We review the cross-sections for low-energy π-γ reactions in the framework of chiral perturbation theory. Charged-pion Compton scattering, π-γ → π-γ , is considered up to one-loop order where the pion's internal structure enters through the difference of the electric and magnetic pion polarizability, απ - βπ . The ongoing COMPASS experiment aims at measuring this important structure constant with high statistics using the Primakoff effect. In the same way, the reaction π-γ → π-π0 serves as a test of the QCD chiral anomaly (via the γ3π -coupling constant F γ3π . Furthermore, we calculate the total cross-sections for neutral and charged pion-pair production, π-γ → π-π0π0 and π-γ → π-π+π- , which are governed by the chiral ππ -interaction. Finally, we investigate the radiative (correction) process π-γ → π-γγ and calculate the corresponding two-photon mass spectrum. This information will be useful for analyzing the π- Primakoff scattering events with photons in the final state.