Green Hydrogen Production Research Articles

Renewable energy in sustainable cities: Challenges and opportunities by the case study of Nusantara Capital City (IKN)

Indonesia's future IKN capital might be sustainable, low-carbon, and climate-resilient. The Low Emissions Analysis Platform (LEAP) simulates energy efficiency in various demand sectors, renewable energy, and sustainable transportation solutions. Sustainable cars, such as renewable-energy-powered electric and green hydrogen-powered vehicles, can reduce energy consumption by 43% in 2045 and 33% in 2060, respectively, compared to BAU. GHG emissions per capita will drop 70% in 2045 and 63% in 2060. In the net-zero emission (NZE) scenario, IKN can reach 100% green energy by 2045 with a 4.4 GW solar power plant, a 0.92 GWh BESS, and a full load hour capability of 4 hours. We will use 1.1 GW of hydropower and 143 MW of wind power by 2045. In 2060, hydropower will be 2.8 GW, wind power will be 184 MW, and solar power will be 8 GW with 1.6 GWh of BESS. Lack of legislation, technical expertise, high prices, inadequate grid infrastructure, and insufficient renewable electricity restrict BESS use in Indonesia. Solar energy installation requirements, subsidies, and off-grid project incentives can all help ease BESS use. Forecasts predict 0.53 GW of rooftop solar PV capacity by 2045 and 3.35 GW by 2060. Net metering and solar tariffs boost rooftop solar system profitability. One ton of green hydrogen production requires 55.7 MWh from a solar power plant. Solar power plant capacity will rise to 0.49 GW by 2045, producing 19,359 tons of green hydrogen, and almost quintuple to 89,594 tons by 2060. Hydrogen generation, storage, transit, and distribution require specific infrastructure due to high capital costs and a lack of networks, yet interest in them is growing.

Design, Operation and Simulation of a Passive Osmosis-Integrated Electrolyzer for Seawater Electrolysis

Abstract Utilizing abundant seawater for green hydrogen production through electrolysis is a promising pathway to produce a sustainable energy carrier. However, modern seawater electrolyzers have shown insufficient durability due to electrode corrosion and/or competitive production of chlorinated products that result from the presence of Cl-. In this work, a new cell, driven by osmotic separation, was designed and operated that can passively draw fresh water from seawater into compartments with high acid and/or alkaline concentration for electrolysis, thereby eliminating the need for an external energy source for desalination. The work focuses first on demonstrating the passive transport of water through membranes over a wide range of acid and base concentrations. Then, electrodes are integrated, and the cells are operated under multiple configurations and current densities. It is observed that some co-ion diffusion occurs, which is quantified through pH measurements and quantitative Cl- titration. Water transport and ion crossover experiments are supported by comprehensive continuum-level modeling. Finally, strategies for improving future performance are discussed. The findings in this work, a first step in the development of an osmosis-driven electrolyzer cell (ODEC), showcase the promise of this novel electrolyzer design for future direct seawater electrolysis.

Progress on Si‐based photoelectrodes for industrial production of green hydrogen by solar‐driven water splitting

AbstractSolar power has been regarded as the ultimate green‐energy source because of its inexhaustibility and eco‐friendliness. The solar‐driven water‐splitting technology for green hydrogen production is considered to be one of effective ways for solar energy harvesting and storage, which may provide solutions for the energy crisis and environmental issues. In the past decades, great progress has been achieved in this area. Photoelectrochemical (PEC) water splitting is especially promising for the production of solar fuels because of expected large‐scale industrial application. Silicon (Si), as an ideal candidate for the photoelectrode, is the most suitable material for the PEC device in industrial photocatalytic water splitting because of its abundance, mature fabrication technology, and suitable band gap. Here, we give a systematic review on the recent progress for Si‐based photoelectrodes for water splitting with a focus on the industrial application. Particularly, the strategies, such as band‐alignment control, morphology design, and surface engineering, are summarized to enhance the PEC performance and durability for practical application. Furthermore, the perspective for the design of commercial Si‐based PEC devices with high PEC performance, long‐term stability, large‐size, and low cost are given at the end, which shall guide the development of PEC water splitting for industrial application.

Developing Practical Catalysts for High‐Current‐Density Water Electrolysis

AbstractHigh‐current‐density water electrolysis is considered a promising technology for industrial‐scale green hydrogen production, which is of significant value to energy decarbonization and numerous sustainable industrial applications. To date, substantial research advancements are achieved in catalyst design for laboratory‐based water electrolysis. While the designed catalysts demonstrate remarkable performance at laboratory‐based low current densities, they suffer from marked deteriorations in both activity and long‐term stability under industrial‐level high‐current‐density operations. To provide a timely assessment that helps bridge the gap between laboratory‐scale fundamental research and industrial‐scale practical water electrolysis technology, here the current advancements in various commercial water electrolyzers are first systematically analyzed, then the key parameters including work temperature, current density, lifetime of stacks, cell efficiency, and capital cost of stacks are critically evaluated. In addition, the impact of high current density on the electrocatalytic behavior of catalysts, including intrinsic activity, long‐term stability, and mass transfer, is discussed to advance the catalyst design. Therefore, by covering a range of critical issues from fundamental material design principles to industrial‐scale performance parameters, here the future research directions in the development of highly efficient and low‐cost catalysts are presented and a procedure for screening laboratory‐designed catalysts for industrial‐scale water electrolysis is outlined.

Chemical Bath Deposition of NiFe Alloy Anode for Efficient Alkaline Water Electrolyzer Integration.

Green hydrogen production from water splitting is a feasible way for intermittent renewable energy storage and utilization, where the exploration and scale-up preparation of high-performance anodic oxygen evolution electrocatalysts are critical prerequisites for its industrial-level applications. Herein, a chemical bath deposition of FeNi3 intermetallic alloys onto Ni mesh support is performed, which delivers a current density of 0.62 Acm-2 at 1.72 V versus reversible hydrogen electrode for alkaline water oxidation in 1 m KOH and an excellent electrolysis stability at 0.2 A cm-2 for over 300 h. Moreover, via 3D computational fluid dynamics simulation and flow field optimization, a homogeneous deposition of ≈5400 cm2 NiFe anode is demonstrated within 4 min using the developed flow bath reactor. Once integrating the as-prepared NiFe anodes into alkaline electrolyzer stack, the voltage variation between each unit cell is below 40 mV at a total operation current of 71 A, or ca. current density of 0.2 A cm-2, confirming the uniformity of this batch synthesis protocol and its great potential for industrial alkaline water electrolysis.

Control Structures for Combined H2/Electricity from Offshore Wind Turbines

Wind energy proves to be a highly favourable choice for electricity generation due to its clean and renewable nature, and is playing a significant role in reducing global greenhouse gas emissions. Offshore wind turbine systems have gained widespread popularity as they can capitalise on elevated and consistent wind speeds surpassing those found in onshore locations, resulting in increased energy efficiency. Furthermore, offshore wind power possesses the potential to emerge as a significant electricity source for the production of green hydrogen. As water electrolysis technology for hydrogen production continues to advance, utilizing offshore wind power for hydrogen generation is becoming more economically viable and practical. Offshore wind power with higher wind speeds in combination with efficient control structures presents an attractive option for electricity generation and hydrogen co-production. This paper aims to present and evaluate four different production structures for combined H2/energy generation from offshore wind turbines. Previous research studies in this area often overlook control structures and lack information on power converter operations. In contrast, this article studies control structures that enable proper functionality and ensure adequate interoperability, enhancing the reliability of renewable energy integration. Each structure, including both wind turbines and electrolyser, is described in detail, along with the corresponding controllers. Simulation results are presented for each structure and controller to demonstrate their effective operation.

Operando Stable Palladium Hydride Nanoclusters Anchored on Tungsten Carbides Mediate Reverse Hydrogen Spillover for Hydrogen Evolution

AbstractProton exchange membrane (PEM) electrolysis holds great promise for green hydrogen production, but suffering from high loading of platinum‐group metals (PGM) for large‐scale deployment. Anchoring PGM‐based materials on supports can not only improve the atomic utilization of active sites but also enhance the intrinsic activity. However, in practical PEM electrolysis, it is still challenging to mediate hydrogen adsorption/desorption pathways with high coverage of hydrogen intermediates over catalyst surface. Here, operando generated stable palladium (Pd) hydride nanoclusters anchored on tungsten carbide (WCx) supports were constructed for hydrogen evolution in PEM electrolysis. Under PEM operando conditions, hydrogen intercalation induces formation of Pd hydrides (PdHx) featuring weakened hydrogen binding energy (HBE), thus triggering reverse hydrogen spillover from WCx (strong HBE) supports to PdHx sites, which have been evidenced by operando characterizations, electrochemical results and theoretical studies. This PdHx‐WCx material can be directly utilized as cathode electrocatalysts in PEM electrolysis with ultralow Pd loading of 0.022 mg cm−2, delivering the current density of 1 A cm−2 at the cell voltage of ~1.66 V and continuously running for 200 hours without obvious degradation. This innovative strategy via tuning the operando characteristics to mediate reverse hydrogen spillover provide new insights for designing high‐performance supported PGM‐based electrocatalysts.

Economic analysis of blue and green hydrogen production in Oman: comparison of various energy sources mix

Economic analysis of blue and green hydrogen production in Oman: comparison of various energy sources mix

“There is plenty of energy at the bottom”: A spectral conversion approach for upconversion-powered water-splitting PEC cell

An avant-garde step towards the use of the long infrared tail of the incident solar radiation with untapped and crucial applications in photocatalysis and energy harvesting schemes is presented: “there is plenty of energy at the bottom”. In detail, a pure photonic approach to enhance titanium dioxide (TiO2) photocatalytic activity is proposed, by using rare-earth doped luminescent glassy materials, capable of performing NIR-to-UV-VIS spectral conversion (up-conversion). Therefore we report infrared-driven boosting of green hydrogen production in a photo-electrochemical water-splitting cell using TiO2 electrodes, revisiting the original design of Fujishima and Honda fifty years later. This proof-of-concept comprises infrared-induced hydrogen and oxygen evolution via water-splitting and determines univocally the role of a solely photonic effect to split water. Thus, the conversion of the incident NIR radiation, before its interaction with the photocatalyst, emerges as a significant contribution to the state-of-the-art for an effective harvest of the near-infrared portions of sunlight.

Heterogeneous oxide/sulfide materials as superior bifunctional electrocatalysts for carbon-neutral green hydrogen production: A short review

Heterogeneous oxide/sulfide materials as superior bifunctional electrocatalysts for carbon-neutral green hydrogen production: A short review

Assessing the environmental and economic viability of floating PV-powered green hydrogen: A case study on inland ferry operations in Türkiye

This paper conducts a comprehensive analysis of the environmental impacts and costs associated with a floating photovoltaic (FPV)-powered green hydrogen production system for a ferry line in Türkiye, utilizing life cycle assessment (LCA) and life cycle cost assessment (LCCA) methods. The methodology involves regridding daily data from 13 Global Climate Models (GCMs) to a consistent 1° × 1° grid, comparing this data with ERA5 datasets using various statistical methods, and identifying the top four GCMs. These models are then used to forecast ambient temperature, wind speed, and solar radiation for 2023–2052. Based on these forecasts, the FPV system's component sizes are determined. The LCA, based on the GREET 2022 database, reveals that green hydrogen is the most environmentally friendly option, reducing global warming potential (GWP) by 77.5 % compared to marine diesel oil (MDO 0.1 % S), with more than 62 % of GWP for the hydrogen-powered ferry attributed to PV production. LCCA results indicate that, without subsidies, green hydrogen is not economically feasible for the selected inland ferry line. Carbon taxes are insufficient to bridge cost differences, highlighting the need for financial incentives. Reducing corporate tax to 10 % is identified as the most effective incentive, and the Production Tax Credit (PTC) option maximizes internal rates of return for green hydrogen producers. This study provides valuable insights for sustainable energy choices in maritime transport, emphasizing the importance of both environmental and economic considerations.

Long‐term Durability of Seawater Electrolysis for Hydrogen: From Catalysts to Systems

AbstractDirect electrochemical seawater splitting is a renewable, scalable, and potentially economic approach for green hydrogen production in environments where ultra‐pure water is not readily available. However, issues related to low durability caused by complex ions in seawater pose great challenges for its industrialization. In this review, a mechanistic analysis of durability issues of electrolytic seawater splitting is discussed. We critically analyze the development of seawater electrolysis and identify the durability challenges at both the anode and cathode. Particular emphasis is given to elucidating rational strategies for designing electrocatalysts/electrodes/interfaces with long lifetimes in realistic seawater including inducing passivating anion layers, preferential OH−adsorption, employing anti‐corrosion materials, fabricating protective layers, immobilizing Cl− on the surface of electrocatalysts, tailoring Cl− adsorption sites, inhibition of OH− binding to Mg2+ and Ca2+, inhibition of Mg and Ca hydroxide precipitation adherence, and co‐electrosynthesis of nano‐sized Mg hydroxides. Synthesis methods of electrocatalysts/electrodes and innovations in electrolyzer are also discussed. Furthermore, the prospects for developing seawater splitting technologies for clean hydrogen generation are summarized. We found that researchers have rethought the role of Cl− ions, as well as more attention to cathodic reaction and electrolyzers, which is conducive to accelerate the commercialization of seawater electrolysis.

Challenges and Opportunities of the Solar Panels Reverse Logistic in the Energetic Transitions of the Green Hydrogen

Objective: This paper aims to collaborate to the development of the reverse logistic for solar panels, impulse by the energetic transition into the green hydrogen. Additionally, it intends to map all the logistic activities linked to the green hydrogen production, including the reverse logistic of solar photovoltaic panels, to take advantage of its components. This paper wanted to identify all the photovoltaic solar panels components, for a more broadly comprehension of its structure, and define all the activities related to the post consumption of the panels. Theoretical Framework: The references explore the photovoltaic solar panels characteristics and the necessity to implement the reverse logistic for this energy source, focusing on green hydrogen production. Also, applying the just-in-time tool. Method: The methodology is detailed, with a clear and objective description of all the steps. Including the mapping of the activities through a flowchart, that illustrates the sequence of the steps, with a detailed description of each step. Results and Discussion: The obtained results revealed the necessity of a perspective for the reversed logistic driven from the energetic transition, especially by the green hydrogen. This problem is linked to the increasing environmental awareness and boosting on the solar panels production, which also increased the demand for the discarded components of those panels in a sustainable manner. Thus logistic can be optimized through the just-in-time tool, that allows the reverse mapping of the steps, improving its logistic aspects. Research Implications: The theoretical and practical implications of this research highlight mainly the questions related to sustainability and awareness in short, medium and long term. The search for an energetic vector capable of supplying the energetic necessities in a clean and abundant way is a topic of constant study. However, the answers to these questions and how they are connected can impact directly the energetic research. Therefore, it must be done in an efficient and strategic way. Originality/Value: This study explores the reverse logistics for solar panels, aiming to demonstrate the possibility to produce in a large scale in a sustainable form. This connection is linked to the GH2 energetic vector, since the source for the production of this vector is directly related to renewable energies, such as solar energy. Thus, this study maps in detail this reverse pathway searching for a sustainable reverse logistic.

Pt-TiO2 Systems for Enhanced Hydrogen Production from Glycerol: Direct vs Sequential Incorporation Through Photodeposition

Pt-TiO2 systems are the most widely used photocatalysts in the production of green hydrogen from glycerol photoreforming. To incorporate metals on the surface of materials, photodeposition is the most used method because it employs mild conditions. However, despite its use, there are some parameters that have not been deeply studied, such as the appropriate metal loading and the method itself, to obtain a better dispersion of Pt. In this work, six Pt-TiO2 catalysts were synthesized by a classical photodeposition method employing UV radiation. The studied Pt wt.% range was 0.15–0.60 wt.%, being incorporated in one step or in subsequent ones. HRTEM analyses showed that both methods allowed a homogeneous distribution of Pt, and in both, the particle size was around 2.3–3.6 nm, increasing with metal loading. The photocatalytic activity of materials was tested in glycerol photoreforming under UV radiation, and the 0.45 wt.% Pt-containing solid that had been synthesized in one step was the one that allowed the highest hydrogen production. This might suggest that around 0.40% is the appropriate metal loading for hydrogen production under these conditions and that incorporating the desired metal percentage in one step is the most efficient method in terms of energy and time savings.

Optimizing green hydrogen strategies in Tunisia: A combined SWOT-MCDM approach

Tunisia's rapid industrial expansion and population growth have created a pressing energy deficit, despite the country's significant, yet largely untapped, renewable energy potential. This study addressed this challenge by developing a comprehensive framework to identify and evaluate strategies for promoting green hydrogen production from renewable energy sources in Tunisia. A Strength, Weakness, Opportunity, and Threat (SWOT) analysis, incorporating social, economic, and environmental dimensions, was conducted to formulate potential solutions. The Step-wise Weight Assessment Ratio Analysis (SWARA) method facilitated the weighting of SWOT factors and sub-factors. Subsequently, a multi-criteria decision-making approach, employing the gray technique for order preference by similarity to ideal solution (TOPSIS-G) method (validated by gray additive ratio assessment (ARAS-G), gray complex proportional assessment (COPRAS-G), and gray multi-objective optimization by ratio analysis (MOORA-G), was used to rank the identified strategies.The SWOT analysis revealed "Strengths" as the most influential factor with a relative weight of 47.3 %, followed by "Weaknesses" (26.5 %), "Threats" (15.6 %), and "Opportunities" (10.6 %). Specifically, experts emphasized Tunisia's renewable energy potential (21.89 %) and robust power system (12.11 %) as primary strengths. Conversely, high investment costs (11.2 %) and political instability (7.77 %) posed substantial threat. Positive socio-economic impacts represented a key opportunity with a score of 5.2 %. As for the strategies prioritizing criteria, production cost ranked first with a score of 13.5 %, followed by environmental impact (12.8 %), renewable energy potential (12.0 %), and mitigation costs (11.3 %). The gray TOPSIS analysis identified two key strategies: leveraging Tunisia's wind and solar resources and fostering regional cooperation for project implementation. The robustness of these strategies is confirmed by the strong correlation between TOPSIS-G, ARAS-G, COPRAS-G, and MOORA-G results. Overall, the study provides a comprehensive roadmap and expert-informed decision-support tools, offering valuable insights for policymakers, investors, and stakeholders in Tunisia and other emerging economies facing similar energy challenges.

Achieving gigawatt-scale green hydrogen production and seasonal storage at industrial locations across the U.S.

Onsite production of gigawatt-scale wind- and solar-sourced hydrogen (H2) at industrial locations depends on the ability to store and deliver otherwise-curtailed H2 during times of power shortages. Thousands of tonnes of H2 will require storage in regions where subsurface storage is scarce, which may only be possible using liquid organic H2 carriers. We evaluate aboveground system with a focus on providing technical insights into toluene/methylcyclohexane (TOL/MCH) storage systems in locations suitable for gigawatt-scale wind- and solar-powered electrolyzer systems in the United States. Here we show that the levelized cost of storage, at a national median of US dollar $1.84/kg-H2 is spatially heterogeneous, causing minor impact on the cost of H2 supply in the Midwest, and significant impact in Central California and the Southeast. While TOL/MCH may be the cheapest aboveground bulk storage solution evaluated, upfront capital costs, modest energy efficiency, reliance on critical materials and pre-sulfided catalysts, and greenhouse gas emissions from heating are opportunities for further development.

Current Status of Green Hydrogen Production Technology: A Review

As a clean energy source, hydrogen not only helps to reduce the use of fossil fuels but also promotes the transformation of energy structure and sustainable development. This paper firstly introduces the development status of green hydrogen at home and abroad and then focuses on several advanced green hydrogen production technologies. Then, the advantages and shortcomings of different green hydrogen production technologies are compared. Among them, the future source of hydrogen tends to be electrolysis water hydrogen production. Finally, the challenges and application prospects of the development process of green hydrogen technology are discussed, and green hydrogen is expected to become an important part of realizing sustainable global energy development.

Multi-synergy enabling Ni-doped MoS2@N-doped carbon composite as versatile catalysts toward hydrogen production and photovoltaics

Construction of efficient non-precious catalyst with desired chemical composition and well-defined nanostructure is of great essential to enhance the kinetics of hydrogen evolution reaction (HER) and triiodide (I3−) reduction reaction (IRR), which is conducive to promote the development of green hydrogen production and obtain impressive photovoltaic performance of dye-sensitized solar cells (DSSCs). Herein, ZIF-8 derived N-doped carbon (NC) wrapped with two-dimensional Ni-doped MoS2 nanosheets (Ni–MoS2@NC) are elaborately designed. The catalytic activity of Ni–MoS2@NC for HER and IRR are significantly improved by modifying electronic structure through heteroatom doping. The optimized Ni–MoS2@NC has lower overpotential of 122 mV at 10 mA cm−2 in comparison with counterpart. Meanwhile, the power conversion efficiency (PCE) of DSSCs based on Ni–MoS2@NC CE catalyst is comparable to that of Pt. Density functional theory (DFT) calculation is used to unveil the mechanism of Ni–MoS2@NC for alkaline HER and IRR, namely, the multi-synergy of various sites endows Ni–MoS2@NC with appropriate Gibbs free energy for H∗ adsorption and water dissociation energy, while the top and interfacial S sites of Ni–MoS2@NC are responsible for the adsorption and activation of I3−. Our work provides a feasible route to design efficient catalysts in the field of energy conversion and understand mechanism.

Synergistic enhancement of hydrogen evolution reaction by one-step pyrolysis synthesis of 1T-2H MoS2 loaded nitrogen-doped carbon

The increasing demand for clean and renewable energy underscores the importance of hydrogen energy, with electrocatalytic water splitting being an efficient method for green hydrogen production. Platinum, while an excellent catalyst for hydrogen evolution reactions (HER), is hindered by high cost and scarcity. This study explores non-precious alternatives, focusing on MoS2 due to its “platinum-like behavior.” The 1T-2H MoS2 loaded on N-doped carbon (NC) catalysts (1T-2H MoS2@NC) were synthesized through a one-step pyrolysis of melamine and ammonium thiomolybdate. Comprehensive analysis revealed that the 2H phase formed at 700 °C, transitioning to a biphasic 1T-2H composition at higher temperatures. The catalyst synthesized at 800 °C with a 1:8 reactant ratio demonstrated exceptional HER performance, with an overpotential of 175 mV at 10 mA cm−2 and a Tafel slope of 92.37 mV dec−1. This study highlights the potential of 1T-2H MoS2@NC as a cost-effective and efficient catalyst for sustainable hydrogen production.

Predictive modeling of membrane reactor efficiency using advanced artificial neural networks for green hydrogen production

The imperative to decarbonize the energy sector has prompted substantial advancements in clean electricity generation, with hydrogen emerging as a promising low-carbon energy carrier. While hydrogen synthesis from renewable sources is crucial, challenges persist, necessitating innovative approaches for efficient and sustainable production. This study leverages diverse artificial neural network (ANN) models to assess and predict system efficiency based on key operational variables in membrane reactor systems. The multilayered perceptron (MLP) and radial basis function (RBF) methodologies are employed, with the MLP models optimized across twelve training algorithms and eight activation functions, exploring up to three hidden layers with variable neuron counts. The MLP model, utilizing the Levenberg-Marquard training algorithm and Tangent-Sigmoid activation function, achieved a high correlation coefficient (R2) of 0.9975 for training and 0.9962 for testing, and a mean squared error (MSE) of 0.00425 for training and 0.23951 for testing, indicating precise and accurate efficiency predictions. The Log-Sigmoid activation function also performed well, with R² values of 0.9971 (training) and 0.9961 (testing), and MSE values of 0.004086 (training) and 0.17694 (testing). Optimization of the RBF network identified the best performance with a spread parameter of 1 and 35 neurons, although the MLP model demonstrated superior accuracy and reduced computational time. Statistical analysis, encompassing correlation coefficient, mean squared error, Root Mean Squared error, absolute average deviation, absolute average relative deviation, and runtime, confirms the network’s consistent and accurate estimation of system efficiency across various input variables. The study highlights that applying tansig and logsig activation functions, configured with neuron counts of 20, 17, 6 and 23, 20, 2 at the first, second and third hidden layers, respectively, offers enhanced accuracy and reliability. The MLP model’s high performance underscores its potential to identify optimal conditions for H2 generation based on system efficiency, thereby advancing membrane reactor technology for hydrogen production.