In this paper, the mechanical properties of reactive powder concrete (RPC) at ultra-low temperatures were studied. RPC prisms (300 mm × 100 mm × 100 mm) were tested at ultra-low temperatures (20 °C, 0 °C, −20 °C, −40 °C, −80 °C, −120 °C, −165 °C) and resulting prism compressive strength, compressive stress-strain curve, and toughness were determined. The increase in prismatic compressive strength of RPC at ultra-low temperatures is greater than that of ordinary concrete, with an overall strength of about 2.12 times that of ordinary concrete. Pore water freezing behavior was also studied to assess the effects on the mechanical properties of RPC in ultra-low temperatures. The water-ice phase transition further improved the RPC strength. With the reduction in temperature, The change in elastic modulus of RPC change is small, the peak strain of specimens at different temperatures increases with the decrease in temperature. The peak strain of RPC showed an overall linear increase with decreasing temperatures, and the water-ice phase transition at negative temperature increases the peak strain of RPC, adding steel fibers improves the RPC ductility, limiting the fracture. With the temperature reduction, RPC toughness first increases and then decreases. The toughness is lowest at room temperature, and highest at −120 °C, which is 2.26 times higher than at room temperature. RPC has better toughness than normal concrete at different temperatures, the reduction of temperature relatively improves the toughness of RPC, and the addition of steel fibers plays a vital role in improving the toughness. This study can serve as technical support for using RPC to design liquefied natural gas full-capacity tanks.
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