The copper molten marks at a fire site provide important clues for determining the causes of fire. Four factors have been presented to quantitatively discriminate copper molten marks, namely the fraction of (001) component perpendicular to the demarcation line, the grain aspect ratio, the fraction of Σ3 boundaries, and the fraction of maximum grain size. However, only laboratory-level results of these parameters have been presented, and their applicability in actual fires is yet to be verified. In this study, a fire reproduction experimental system was configured to generate molten marks similar to those in actual fire sites. The molten marks were measured by electron backscatter diffraction and applied to the four discriminant factors. The results obtained similar characteristics to those of the laboratory unit, confirming the applicability of the four discriminant factors. Discriminant equations and processes that can distinguish the primary and secondary arc beads were derived using the molten marks generated in the laboratory and reproduction experiments. Furthermore, a probabilistic discrimination method and classification model developed by machine learning were proposed. Therefore, the use of the discriminants in actual fires can improve the reliability of the statistics and prevent the recurrence of similar fires.
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