Pressure-temperature Estimates Research Articles

Ultrahigh-pressure to high-pressure eclogite in Cuban ophiolitic mélange reveals proto-Caribbean spreading ridge subduction

Proto-Caribbean oceanic crust produced during ocean-floor spreading between diverging North and South American plates was subsequently subducted beneath the Caribbean plate. However, the timing and spatial configuration of proto-Caribbean spreading ridge subduction remain subjects of debate. High-pressure (HP) basaltic metamorphic rocks, representing relics of the subducted proto-Caribbean oceanic crust, commonly occur in Cuban ophiolitic mélanges. In this study, an integrated set of petrological, geochemical, and geochronological data is presented for eclogite from the Las Villas mélange, central Cuba. The typical geochemical signature of mid-ocean-ridge basalt (MORB) indicates that the protolith of eclogite formed at the proto-Caribbean spreading ridge. Based on pressure-temperature (P-T) estimates obtained by pseudosection analysis as well as Zr-in-rutile and Ti-in-zircon thermometry, the following P-T paths for representative samples can be derived: a prograde path from 24−25 kbar and 510−520 °C to peak conditions of 29−31 kbar and 525−575 °C, and a complex retrograde path initially following almost isothermal exhumation to 25−27 kbar, followed by near-isobaric heating to 610−640 °C before final exhumation. This is the first documentation of prograde oceanic ultrahigh-pressure (UHP) metamorphism in the northern Caribbean area. U-Pb dating of magmatic zircon with steep heavy rare earth element (HREE) patterns and negative Eu anomalies yielded a protolith age of 126.3 ± 0.7 Ma. In contrast, metamorphic zircon with flat HREE patterns and without an Eu anomaly yielded a weighted mean age of 118.6 ± 1.6 Ma. The short time interval of >8 m.y. between MORB magmatism and UHP metamorphism suggests that the oceanic crust was subducted to great depth (∼100 km) shortly after generation in an oceanic ridge, which provides robust evidence for subduction of the proto-Caribbean spreading ridge. Furthermore, this work demonstrates high potential to trace ancient spreading ridge subduction by joint petrological, geochemical, and geochronological study of oceanic eclogite.

Coesite-bearing garnet xenocrysts from diatexite in the Nordøyane domain, Western Gneiss Region, Norway: Implications for eclogite-melt interaction at ultra-high pressure

Ultra-high-pressure (UHP) metamorphic rocks in the Western Gneiss Region (WGR) of Norway formed in subducted Baltican crust during the Scandian phase of the Caledonian orogeny. In the Nordøyane UHP domain, eclogites locally preserve coesite and microdiamond. Along the north coasts of Haramsøya and Flemsøya, in situ orthopyroxene-eclogite bodies are surrounded by dioritic "diatexite selvages" containing abundant eclogitic enclaves and xenocrysts. In one location eclogite and diatexite are associated with a quartz diorite dyke that is highly contaminated with eclogitic material. The diatexite matrix and dyke have similar plagioclase + quartz + biotite assemblages with abundant embayed and fragmented garnet and clinopyroxene xenocrysts. Coesite is present in some garnet xenocrysts but has not been found in the adjacent eclogite bodies. Pressure-temperature (P-T) estimates from in situ eclogites range from 2.2-3.2 GPa and 810-840 °C, spanning the quartz-coesite transition, with P-T estimates from xenocrysts spanning a wider range. Diorites and retrogressed eclogites record amphibolite-facies conditions, ca. 1.0-1.5 GPa and 700-800 °C. The wide range and large uncertainties in P-T estimates reflect high-temperature re-equilibration and a relative lack of P-sensitive assemblages. Differences in texture, composition, and included assemblages indicate that the xenocrysts were not derived from the nearby eclogite bodies. By implication, their dioritic hosts were not locally derived but must have originated from a different, probably deeper, source. The results are integrated with a numerical model for WGR tectonic evolution to assess the sources of the melts and their possible effects on the exhumation of UHP rocks in western Norway.

New P-T path of Huwan high-pressure unit from Hong'an orogen, Central China Orogenic Belt: Implications for oceanic to continental subduction and exhumation in the subduction zones

Oceanic to continental subduction is a pivotal process in plate tectonics, yet characterizing this tectonic transition and subsequent exhumation remains a challenging task. This study integrates our novel pressure-temperature (P-T) estimates on a metabasite lens and its hosting metasedimentary rock in the Xiongdian area of the Huwan high-pressure unit of the Hong'an orogen, Central China Orogenic Belt, with existing geochronological data from the same and neighboring outcrops. Our preliminary but comprehensive findings reveal the evolution of this subduction transition process. After the opening at ca. 430–400 Ma the Paleotethyan ocean subducted northward and formed a warm oceanic subduction zone at ca. 400–385 Ma, marked by relatively low P and high T conditions (∼610–740 °C and ∼1.5–1.8 GPa; M1 stage). Subsequently, the Paleotethyan oceanic plate continued its subduction and cooled the overlying mantle until its final closure during ca. 385–300 Ma. This phase led to the subduction of South China Block (SCB) and the formation of a cold continental subduction zone at ca. 300–270 Ma, featured by relatively high P and low T conditions (∼570–610 °C and ∼2.1–2.7 GPa; M2 stage). Following the delamination from the subducted SCB continental lithospheric mantle, the detached high-pressure rocks experienced a two-stage accelerated exhumation process, i.e., early slow exhumation (∼0.7 ± 0.4 mm/a) to shallower mantle depth (∼610–730 °C and ∼1.5–2.1 GPa; M3 stage) at ca. 270–243 Ma and later rapid exhumation (>2.5 ± 0.9 mm/a) to approximately the Moho depth (∼550–600 °C and ∼0.8–1.3 GPa; M4 stage) at ca. 243–233? Ma. To facilitate the buoyancy-driven exhumation of eclogite blocks from their maximum depth (M2 stage), a minimum of ∼16–25 vol% of low-density metasedimentary rock is required. The increasing buoyancy caused by decreasing densities of the high-pressure rocks with exhumation (from M2 to M4 stage), slab break-off induced rebound forces, and other tectonic factors may jointly explain the accelerated exhumation pattern. Our density results also emphasize that, partly owing to a stronger contribution from a buoyancy-driven mechanism, the high-pressure rocks would be preferentially exhumed in warm to extremely warm oceanic subduction zones compared to their intermediate to cold counterparts.

Petrology and Geochemistry of an Unusual Granulite Facies Xenolith of the Late Oligocene Post-Obduction Koum Granodiorite (New Caledonia, Southwest Pacific): Geodynamic Inferences

Pressure–temperature estimates of a xenolith found within a post-obduction granodiorite in southern New Caledonia provide evidence for subcrustal, granulite facies, peak crystallisation conditions (ca. 850 °C—8.5 ± 1.0 kbar), followed by isobaric cooling to 700 °C, and final decompression with partial rehydration at ca. 650 °C—3.5 kbar. The xenolith, dated at 24.7 Ma (U-Pb zircon), i.e., the same age as the granodiorite host rock, has low SiO2 (35.5 wt%) and high Al2O3 (33.2 wt%) contents, suggesting that it is the restite of a previous melting episode, while the elevated Ca (Ba and Sr) contents suggest mantle metasomatism. Although the concentrations of Rb, K, Ca, Ba, and Sr have been strongly modified, some geochemical (REE patterns and some “immobile” trace element ratios) and isotopic (Sr and Nd isotopic ratios, U-Pb zircon age) characteristics of the granulite facies xenolith are similar to those of the xenoliths found in other Late Oligocene intrusions in southern New Caledonia; therefore, this rock is interpreted to be related to an early magmatic episode. The rock protolith was emplaced and equilibrated at the base of the crust where it underwent ductile deformation. Younger ascending magma picked it up and they eventually crystallised together at a shallow crustal level, near the tectonic sole of the ophiolite. The recrystallisation and ductile deformation at ~8.5 kbar suggest that a rheological discontinuity existed at about 25–28 km, probably representing the Moho. It is concluded that a continental crust of normal thickness must have existed beneath New Caledonia at about 24 Ma, i.e., 10 Ma after obduction.

Tracking the Ti4+ substitution in phlogopite by spectroscopic imaging: A tool for unravelling the growth of micas at HP-HT conditions

Phlogopite solid-solutions have a wide pressure–temperature (P-T) stability field and are ubiquitous in a wide variety of geological settings, from deep lithosphere magmatic environments to upper crust metamorphic domains. Phlogopite composition represents therefore a valuable physical–chemical archive and may provide important information regarding its crystallization and the petrogenesis of the host-rock. In this paper we examine the phlogopite phenocrysts from the well-known Fort Regent mica-bearing lamprophyre minette from St. Helier (Island of Jersey, UK). Phlogopite phenocrystals from lamprophyres generally show normal-step and continuous compositional zoning, however those from the Fort Regent minette show a peculiar texture characterized by dark brown high-Ti (average TiO2 ≈ 8.5 wt.%) cores enveloped by euhedral low- to mid-amplitude zonation due to oscillatory contents in Ti, Fe and Mg. Thermo-barometry modelling based on biotite-only composition yields relatively high P-T estimates (T ≈ 970 ± 54 °C at P ≈ 0.73 ± 0.13 GPa) for cores whereas lower values (T ≈ 790 ± 54 °C at P ≈ 0.29 ± 0.13 GPa) are obtained for the outer rims. Comparable temperatures (T ≈ 1075 ± 54 °C) but extremely high and anomalous pressure values (P ≈ 1.82 ± 0.13 GPa) are obtained for the yellowish inner rims. The combination of electron micro probe (EMP) analysis and single-crystal infra-red (FTIR) imaging in the OH-stretching region shows that the exceptional and oscillatory Ti contents are due to the Ti-vacancy substitution, typical of crystallization and growth processes of HP/HT environments. Raman imaging provides additional insight for this process, confirming the dominant dioctahedral nature for the Ti-Fe-rich cores and outer rims. Interpretation of thermobaric estimates obtained from the phlogopite composition-only model, based on the fine-scale compositional evolution, shows that pressure–temperature values from low-Ti high-Mg domains should be carefully evaluated because the substitution mechanisms during the dark mica growth are not univocally related to pressure–temperature variation of the crystallizing environment. Our results demonstrate how a multidisciplinary approach based on the combination of chemical investigations and vibrational spectroscopies could represent a valuable tool to evaluate pressure–temperature estimates from biotite composition-only thermo-barometry models and therefore to correctly unravel HP/HT petrogenetic processes at a very fine scale.

Metamorphic and geochronological constraints on the final assembly of West Gondwana: an Ediacaran-Cambrian collisional setting in the northern Araguaia Orogen, central Brazil

ABSTRACT The Araguaia Orogen, located in Central Brazil, represents an Ediacaran-Cambrian collisional orogen associated with the final assembly of West Gondwana. Two contrasting tectonic models have been proposed for the evolution of this orogen, involving different histories for the Amazonian palaeocontinent drift: (i) subduction of a large ocean and final collision of the Amazonian palaeocontinent with Gondwana between ~ 560 and 500 Ma and (ii) intracontinental orogeny after early amalgamation of the Amazonian palaeocontinent at ca. 620 Ma. Detailed tectono-metamorphic studies in this key locality for the evolution of Gondwana are also still scarce. Hence, in this study we present a detailed metamorphic investigation of two metapelite samples (schists) and one garnet amphibolite aiming to unravel the pressure-temperature-time (P-T-t) paths for the higher grade rocks exposed in this orogen. Pressure-temperature estimates based on thermodynamic modelling using isochemical phase diagrams in the MnNCKFMASHTO system for the schists constrained a single and continuous prograde metamorphic path (burial and heating) from ~ 4–6 kbar and ~ 450–500°C to ~ 7–8 kbar and ~ 580–650°C. The near-peak metamorphic conditions of the garnet amphibolite were estimated from classic geothermobarometry at 7.5 ± 0.8 kbar and 552 ± 40°C. Lutetium-hafnium garnet dating constrained an average age for the prograde metamorphism at around 537–533 Ma. These results show that the Araguaia Orogen records one single metamorphic event during the late Ediacaran-early Cambrian, and likely represents part of a collisional system developed between the Amazonian Craton and Parnaíba Block after the closure of the Clymene Ocean.

Early Neoproterozoic magmatism and Caledonian metamorphism recorded by the Mårma terrane, Seve Nappe Complex, northern Swedish Caledonides

Petrology, geochronology and bulk-rock chemistry are combined to investigate the early Neoproterozoic magmatism and Cambrian–Ordovician metamorphism in the northern Swedish Caledonides. This work includes several lithologies of the Mårma terrane in the Seve Nappe Complex exposed in the Kebnekaise region. U–Pb zircon geochronology yielded crystallization ages of 835 ± 8 Ma for a mylonitic orthogneiss, 864 ± 3 Ma for the Vistas Granite and 840 ± 7 Ma for an intruded granitic dyke, whereas a gabbro and a granodiorite intrusion gave U–Pb zircon crystallization ages of 856 ± 3 Ma and 850 ± 1 Ma, respectively. U–Pb monazite dating of the mylonitic orthogneiss gave an upper intercept age of 841 ± 7 Ma and a lower intercept age of 443 ± 20 Ma. Pressure–temperature estimates derived for the mylonitic orthogneiss reveal metamorphic peak-pressure and peak-temperature of 10.5–11.75 kbar and 550–610°C and 7.4–8.1 kbar at 615–675°C, respectively. Metamorphic pressure–temperature estimates for the Vistas Granite yield 6.5–7.5 kbar at 600–625°C. Whole-rock chemistry coupled with U–Pb geochronology indicates that bimodal magmatism was related to attempted rifting of Rodinia between 870 and 840 Ma. Supplementary material: Supplementary figures and tables are available at https://doi.org/10.6084/m9.figshare.c.6675075 Thematic collection: This article is part of the Caledonian Wilson cycle collection available at: https://www.lyellcollection.org/topic/collections/the-caledonian-wilson-cycle

Monazite in the eclogite and blueschist of the Svalbard Caledonides: its origin and forming-reactions

High-pressure low-temperature rocks from Svalbard are an excellent target for studying metamorphic reactions in Phanerozoic subduction zones. This study reveals the presence of monazite in an eclogite and a blueschist from the Vestgötabreen Complex, southwestern Svalbard. In order to investigate the monazite-forming reaction, we obtained pressure–temperature estimates coupled with U–Pb and Lu–Hf dating. Combined geothermobarometry allows to constrain three evolutionary stages of garnet growth in the eclogite: nucleation (1.6 ± 0.3 GPa at 460 ± 60 °C), peak-pressure (2.3 ± 0.3 GPa at 507 ± 60 °C), and peak-temperature (2.1 ± 0.3 GPa at 553 ± 60 °C). A zircon age of 482 ± 10 Ma is interpreted to belong to the prograde part of the pressure–temperature path. Monazite forms inclusions within garnet rims, or it is surrounded by allanite and apatite, altogether forming pseudomorphs of a tabular shape in the matrix. Textures, geothermobarometry and geochronology support the conclusion the monazite formed under high-pressure conditions at 471 ± 6 Ma. We propose that the monazite crystallization in the eclogite happened due to a decomposition of accessory phases during the decompression after peak-pressure of the metamorphic cycle. Monazite in the blueschist occurs as inclusions in garnet cores and gives an indicative age of 486 ± 6 Ma, which is interpreted to reflect the prograde growth of the garnet. Lu–Hf garnet dating resolves an age of peak-pressure metamorphism in the blueschist at 471.1 ± 4 Ma under conditions of 2.0 ± 0.03 GPa and 500 ± 30 °C. The Vestgötabreen Complex provides evidence for an early Ordovician modern-style subduction system in the proximity of the Baltica margin. Hence, this study also supports the tectonic models that favour a mixed Baltican and Laurentian provenance of south-western Svalbard.

To sink, or not to sink: The thermal and density structure of the modern northern Andean arc constrained by xenolith petrology

Abstract The thermal and compositional structure of arcs influence magmatic differentiation and lower-crustal foundering, two key processes impacting the evolution of the continental crust. Although many studies have proposed time scales of lithospheric recycling based on convective downwelling calculations, these models depend on the composition, density (ρ), and thermal structure of the lower crust and mantle, which are difficult to quantify in active continental arcs. Here, we constrained these properties for the Andean Northern Volcanic Zone using direct petrologic observations from a unique suite of lower-crust and mantle xenoliths from Mercaderes, Colombia. Chemical abrasion–isotope dilution–thermal ionization mass spectrometry (CA-ID-TIMS) U-Pb dates for zircons within the host tuff indicate the xenoliths erupted no earlier than 238 (±19) ka and thus capture a recent snapshot of the arc and subarc mantle. Equilibrium pressure-temperature (P-T) estimates for 81 xenoliths define three distinct thermal domains, interpreted as (1) a steep conductive geothermal gradient in the lower arc crust; (2) a convecting mantle wedge; and (3) cooled mantle in proximity to the subducting slab. Our results indicate the presence of an ~10–14-km-thick, high-density lithospheric root that is ~0.1 g/cm3 denser than the underlying mantle. Unlike records from exhumed paleoarcs, Rayleigh-Taylor instability calculations using our P-T-ρ constraints are unrealistically short for the northern Andes. We suggest the presence of partial melts in this hot arc root as a potential source of buoyancy preventing or significantly slowing down foundering.

Diversity of origin and geodynamic evolution of the mantle beneath the Variscan Orogen indicating rapid exhumation within subduction-related mélange (Moldanubian Zone, Bohemian Massif)

A variable assemblage of ultrabasic rocks along with minor eclogites investigated on a small area of a few km2 (Gföhl unit, Moldanubian Zone of the Bohemian Massif) reflects incorporation of contrasting mantle domains within a subduction-related tectonic mélange during the Variscan orogeny. Based on mineral composition, whole-rock chemistry, isotopic signatures, and pressure-temperature (P–T) estimates, four principal lithological types have been distinguished (1) spinel harzburgite (2) garnet lherzolite (3) spinel websterite and (4) eclogite. Spinel harzburgite, exclusively associated with HT migmatized gneisses, corresponds to the refractory oceanic lithosphere, as demonstrated by whole-rock composition (low Al2O3, CaO), chemistry of spinel (Cr# <0.4) and Al-rich pyroxene (Al2O3 up to 9 wt%). By contrast, garnet lherzolite, predominantly enclosed in HP felsic granulite, represents a fragment of the subcontinental mantle wedge, considering the strong fertile character (high Al2O3, TiO2, Yb) and spinel chemistry (Cr# >0.5). Websterites likely represent products of decompression partial melting of the asthenospheric mantle with a variable input of crustal component, whereas eclogites correspond to HP crystal cumulates from partial melts migrating through the Variscan mantle wedge. Both peridotite protoliths experienced various degrees of secondary refertilization, recorded as a cryptic metasomatic overprint, due to interaction with subduction-related silicate melts, from which numerous websterite and rare eclogite layers crystallized. The secondary mantle refertilization via melt-peridotite reaction is well-documented by decreasing bulk Mg# along with MgO/SiO2, elevated Al2O3/SiO2, TiO2 and FeOtot contents, and isotopic composition (87Sr/86Sr338 ~ 0.7051). Moreover, the positive correlation between highly fluid-immobile incompatible trace elements (e.g. Ti, Sc, V, Zr, Yb) and distribution of REE and Li is consistent with the melt refertilization trend.

Late Neoarchean terrane and Paleoproterozoic HT–UHT metamorphism on southern Devon Island, Canadian Arctic

The northernmost exposures of the Laurentian shield in Canada outcrop on Devon and Ellesmere islands, near the tectonic domains of the ≥2.6 Ga Rae Province and ca. 2.0–1.9 Ga Thelon–Inglefield orogenic arc. We report (Th)–U–Pb zircon and monazite ages along with phase equilibrium modelling pressure–temperature estimates for southern Devon Island, the only area on Devon or Ellesmere islands with previously known Archean rocks. Our results demonstrate that southern Devon Island is a late Neoarchean (ca. 2.55–2.47 Ga) terrane composed of lower to middle crustal, granulite facies rocks with evidence of anatexis and pervasive solid-state ductile deformation. Protoliths of clinopyroxene–garnet quartzofeldspathic gneiss, orthopyroxene quartzofeldspathic gneiss, two-pyroxene metabasite and biotite granite gneiss were emplaced between ca. 2.55–2.51 Ga, and a clastic sedimentary protolith for rutile–garnet metasedimentary rocks was deposited at ca. ≥2.47 Ga. Earlier, poorly constrained metamorphic events are recorded at ca. 2.54, 2.47 and 2.30 Ga, possibly associated with pulses of the Arrowsmith orogen (ca. 2.5–2.3 Ga). Most recently, this terrane was reworked by high temperature (HT) to ultrahigh temperature (UHT) metamorphism at ca. 1.91 Ga during with the Thelon–Inglefield orogen; obtaining peak P–T conditions of ca. 9 kbar and >850 °C. The discovery of a sapphirine–quartz metapelite assemblage is a first for the Canadian Arctic and is diagnostic evidence of UHT conditions within the Thelon-Inglefield orogenic zone.

Compositional and metamorphic controls on tectonic erosion along a continental subduction-collision zone: Implications from mafic granulites in the northern Sulu orogen

Abstract Subduction erosion has been reported recently in continental subduction-collision zones, and the response of the upper plate remains enigmatic. The Dabie-Sulu orogen is considered to have formed by deep northward subduction of the Yangtze block (lower plate) beneath the North China block (upper plate). However, within the northern Sulu ultrahigh-pressure (UHP) belt, the Haiyangsuo complex has intriguingly been accepted as Neoarchean–Paleoproterozoic metamorphic basement from the North China block, implying subduction-erosion could have occurred. Here, we examined new petrographic, mineral chemical, and published geochronological data from the Haiyangsuo mafic granulites to decipher their multiphase metamorphic evolution. Pressure-temperature (P-T) estimates from pseudosection modeling and geothermobarometry show two major metamorphic events: a medium-pressure granulite-facies event (7.3–8.3 kbar and 830–895 °C) and a later high-pressure granulite-facies event (12.2–16.6 kbar and 800–875 °C). Geochronology and mineral geochemistry link these events to Paleoproterozoic and Triassic metamorphism, respectively. Peak Triassic high-pressure granulite-facies metamorphism was followed by near-isothermal decompression and then near-isobaric cooling. These rocks derive from the upper plate and were metamorphosed at the same time as UHP eclogites, but maximum pressures were substantially lower, and P-T paths did not converge until late-stage exhumation. Evidently, metamorphic basement from the North China block was dragged to lowercrustal to upper-mantle depths (50–60 km) while that from the Yangtze block was subducted deeply, and then they were tectonically juxtaposed during exhumation. These data corroborate thermal-mechanical models that predict tectonic erosion as a major process during continental subduction and collision.

Basement domes in a greenschist facies context: Tectono-metamorphic evolution of the southern Quadrilátero Ferrífero, southeast Brazil

New petrostructural data are presented from the southeastern Quadrilátero Ferrífero, a distinct polyorogenic domain of the São Francisco Craton characterized by granite-gneiss domes and keel structures. The Minas Supergroup of Siderian age that hosts a huge volume of ferriferous sediments was deposited on the flat and eroded surface of the Archean basement. The domes of Archean gneisses and granites represent semi-rigid extrusions around which the Minas Supergroup accumulated in deep synclines with common triple junctions. This study focuses first on the petro-structural context of low-pressure thermal aureoles observed towards the dome margins. Pressure-temperature estimates on these mineral assemblages indicate nearly static burial to ≥ 10 km depths of the Minas Supergroup cover, followed by decompression and heating during the intrusion of pegmatites and granitoids of late Rhyacian age in basement and cover. The Archean basement and the thermal aureoles were severely overprinted by synkinematic greenschist facies metamorphism portrayed by chloritoid, chlorite, pyrophyllite, kyanite, phengitic mica and secondary biotite. This deep greenschist facies metamorphism (T ca. 420°C and P = 0.4 to 0.45 GPa) is regionally observed in all units from the domes and the keels ranging in age from Archean to Ediacaran. It is concluded that this major tectono-metamorphic event relates to tectonic burial of the southern Quadrilatero Ferrifero below the west-verging nappes of the Araçuaí belt during the Early Paleozoic, as documented by 40Ar/39Ar ages of 490-485 Ma obtained on syn-kinematic metamorphic micas [Chauvet et al., 2001]. It is proposed that building up of the dome and keel tectonic style is first a consequence of the high-density contrast estimated around 0.5 g/cm3 between the crystalline basement and the Minas Supergroup, the final architecture being achieved during the Cambro-Ordovician stage of the E-W Late Neoproterozoic collision.

Tectono‐Metamorphic Evolution of the Northern Dom Feliciano Belt Foreland, Santa Catarina, Brazil: Implications for Models of Subduction‐Driven Orogenesis

AbstractThe Dom Feliciano Belt in southern Brazil and Uruguay represents the western half of a Neoproterozoic orogenic belt located in the southern portion of the South Atlantic Neoproterozoic Orogenic System. Current interpretations are divided as to the nature of orogenesis in this belt, in part owing to lacking geochronological constraints. Metamorphosed and deformed supracrustal sequences of the Brusque Complex in the northern Dom Feliciano Belt, representing part of the orogenic foreland, record the onset and duration of crustal thickening. Structural analysis and pressure–temperature estimates indicate that the complex reached peak regional metamorphic conditions of 540–570°C and 5.5–6.7 kbar during thrusting and burial, consistent with orogenic metamorphism and early crustal thickening. Garnet–whole rock Lu–Hf and Sm–Nd isochron ages date this event to between circa 660–650 Ma. Ar–Ar dating of mica suggests thrust‐controlled exhumation and partial cooling by circa 635 Ma, and that localized deformation occurred into the late Ediacaran. Our results show that the orogenic foreland reached metamorphic conditions typical for crustal thickening 20–30 million years prior to the onset of massive magmatic activity in the hinterland. Such a delay is typical of hot, internal parts of orogens, which supports interpretations that hinterland magmatism in the northern Dom Feliciano Belt represents post‐collisional magmatism and not arc magmatism above a subduction zone. Instead, we suggest that orogenesis in the northern Dom Feliciano Belt was initiated by rift‐basin inversion driven by far‐field forces transmitted through the crust in an intracontinental rift or back‐arc rift setting.

Magmatic evolution and architecture of an arc-related, rhyolitic caldera complex: The late Pleistocene to Holocene Cerro Blanco volcanic complex, southern Puna, Argentina

Abstract Through the lens of bulk-rock and matrix glass geochemistry, we investigated the magmatic evolution and pre-eruptive architecture of the siliceous magma complex beneath the Cerro Blanco volcanic complex, a Crater Lake–type caldera complex in the southern Puna Plateau of the Central Andes of Argentina. The Cerro Blanco volcanic complex has been the site of two caldera-forming eruptions with volcanic explosivity index (VEI) 6+ that emplaced the ca. 54 ka Campo Piedra Pomez ignimbrite and the ca. 4.2 ka Cerro Blanco ignimbrite. As such, it is the most productive recent explosive volcano in the Central Andes. The most recent eruptions (younger than 4.2 ka) are dominantly postcaldera effusions of crystal-rich domes and associated small explosive pulses. Previous work has demonstrated that andesitic recharge of and mixing with rhyolitic magma occurred at the base of the magma complex, at ~10 km depth. New isotopic data (Sr, Nd, Pb, and O) confirm that the Cerro Blanco volcanic complex rhyolite suite is part of a regional southern Puna, arc-related ignimbrite group. The suite defines a tight group of consanguineous siliceous magmas that serves as a model for the evolution of arc-related, caldera-forming silicic magma systems in the region and elsewhere. These data indicate that the rhyolites originated through limited assimilation of and mixing with upper-crustal lithologies by regional basaltic andesite parent materials, followed by extensive fractional crystallization. Least squares models of major elements in tandem with Rayleigh fractionation models for trace elements reveal that the internal variations among the rhyolites through time can be derived by extensive fractionation of a quartz–two feldspar (granitic minimum) assemblage with limited assimilation. The rare earth element character of local volumes of melt in some samples of the Campo Piedra Pomez ignimbrite basal fallout requires significant fractionation of amphibole. The distinctive major- and trace-element characteristics of bulk rock and matrix of the Campo Piedra Pomez and Cerro Blanco tephras provide useful geochemical fingerprints to facilitate regional tephrochronology. Available data indicate that rhyolites from other neighborhood centers, such as Cueros de Purulla, share bulk chemical characteristics with the Campo Piedra Pomez ignimbrite rhyolites, but they appear to be isotopically distinct. Pre-eruptive storage and final equilibration of the rhyolitic melts were estimated from matrix glass compositions projected onto the haplogranitic system (quartz-albite-orthoclase-H2O) and using rhyolite-MELTS models. These revealed equilibration pressures between 360 and 60 MPa (~10–2 km depth) with lowest pressures in the Holocene eruptions. Model temperatures for the suite ranged from 695 to 790 °C. Integrated together, our results reveal that the Cerro Blanco volcanic complex is a steady-state (low-magmatic-flux), arc-related complex, standing in contrast to the flare-up (high-magmatic-flux) supervolcanoes that dominate the Neogene volcanic stratigraphy. The silicic magmas of the Cerro Blanco volcanic complex were derived more directly from mafic and intermediate precursors through extensive fractional crystallization, albeit with some mixing and assimilation of local basement. Geochemical models and pressure-temperature estimates indicate that significant volumes of remnant cumulates of felsic and intermediate composition should dominate the polybaric magma complex beneath the Cerro Blanco volcanic complex, which gradually shallowed through time. Evolution to the most silicic compositions and final equilibration of some of the postcaldera domes occurred during ascent and decompression at depths less than 2 km. Our work connotes an incrementally accumulated (over at least 54 k.y.), upper-crustal pluton beneath the Cerro Blanco volcanic complex between 2 and 10 km depth. The composition of this pluton is predicted to be dominantly granitic, with deeper parts being granodioritic to tonalitic. The progressive solidification and eventual contraction of the magma complex may account for the decades of deflation that has characterized Cerro Blanco. The presently active geothermal anomaly and hydrothermal springs indicate the Cerro Blanco volcanic complex remains potentially active.

Quantitative X-ray Maps Analaysis of Composition and Microstructure of Permian High-Temperature Relicts in Acidic Rocks from the Sesia-Lanzo Zone Eclogitic Continental Crust, Western Alps

Three samples of meta-acidic rocks with pre-Alpine metamorphic relicts from the Sesia-Lanzo Zone eclogitic continental crust were investigated using stepwise controlled elemental maps by means of the Quantitative X-ray Maps Analyzer (Q-XRMA). Samples were chosen with the aim of analysing the reacting zones along the boundaries between the pre-Alpine and Alpine mineral phases, which developed in low chemically reactive systems. The quantitative data treatment of the X-ray images was based on a former multivariate statistical analytical stage followed by a sequential phase and sub-phase classification and permitted to isolate and to quantitatively investigate the local paragenetic equilibria. The parageneses thus observed were interpreted as related to the pre-Alpine metamorphic or magmatic stages as well as to local Alpine re-equilibrations. On the basis of electron microprobe analysis, specific compositional ranges were defined in micro-domains of the relict and new paragenetic equilibria. In this way calibrated compositional maps were obtained and used to contour different types of reacting boundaries between adjacent solid solution phases. The pre-Alpine and Alpine mineral parageneses thus obtained allowed to perform geothermobarometry on a statistically meaningful and reliable dataset. In general, metamorphic temperatures cluster at 600–700 °C and 450–550 °C, with lower temperatures referred to a retrograde metamorphic re-equilibration. In all the cases described, pre-Alpine parageneses were overprinted by an Alpine metamorphic mineral assemblage. Pressure-temperature estimates of the Alpine stage averagely range between 420 to 550 °C and 12 to 16.5 kbar. The PT constraints permitted to better define the pre-Alpine metamorphic scenario of the western Austroalpine sectors, as well as to better understand the influence of the pre-Alpine metamorphic inheritance on the forthcoming Alpine tectonic evolution.

Origins of olivine in Earth’s youngest kimberlite: Igwisi Hills volcanoes, Tanzania craton

Monomineralic millimeter-sized olivine nodules are common in kimberlites worldwide. It is generally thought that such ‘dunitic nodules’ originate from the base of the cratonic lithosphere and that their formation marks the onset of deep-rooted kimberlite magmatic plumbing systems. However, thermobarometric constraints to support such a model have been lacking thus far. This study focuses on the petrography and textures, as well as on pressure–temperature estimations, of well-preserved dunitic nodules from the Quaternary Igwisi Hills kimberlite lavas on the Tanzania craton, with the ultimate goal to constrain their origins. We utilize EBSD-determined textural information in combination with olivine geochemistry data determined by EPMA and LA-ICP-MS methods. We find that host olivine grains in these nodules are compositionally similar to olivine in garnet-facies cratonic mantle peridotites, and such an association is supported by garnet inclusions within olivine. Projection of Al-in-olivine temperatures onto a regional geotherm suggests that the host olivine grains equilibrated at ~ 100–145 km depth, which points to origins from mid-lithospheric levels down to the lower cratonic mantle if a depth of 160–180 km is considered for the lithosphere–asthenosphere transition beneath the Tanzania craton. These first pressure–temperature estimates for dunitic nodules in kimberlites suggest that their formation also occurs at much shallower depths than previously assumed. Recrystallized olivine grains (i.e., neoblasts) show random crystallographic orientations and are enriched in minor and trace elements (e.g., Ca, Al, Zn, Sc, V) compared to the host olivine grains. These features link neoblast formation to melt-assisted recrystallization of cratonic mantle peridotite, a process that persisted during kimberlite magma ascent through the lower half of thick continental lithosphere. Partial recrystallization of olivine-rich mantle xenoliths makes these materials texturally weaker and subsequent liberation of mineral grains promotes the assimilation of compositionally ‘unstable’ orthopyroxene in rising carbonate-rich melts, which is considered to be an important process in the evolution of kimberlite magmas. Dunitic nodules in kimberlites and related rocks may form as melt–rock equilibration zones along magmatic conduits within the lower half of the cratonic mantle column all the way up to mid-lithospheric depth. Such an origin potentially links dunitic nodules to olivine megacrysts, which are equally considered as melt/fluid-assisted recrystallization products of peridotitic mantle lithosphere along the ascent pathways of deep-sourced CO2–H2O-rich ultramafic melts.

Evidence of two metamorphic cycles preserved in garnet from felsic granulite in the southern Variscan belt of Corsica, France

The Solenzara-Fautea unit is composed of Variscan migmatites and garnet-kyanite granulitic gneisses with pyroxenite boudins outcropping between the villages of Fautea and Solenzara in southeast Corsica. We investigated felsic granulite samples exposed at the seashore south of the village of Tarcu to improve existing pressure-temperature (P-T) estimates of the metamorphic evolution. Relictic garnet (Grt1) is overgrown by a second generation of garnet (Grt2) that also appears as small, euhedral crystals in the matrix. The P-T history of the gneiss was reconstructed on the basis of garnet composition and isochemical phase diagrams. Grt1 formed at 1.3–1.75 GPa, 650–700 °C, whereas Grt2 reflects higher temperature conditions between 750 and 800 °C at 0.9 GPa. The P-T conditions obtained for Grt2 formation are supported by the application of Zr-in-rutile thermometry yielding average temperatures of 708–719 °C at 0.9 GPa. Temperatures calculated with ternary feldspar thermometry on reintegrated feldspar compositions are in the range 745–812 °C. Although a precise P-T path could not be obtained, the microstructural evidences and new P-T estimates support two cycles on which each garnet type was formed by prograde metamorphism. We hypothesize that the felsic granulites were part of a series of metamorphic slices of the Variscan Corsica-Sardinia block which were involved into a sequence of deep crustal movements. According to existing geochronological data, the two metamorphic cycles are Variscan and occurred within the time frame 365–335 Ma.

Epidote – lawsonite coexistence in blueschist-facies block from the Tavşanlı Zone – Turkey: petrological implications

Metamorphic evolution of an epidote–lawsonite blueschist sample characterized by the coexistence of lawsonite and epidote from Sivrihisar area (Tavşanlı Zone) was studied herein in terms of petrology and mineral equilibria. Based on the textural evidence and phase composition, 2 prograde stages, defined by assemblage-I and -II, and 1 retrograde stage were recognized. Assemblage-I indicates epidote-blueschist facies conditions (12 ± 1 kbar / 485 ± 10 °C). Assemblage-II is characterized by the coexistence of epidote and lawsonite (17 ± 1 kbar / 515 ± 10 °C) corresponding to the interface of lawsonite blueschist and epidote blueschist facies. Phase diagram calculations and mineral compositions revealed that along this interface, an equilibrium field with lawsonite and epidote is stable. This closed-equilibrium field is controlled by high aH2O and an elevated Fe3+/Al ratio of minerals. Pressure-temperature (P–T) estimates and textural observations indicated a counter-clockwise path during the subduction and exhumation history. The preservation of lawsonite and epidote during the retrograde stage pointed to the fact that the path followed the stability field of lawsonite and epidote during exhumation.

Petrogenesis of the Higashi-Akaishi Ultramafic Body: Implications for Lower Crustal Foundering and Mantle Wedge Processes

AbstractRecycling of ultramafic lower crustal cumulates via delamination or foundering is often invoked as a mechanism to return mafic material to the mantle during continental crust formation. These recycled pieces of the lower crust are rarely sampled but are preserved in several locations including the Kohistan and Talkeetna arc sections, Sierra Nevada and Colorado Plateau pyroxenite xenoliths and, as discussed here for the first time, the exhumed Higashi-Akaishi (HA) ultramafic body in Japan. The HA is located in the Besshi region of the Sanbagawa metamorphic belt in southwestern Japan and is dominantly composed of dunite with lesser garnet pyroxenite and harzburgite lenses. Although the petrogenetic history of the HA body is still debated, our new bulk major and trace element compositions, radiogenic isotope data, as well as petrologic and field observations, are consistent with a lower crustal cumulate origin for the HA dunite and pyroxenite, with a later slab-derived fluid overprint. Clinopyroxene and olivine in the foliated HA dunite have compositions consistent with ultramafic cumulates with high Mg#s (Mg# clinopyroxene = 0·94, Mg# olivine = 0·88), high NiO in olivine (∼0·26 wt %) and low-Al clinopyroxene. In addition, the bulk major element chemistry of the HA dunite and garnet pyroxenite follow systematic behavior in Mg# vs SiO2 wt %, similar to those observed in other lower crustal cumulate lithologies and corresponding intrusive lithologies, pointing to different liquid lines of descent for the corresponding melts. Our new thermobarometric estimates (peak pressure–temperature at 2·6 GPa, 713ºC) are consistent with a hot slab surface subduction path, rather than the lower crustal temperatures recorded in arc sections (Kohistan &amp; Talkeetna: 1 GPa, 800ºC). A pervasive slab-fluid influence is also indicated in the HA lithologies by LREE and Ce enrichments and strong Nb and Zr depletions. The trace elements and the pressure–temperature estimates, as well as the thermodynamic modeling results necessitate removal of the HA body from the lower crust and incorporation into cooler portions of a mantle wedge. At lower crustal conditions, the bulk density of the HA lithologies is greater than the background mantle, indicating the feasibility of lower crustal foundering into a mantle wedge where the HA was incorporated in the subduction channel to reach its peak conditions. Hydration of the HA body while in the subduction channel likely provided the change in density necessary to facilitate its rapid exhumation to the surface. Thus, the HA cumulate likely represents a piece of the subduction system that is rarely preserved, as well as a key component in the compositional evolution of the continental crust.