Primary Cracking Research Articles

Noble metal-free tandem catalysis enables efficient upcycling plastic waste into liquid fuel components

The lack of effective approaches for upcycling waste plastic has led to severe environmental pollution and squandering of carbon resources. While hydrocracking macromolecular polyolefins over typical metal-zeolite catalyst produces high quality liquid fuel components, the limited activity of base metal and restricted accessibility of acid sites within microporous zeolite renders this process still not in practical scale. A tandem catalyst comprising Ni-WO3/Al2O3 and Beta zeolite was developed for consecutive hydrocracking polyolefins, achieving a yield of 86.2 % of primarily gasoline-jet ranged hydrocarbons (mainly C5-C16 and minor C16+) at 280 °C. The incorporation of tungsten species onto Ni/Al2O3 largely enhances the surface acidity and accelerates the primary cracking process that converts polyethylene (PE) into medium-sized intermediates, which would readily diffuse into the pore networks of Beta and undergo further cracking to yield desired liquid hydrocarbons. In addition, this tandem catalyst also promotes facile hydrocracking of consumer-grade plastic waste and maintains excellent stability over 5 recycling tests. The noble-metal-free catalyst achieves an impressive liquid formation rate of 5.74 g·gcat.−1·h−1, rivaling the noble metal-based catalyst and demonstrating high application prospects.

Nano-micrometer scale characterization of PWSCC crack tips in the transition zone of 52M overlay and the implication to intergranular cracking

This study examines the microstructural characteristics of the primary water stress corrosion cracking (PWSCC) crack tip in the transition zone (TZ) of the 52 M overlay and its implications for intergranular cracking. In the TZ, the Cr content at grain boundaries near the fusion boundary (FB) is lower than those farther from the FB. Additionally, residual strain at grain boundaries near the FB is higher than that farther away, with the fine-grained zone around the FB showing higher local deformation than the surrounding columnar grains. Stress corrosion cracking (SCC) crack growth rate (CGR) test results indicate that the TZ showed certain SCC sensitivity, and the closer to the FB, the lower the SCC resistance. Analysis of the SCC crack tip found that the distinctive composition distribution of the 52 M overlay TZ, characterized by low Cr and high Fe near the FB, is prone to intergranular oxidation, thereby reducing SCC resistance. Conversely, higher Cr and lower Fe content at grain boundaries in the TZ farther from the FB form dense, Cr-rich oxides ahead of the crack tip that slow SCC crack growth, resulting in the diffusion of oxidation along the dislocation structure into the grains and forming a fibrous oxidation zone.

A cumulative damage model for tubes in nuclear power plants subject to continuous degradation and multi-effect shocks under dynamic environments

Continuous degradation and shocks are two vital damage mechanisms for tubes under dynamic environments in nuclear power plants (NPPs). In this work, we presented a cumulative damage model to evaluate the reliability of tubes in NPPs, which accounts for continuous degradation and random shocks. The dynamic environments were assumed to obey a homogenous Markov process. Continuous degradation was described as a general stochastic process with independent increments. A multinomial distribution was used to depict the multiple effects of Poisson-distributed shocks on tubes. The influence of dynamic environments on the cumulative damage process of tubes was also explicitly modeled. Closed-form reliability measures were derived, such as reliability functions and mean time to failure (MTTF) of tubes. Drawing upon a case study from the existing literature, the analytical solution was validated through a comparative analysis with the outcomes of Monte Carlo simulation (MCS) and other methodologies referenced in the literature. As a practical engineering application, the reliability of steam generator tubes made of Alloy 690 within pressurized water reactors (PWRs), which are susceptible to primary side stress corrosion cracking (PWSCC) and the effects of water hammer, was calculated. The findings indicate that the probabilities of steam generator tube rupture (SGTR) as estimated by the model and those inferred from operational experience have the same order of magnitude.

The generation mechanism of deep natural gas in Tabei uplift, Tarim Basin, Northwest China: insights from instantaneous and accumulative effects

The natural gas heavy carbon isotope and high dryness coefficients genesis in Tabei uplift, Tarim Basin has been highly controversial. To investigate the generation mechanisms of natural gas in the Tabei Uplift. Natural gas chemical composition, carbon isotopes were used to analyze the genesis of natural gas, source rock maturity, and basin modeling were conducted to reconstruct the natural gas generation process, and the influences of instantaneous and cumulative effects on natural gas properties was discussed. The results show that the dryness coefficients of natural gas range from 0.62 to 0.99 (average: 0.92), the methane contents range from 30.42% to 96.4% (average: 85.10%), ethane contents from 0.43% to 15.58% (average: 3.39%), propane contents from 0.11% to 11.43% (average: 1.78%), and the methane carbon isotopes range from −47.30‰ to −33.80‰ (average: −36.96‰), ethane carbon isotopes range from −39.60‰ to −33.20‰ (average: −35.57‰), propane carbon isotopes range from −36.90‰ to −28.50‰ (average: −35.49‰). Compared with the actual regional thermal evolution of the source rock (Ro% range from 1.4%∼1.7%), the natural gas exhibits excessively high dryness coefficients and heavy methane carbon isotope characteristics. The natural gas is primary cracking gas and sourced from marine type II kerogen. The dryness coefficient, methane carbon isotopes, and source rock maturity gradually increases from the west to the east. Instantaneous effects and leakage led to the dry gas and relative heavy methane carbon isotopes generated at a low maturity level. The current natural gas in the Ordovician reservoirs was all generated during the Himalayan orogeny. Long period pause of the gas generation between the two hydrocarbon generation phases is the main cause for the instantaneous effects.

In Situ Combustion Characteristics of Heavy Oil in the Liaohe Oilfield at Different Temperatures

This study conducted in situ combustion oxidation experiments on crude oil from Block D within the Liaohe Oilfield, utilizing a kettle furnace low-pressure oxidation reaction method at various temperatures. The molecular composition of oxidation products was analyzed using gas chromatography–mass spectrometry (GC–MS) and high-resolution mass spectrometry. The results reveal that the molecular composition of the products remains relatively stable up to 300 °C, exhibiting a slight increase in C13-C30 alkanes. The ratio of the peak area for C21 to bisnorhopane is 0.082. From 300 °C to 450 °C, compounds with long alkyl chains gradually undergo thermal cracking, resulting in a significant increase in the production of alkanes within the C10–C30 range. The concentration of saturated hydrocarbons produced through thermal cracking reaches its maximum at a temperature of 400 °C. The most abundant peak of n-alkane is observed at C21, with a quantified ratio of peak area for C21 to bisnorhopane at 6.5, indicating a two-order magnitude increase compared to crude oil. From 500 °C to 600 °C, compounds undergo more profound thermal cracking and condensation processes. The predominant hydrocarbons consist of aromatic molecules containing two to six rings substituted with short side chains. The double bond equivalent (DBE) values of carbazoles and carboxylic acids are determined as 30 and 25, respectively. At 600 °C, the peak area ratio of naphthalene to biodecane is 300, indicating a remarkable increase of five orders of magnitude compared to the crude oil. The present study elucidates the correlation between the characteristics of combustion components in crude oil and the corresponding combustion temperature. Primary cracking reactions within crude oil are promoted effectively when keeping the combustion zone at 350 °C and 450 °C. This process significantly reduces the viscosity of heavy oil and enhances its fluidity.

Quantitative study on the influence of strain amplitude on deformation mechanisms and cracking modes during cyclic torsion of AZ31 magnesium alloy

AbstractThe influence of strain amplitude on deformation mechanisms and cracking modes during cyclic torsion of the AZ31 magnesium (Mg) alloy was quantitatively investigated via EBSD‐SEM characterization. At 0.42% strain amplitude, basal slip was the dominated deformation mechanism throughout the entire fatigue life. At 1.732% strain amplitude, the activation of deformation mechanisms was featured by the periodic transition: tension twinning + basal slip (during counterclockwise torsion) then detwinning + tension twinning + basal slip (during reverse torsion). Moreover, cracking along slip traces (ST) and tension twins (TTW) were the primary cracking modes at 0.42% and 1.732% strain amplitude, respectively. ST cracking and TTW cracking preferentially appeared in soft‐oriented grains for basal slip and tension twinning, respectively. The underlying mechanisms governing the activation of various deformation mechanisms, cracking modes, and cyclic stress–strain responses were systematically discussed.

Estimation of residual stress in dissimilar metals welding using deep fuzzy neural networks with rule-dropout

Welding processes are used to connect several components in nuclear power plants. These welding processes can induce residual stress in welding joints, which has been identified as a significant factor in primary water stress corrosion cracking. Consequently, the assessment of welding residual stress plays a crucial role in determining the structural integrity of welded joints. In this study, a deep fuzzy neural networks (DFNN) with a rule-dropout method, which is an artificial intelligence (AI) method, was used to predict the residual stress of dissimilar metal welding. ABAQUS, a finite element analysis program, was used as the data collection tool to develop the AI model, and 6300 data instances were collected under 150 analysis conditions. A rule-dropout method and genetic algorithm were used to optimize the estimation performance of the DFNN model. DFNN with the rule-dropout model was compared to a deep neural network method, known as a general deep learning method, to evaluate the estimation performance of DFNN. In addition, a fuzzy neural network method and a cascaded support vector regression method conducted in previous studies were compared. Consequently, the estimation performance of the DFNN with the rule-dropout model was better than those of the comparison methods. The welding residual stress estimation results of this study are expected to contribute to the evaluation of the structural integrity of welded joints.

The mechanism of oleic acid deoxygenation to green diesel hydrocarbon using porous aluminosilicate catalysts

The role of mesoporous solid acid aluminosilicate in the oleic acid deoxygenation was elucidated using ZSM-5 and Al-MCM-41 impregnated with Ni. The mesoporous supports were synthesized using a similar initial Si/Al ratio but employing different templates to vary the mesopores. ZSM-5_T produced interparticle mesopores when using TPAOH (tetrapropylammonium hydroxide) as a template. Meanwhile, ZSM-5_S with a well-defined intraparticle mesoporous channel was formed using a silicalite template. Al-MCM-41 synthesized without a template produced one-dimensional highly ordered mesoporous channels. The arrangement of mesoporosity in aluminosilicate determined the mechanistic pathway of oleic acid conversion into hydrocarbon. Oleic acid underwent primary thermal cracking into carboxylic acid before progressing into the subsequent decarbonylation reaction. The diesel hydrocarbon yield was enhanced following the order of Al-MCM-41>ZSM-5_S>ZSM-5_T>blank reaction. Large intraparticle mesoporosity produced long-chain carboxylic acid from catalytic cracking of oleic acid, which was subsequently deoxygenated into long-chain hydrocarbons.

Hydrogen transfer reaction in butene catalytic cracking over ZSM-5

Hydrogen transfer reaction (HTR) is the pivotal side reaction in the catalytic cracking process of low carbon olefins. The intricate reaction pathways and product diversity of HTR directly impact the selective formation of ethylene and propylene. Therefore, elucidating the key HTR in various reaction pathways and defining the hydrogen transfer index (HTI) as a criterion lay a scientific foundation for precisely regulating HTR during olefin catalytic cracking process. Herein, the influence of the acid strength of ZSM-5 zeolites on the HTR degree was analyzed in butene catalytic cracking. Results showed that isobutane was the predominant component of HTR products, mainly derived from HTR during the dimerization-cracking of pentene (butene primary cracking product). Subsequent pentene catalytic cracking experiments validated this conclusion. Thus, the HTI in butene or pentene cracking process was defined as follows: for butene cracking process, HTI = Si–C4H10/SC5H10; for pentene cracking process, HTI = Si–C4H10/SC4H8. The HTI accurately reflected the extent of HTR with respect to the acid properties of the catalysts. Moreover, the reaction network of butene catalytic cracking process was optimized, providing a comprehensive explanation for the intriguing phenomenon of decreasing butene conversion with increasing reaction temperature when the acid strength of ZSM-5 was weak. Finally, a high-performance butene catalytic cracking catalyst, De-TS-1-0.25%P, was developed, exhibiting high olefin selectivity (92.33 %) and outstanding stability (307 h) in the conversion of butene.

Characteristics of 3D Printed Functionally Graded Material for Replacement of Dissimilar Metal Weld in Nuclear Reactor

The dissimilar metal welds in the most of the reactors are connections between low alloy steel parts and stainless steel piping. There is a high possibility of primary water stress corrosion cracking (PWSCC) damage attributed to residual stress caused by the difference in material properties in the dissimilar metal weld joints. A number of accidents such as leakage of radioactive coolant due to PWSCC have been reported around the world, posing a great threat to nuclear safety. The objective of this study is to develop a technology that can fundamentally remove dissimilar metal welds by replacing the existing dissimilar metal parts with the functionally graded material (FGM) manufactured by metal 3D printing consisting of low alloy steel and austenitic stainless steel. A powder production, mixing ratio calculation, and metal 3D printing were performed to fabricate the low alloy steel-stainless steel FGM, and microstructure analysis, mechanical properties, and coefficient of thermal expansion (CTE) measurement of the FGM were performed. As a result, it is observed that CTE tended to increase as the austenite content increased in FGM. The gradual change of coefficient of thermal expansion in a FGM showed that the additive manufacturing using 3D printing was effective for preventing an abrupt change in thermal expansion properties throughout their layers.

Preferential intergranular oxidation as a potential degradation mechanism for Alloy X-750 CANDU spacers

Oxidation experiments on Alloy X-750 were performed in reducing CO-CO2 mixtures to assess the possibility of preferential intergranular oxidation (PIO) in relation to CANDU garter-spring spacers. The testing environments simulate hypothetical off-chemistry scenarios, promoting the oxidation of the alloying elements, but not Ni. Surface and cross-section microscopy corroborated by Auger electron spectroscopy confirmed the occurrence of internal and intergranular oxidation in Alloy X-750, accompanied by Ni nodule expulsion to the surface. Results are qualitatively similar to observations in Alloy 600 exposed to 480°C hydrogenated steam, used as an accelerated environment for primary water stress corrosion cracking (PWSCC) testing.

Geochemistry of Liquid Hydrocarbons and Natural Gases Combined with 1D Basin Modeling of the Oligocene Shale Source Rock System in the Offshore Nile Delta, Egypt.

The current study aims to integrate the geochemical characteristics of the Oligocene shale source rock system, oil, condensate, and natural gas samples in the Oligocene sandstone reservoirs from three exploration wells located in the offshore Nile Delta, East Mediterranean Sea, using organic geochemistry and a 1D basin modeling scheme. The Tineh shales exhibit total organic carbon values ranging between 0.90 and 1.89 wt %, along with hydrogen index values in the range of 54-240 mg hydrocarbon/g rock. The geochemical characterization suggests that the shale intervals of the Oligocene Tineh Formation contain type II-III and type III kerogens and, thereby, could be regarded as promising oil- and gas-prone source rocks with high contributions of gas generation potential. The study also reconstructs the 1D thermal and burial history models, showing that the Oligocene Tineh source rock system is in the main oil and wet gas generation phases from the late Miocene to the present time. The simulated basin models reveal the transformation (TR) of 10-50% kerogen to oil during the late Miocene-early Pliocene period and that the Oligocene Tineh source rock system has larger oil generation and expulsion competency, with a TR value of up to 65% during the early Pliocene-Pleistocene time period. The thermogenic gas was also formed during this time and continued to the present day. This study also investigated the presence of oil and condensate in the Oligocene sandstone reservoir samples and revealed that they were generated from mature source rock, ranging from moderately to highly mature stages. This source rock unit was deposited in fluvial to fluvial-deltaic environments under oxic mixed organic conditions and accumulated during the Tertiary time, as evidenced by the presence of the oleanane biomarker dating indicator. The molecular and isotope compositions of natural gases revealed that most of the natural gases in the Oligocene sandstone reservoir are mainly thermogenic methane gases that were generated from mainly mixed organic matter. The thermogenic methane gases were formed mainly from secondary cracking of oil and gas, with small contributions of primary kerogen cracking. The properties of natural gases together with oil and condensate in the Oligocene reservoir rocks suggest that most of the thermogenic methane gases and associated liquid hydrocarbons are derived primarily from the Oligocene shale source rock system and formed by primary kerogen cracking and secondary oil and oil/gas cracking in different thermal maturity stages. Therefore, the Oligocene Tineh Formation can be regarded as self-source generation and self-reservoir rock; hence, an intensive oil exploration and production program can be recommended whenever the Tineh source rock system is is well developed and deeply buried.

Modeling damage caused by combined thermal and traffic loading using viscoelastic continuum damage theory

Various engineering models have been proposed to mitigate fatigue cracking associated with thermal and traffic loadings, which are the two primary fatigue cracking mechanisms that negatively affect the service life of asphalt pavement. Thermal fatigue cracking is induced by cycles of temperature changes with relatively long time periods, which can be regarded as slow frequency sinusoidal loading. Traffic fatigue cracking is induced by numerous vehicle load repetitions and is often characterized using fast frequency sinusoidal loading. These two loading types occur simultaneously in the field. In order to investigate how to properly model the damage due to these two loading types, a set of tests that vary the load, frequency, and mode of testing was designed to mimic the scenarios that asphalt pavements experience under thermal loading and traffic loading separately and under the combined and simultaneous effects of both thermal and traffic loading. The viscoelastic continuum damage (VECD) model was applied to simulate the changes in material integrity under each condition. After determining the appropriate configuration for the proposed prediction model, the material integrity predictions were found to be accurate for the fast frequency tests but less accurate for the slow frequency tests. This difference is attributable to plasticity being a much more significant factor under slow frequency conditions than under fast frequency conditions. For the tests combining both fast and slow frequency conditions, the material integrity results oscillated continuously. It was postulated that these oscillations were due to the recovery mechanisms of asphalt concrete such as nonlinearity and healing. When the simplified viscoelastic continuum damage (S-VECD) model was applied, which does not consider the material’s recovery characteristics, the predicted material integrity was able to match the overall trend observed in the tests. Ultimately, a new way to model combined damage simultaneously under two cracking mechanisms (thermal fatigue cracking and traffic fatigue cracking) is introduced in this paper.

Quantitative investigation on the deformation modes and cracking behavior during cyclic torsional loading of extruded pure Mg and Mg‐3Y alloy

AbstractThis study explores the effect of adding 3 wt.% Y to pure magnesium (Mg) on its mechanical behavior under cyclic torsional loadings at room temperature. The research examines deformation and cracking modes in both pure Mg and Mg‐3Y samples. Deformation modes are monitored using quasi‐in‐situ EBSD observations coupled with slip trace analysis. The findings reveal that basal slip dominates the cyclic deformation throughout the fatigue life of the pure Mg sample, while both basal and pyramidal slip dominate the cyclic deformation in the Mg‐3Y sample. Intergranular cracking is the primary cracking mode for both samples under cyclic torsional loadings. Basal and pyramidal slip persistent slip band (PSB) cracking serves as a primary transgranular cracking mode in the pure Mg and Mg‐3Y samples, respectively. The study also investigates the underlying mechanism governing the activity of various deformation modes, cracking modes, and mechanical behavior.

The influence of pore-architecture over n-heptane cracking using MFI, *BEA and MSE zeolite catalysts: Multipore versus hierarchical porosity

The catalytic properties of zeolitic materials are governed by the intricate interplay between catalytic and transport processes, which, in turn, depend critically on the topology and morphology features. Here, the catalytic performance of typical three dimensional zeolites, including medium pore MFI, large pore *BEA and multi-pore MSE topologies with comparable Si/Al ratios are employed as n-heptane cracking catalysts to inspect the influence of topology on product slates for naphtha molecules. Furthermore, a bead-milling coupled with porogen assisted recrystallization method is used to fabricate hierarchically porous MSE zeolite for the first time. The catalytic n-heptane cracking properties of hierarchical MSE zeolite are compared with the hierarchical MFI and *BEA analogues, derived from the cracking mechanism ratio and the hydrogen transfer coefficient, respectively, to exam the influence of transport on product distributions. Multi-pore MSE zeolite outperforms MFI and *BEA zeolites in terms of light olefin selectivity and yield, owing to an exaggerated contribution from Haag-Dessau mechanism mediated cracking and a reduced probability for side-reactions, as a consequence of decreased residence time for the primary cracking product olefins. The developed methods to fabricated hierarchical zeolites and the revelation of structure-catalysis relationship may inspire future catalyst design for catalytic naphtha cracking.

Biomarker and isotopic characteristics of Miocene condensates and natural gases, West Delta deep marine concession, Eastern Mediterranean, Egypt

The Western Delta Deep Marine Concession (WDDM) in the Eastern Mediterranean Sea is one of northern Africa's most recent petroleum-potential regions for gas and condensate exploration. The present study aims to determine the characteristics of the 15 natural gases and 5 associated condensate samples, using molecular compositions and isotopes from the Miocene reservoir rocks in the various wells located in the WDDM. The results of this study are also used to determine the gas-condensate correlation for their probable source rocks as well as the methane-generating mechanisms (i.e., thermogenic or microbiological). Results highlighted in this research reveal that most of the natural gases in WDDM are mainly thermogenic methane gases, with small contributions of biogenic methane gases that were generated from mainly mixed sources, with a high sapropelic organic matter input for biogenic gases. The thermogenic methane gases were formed from secondary oil and oil/gas cracking at the high maturity stage of the gas window. The biogenic gases are also contributed to the Miocene reservoirs, which are formed from the primary cracking of kerogen at low maturity stage by the action of CO2 bacterial reduction. In addition, the saturated and aromatic biomarker results show that the condensate samples were generated from clay-rich source rocks. This source unit of the Miocene condensates were deposited in a fluvial deltaic environmental setting, containing mixed kerogen type II/III and accumulated during the Jurassic–Cretaceous, as evidenced by the age dating indicators. The properties of the natural gases and associated condensates in the Miocene reservoir rocks suggest that most of the thermogenic methane gases, together with the condensate, are derived primarily from mature Jurassic–Cretaceous source rocks and formed by secondary oil and oil/gas cracking at the gas generation window, as demonstrated by the 1-D basin modelling results highlighted in the prior works. Therefore, most of the natural gases in WDDM are non-indigenous and migrated from more mature Jurassic–Cretaceous source rocks in the nearby Northern Sinai provinces or the deeper sequences in the offshore Nile Delta provinces.

Numerical analysis of the enrichment of CH4/H2 in ammonia combustion in a hot co-flow environment

A numerical investigation is conducted using OpenFOAM to study the characteristics of ammonia flames enriched with methane and hydrogen, influenced by a diluted co-flow (exhaust gas). The study aims to explore various flame characteristics, including fuel consumption, ignition delay time, lift-off height and position, temperature, and CO and NO emissions while maintaining a constant energy input of 5 kW. Non-stabilized flames are identified by analyzing the OH peak in the computational domain among ammonia flames enriched with CH4/H2 for different dilutions of O2 (6 %, 9 %, and 12 %). The study is structured into three stages of numerical simulations corresponding to stabilized flames: (1) no reaction, (2) reaction in the absence of O2, and (3) reaction with O2 to see the sole impact of the hot co-flow and local turbulence mixing on the primary cracking of ammonia. Furthermore, the rates of H2 and N2 formation resulting from the utilization of ammonia in the presence of hot co-flow are thoroughly examined. Additionally, the behavior of ammonia flames and CH4/H2-enriched ammonia flames under preheated air conditions (23 % O2) is analysed. Stable flames are observed in the co-flow at 12 % O2, displaying characteristics of Moderate or Intense Low-oxygen Dilution (MILD) combustion. Conversely, ammonia flames under preheated air conditions exhibit conventional flame behavior. Pure ammonia flames exhibit stronger temperature gradients and higher levels of CO and NO emissions. As the enrichment of NH3 with CH4/H2 increases, peak temperatures decrease while lift-off heights increase, indicating a transition towards more distributed flame structures. Notably, the instance with 40 % H2 enrichment exhibits lower NO emissions and a higher rate of ammonia consumption along with more distributive flame characteristics.

The effect of precipitates on low-cycle fatigue behavior of WE54 magnesium alloys under stress-controlled mode

The precipitates have a significant influence on fatigue behavior in magnesium (Mg) alloy. In this work, the effects of precipitates on deformation mode, cracking mode and mechanical behavior during low-cycle fatigue under stress-controlled mode in WE54 Mg alloy at room temperature (RT) was analyzed quantitively and statistically via quasi-in-situ electron backscattered diffraction (EBSD), slip trace analysis, coupled with transmission electron microscopy (TEM). The results reveal that precipitates promoted the activation of pyramidal < c + a > dislocation slip and suppressed the activation of tension twinning in the T6 alloy. In the T4 alloy, persistent slip band (PSB) induced cracking together with intergranular cracking dominated fatigue damage, while intergranular cracking was the primary cracking mode in the T6 alloy. The obvious cyclic hardening behavior of the T4 alloy was attributed to dynamic precipitation, whereas suppressed dynamic precipitation, restrained multiplication of dislocations, together with the appearance of PFZ generated the marginal cyclic hardening behavior in the T6 alloy. Both the T4 and T6 alloys exhibited ratcheting behavior, and precipitates suppressed ratcheting deformation in the T6 alloy. Moreover, the underlying mechanism for the higher fatigue resistance in the T6 alloy was also discussed.

Maceral evolution of lacustrine shale and its effects on the development of organic pores during low mature to high mature stage: A case study from the Qingshankou Formation in northern Songliao Basin, northeast China

Organic matter (OM) hosted pores are crucial for the storage and migration of petroleum in shale reservoirs. Thermal maturity and macerals type are important factors controlling the development of pores therein. In this study, six lacustrine shale samples with different thermal maturities from the first member of the Qingshankou Formation in the Songliao Basin, of which vitrinite reflectance (Ro) ranging from 0.58% to 1.43%, were selected for a comparative analysis. Scanning electron microscopy (SEM) and reflected light microscopy were combined to investigate the development of organic pores in different macerals during thermal maturation. The results show that alginite and liptodetrinite are the dominant primary macerals, followed by bituminite. Only a few primary organic pores developed in the alginite at the lowest maturity (Ro = 0.58%). As a result of petroleum generation, oil-prone macerals began to transform to initial-oil solid bitumen at the early oil window (Ro = 0.73%) and shrinkage cracks were observed. Initial-oil solid bitumen cracked to oil, gas and post-oil bitumen by primary cracking (Ro = 0.98%). Moreover, solid bitumen (SB) was found to be the dominant OM when Ro > 0.98%, which indicates that SB is the product of oil-prone macerals transformation. Many secondary bubble pores were observed on SB, which formed by gas release, while devolatilization cracks developed on migrated SB. Additionally, at the late oil window (Ro = 1.16%), migrated SB filled the interparticle pore spaces. With further increase in temperature, the liquid oil underwent secondary cracking into pyrobitumen and gas, and spongy pores developed on the pyrobitumen at higher levels of maturity (Ro = 1.43%), which formed when pyrobitumen cracked into gas. Vitrinite and inertinite are stable without any visible pores over the range of maturities, verifying their low petroleum generation potential. In addition, it was concluded that clay minerals could have a catalytic effect on the petroleum generation, which may explain why organic-clay mixtures had more abundant pores than single OM particles. However, after Ro > 0.98%, authigenic minerals occupied the organic pore spaces on the organic-clay mixtures, resulting in fewer pores compared to those observed in samples at the early to peak oil window.

Optimization of dissolved hydrogen concentration for mitigating corrosive conditions of pressurized water reactor primary coolant under irradiation (1) evaluation of water radiolysis

ABSTRACT A major subject for evaluating the corrosive conditions in the pressurized water reactor (PWR) primary coolant is to determine the optimal hydrogen concentration for mitigating primary water stress corrosion cracking (PWSCC) without adverse effects on major structural materials. An analytical method combining water radiolysis and electrochemical corrosion potential (ECP) analyses was proposed for evaluating the corrosive conditions in PWR primary coolant. These procedures originally developed for boiling water reactors (BWRs) were successfully extended to PWRs with different water chemistry parameters, including pH, temperature, and radiation qualities, after minor changes in the original procedures and major input parameters, such as the inclusion of the effects of alpha radiolysis and Li+ (Na+) and H+ effects for the anodic polarization curve. This study discusses the results of water radiolysis analysis for PWR primary coolant, and the characteristic behavior of hydrogen peroxide (H2O2) as a function of hydrogen inlet concentrations in PWR primary coolant conditions (higher pH and α-ray irradiation). A possible reaction scheme involving eaq – was proposed for H2O2 suppression under alkaline conditions. The corrosive conditions were discussed in the following publication, using ECP as the major index for PWR corrosive conditions.