Transport systems are essential for the path toward sustainable urbanisation and the transition to more sustainable living. Recently, European cities have undergone substantial changes, and suburbanisation is posing new challenges. Suburban areas are often more affordable in terms of housing, but these neighbourhoods tend to be car-oriented. This leads to higher commuter costs, immobility, transport and time poverty, pollution, higher accident rates and a lack of social interactions. To offer sustainable mobility options to citizens, we must comprehensively understand, together with their individual characteristics, their specific mobility practices and the built environment where they live. This study is centred on the Barcelona Metropolitan Region, which has a public transport network that covers its entire area. The aim of this study is to examine the relationships between travel behaviour, transport mode use, individual characteristics and built environment characteristics in the place of residence using detailed information sources. Herein, we used data from the 2018 to 2021 annual travel survey conducted in the Barcelona region, together with land use and sociodemographic information. Our findings suggest that transport policies have encouraged sustainable mobility practices, particularly in the centre of Barcelona. Despite the positive results, considerable disparities exist between the inner and outer city, with a notable decline in sustainable mobility practices in the latter, due to the uneven distribution of basic services and uneven provision of public transport, together with lower density areas. Our results demonstrate that this uneven distribution reduces the available sequence profiles of inhabitants. In conclusion, the promotion of sustainable mobility policies necessitates further advances in transport, city and land-use planning that consider equity, gender, the socioeconomic profiles of citizens and mixed urban planning.