Printed Circuit Boards are the fundamental component of almost every electronic device with usage intensifying at an average rate of 8.7 %. However, this leads to a generation of 45 million tons of electronic waste (E-waste) annually posing significant and concerning environmental risks. Recycling these waste printed circuit boards (PCBs) is vital, in terms of environmental pollution, prevention and resource recycling. Activating these non-metallic fractions of the printed circuit boards results in the development of unique textural properties and functionalities which resemble aluminosilicates; confirmed by FTIR, XRD, XPS, XRF, and TGA and could potentially be applied for the uptake of Fluoride and Arsenate. In this study, Activated Non-metallic fraction of the Printed Circuit Boards (A-NMP) was used to investigate various physio-chemical parameters, including contact time, pH, adsorbent dose, and initial concentration to optimize the reaction conditions for the uptake of F− and As(V) from aqueous solutions and, compared its adsorption capacity with other natural and synthetic aluminosilicate. The maximum adsorption capacity comes out to be 4.33 mg g−1 and 4.65 μg g−1 for F− and As(V) and best fit to Langmuir and Freundlich adsorption isotherms, respectively. Kinetic modelling reveals that the adsorption of F− follows pseudo-first-order kinetics whereas, As(V) follows pseudo-second-order kinetics. Moreover, Intra-particle diffusion revealed a chemisorption-controlled process for both the adsorbates. Furthermore, in a binary component system the F− and As(V) showed the maximum percentage removal of 92 % and 76 %, respectively at pH 5, and best fit to Langmuir adsorption isotherm.
Read full abstract