The 4${s}_{1/2}$-4${p}_{1/2}$ and 4${s}_{1/2}$-4${p}_{3/2}$ transitions in the Cu-like ions of the elements Sn, Xe, La, Nd, Eu, Gd, Dy, and Yb (atomic numbers Z=50, 54, 57, 60, 63, 64, 66, and 70) have been observed in the spectra from the Princeton Large Torus tokamak. The experimentally determined transition energies were compared to the transition energies calculated using the multiconfiguration Dirac-Fock technique. By including previously published observations, the experimental and calculated transition energies were compared for the entire Cu i isoelectronic sequence from Ru (Z=44) to U (Z=92). Contrary to the conclusion of Cheng and Wagner [Phys. Rev. A 36, 5435 (1987)], we find significant discrepancies between the experimental and calculated transition energies. The discrepancies are attributable to electron correlation corrections that are not accounted for in the calculation.
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