to anoxic conditions in the interstitial water preserving these layers. Elevated frequencies of black layer occurrence between 3600 and 1800 cal yr BP reflect vegetation changes in the catchment as well as large-scale climatic change. Soil erosion during snowmelt flood events increased with a tree line descent since the onset of the neoglacial period (~4000 cal yr BP). The peak in black layer occurrence coincides with a prominent solar minimum ~2600 cal yr BP, which may have accentuated the observed pattern due to the prevalence of a negative NAO index, a longer snow accumulation period and consequently stronger snowmelt floods.

Laboratory Setup for Scanning-Free Grazing Emission X-ray Fluorescence.

Grazing incidence and grazing emission X-ray fluorescence spectroscopy (GI/GE-XRF) are techniques that enable nondestructive, quantitative analysis of elemental depth profiles with a resolution in the nanometer regime. A laboratory setup for soft X-ray GEXRF measurements is presented. Reasonable measurement times could be achieved by combining a highly brilliant laser produced plasma (LPP) source with a scanning-free GEXRF setup, providing a large solid angle of detection. The detector, a pnCCD, was operated in a single photon counting mode in order to utilize its energy dispersive properties. GEXRF profiles of the Ni-Lα,β line of a nickel-carbon multilayer sample, which displays a lateral (bi)layer thickness gradient, were recorded at several positions. Simulations of theoretical profiles predicted a prominent intensity minimum at grazing emission angles between 5° and 12°, depending strongly on the bilayer thickness of the sample. This information was used to retrieve the bilayer thickness gradient. The results are in good agreement with values obtained by X-ray reflectometry, conventional X-ray fluorescence and transmission electron microscopy measurements and serve as proof-of-principle for the realized GEXRF setup. The presented work demonstrates the potential of nanometer resolved elemental depth profiling in the soft X-ray range with a laboratory source, opening, for example, the possibility of in-line or even in situ process control in semiconductor industry.

Holocene multidecadal‐ to millennial‐scale variations in Iceland‐Scotland overflow and their relationship to climate

AbstractThe Nordic Seas overflows are an important part of the Atlantic thermohaline circulation. While there is growing evidence that the overflow of dense water changed on orbital time scales during the Holocene, less is known about the variability on shorter time scales beyond the instrumental record. Here we reconstruct the relative changes in flow strength of Iceland‐Scotland Overflow Water (ISOW), the eastern branch of the overflows, on multidecadal‐millennial time scales. The reconstruction is based on mean sortable silt ( ) from a sediment core on the Gardar Drift (60°19′N, 23°58′W, 2081 m). Our record reveals that the main variance in ISOW vigor occurred on millennial time scales (1–2 kyr) with particularly prominent fluctuations after 8 kyr. Superimposed on the millennial variability, there were multidecadal‐centennial flow speed fluctuations during the early Holocene (10–9 kyr) and one prominent minimum at 0.9 kyr. We find a broad agreement between reconstructed ISOW and regional North Atlantic climate, where a strong (weak) ISOW is generally associated with warm (cold) climate. We further identify the possible contribution of anomalous heat and freshwater forcing, respectively, related to reconstructed overflow variability. We infer that ocean poleward heat transport can explain the relationship between regional climate and ISOW during the middle to late Holocene, whereas freshwater input provides a possible explanation for the reduced overflow during early Holocene (8–10 kyr).

A shift towards wetter and windier conditions in southern Sweden around the prominent solar minimum 2750 cal a BP

A variety of palaeoclimatic records show a shift towards cooler, wetter and windier conditions in Europe around 2800 cal a BP. The shift broadly coincides with an increase of the atmospheric 14C concentration, suggesting a connection between solar activity variations and climate change. Here we investigate a peat record from Undarsmosse in southern Sweden. In a previous study, based on a low-resolution chronology, this record showed increased aeolian sand influx and Sphagnum spore content around 2800 cal a BP, indicating high storm activity and wetter conditions. We applied the 14C wiggle-match dating technique on the same record to construct a robust chronology to evaluate the temporal relationship to solar forcing. In addition, we performed plant macrofossil analysis to determine local vegetation changes. Based on the new chronology, a shift to a Sphagnum-dominated bog, representing wetter conditions, and the onset of a period with increased storminess occurred around 2700 cal a BP. These changes are, within age model uncertainties, synchronous with climatic changes inferred from other sites in Europe, suggesting a shift in the larger scale atmospheric circulation, possibly triggered by decreased solar activity.

Refining the Quaternary Geomagnetic Instability Time Scale (GITS): Lava flow recordings of the Blake and Post-Blake excursions

The Blake excursion was among the first recognized with directional and intensity behavior known mainly from marine sediment and Chinese loess. Age estimates for the directional shifts in sediments are poorly constrained to about 118−100 ka, i.e., at the marine isotope stage (MIS) 5e/5d boundary. Moreover, sediments at Lac du Bouchet maar, France and along the Portuguese margin reveal what may be a "post-Blake" excursion at about 105−95 ka. The excursional directions are associated with a prominent paleointensity minimum between about 125 and 95 ka in global stacked records. Lava flow recordings of the Blake excursion(s) have, however, been questionable because precise ages required for correlation with these sediment records are lacking. To establish new, independent records of the Blake excursion, and link these into a larger Quaternary GITS, we have undertaken 40Ar/39Ar incremental heating and unspiked K-Ar experiments on groundmass from the transitionally magnetized Inzolfato flow on Lipari Island. We also obtained 40Ar/39Ar incremental heating results for a lava flow on Amsterdam Island originally thought to record the Mono Lake excursion and from the transitionally magnetized El Calderon basalt flow, New Mexico that was K-Ar dated by Champion et al. (1988) at 128 ± 66 ka.Unspiked K-Ar ages of four samples from the Inzolfato flow are 102.5 ± 4.7, 101.3 ± 3.3, 97.1 ± 2.6, and 96.8 ± 3.1 ka and thus indistinguishable from one another. 40Ar/39Ar results are more complex, with three samples yielding discordant age spectra. Based on incremental heating data obtained in both the UW-Madison and Gif-sur-Yvette 40Ar/39Ar laboratories, a fourth sample yields six concordant age plateaus and a weighted mean age of 105.2 ± 1.4 ka that we take as the best estimate of time since the flow erupted. Five 40Ar/39Ar incremental heating experiments on the Amsterdam Island lava yield a plateau age of 120 ± 12 ka, whereas ages from two sites in the Calderon flow are 112 ± 23 and 101 ± 14 ka, together giving a weighted mean of 104 ± 12 ka. The age of 120 ± 12 ka from Amsterdam Island, though imprecise, correlates with the Blake excursion. In contrast, the 104–105 ka age obtained from both Lipari and New Mexico indicates that these lavas record a younger period of dynamo instability, most probably associated with the post-Blake excursion. These radioisotopic ages are consistent with the astronomical ages of two paleointensity minima in the PISO-1500 global stack. Our findings indicate that the Blake and post-Blake excursions are both global features of past geodynamo behavior and support the hypothesis that Brunhes chron excursions are temporally clustered into two groups of at least a half-dozen each spanning over 220 to 30 ka and 720 to 520 ka.

Thermodynamic anomalies of a network former in a periodic field

We study the effect of an external one-dimensional periodic field on thermodynamic anomalies associated with a two-dimensional model liquid with anisotropic interactions. The model system, a 50 : 50 binary mixture of two species of particles interacting with an angle-dependent Lennard-Jones potential, has a rich phase diagram and shows many features of network-forming liquids like water and silica such as a prominent minimum in the pressure-temperature isochore. Confining the system by a commensurate one-dimensional periodic field shifts the temperature of minimum pressure to higher temperatures. A mean-field theory of a lattice-gas in an external field which couples to internal orientational states reproduces these results.

Geochemistry of the Paleoproterozoic metaterrigenous rocks of the Biryusa Block, southwestern Siberian Craton

Major and trace element compositions of the Paleoproterozoic metaterrigenous rocks (Neroi Group) formed in a large sedimentation basin in the southwestern Siberian Craton (Biryusa Block) were determined to reconstruct the protoliths of metasediments, degree of their recycling, and maturity of source rocks. Primary rocks from the lower part of the sequence (Alkhadyr Formation) are represented by both petrogenic (“first cycle”) and recycled sediments of the graywacke to siltstone and aluminous pelite series. Protoliths of the micaceous and carbonaceous schists from the upper part of the sequence (Tumanshet Formation) correspond to silty pelites and pelites. As the micaceous schists of the Alkhadyr Formation, these rocks have K2O/Al2O3 < 0.3 and elevated Th concentrations, indicating the contribution of recycling in the formation of the fine-grained rocks. Distribution of trace and rare earth elements (REE) in metaterrigenous rocks of the Neroi Group testifies to the predominance of felsic rocks in the source area, while the prominent Eu minimum indicates the presence of granitoids—the products of crustal melting. Rocks of the Alkhadyr Formation also show elevated contents of Cr, Co, Ni, Sc, and Fe, indicating the development of mafic rocks in the source area. Comparison of the trace element contents and their ratios in rocks of the Neroi Group with those in the Archean (3.5–2.5 Ga) and Paleoproterozoic (2.5–1.6 Ga) upper continental crust made it possible to establish that metasedimentary rocks of the Neroi Group were formed by the erosion of sufficiently mature (geochemically differentiated) protoliths, which are similar to the Paleoproterozic crust. Judging from the Sm-Nd isotope data, one of the components of source areas for the terrigenous rocks of the Neroi Group were Archean rocks similar to basement rocks of the Biryusa block with the Nd model ages within 2.8–2.6 Ga. The second component in the source area could be juvenile Paleoproterozoic crust (Nd model age ∼1.9 Ga), which was probably represented by the metavolcanic associations of grabens surrounding the Biryusa block. The minimum Nd model ages for metaterrigenous rocks of the Neroi Group define the lowermost sedimentation boundary at 1.9 Ga.