Printed Polylactic Acid Research Articles

The mechanics of extruded polylactic acid: an investigation into the effects of its multiple recycling and the inclusion of fly ash

Abstract This study examines variations in the material properties of the 3D printed polylactic acid (PLA) components after they have been recycled multiple times. Additionally, virgin polylactic acid was supplemented with fly ash from the thermal power plant, and the material’s behavior was examined after it was recycled on multiple times. By means of different tests, the impacts of filler addition on the mechanical behavior of the recycled materials are investigated. Using various forms including broken pieces, flakes, and fine powders, the filament extrusion was performed using used polylactic acid material during recycling. Under multiple recycling conditions, the mechanical characteristics of the polylactic acid and fly ash added polylactic (PLA-FA) were investigated. This work also investigates the impact of the polymer’s particulate size during the filament extrusion process. After recycling, it was found that the fine powder additions during the extrusion process provided high tensile strength of 32.61 MPa and flexural strength of 47.32 MPa for the PLA specimens. After recycling processes, the maximum tensile strength of 25.64 MPa and flexural strength of 50.22 MPa were found in fly ash enriched PLA. In contrast, the hardness of both PLA and fly ash-included PLA increased following each recycling procedure. Multiple recycling of PLA material turned the ductile material into brittle material by means of amorphous phase emergence. When compared to other particle sizes which were bigger in size, the specimens developed with filaments extruded with fine powder showed maximum results in all the tests. The tensile strength of PLA material decreased by 17.25%, while the tensile strength of PLA-FA material decreased by 21.35% after recycling. In PLA, the flexural strength drop following three recycling was 17.56% while in PLA-FA material it was 9.01%. After three times of material recycling, the hardness increased by 3.52% in PLA and by 2.48% in PLA-FA.

Mechanical characterization of a 3D printed lattice core sandwich structure

AbstractSandwich structures have garnered interest as versatile structures for applications in advanced engineering structures. To fabricate sandwich structures, plastics have replaced conventional materials; however, most of these plastics remain in the environment beyond their functional lifespan. This study describes the fabrication of sustainable hybrid sandwich structures with 3D printed poly‐lactic acid (PLA) cores and self‐reinforced polyethylene terephthalate (srPET) face sheets. The mechanical responses of the hybrid sandwich structures with three types of lattice cores, S‐90, S‐45, and S‐V, were compared with those of the parent material sandwich structures after performing bending and impact tests. The face sheet in the hybrid sandwich structure transferred the load to the core without failure. The hybrid sandwich structure containing the S‐90 core exhibited a higher fracture strength (52.4 MPa) and tangent modulus of elasticity (2860 MPa) than those of the other structures. S‐V exhibited the highest fracture strains of 3.3% and 5% for parent material and hybrid sandwich structures, respectively. This study highlights the sandwich structures with excellent mechanical properties for structural applications.Highlights Novel sandwich structures with 3D printed PLA cores are fabricated. Three‐point bending and low‐velocity impact tests are performed. Failure occurred in the core, but the Sr‐PET face sheets did not deform. Hybrid sandwich structures significantly improve mechanical performance.

Heat‐Treatment and Water Immersion Effect on the Mechanical Properties and Joint Strength of 3D‐Printed Polylactic Acid Parts

ABSTRACTThis paper investigates the effect of short‐time water immersion (WI) and heat‐treatment (HT) post‐processes on the mechanical properties and joint strength of printed polylactic acid (PLA) parts with various raster angles. Using these post‐processing methods to enhance the joint strength of printed PLA parts could be deemed as the novelty and the contribution of the current study. The WI and HT of the tensile test specimens and the adherends of the bonded joints were carried out at 21°C and 90°C, respectively. Depending on the raster angle, the tensile strength of the heat‐treated specimens was about 11%–43% higher than that of the untreated specimens. Interestingly, it was found that WI had a more significant effect on the strength of printed parts than HT. In the case of WI, the tensile strength was increased by about 27%–57% as compared to the untreated specimens. Joint tests revealed that HT and WI exerted a similar positive effect on the strength of the joints. The findings highlighted that short‐time WI is at least as effective as HT in increasing the tensile and joint strengths of 3D‐printed PLA parts.

Influence of Printing Parameters to optimize mechanical properties in additive manufacturing – A Review

Abstract Additive manufacturing (3D printing) is a revolutionary technology with widespread applications among various industries. It is a cost effective and fast prototyping technology of 20th century, the parts produced by 3D printing are not only used for pre-production samples but also for replacement of functional parts in various applications. Various methods of 3D printing technologies viz., Fused Deposition, Resin printing etc., are available, however Fused Deposition Modelling (FDM) technique is very popular since it is promising and cost effective. There are two major aspects needs to be considered in preparing a sample from 3D printing, i.e., selection of material and printing parameter. With the advancement of material technology from time to time, the efficient and quality products that are produced with this technology. The present study explores the impact of various parameters that affect mechanical properties of 3D printed Polylactic Acid (PLA) in horizontal orientation.

Effect of Infill Pattern on Flexural Behaviour and Surface Roughness Behaviour of 3D Printed Poly Lactic Acid (PLA) Material

Effect of Infill Pattern on Flexural Behaviour and Surface Roughness Behaviour of 3D Printed Poly Lactic Acid (PLA) Material

Hybrid toughening effect of flax fiber and thermoplastic polyurethane elastomer in 3D‐printed polylactic acid composites

AbstractFlax fiber has emerged as a promising, eco‐friendly alternative to traditional synthetic reinforcement in polymer composites. However, manufacturing biocomposites using three‐dimensional (3D) printing technology is typically accompanied by significant processing challenges and weak product performance under dynamic loading conditions. This study aims to unlock the potential of 3D‐printed polylactic acid (PLA) by incorporating chemically modified chopped flax fibers and thermoplastic polyurethane elastomer to improve impact strength and processability. To achieve this, we employed the fused deposition modeling (FDM) technique to prepare composite specimens for the study. The crystallization behavior, tensile and impact properties, as well as the fracture behavior of the composites were investigated. The findings suggest that our approach stands out because it not only facilitates the challenging task of 3D printing PLA with fiber additives of high weight fraction and high aspect ratio but also results in a remarkable 120% enhancement in impact strength and an around 31.2% increase in tensile elongation compared to neat PLA, without compromising the elastic modulus.Highlights Flax fibers were modified through alkalization and silanization. Alkalization significantly enhanced printing quality. Silanization reduced fiber attrition and doubled the fiber aspect ratio. TPU particles facilitated the 3D printing of biocomposites. For the first time, the hybrid strategy doubled the impact strength of PLA.

Bending performance and failure mechanisms of composite sandwich structures with 3D printed hybrid triply periodic minimal surface cores

In this paper, a novel hybrid triply periodic minimal surface (TPMS) core with a nonlinear transition region was designed by combining two types of TPMS (Diamond and Schwarz P) structures using the sigmoid function. The width of the transition region was precisely regulated by adjusting the gradient control parameter r in the sigmoid function. Composite sandwich structures (CSS) were fabricated by bonding two carbon fiber reinforced polymer (CFRP) face sheets to a 3D printed polylactic acid (PLA) core. The bending performance and failure mechanisms of the CSSs with the hybrid TPMS cores were analyzed through three-point bending tests and finite element analysis (FEA). The results indicate that as r increases, the transition region of the hybrid TPMS cores becomes narrower, leading to a gradual decrease in bending strength, bending stiffness, and core shear stress. The failure process of the CSSs in the experiment aligns well with the FEA results. Through comparative analysis of the stiffness-to-weight and strength-to-weight ratios of the CSSs with the native TPMS cores, the hybrid TPMS cores with a wider transition region enhance the structural efficiency of the CSSs, while those with a narrower transition region negatively impact the performance of the CSSs.

3D Printed and Electrospun, Transparent, Hierarchical Polylactic Acid Mask Nanoporous Filter.

Face masks are becoming one of the most useful personal protective equipment with the outbreak of the coronavirus (CoV) pandemic. The entire world is experiencing shortage of disposable masks and melt-blown non-woven fabrics, which is the raw material of the mask filter. Recyclability of the discarded mask is also becoming a big challenge for the environment. Here, we introduce a facile method based on electrospinning and three-dimensional printing to make changeable and biodegradable mask filters. We printed polylactic acid (PLA) polymer struts on a PLA nanofiber web to fabricate a nanoporous filter with a hierarchical structure and transparent look. The transparent look overcomes the threatening appearance of the masks that can be a feasible way of reducing the social trauma caused by the current CoV disease-19 pandemic. In this study, we investigated the effects of nozzle temperature on the optical, mechanical, and morphological and filtration properties of the nanoporous filter.

Shear bond strength in two types of indirect orthodontic cementation.

To compare the shear bond strength of brackets cemented to dental enamel according to the cementation techniques. Experimental study. We used 90 premolars and placed them in printed polylactic acid (PLA) filament models to simulate the dental arch shape and to then cement brackets using the direct, indirect technique with Transbond™XT and indirect technique with Orthocem®. Then, we carried out a shear bond strength test using a universal testing machine, and we evaluated the enamel surface using the adhesive resin remaining index. Dunn's test was used for the inferential statistical analysis of shear bond strength, and Fisher's exact test was used for the adhesive resin remaining index. The shear bond strength of the brackets recorded mean values of 16.74±4.48Mpa, 15.93±6.49Mpa and 12.09±5.07Mpa in the direct, indirect technique with Transbond™XT and indirect technique with Orthocem® respectively. At an inferential level, a lower statistically significant difference was found in the indirect group with OrthoCem® in contrast to the other two groups. In the evaluation of resin remaining after detachment, the direct technique group registered 46.7% of teeth with more than half of resin remaining and the indirect technique groups with Transbond™XT and Orthocem® registered less than half of resin remaining with an incidence of 53.3% and 43.3% respectively. At an inferential level, a statistically significant difference between groups was evidenced. The indirect cementation technique using Transbond™ XT is more recommended since it presents a higher shear bond strength than using Orthocem®. Key words:Orthodontics, Adhesion, orthodontic adhesives, shear bond strength.

Whey protein-loaded 3D-printed poly (lactic) acid scaffolds for wound dressing applications

Chronic skin wounds pose a global clinical challenge, necessitating effective treatment strategies. This study explores the potential of 3D printed Poly Lactic Acid (PLA) scaffolds, enhanced with Whey Protein Concentrate (WPC) at varying concentrations (25, 35, and 50% wt), for wound healing applications. PLA’s biocompatibility, biodegradability, and thermal stability make it an ideal material for medical applications. The addition of WPC aims to mimic the skin’s extracellular matrix and enhance the bioactivity of the PLA scaffolds. Fourier Transform Infrared Spectroscopy results confirmed the successful loading of WPC into the 3D printed PLA-based scaffolds. Scanning Electron Microscopy (SEM) images revealed no significant differences in pore size between PLA/WPC scaffolds and pure PLA scaffolds. Mechanical strength tests showed similar tensile strength between pure PLA and PLA with 50% WPC scaffolds. However, scaffolds with lower WPC concentrations displayed reduced tensile strength. Notably, all PLA/WPC scaffolds exhibited increased strain at break compared to pure PLA. Swelling capacity was highest in PLA with 25% WPC, approximately 130% higher than pure PLA. Scaffolds with higher WPC concentrations also showed increased swelling and degradation rates. Drug release was found to be prolonged with increasing WPC concentration. After seven days of incubation, cell viability significantly increased in PLA with 50% WPC scaffolds compared to pure PLA scaffolds. This innovative approach could pave the way for personalized wound care strategies, offering tailored treatments and targeted drug delivery. However, further studies are needed to optimize the properties of these scaffolds and validate their effectiveness in clinical settings.

Experimental characterization of bending modes and investigation of multi-stable solutions of PLA-based additively manufactured beams

This study examines the experimental characterization of three identically 3D printed polylactic acid (PLA)-based cantilever beams subjected to various vibrational excitations with investigating the possible existence of multiple solutions and compares the results of the beams to one another to reveal uncertainties and possible issues of reproducibility of the additively-manufactured systems. Free, random, and harmonic excitations are performed to evaluate the responses of identically manufactured PLA-based beams with focusing on the first three modes of vibrations. The results show that nonlinear damping and nonlinear softening are present for the first three modes of vibration for the systems under consideration. It is proved that significant uncertainties may be found in estimating the linear and nonlinear characteristics of “identically” manufactured beams. It is also demonstrated that the reproducibility of these systems is not feasible from systems under vibratory excitations. In addition, the experiments indicate that the same additively manufactured beam may encounter multi-stable solutions which questions the reliability of manufacturing 3D printed systems subjected to dynamical excitations.

The effects of 3D printing designs on PLA polymer flexural and fatigue strength

This study assessed the comprehensive assessment of flexural and fatigue strength of the three-dimensional (3D)-printed polylactic acid (PLA) samples across diverse printing designs and parameters. The experiment framework included a diverse array of printing parameters: layer heights, first layer thicknesses, infill densities, top/bottom infill patterns, extruder temperatures, perimeters, and types of solid layer top and bottom. Our findings suggest that there is an interplay between these parameters and the mechanical properties of PLA specimens. Notably, the fatigue strength of PLA printing specimens is more significantly influenced (0.44%) by an increase in the thickness of the first layer compared to flexural strength (87%). The rate of increase in bending strength is lower in cases of layer height (3.55%) and initial layer height (0.44%) in contrast with other factors. Specimens with an initial layer thickness of 0.4 mm reached the highest number of cycles until failure, recording 21 022 cycles. Furthermore, the study identifies the infill pattern’s impact on strength, highlighting that the line infill pattern type case has the highest bending strength of 75.97 MPa and surpasses the honeycomb pattern in bending strength. Compared to the Honeycomb pattern, the rectilinear design has 2.1% higher bending strength. The number of cycles to failure of the rectilinear pattern is greater than those of the honeycomb pattern. In comparison to other patterns, the Rectilinear Top/Bottom infill pattern has a higher interest rate of 27.5% for bending strength and 200.83% for fatigue strength. Additionally, greater bending and flexural strength are obtained by raising the solid layer top, bottom, and perimeter values, respectively. In comparison to the other temperatures, the bending strength and fatigue strength are highest at 200 °C. Therefore, the first layer height of 0.4 mm, the top/bottom rectilinear infill pattern, the extruder temperature of 200 °C, the perimeter value of 3, the solid layer/top value of 3, and the solid layer/bottom value of 3 are the optimal values for the part subjected to at the same time bending strength combined with fatigue strength. This comprehensive study may provide a broader and deeper understanding of individual and combined effects on an overview of the bending and fatigue strength in connection to printing design and printing parameters, as well as the ideal optimal parameters for 3D printing with the PLA material. Manufacturers and designers can use the recommended parameters to optimize the strength of their printed parts, considering both bending and fatigue performance.

Low-cycle compression-compression fatigue behavior of MEX-printed PLA parts

Due to cyclic loads, additively manufactured (AM) parts can collapse at lower stress values than the strength corresponding to static loads. To date, there is limited research on the fatigue life of AM polymers. The present work investigates the fatigue behavior of material extrusion (MEX) printed Polylactic acid (PLA) parts. In this regard, the low-cycle fatigue (LCF) domain was studied and a compression-compression fatigue test setup was adopted. Initially, before the experimental tests, the MEX-printed samples were subjected to physical assessments. The printed fatigue samples presented a high accuracy with dimensional relative errors below 0.04%, while 6.66% was noted as their mass relative error. Subsequently, quasi-static and cyclic tests were performed in order to determine the mechanical behavior of the AM parts, with special focus on the low-cycle domain of the S-N (or Wöhler) curve. The quasi-static compression behavior of the PLA samples is typical of cellular materials, the samples highlighting a shear band as a failure mechanism. Five load levels were used to plot the low-cycle domain of the S-N (or Wöhler) curve with its 95% level confidence bands. The tests were performed in force-controlled mode with the stress asymmetry ratio R = 0.1 and at the test frequency of f = 10 Hz. An exponential relationship was also found between the strain at break and the number of cycles until failure. The failure of the samples in fatigue load occurred suddenly.

Study on the static and dynamic mechanical properties and constitutive models of 3D printed PLA and PLA-Cu materials

The failure of mechanical properties in 3D printed polylactic acid (PLA) for many functional applications has made exploring ways for improving these properties essential; the use of copper powder for producing a composite material known as PLA-Cu is one of these ways. The mechanical responses of both PLA and PLA-Cu under both static and dynamic loading were studied using a universal testing machine and a split Hopkinson pressure bar apparatus, respectively. This experimental study helped to develop a constitutive model for each material according to their mechanical behavior. However, PLA-Cu, affected by ‘impact embrittlement,’ indicates a purely linear elastic behavior during dynamic conditions. Addition of copper powder increases the yield strength of the composite material significantly as compared to pure PLA, with both materials being strain rate sensitive as they change from static to dynamic states. The calibration of the Johnson-Cook constitutive model with the inclusion of the Cowper-Symonds strain rate term for these materials promises useful information for numerical models, improving the predictive models on their behavior under different loading scenarios.

Designing Lightweight 3D-Printable Bioinspired Structures for Enhanced Compression and Energy Absorption Properties.

Recent progress in additive manufacturing, also known as 3D printing, has offered several benefits, including high geometrical freedom and the ability to create bioinspired structures with intricate details. Mantis shrimp can scrape the shells of prey molluscs with its hammer-shaped stick, while beetles have highly adapted forewings that are lightweight, tough, and strong. This paper introduces a design approach for bioinspired lattice structures by mimicking the internal microstructures of a beetle's forewing, a mantis shrimp's shell, and a mantis shrimp's dactyl club, with improved mechanical properties. Finite element analysis (FEA) and experimental characterisation of 3D printed polylactic acid (PLA) samples with bioinspired structures were performed to determine their compression and impact properties. The results showed that designing a bioinspired lattice with unit cells parallel to the load direction improved quasi-static compressive performance, among other lattice structures. The gyroid honeycomb lattice design of the insect forewings and mantis shrimp dactyl clubs outperformed the gyroid honeycomb design of the mantis shrimp shell, with improvements in ultimate mechanical strength, Young's modulus, and drop weight impact. On the other hand, hybrid designs created by merging two different designs reduced bending deformation to control collapse during drop weight impact. This work holds promise for the development of bioinspired lattices employing designs with improved properties, which can have potential implications for lightweight high-performance applications.

Experimental investigation of ultrasonic assisted coating on three-point bending behavior of 3D printed polymeric bone plates for biomedical applications

3D printed Poly Lactic Acid (PLA) bone plates exhibit limited three-point bending strength, restricting their viability in biomedical applications. The application of polydopamine (PDM) enhances the three-point bending strength by undergoing covalent interactions with PLA molecular structure. However, the heavy nature of PDM particles leads to settling at the container base at higher coating solution concentrations. This study investigates the impact of ultrasonic-assisted coating parameters on the three-point bending strength. Utilizing Response Surface Methodology (RSM) for statistical modeling, the study examines the influence of ultrasonic vibration power (UP), coating solution concentration (CC), and submersion time (TIME). RSM optimization recommended 100 % UP, 6 mg/ml CC, and 150 min TIME, resulting in maximum three-point bending strength of 83.295 MPa. Microscopic images from the comparative analysis revealed non-uniform coating deposition with mean thickness of 6.153 µm under normal coating. In contrast, ultrasonic-assisted coating promoted uniform deposition with mean thickness of 18.05 µm. The results demonstrate that ultrasonic-assisted coating induces PDM particle collision, preventing settling at the container base, and enhances three-point bending strength by 7.27 % to 23.24 % compared to the normal coating condition. This study emphasizes on the potential of ultrasonic-assisted coating to overcome the limitations of direct immersion coating technique.

Feasibility study on thermo‐mechanical performance of 3D printed and annealed coir fiber powder/polylactic acid eco‐friendly biocomposites

AbstractThe enhancement of the mechanical and thermal characteristics of 3D printed polylactic acid (PLA) composites reinforced by coir fiber powder (CFP) has been investigated by varying the weight percentage (wt%) of the reinforcement and annealing process. CFP/PLA composite filaments with CFP compositions of 0.1, 0.3, and 0.5 wt% were fabricated. These filaments were used to print CFP/PLA test specimens. The specimens were annealed at 90°C for 120 min in a hot air oven followed by cooling at room temperature. Mechanical, morphological, crystalline, and thermal characterizations were conducted on these specimens. The tensile and flexural strength of neat PLA were observed as 49.7 and 82.4 MPa which decreased by 6.4% and 8.13% respectively for printed composite specimens with 0.5 wt% CFP as reinforcement material. On the other hand, the annealed CFP/PLA composite specimen, with 0.1 wt% CFP as a reinforcement material, demonstrated higher tensile and flexural strength. Specifically, it exhibited a maximum tensile strength of 56.4 MPa and a maximum flexural strength of 92.9 MPa, which are 13.5% and 12.7% higher, respectively, than neat PLA. These strengths are 15.5% and 16.7% higher, respectively, than those of the unannealed CFP/PLA composite specimen with the same wt% of CFP reinforcement. The annealing process increased the crystallinity of composites by enhancing the crystallinity index (63%) and crystalline size (6.7 nm). The high thermal stability of composites (with a glass transition temperature of 256°C) makes them suitable for applications in food and medical packaging.Highlights Enhancement of thermo‐mechanical characteristics of 3D printed bio‐composites. Annealing process improved mechanical features of 3D printed bio‐composites. Annealed composite with 0.1 wt% as reinforcement demonstrated better properties. SEM and XRD studies confirmed failure mechanisms and crystalline structure. Thermal and mechanical assets favor its utilization in food wrapping applications.

Mechanical properties of laminate materials based on polylactic acid and polyvinyl chloride meshes as reinforcement

The 3D printing parameters are known to have a significant impact on manufactured parts, and the layered morphology of these parts makes mechanical design analysis for engineering applications difficult. In this work, the tensile strengths and microhardness of 3D printed polylactic acid (PLA) specimens with different orientations and numbers of individual layers of mesh material (polyvinyl chloride – PVC) were investigated as a laminate composite. Composite specimens were obtained using 3D printing via fused deposition modelling (FDM). Moreover, the influence of printing parameters (i.e. infill density and layer height) and the number and orientation of reinforced meshes on the mechanical response was investigated. Fracture strength of PLA/PVC laminate composites ranges from 31.30 MPa (3 PVC mesh layers; mesh height position: 25 %│50 %│75 %; infill density: 60 %; PVC mesh orientation: 90°│45°│90°; layer height: 0.2 mm) to 18.62 MPa (without PVC mesh; infill density: 30 %; layer height: 0.1 mm) demonstrating a significant impact of the number of the PVC mesh layers, infill density of PLA and layer height on the final mechanical parameters of printing PLA/PVC elements. The surface hardness at the micro load level showed that the number of reinforcement layers affects the microhardness value, as well as material filling and mesh orientation. The specimen with the following parameters gave the best results: layer height: 0.2 mm; 3 PVC mesh layers; infill density: 60 %; PVC mesh orientation: 90°│45°│90°. The average hardness values for one layer and three layers of mesh were in accordance with tensile test results.

Enhancing shape-recovery ratio of 4D printed polylactic acid (PLA) structures through processing parameter optimization

Enhancing shape-recovery ratio of 4D printed polylactic acid (PLA) structures through processing parameter optimization

Optimisation of Process Parameters on Tensile Strength of 3D Printed Polylactic Acid (PLA) Parts: ASTM D638 Type – IV

Purpose: The purpose of this study is to optimize the influence of 3D printing processing parameters on the ultimate tensile strength of 3D printed Polylactic Acid (PLA) parts. The objective is to develop predictive models to help predict and attain optimised mechanical strength integrity of 3D printed parts.
 Design/Methodology/Approach: In the present study, 3D printed PLA samples were modelled and fabricated using carefully selected processing parameters-processing speed, processing temperature and nozzle diameter. Tensile tests were performed by ASTM D638 standard. Two characteristics response optimisation models based on Taguchi Technique and multi-linear regression models were developed to optimise the process parameters and the ultimate tensile strength of the 3D printed samples.
 Findings: Results of this study reveal that ultimate tensile strength is significantly affected by the Nozzle diameter. The ultimate tensile strength of the 3D-printed PLA sample was found to be significantly higher than the strength of the original PLA filament printed.
 Research Implications/Limitations: In this study, only three critical 3D printing processing parameters including, processing speed; processing temperature and nozzle diameter were implemented concurrently.
 Practical implication: The optimisation of process parameters for enhancing the tensile strength of 3D-printed PLA parts holds significant practical consequences, including cost savings, improved performance, sustainability, and innovation. The aforementioned consequences render PLA a more feasible and appealing material option for a diverse array of applications and industries.
 Social implication: Optimisation of PLA printing can promote community engagement by allowing individuals to bring their creative ideas to life, fostering a sense of community and innovation.
 Originality / Value: The unique aspect of this research resides in its particular emphasis on PLA, the utilization of empirical and data-based techniques to optimise process parameters, and its potential to enhance the real-world implementation of 3D printing with PLA across diverse industries.